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    • 13. 发明授权
    • Negative-working diazotype photoreproduction
    • 负面工作的重氮型光复制
    • US4252884A
    • 1981-02-24
    • US66401
    • 1979-08-14
    • Everett W. Bennett
    • Everett W. Bennett
    • G03C1/58G03C1/727G03C5/18
    • G03C1/58
    • Negative-working diazography material is comprised of (i) at least one diazonium compound, (ii) at least one acid labile enolic, preferably phenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, and (iii) at least one light-sensitive acid progenitor. The diazonium compound can itself concurrently function as the acid progenitor, e.g., when complexed with a Lewis acid. Upon imagewise exposure to light, acid catalyst is photochemically liberated, thus unblocking coupler molecules such that dye image forms under alkaline developing conditions only where the material has been irradiated.
    • 负极重氮复合材料由(i)至少一种重氮化合物,(ii)适于在酸存在下转化为活性偶氮偶合组分的至少一种酸不稳定烯醇,优选酚封闭偶联剂,以及 (iii)至少一种光敏酸性祖细胞。 重氮化合物本身可以同时用作酸性祖细胞,例如当与路易斯酸络合时。 在成像曝光后,光催化剂释放出酸催化剂,从而阻断成色剂分子,使染料图像在碱性显影条件下仅在材料被照射下形成。
    • 16. 发明授权
    • Thermal recording method and material
    • 热敏记录方法和材料
    • US4788124A
    • 1988-11-29
    • US86853
    • 1987-08-19
    • Richard F. Wright
    • Richard F. Wright
    • B41M5/382B41M5/40B41M5/41G03F7/00G03F7/004G03C1/00G03C1/40G03C1/727G03C5/00
    • G03F7/002Y10S430/115Y10T428/24934Y10T428/2984
    • An imaging process which comprises image-wise simultaneously exposing to heat and light or ultraviolet radiation an imaging material comprising a support having a layer of photosensitive microcapsules on the surface thereof, said microcapsules containing an internal phase including an image-forming agent and a photosensitve composition which undergoes a change in viscosity, melting point, softening point to heat and light or ultraviolet radiation but which remains essentially unchanged in the presence of either heat or light or ultraviolet radiation alone; assembling said imaging material with an image-receiving sheet and subjecting the assembly to a uniform transfer force such that said image-forming agent is image-wise transferred to said imaging material; wherein said photohardenable composition includes a free radical addition polymerizable or crosslinkable compound and an ionic dye-reactive counter ion compound, said ionic dye-reactive counter ion compound, said ionic dye-reactive counter ion compound being capable of absorbing light and producing free radicals which initiate free radical polymerization or crosslinking of said polymerizable or crosslinkable material in the presence of heat.
    • 一种成像方法,其包括成像同时暴露于热和光或紫外线辐射下的成像材料,所述成像材料包括其表面上具有感光性微胶囊层的支持体,所述微胶囊含有包含成像剂和光敏组合物的内相 其经历粘度,熔点,软化点对热和光或紫外线辐射的变化,但在单独存在热或光或紫外线辐射的情况下基本上保持不变; 用图像接收片组装所述成像材料并对所述组件进行均匀的转印力,使得所述图像形成剂被成像地转印到所述成像材料; 其中所述可光硬化组合物包括自由基加成聚合或可交联的化合物和离子染料反应性反离子化合物,所述离子染料反应性反离子化合物,所述离子染料反应性反离子化合物能够吸收光并产生自由基, 在存在热的情况下引发所述可聚合或可交联材料的自由基聚合或交联。
    • 18. 发明授权
    • Processless color imaging and film therefor
    • 无色彩色成像及其影像
    • US4705741A
    • 1987-11-10
    • US839391
    • 1986-03-14
    • David F. LewisJames R. Kuszewski
    • David F. LewisJames R. Kuszewski
    • G03C1/73G03C5/56G03C7/46G03C1/727
    • G03C7/46G03C1/732G03C1/733G03C5/56
    • The invention relates to a multilayered image receptive film developed in distinguishable colors by kinetic energy imparted by radiant beam exposure which comprises (a) a first imaging layer composed of an aliphatic, polymeric binder containing from about 40 wt. % to about 70 wt. % of labile halogen, said binder capable of dehydrohalogenation at address points of radiant energy exposure and having dispersed therein a first polyphenylmethane compound capable of forming a first halide salt dye upon generation of hydrogen halide from said binder; (b) a second imaging layer similar to said first imaging layer and contiguously disposed below said first imaging layer, containing a second and distinct polyphenylmethane compound capable of forming a halide salt dye of a color distinguishable from that of said first halide salt dye and (c) a conductive support for layers (a) and (b).The invention also relates to a process of multi-color imaging by subjecting said film to a plurality of radiant energy exposures at critically distinct beam energies individually modulated in accordance with the thickness of each imaging layer to effect penetration and exposure of the first and second imaging layers separately and to form halide salt dyes of distinguishable colors in said first and second imaging layers at the respective points of beam address.
    • 本发明涉及一种通过由辐射束曝光赋予的动能以可分辨颜色显影的多层图像接受膜,其包括(a)由脂肪族聚合物粘合剂组成的第一成像层,所述第一成像层含有约40wt。 %至约70wt。 %的不稳定卤素,所述粘合剂能够在辐射能量暴露的地址处脱卤化氢,并且在其中分散有能够从所述粘合剂产生卤化氢时能够形成第一卤化物盐染料的第一聚苯基甲烷化合物; (b)类似于所述第一成像层并连续地设置在所述第一成像层下方的第二成像层,其包含能够形成与所述第一卤化物盐染料区别的颜色的卤化物盐染料的第二和不同的聚苯基甲烷化合物,和 c)层(a)和(b)的导电支撑。 本发明还涉及一种多色成像的方法,该方法通过使所述薄膜经受根据每个成像层的厚度单独调制的关键不同光束能量的多个辐射能量照射,以实现第一和第二成像的穿透和曝光 并且在波束地址的各个点处在所述第一和第二成像层中形成可区分颜色的卤化物染料。