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    • 18. 发明申请
    • EXTRACTION PROCESS FOR ALDEHYDE PRODUCT SEPARATION AND CATALYST RECOVERY
    • 阿尔德产品分离和催化剂回收的萃取方法
    • US20100228057A1
    • 2010-09-09
    • US12664220
    • 2008-05-30
    • Wei-Jun Peng
    • Wei-Jun Peng
    • C07C45/78
    • C11C3/00C07C67/347C07C67/58C07C69/716
    • An extraction process for a non-aqueous hydroformylation product composition to separate an aldehyde product and to recover a hydroformylation catalyst. The process involves mixing a non-aqueous hydroformylation product composition containing a mixture of formyl-substituted fatty acid triglyceride esters derived from hydroformylating a seed oil, a transition metal-organophosphine ligand wherein the organophosphine is ionically-charged, optionally free ionically-charged organophosphine ligand, and a polar organic solubilizing agent with water and an extraction solvent having low water solubility to recover an organic phase containing the mixture of formyl-substituted fatty acid triglycerides and the low solubility extraction solvent and an aqueous phase containing the transition metal-organophosphine ligand, optional free ligand, the organic solubilizing agent, and water. Optionally, the low solubility extraction solvent can be prepared in situ in the hydroformylation step.
    • 用于非水羰基化产物组合物分离醛产物并回收加氢甲酰化催化剂的提取方法。 该方法包括混合含有衍生自加氢甲酰化种子油的甲酰取代的脂肪酸甘油三酸酯混合物的非水性加氢甲酰化产物组合物,其中有机膦被离子带电的过渡金属 - 有机膦配体,任选的游离离子电荷的有机膦配体 和具有低水溶性的水和萃取溶剂的极性有机增溶剂,以回收含有甲酰取代的脂肪酸甘油三酸酯和低溶解度提取溶剂的混合物的有机相和含有过渡金属 - 有机膦配体的水相, 任选的游离配体,有机增溶剂和水。 任选地,低溶解度提取溶剂可以在加氢甲酰化步骤中原位制备。
    • 19. 发明申请
    • METHOD FOR PURIFYING ACETONE
    • 净化乙腈的方法
    • US20100145103A1
    • 2010-06-10
    • US12633737
    • 2009-12-08
    • Mark Erik NelsonAndrey Yurievich SokolovIlya Yurievich KrupenkoValery Yurievich Aristovich
    • Mark Erik NelsonAndrey Yurievich SokolovIlya Yurievich KrupenkoValery Yurievich Aristovich
    • C07C45/78
    • C07C45/85C07C49/08
    • A method for purifying a crude acetone raw material containing low molecular weight impurities using three columns in sequence is disclosed. The method comprises the steps of feeding the crude acetone raw material into a first column; adding an alkaline reagent and an oxidative reagent into the first column; feeding the first bottom fraction to a second rectification column; optionally adding an alkaline reagent to the second column above the charge point of the bottom fraction; separating a purified acetone from the high molecular weight impurities and removing the purified acetone as a top fraction by distillation in the second column, thereby forming a second bottom fraction comprising an acetone mixture comprising high molecular weight impurities; feeding the second bottom fraction comprising the acetone mixture to a third rectification column; removing a top fraction from the third column; and returning the top fraction removed from the third column to the first column, wherein the second rectification column is operated at atmospheric pressure, and wherein the purified acetone has an acetaldehyde level of less than 5 ppm and a KT-Test time of greater than 11 hours, as measured by the SABIC KT-Test method.
    • 公开了一种使用三列依次纯化含有低分子量杂质的粗丙酮原料的方法。 该方法包括将粗丙酮原料进料到第一塔中的步骤; 在第一塔中加入碱性试剂和氧化试剂; 将第一底部馏分送入第二精馏塔; 任选地在底部馏分的充电点上方的第二塔中加入碱性试剂; 将纯化的丙酮与高分子量杂质分离,并在第二塔中通过蒸馏除去纯化的丙酮作为顶级馏分,由此形成包含含有高分子量杂质的丙酮混合物的第二塔底馏分; 将包含丙酮混合物的第二底部馏分进料至第三精馏塔; 从第三列移除顶部馏分; 并将从第三塔取出的顶馏分返回到第一塔,其中第二精馏塔在大气压下运行,其中纯化丙酮的乙醛水平小于5ppm,KT-测试时间大于11 小时,由SABIC KT-Test方法测量。