专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

21. 发明授权

US4515923A Polyamines and a process for their production 失效
标题翻译：多胺及其生产工艺
公开(公告)号：US4515923A
公开(公告)日：1985-05-07
申请号：US506471
申请日：1983-06-21
申请人： Rudolf Fauss , Hans J. Meiners , Werner Rasshofer , Holger Meyborg
发明人： Rudolf Fauss , Hans J. Meiners , Werner Rasshofer , Holger Meyborg
IPC分类号： C08G18/00 , B01J31/02 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/48 , C07C211/51 , C07C211/53 , C08G18/10 , C08G18/30 , C08G18/50 , C08G18/83 , C08G73/00 , C08G73/02 , C08G18/18 , C09K3/00
CPC分类号： C08G18/5048 , C08G18/10
摘要： Polyamines containing aromatically bound primary amino groups having an NH.sub.2 -content of from 0.19 to 20.3 wt % are produced by a single stage process. A compound containing aromatically bound NCO-groups and having an isocyanate content of from 0.5 to 40 wt % is hydrolyzed with an excess of water in the presence of a water-miscible polar solvent and optionally a catalyst. The hydrolysis is carried out at a temperature of from -10.degree. to 150.degree. C. in a manner such that the reaction mixture is substantially homogeneous. The water-miscible polar solvent generally has a boiling point of from 56.degree. to 250.degree. C. and a dielectric constant of at least 10. This polar solvent is used in a quantity of at least 5 parts solvent for every 100 parts of isocyanate. Tertiary amines are the preferred catalysts. These polyamines are particularly useful in the production of polyurethanes.
摘要翻译：含有0.19〜20.3重量％NH 2含量的芳香结合的伯氨基的多胺通过单阶段方法制备。含有芳香结合的NCO-基团并且异氰酸酯含量为0.5〜40重量％的化合物在水混溶性极性溶剂和任选的催化剂的存在下，用过量的水分水解。水解是在-10至150℃的温度下进行的，使得反应混合物基本上是均匀的。水混溶性极性溶剂的沸点通常为56-250℃，介电常数至少为10.该极性溶剂的用量为每100份异氰酸酯至少为5份溶剂。叔胺是优选的催化剂。这些多胺在聚氨酯的生产中特别有用。

22. 发明授权

US4501873A Preparation of polyamines by hydrolyzing a polyisocyanate in the presence of an isocyanate-reactive compound with water 失效
标题翻译：在异氰酸酯反应性化合物与水的存在下水解多异氰酸酯制备多胺
公开(公告)号：US4501873A
公开(公告)日：1985-02-26
申请号：US555241
申请日：1983-11-25
申请人： Werner Rasshofer
发明人： Werner Rasshofer
IPC分类号： C08G18/00 , C08G18/30 , C08G18/40 , C08G18/50 , C08G18/82 , C08G18/83 , C08J9/02
CPC分类号： C08G18/302 , C08G18/5048
摘要： High molecular weight aromatic polyamines are produced by hydrolyzing a polyisocyanate having an isocyanate content of from 21 to 52.5% and an isocyanate-reactive group-containing compound having a molecular weight of from 400 to 10,000 in the presence of an excess of water. The reactants are used in quantities such that the equivalent ratio of isocyanate to isocyanate-reactive groups is from 0.1 to 5. Further, water is used in an amount such that the equivalent ratio of water to isocyanate groups is greater than 1. Low molecular weight compounds containing isocyanate-reactive groups, solvents, basic catalysts and urethanization catalysts may also be included in the mixture to be hydrolyzed. The hydrolysis is carried out at a temperature of from -20.degree. to 175.degree. C. The product amine is isolated from the reaction mixture by procedures such as phase separation, extraction and distillation. The polyamines thus-produced are particularly useful in the production of polyurethanes.
摘要翻译：通过在过量的水的存在下水解异氰酸酯含量为21至52.5％的多异氰酸酯和分子量为400至10,000的含异氰酸酯反应性基团的化合物来制备高分子量芳族多胺。反应物的用量使得异氰酸酯与异氰酸酯反应性基团的当量比为0.1至5.此外，水的用量使得水与异氰酸酯基的当量比大于1.低分子量含有异氰酸酯反应性基团的化合物，溶剂，碱性催化剂和氨基甲酸酯化催化剂也可以包括在待水解的混合物中。水解在-20℃至175℃的温度下进行。通过相分离，萃取和蒸馏等方法从反应混合物中分离产物胺。如此生产的聚胺在聚氨酯的生产中特别有用。

