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1. 发明授权

US07300738B2 Azolinyl acetic acid derivative and azolinyl acetic acid derivative containing recording material 失效
标题翻译：含有苯乙烯基乙酸衍生物和含有记录材料的吡咯烷基乙酸衍生物
公开(公告)号：US07300738B2
公开(公告)日：2007-11-27
申请号：US10773366
申请日：2004-02-09
申请人： Naoki Saito , Tetsunori Matsushita , Akinori Fujita , Yohsuke Takeuchi , Satoshi Higuchi , Kimi Ikeda
发明人： Naoki Saito , Tetsunori Matsushita , Akinori Fujita , Yohsuke Takeuchi , Satoshi Higuchi , Kimi Ikeda
IPC分类号： G03F7/021
CPC分类号： G03C1/54 , G03C1/58
摘要： A recording material having, on a support, a recording layer containing an azolinyl acetic acid derivative and a diazo compound. The azolinyl acetic acid derivative is preferably is a compound represented by the following general formula (1): wherein X represents an oxygen atom or a sulfur atom; R11 represents an alkyl group, an aryl group, a heterocyclic group, —OR13 or —NR14R15; R12 represents a substituent; R13 represents an alkyl group, an aryl group or a heterocyclic group; R14 and R15 each independently represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; n represents an integer from 0 to 4; and, when n is an integer of 2 or greater, two or more R12s may be linked with each other to form a ring.
摘要翻译：一种记录材料，在载体上具有包含偶氮二乙酸乙酯衍生物和重氮化合物的记录层。噻唑啉基乙酸衍生物优选为由以下通式（1）表示的化合物：其中X表示氧原子或硫原子; R 11表示烷基，芳基，杂环基，-OR 13或-NR 14 R 15， SUP>; R 12表示取代基; R 13表示烷基，芳基或杂环基; R 14和R 15各自独立地表示氢原子，烷基，芳基或杂环基; n表示0〜4的整数，并且当n为2以上的整数时，可以将两个以上的R 12彼此连接形成环。

2. 发明申请

US20040048185A1 Heat-sensitive recording material 审中-公开
标题翻译：热敏记录材料
公开(公告)号：US20040048185A1
公开(公告)日：2004-03-11
申请号：US10650771
申请日：2003-08-29
申请人： FUJI PHOTO FILM CO., LTD
发明人： Hisao Yamada , Hiroshi Sato , Yoshimitsu Arai , Kimi Ikeda
IPC分类号： G03C001/52 , G03C001/72
CPC分类号： G03C1/54 , G03C1/002 , G03C1/58
摘要： A heat-sensitive recording material containing a support and a heat-sensitive recording layer formed on the support, the heat-sensitive recording layer including a diazonium salt and a coupler that thermally reacts with the diazonium salt to develop color. The coupler contains a compound represented by the following general formula (1): 1 wherein R1 and R2 each independently represent one selected from the group consisting of a hydrogen atom, a halogen atom, an aryl group, an alkyl group, a cyano group, an acyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an acyloxy group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a sulfamoyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylphosphoryl group, an arylphosphoryl group, and an amino group; and R3 represents one selected from the group consisting of an alkoxy group, an aryloxy group, and an alkylamino group.
摘要翻译：一种热敏记录材料，其包含形成在载体上的载体和热敏记录层，所述热敏记录层包括重氮盐和与所述重氮盐热反应以显色的成色剂。成色剂含有下列通式（1）表示的化合物：其中R 1和R 2各自独立地表示选自氢原子，卤素原子，芳基，烷基，氰基，酰基，氨基甲酰基，烷氧基羰基，芳氧基羰基，酰氧基，烷氧基，芳氧基，烷硫基，芳硫基，氨磺酰基，烷基磺酰基，芳基磺酰基，烷基磷酰基，芳基磷酰基和氨基; R 3表示选自烷氧基，芳氧基和烷基氨基的一个。