23. 发明授权

US4469856A Non-crystalline polyamine/carbonic acid salt compositions, a process for their preparation and their use for the production of polyurethane ureas, especially foamed coatings 失效
标题翻译：非结晶多胺/碳酸盐组合物，其制备方法及其用于生产聚氨酯脲，特别是泡沫涂料的用途
公开(公告)号：US4469856A
公开(公告)日：1984-09-04
申请号：US434788
申请日：1982-10-18
申请人： Werner Rasshofer , Wilhelm Thoma , Anton Schmitz
发明人： Werner Rasshofer , Wilhelm Thoma , Anton Schmitz
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C211/09 , C07C211/36 , C07C213/00 , C07C215/12 , C08G18/10 , C08G18/32 , C08G18/65 , C08J9/02 , C09D175/04 , C08G18/81
CPC分类号： C08G18/10
摘要： This invention relates to new liquid or fluid polyamine/carbonic acid salt compositions free from crystalline content and their preparation from mixtures containing at least one aliphatic or cycloaliphatic polyamine, an aliphatic or cycloaliphatic hydroxyamine having at least one hydroxyl group and at least one amino group, and water and optionally diluents and/or conventional auxiliary agents and additives, by the addition of carbon dioxide. The proportion of polyamine to hydroxyamine is in the range of from about 95:5 to 10:90 % by weight, the quantity of water added is from about 0.01 to 5 mol of H.sub.2 O per amine equivalent (but at least 1 mol of water per mol of CO.sub.2) and the quantity of CO.sub.2 added is from about 0.01 to 0.99 mol of CO.sub.2 per amine equivalent. The invention further relates to the use of these liquid polyamine/carbonic acid salt compositions for the production of foamed polyurethane ureas, especially for coating substrates or for the production of sheet products, using prepolymers preferably containing blocked isocyanate groups and the liquid polyamine/carbonic acid salt compositions as chain lengthening agents and/or crosslinking agents and at the same time as physiologically harmless blowing agents.
摘要翻译：本发明涉及不含结晶含量的新的液体或流体多胺/碳酸盐组合物，它们由含有至少一种脂族或脂环族多胺，至少具有一个羟基和至少一个氨基的脂族或脂环族羟胺的混合物制备，和水以及任选的稀释剂和/或常规助剂和添加剂，通过加入二氧化碳。多胺与羟基胺的比例在约95:5至10:90重量％的范围内，加入的水的量为约0.01至5摩尔每胺相当的H 2 O（但每个至少1摩尔水二氧化碳的摩尔数），加入的二氧化碳的量为每个胺当量约0.01至0.99mol的CO 2。本发明还涉及这些液态多胺/碳酸盐组合物用于生产泡沫聚氨酯脲，特别是用于涂覆基材或用于生产片状产品的优选使用含有封端异氰酸酯基团的预聚物和液态多胺/碳酸盐组合物作为增链剂和/或交联剂，并且同时具有生理上无害的发泡剂。

24. 发明授权

US4368278A Process for the production of polyurethanes using cyclic N-hydroxyalkyl-substituted compounds containing amidine groups as catalysts 失效
标题翻译：使用含有脒基作为催化剂的环状N-羟基烷基取代的化合物生产聚氨酯的方法
公开(公告)号：US4368278A
公开(公告)日：1983-01-11
申请号：US251011
申请日：1981-04-03
申请人： Werner Rasshofer , Gerhard Grogler , Kurt Findeisen
发明人： Werner Rasshofer , Gerhard Grogler , Kurt Findeisen
IPC分类号： C08G18/00 , C08G18/18 , C08G18/20 , C08G18/14
CPC分类号： C08G18/2009
摘要： A polyurethane is made by reacting a polyisocyanate with a compound having at least two isocyanate-reactive hydrogen atoms and having a molecular weight of from 400 to 10,000 in the presence of a catalyst. The catalyst employed is a cyclic N-hydroxyalkyl-substituted compound containing an amidine group. Polyurethanes made in accordance with this process are useful as shoe soles, upholstery material, sound insulating materials, coating compositions, packaging materials and mattresses.
摘要翻译：通过使多异氰酸酯与具有至少两个异氰酸酯反应性氢原子且在催化剂存在下的分子量为400至10,000的化合物反应制备聚氨酯。所使用的催化剂是含有脒基的环状N-羟烷基取代的化合物。根据该方法制备的聚氨酯可用作鞋底，装饰材料，隔音材料，涂料组合物，包装材料和床垫。

25. 发明授权

US06296908B1 Stable adhesive composite material made of polyurethane and of another thermoplastic material, a process for its production and a method for its use in motor vehicles 失效
标题翻译：由聚氨酯和另一种热塑性材料制成的稳定的粘合剂复合材料，其生产方法及其用于机动车辆的方法
公开(公告)号：US06296908B1
公开(公告)日：2001-10-02
申请号：US09571226
申请日：2000-05-16
申请人： Karsten Reihs , Werner Rasshofer , Holger Warth , Dirk Wegener , Manfred Schmidt , Peter Heitkämper
发明人： Karsten Reihs , Werner Rasshofer , Holger Warth , Dirk Wegener , Manfred Schmidt , Peter Heitkämper
IPC分类号： B05D702
CPC分类号： B32B27/40 , B32B5/18 , B32B27/32 , B32B27/34 , B32B27/365 , B32B2266/0278 , B32B2323/04 , B32B2323/10 , B32B2367/00 , B32B2369/00 , B32B2375/00 , C08J5/12 , C08J2375/04 , C09J175/08 , Y10T428/31507 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31587 , Y10T428/31598 , Y10T428/31739
摘要： The present invention relates to composite materials made of at least one composite layer of a polyurethane and of a second composite layer which is directly bonded to the first layer and which consists of a thermoplastic material that is different from the polyurethane of layer A). The polyurethane material of layer A) is characterized by a residual content of free reaction components containing ether groups of no more than 400 ppm, and preferably of no more than 100 ppm. The invention also relates to a process for the production of these composite materials and to a method of their use as materials in motor vehicles.
摘要翻译：本发明涉及由聚氨酯和第二复合层的至少一个复合层制成的复合材料，所述复合层直接结合到第一层，并且由不同于层A）的聚氨酯的热塑性材料组成。层A）的聚氨酯材料的特征在于含有不超过400ppm，优选不超过100ppm的醚基的游离反应组分的残留含量。本发明还涉及一种生产这些复合材料的方法及其作为机动车辆材料的方法。

26. 发明授权

US5538679A Process of making molded products 失效
标题翻译：制造成型产品的工艺
公开(公告)号：US5538679A
公开(公告)日：1996-07-23
申请号：US381604
申请日：1995-01-27
申请人： Joachim Wagner , Werner Rasshofer , Eberhard Jurgens , Ulrich Eisele
发明人： Joachim Wagner , Werner Rasshofer , Eberhard Jurgens , Ulrich Eisele
IPC分类号： C08G18/08 , C08G18/50 , C08G18/65 , C08L75/04 , C08J5/00
CPC分类号： C08G18/6505 , C08G18/08 , C08G18/5048 , C08L75/04
摘要： The invention relates to a process for the preparation of single-layered or multilayered molded articles from particles of polyisocyanate-polyaddition products by shaping a specified mixtures under heat and pressure. The mixture contains quasi-thermoplastic particles of polyisocyanate-polyaddition products and one or more processing aids.
摘要翻译：本发明涉及通过在加热和压力下成型特定混合物从多异氰酸酯加聚产物的颗粒制备单层或多层模塑制品的方法。该混合物含有多异氰酸酯加成产物的准热塑性颗粒和一种或多种加工助剂。