3. 发明授权

US06190823B1 Diazo-containing photosensitive material 失效
标题翻译：含重氮的感光材料
公开(公告)号：US06190823B1
公开(公告)日：2001-02-20
申请号：US09509501
申请日：2000-06-09
申请人： Yoko Suzukawa , Nobue Abiko , Hiroshi Maruyama
发明人： Yoko Suzukawa , Nobue Abiko , Hiroshi Maruyama
IPC分类号： G03F7021
CPC分类号： G03C1/58 , G03C1/52 , G03C1/54
摘要： A diazo-containing photosensitive material comprising a transparent support, and a diazo-containing photosensitive layer provided over a surface of the support and containing a binder, a diazo compound and a coupler, wherein the diazo compound is represented by the following formula: (wherein R1 and R2 stand, independently from each other, for a lower alkyl group and X stands for an anionic group), wherein the coupler comprises phenylphenol and 3,5-dihydroxy-4-bromobenzoic acid, and wherein the binder comprises a cellulose ester cross-linked with a lower-alkylated urea resin.
摘要翻译：一种含重氮的感光材料，其包含透明载体和在载体的表面上设置并含有粘合剂，重氮化合物和偶联剂的重氮感光层，其中重氮化合物由下式表示：（其中 R1和R2彼此独立地表示低级烷基，X表示阴离子基团），其中所述成色剂包括苯基苯酚和3,5-二羟基-4-溴苯甲酸，并且其中所述粘合剂包含纤维素酯交叉与低级烷基化脲树脂连接。

4. 发明授权

US5407777A Diazo-type recording material comprising a 1-phenyl-3-pyrazolidone(phenidone) as an anti-oxidant 失效
标题翻译：包含1-苯基-3-吡唑烷酮（菲尼酮）作为抗氧化剂的重氮型记录材料
公开(公告)号：US5407777A
公开(公告)日：1995-04-18
申请号：US977639
申请日：1992-11-17
申请人： Hirokazu Shimada , Akihiro Shimomura
发明人： Hirokazu Shimada , Akihiro Shimomura
IPC分类号： G03C1/52 , B41M5/323 , G03C1/00 , G03C1/58 , G03C1/61 , G03C1/76 , G03C1/72
CPC分类号： G03C1/002 , G03C1/61 , G03C1/58
摘要： A diazo-type recording material comprising a support having thereon a recording layer comprising a photosensitive diazo compound enclosed in microcapsules, a coupling component which reacts with said diazo compound by heating at a basic pH to develop a color, and a 1-phenyl-3-pyrazolidone compound represented by the formula: ##STR1## wherein the substituents X, and R.sub.1 -R.sub.4 are defined in the specification.
摘要翻译：一种重氮型记录材料，其包括其上具有包含微胶囊中的光敏重氮化合物的记录层的载体，通过在碱性pH下加热以形成颜色与所述重氮化合物反应的偶联组分和1-苯基-3 由下式表示的吡唑烷酮化合物：其中取代基X和R 1 -R 4在说明书中定义。

5. 发明授权

US4770973A Heat-sensitive diazo recording material with diphenyl alkene coupler 失效
标题翻译：具有二苯基烯烃偶合剂的热敏重氮记录材料
公开(公告)号：US4770973A
公开(公告)日：1988-09-13
申请号：US928050
申请日：1986-11-07
申请人： Nobuo Kanda , Katsuhiko Ishida , Tosaku Okamoto , Mitsuru Kondo
发明人： Nobuo Kanda , Katsuhiko Ishida , Tosaku Okamoto , Mitsuru Kondo
IPC分类号： C09B23/00 , B41M5/323 , G03C1/58 , B41M5/18
CPC分类号： G03C1/58
摘要： In a heat-sensitive recording material which comprises a substrate and a heat-sensitive recording layer thereon containing a diazonium salt and coupler compound, the heat-sensitive recording material characterized in that the coupler compound comprises at least one compound represented by the formula [I] below ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are each hydrogen atom, halogen atom, alkyl or alkoxyl; R.sub.9 is hydrogen atom or alkyl; X and Y are each hydrogen atom, --OR.sub.10 or --N(R.sub.11)(R.sub.12), R.sub.10, R.sub.11 and R.sub.12 being each hydrogen atom, alkyl, alicyclic group, aryl or aralkyl, these R.sub.10, R.sub.11 and R.sub.12 may have a substituent selected from among halogen atom, alkyl and alkoxy, R.sub.11 and R.sub.12 may link together to form a heteroring, or, one or both of R.sub.11 and R.sub.12 may form a heteroring together with an adjacent benzene ring; n is 0 or 1.
摘要翻译：在包含基材和其上含有重氮盐和偶联剂化合物的热敏记录层的热敏记录材料中，热敏记录材料的特征在于，成色剂化合物包含至少一种由式[I ]其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8各自为氢原子，卤原子，烷基或烷氧基; R9为氢原子或烷基; X和Y各自为氢原子，-OR 10或-N（R 11）（R 12），R 10，R 11和R 12各自为氢原子，烷基，脂环基，芳基或芳烷基，这些R 10，R 11和R 12可以具有选定的取代基从卤素原子，烷基和烷氧基中，R 11和R 12可以连接在一起以形成杂环，或者，R11和R12中的一个或两个可以与相邻的苯环一起形成杂环; n为0或1。

6. 发明授权

US4486527A Thermo-developable type diazo copying material with 2-naphthol coupler having long aliphatic chain amide substitution 失效
标题翻译：具有长脂肪族链酰胺取代基的2-萘酚成色剂的热显影型重氮复印材料
公开(公告)号：US4486527A
公开(公告)日：1984-12-04
申请号：US466279
申请日：1983-02-14
申请人： Norio Kurisu , Tsutomu Matsuda , Masaru Shimada , Keishi Kubo
发明人： Norio Kurisu , Tsutomu Matsuda , Masaru Shimada , Keishi Kubo
IPC分类号： G03C1/52 , B41M5/323 , C09B29/00 , G03C1/58 , G01D15/10 , G03C1/60
CPC分类号： G03C1/58
摘要： A thermo-developable type diazo copying material including a substrate and a heat sensitive recording layer, superposed on said substrate, which consists essentially of a diazo compound, a coupler and a heat-fusible color assistant, characterized in that said heat sensitive recording layer is of the multilayered type comprising a diazo compound-containing layer and a coupler-containing layer, and said coupler is composed of one or two or more of the compounds having the following general formula: ##STR1## wherein X is hydrogen, halogen, an alkyl group having 1-4 carbon atoms or an alkoxyl group having 1-4 carbon atoms; R.sup.1 is an alkyl group having 10-25 carbon atoms; and R.sup.2 is hydrogen or an alkyl group having 1-30 carbon atoms.
摘要翻译：一种热可显影型重氮复制材料，其包括基板和热敏记录层，叠加在所述基板上，其基本上由重氮化合物，耦合器和热熔颜色助剂组成，其特征在于，所述热敏记录层是包含含重氮化合物的层和成色剂层的多层型，并且所述成色剂由一种或两种或更多种具有以下通式的化合物组成：其中X是氢，卤素，烷基具有1-4个碳原子的烷基或具有1-4个碳原子的烷氧基; R1是具有10-25个碳原子的烷基; 并且R 2是氢或具有1-30个碳原子的烷基。

7. 发明授权

US4304831A Black-color forming two-component type diazo copying material 失效
标题翻译：黑色成型双组分型重氮复印材料
公开(公告)号：US4304831A
公开(公告)日：1981-12-08
申请号：US63308
申请日：1979-08-02
申请人： Tsutomu Matsuda , Masanori Rimoto
发明人： Tsutomu Matsuda , Masanori Rimoto
IPC分类号： G03C1/52 , G03C1/58 , G03C1/54
CPC分类号： G03C1/58
摘要： A two-component type diazo copying material according to this invention, which comprises a support and a photosensitive layer formed thereon, said layer consisting essentially of a diazo compound expressed by the following general formula I and a coupler mixture consisting of a compound expressed by the following formula II, a compound expressed by the following general formula III and a compound expressed by the following general formula IV, can form a genuine black-color image and is especially optimum for preparing a secondary original used in electrophotographic copying machines. General formula I ##STR1## (wherein R represents alkyl radical having 1 to 5 carbon atoms; R.sub.1 and R.sub.2 represent substituted or non-substituted alkyl radical, aralkyl radical or cycloalkyl radical, or R.sub.1 and R.sub.2 may form a heterocyclic ring together with the nitrogen atom to which they bond; and X represents anion.) ##STR2## (wherein X is of no account or represents O, S, SO or SO.sub.2.) ##STR3## [wherein R.sub.3 represents hydrogen, alkyl radical having 1 to 4 carbon atoms or halogen; R.sub.4 represents hydrogen, --(CH.sub.2).sub.n OH (wherein n is an integer ranging from 2 to 4) or ##STR4## (wherein n is an integer ranging from 2 or 4; R.sub.5 and R.sub.6 represent alkyl radical having 1 to 4 carbon atoms, or R.sub.5 and R.sub.6 may form heterocyclic ring together with nitrogen atoms to which they bond.)]
摘要翻译：根据本发明的双组分型重氮复制材料，其包含载体和形成在其上的感光层，所述层基本上由以下通式I表示的重氮化合物和由以下通式I表示的化合物组成的成色剂混合物组成：按照下式II，由以下通式III表示的化合物和由以下通式IV表示的化合物可以形成真正的黑色图像，并且对于制备用于电子照相复印机中的次级原稿尤为适用。通式I （其中R表示具有1至5个碳原子的烷基; R 1和R 2表示取代或未取代的烷基，芳烷基或环烷基，或者R 1和R 2可与氮一起形成杂环原子，X表示阴离子。）式Ⅱ通式III（其中X不考虑或表示O，S，SO或SO2）通式IV其中R 3 表示氢，具有1至4个碳原子的烷基或卤素; R 4表示氢， - （CH 2）n OH（其中n是2至4的整数）或（其中n是2或4的整数; R 5和R 6表示具有1至4个碳原子的烷基，或者R 5和R 6可以与它们键合的氮原子一起形成杂环。