27. 发明授权

US5283364A Hydrolysis process for polyamines 失效
标题翻译：多胺的水解过程
公开(公告)号：US5283364A
公开(公告)日：1994-02-01
申请号：US4808
申请日：1993-01-15
申请人： Werner Rasshofer , Klaus Konig , Hans-Joachim Meiners , Gerhard Grogler
发明人： Werner Rasshofer , Klaus Konig , Hans-Joachim Meiners , Gerhard Grogler
IPC分类号： C08G18/10 , C08G18/46 , C08G18/50 , C07C85/00
CPC分类号： C08G18/5048 , C08G18/10 , C08G18/4623
摘要： Polyamines containing primary amino groups are made by hydrolyzing an isocyanate with water in the presence of a solvent which is a carboxylic acid amide. The solvent must be used in a quantity of at least 10% by weight solvent based on 100% by weight of isocyanate. The weight ratio of solvent to water must be from 3 to 200. A homogeneous phase is maintained during the hydrolysis which is carried out at temperatures of from 20.degree. to 210.degree. C. A not incorporable basic and/or metal catalyst particularly alkali metal hydroxides may be employed. The polyamines produced by this process are particularly useful for the production of polyurethanes.
摘要翻译：含羧基酰胺的溶剂存在下，通过用水水解异氰酸酯制备含有伯氨基的多胺。溶剂必须使用至少10重量％的溶剂，基于100重量％的异氰酸酯。溶剂与水的重量比必须为3至200.在水解期间保持均相，其在20至210℃的温度下进行。不合并的碱性和/或金属催化剂，特别是碱金属氢氧化物可以被雇用。通过该方法生产的多胺特别可用于生产聚氨酯。

28. 发明授权

US4732960A Process for the production of new polyisocyanate compositions and their use for the production of plastics by the isocyanate polyaddition process 失效
标题翻译：用于生产新型多异氰酸酯组合物的方法及其通过异氰酸酯加聚方法生产塑料的用途
公开(公告)号：US4732960A
公开(公告)日：1988-03-22
申请号：US818926
申请日：1986-01-15
申请人： Werner Rasshofer , Reiner Paul , Joachim Probst
发明人： Werner Rasshofer , Reiner Paul , Joachim Probst
IPC分类号： C08G18/00 , C08G18/10 , C08G18/12 , C08G18/62 , C08G18/67
CPC分类号： C08G18/6254 , C08G18/10 , C08G18/12 , C08G18/6229 , C08G2101/0008 , C08G2101/0016 , C08G2101/0025 , C08G2101/0033 , C08G2101/0066 , C08G2120/00
摘要： The present invention relates to a process for the production of polyisocyanate compositions containing urethane groups and having an isocyanate content of about 0.5 to 45% by weight by the reaction of(a) an organic polyisocyanate or mixtures thereof having an isocyanate content of about 30 to 50% by weight with(b) organic polyhydroxyl compounds using an equivalent ratio of isocyanate groups to hydroxyl groups of at least 1.8:1, characterized in that the polyhydroxyl compounds (b) are based on(b1) polyhydroxypolyacrylates having an average molecular weight, determined by vapor pressure osmometry, of 232 to about 100,000 which optionally contain urethane or ester groups in side chains, and a statistical average of at least one alcoholic hydroxyl group per molecule(b2) optionally in admixture with up to about 250% by weight, based on (b1), of other polyhydroxyl compounds in the molecular weight range of 62 to about 12,000.The invention also relates to the polyisocyanate compositions obtainable by this process and their use as components for the production of polyurethanes or polyurethane ureas.
摘要翻译：本发明涉及通过（a）有机多异氰酸酯或其混合物与异氰酸酯含量为约30的反应制备含有氨基甲酸酯基团并具有约0.5至45重量％的异氰酸酯含量的多异氰酸酯组合物的方法， 50重量％与（b）异氰酸酯基与羟基的当量比至少为1.8:1的有机多羟基化合物，其特征在于多羟基化合物（b）基于（b1）具有平均分子量的聚羟基聚丙烯酸酯，通过蒸汽压力渗透压测定，为232至约100,000，其任选地在侧链中含有氨基甲酸酯或酯基，以及每分子至少一个醇羟基（b2）的统计平均值，任选地与至多约250重量％基于（b1）的分子量范围为62至约12,000的其它多羟基化合物。本发明还涉及通过该方法获得的多异氰酸酯组合物及其作为生产聚氨酯或聚氨酯脲的组分的用途。