8. 发明授权

US4207110A Diazotype material 失效
标题翻译： Diazotype材料
公开(公告)号：US4207110A
公开(公告)日：1980-06-10
申请号：US951247
申请日：1978-10-13
申请人： Siegfried Scheler , Heinz Schafer
发明人： Siegfried Scheler , Heinz Schafer
IPC分类号： G03C1/52 , G03C1/58
CPC分类号： G03C1/58
摘要： This invention relates to an improvement in a diazotype material comprising, in the light-sensitive layer, a diazo component and a coupling component which yields a black dyestuff image, the improvement that the diazo component is a 2,5-dialkoxy-4-morpholino-benzene diazonium salt and the coupling component is a combination of(a) 6-methoxy-2-hydroxy-3-naphthoic acid-N(.omega.-aminoalkyl)-amide as a blue coupler,(b) a 2-alkyl- or 2-aryl-1,3-dihydroxybenzene or a cyanoacetoamide as a yellow coupler, and(c) at least one compound of the general formula ##STR1## wherein X is zero, =S, =SO, or =SO.sub.2, as a reddish-brown coupler, the molar ratio of blue coupler to yellow coupler being in the range of about (0.7 to 0.9):1, and the molar ratio of blue coupler to reddish-brown coupler being in the range of about (6 to 12):1.
摘要翻译：本发明涉及一种重氮化物质的改进，其包含在感光层中的重氮组分和产生黑色染料影像的偶合组分，重氮组分是2,5-二烷氧基-4-吗啉代 - 苯重氮盐和偶联组分是（a）6-甲氧基-2-羟基-3-萘甲酸-N（ω-氨基烷基） - 酰胺作为蓝色偶合剂的组合，（b）2-烷基 - 或 2-芳基-1,3-二羟基苯或氰基乙酰胺作为黄色成色剂，和（c）至少一种通式为“IMAGE”的化合物，其中X为零，= S，= SO或= SO 2，为红色蓝色成色剂与黄色成色剂的摩尔比在约（0.7〜0.9）：1的范围内，蓝色成色剂与红棕色成色剂的摩尔比在约（6〜12）范围内，：1。

9. 发明授权

US3976491A Diazo compositions and diazotype materials prepared from same 失效
标题翻译：重氮组合物和由其制备的重氮基化物质
公开(公告)号：US3976491A
公开(公告)日：1976-08-24
申请号：US527409
申请日：1974-11-26
申请人： Robert C. Desjarlais
发明人： Robert C. Desjarlais
IPC分类号： C07C43/23 , C07C27/00 , C07C37/18 , C07C39/15 , C07C41/00 , C07C67/00 , C09B29/12 , G03C1/58
CPC分类号： G03C1/58 , C07C37/18 , C09B29/12
摘要： Light-sensitive diazo compositions which comprise a resorcinol substituted in the 2-position with an alkyl group and in the 4-position with an aralkyl group as the yellow azo coupling component, and diazotype materials prepared therefrom.
摘要翻译：包含在2位被烷基取代的间苯二酚和4位具有芳烷基作为黄色偶氮偶合组分的光敏重氮组合物和由其制备的二嗪类材料。

10. 发明授权

US3791832A Diazotype photoprinting material 失效
标题翻译： DIAZOTYPE光电材料
公开(公告)号：US3791832A
公开(公告)日：1974-02-12
申请号：US3791832D
申请日：1972-03-10
申请人： RICOH KK
发明人： MARUYAMA S , SAITO T , YOSHIDA S , SHIMADA M
IPC分类号： G03C1/58
CPC分类号： G03C1/58
摘要： This invention describes diazotype photoprinting material containing as a coupling component a compound of the formula:

WHEREIN R1 and R2 are hydrogen, alkyl, phenyl, or taken together form a heterocyclic ring and Y is an alkyl or alkoxy. This photoprinting material gives a dense dye-image having high preservability. It could be developed by both dry and wet development methods.

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