29. 发明授权

US4644016A Process for the production of polyurethanes 失效
标题翻译：聚氨酯生产工艺
公开(公告)号：US4644016A
公开(公告)日：1987-02-17
申请号：US761278
申请日：1985-08-01
申请人： Werner Rasshofer , Hans-Albrecht Freitag
发明人： Werner Rasshofer , Hans-Albrecht Freitag
IPC分类号： C08G18/18 , C08G18/14 , C08G18/20
CPC分类号： C08G18/1866
摘要： Polyurethanes are made by reacting a polyisocyanate with a compound containing at least two isocyanate-reactive hydrogen atoms having a molecular weight of from 400 to 10,000 in the presence of a catalyst containing tertiary amino groups. The required catalyst corresponds to the formula ##STR1## in which R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 represent a specified group or radical. A blowing agent and/or stabilizer and/or chain extending agent and/or other additives commonly used in the production of polyurethanes may optionally be included in the reaction mixture. The catalyst employed in the process is particularly advantageous in that it does not have a noticeable amine odor.
摘要翻译：聚氨酯通过使多异氰酸酯与含有至少两个分子量为400至10,000的异氰酸酯反应性氢原子的化合物在含有叔氨基的催化剂存在下反应而制备。所需的催化剂对应于其中R，R 1，R 2，R 3，R 4，R 5，R 6和R 7表示指定基团或基团的式“IMAGE”。在制备聚氨酯中通常使用的发泡剂和/或稳定剂和/或增链剂和/或其它添加剂可任选地包括在反应混合物中。在该方法中使用的催化剂特别有利的是它不具有明显的胺气味。

30. 发明授权

US4575518A Homogeneous storage stable salt-containing mixture 失效
标题翻译：均相储存稳定含盐混合物
公开(公告)号：US4575518A
公开(公告)日：1986-03-11
申请号：US682221
申请日：1984-12-17
申请人： Werner Rasshofer , Reiner Paul
发明人： Werner Rasshofer , Reiner Paul
IPC分类号： C08G18/00 , C08G18/08 , C08G18/66 , C08L71/02 , C08G18/14
CPC分类号： C08L71/02 , C08G18/6666 , C08G2120/00 , C08G2130/00 , Y10S521/914
摘要： Homogeneous storable mixtures containing small quantities of salts and having a high mixed hydroxyl number of mixed hydroxyl/amine number are made by mixing (a) a polyoxyalkylene polyol and/or polyolamine and/or polyamine based on an alkyloxirane having a molecular weight of from 400 to 12,000, (b) a low molecular weight polyol which is not completely miscible with (a) and a solution-promoting additive in quantities such that for every 100 parts of (a), from 1 to 200 parts of (b) and from 0.01 to 10 parts of (c) are present. The solution-promoting additives are salts of cations of Groups IA, IIA and IIIA of the Periodic System of Elements or ammonium or mono- to tetra-alkylammonium ions and anions formed by removing at least one proton from an acid having a K.sub.s -value of at least 10.sup.-7. These mixtures are particularly useful in the production of polyurethanes.
摘要翻译：通过混合（a）基于分子量为400的烷基环氧乙烷和/或多胺胺和/或多胺的聚氧化烯多元醇和/或多胺来制备含有少量盐并具有高混合羟基/羟基数的混合羟值的均匀的可储存混合物至（12），（b）与（a）不完全混溶的低分子量多元醇和一种溶液促进添加剂，其数量使得每100份（a），1至200份（b）和存在0.01〜10份（c）。溶液促进添加剂是元素周期体系的IA，IIA和IIIA族的阳离子盐，或铵或单烷基铵盐和一至四烷基铵离子，以及通过从具有Ks值的Ks值的酸除去至少一个质子形成的阴离子至少10-7。这些混合物在聚氨酯的生产中特别有用。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式