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1. 发明授权

US09725401B2 Processes for the production of esters 有权
公开(公告)号：US09725401B2
公开(公告)日：2017-08-08
申请号：US13805951
申请日：2011-07-19
申请人： Nicolaas A. De Munck , Eddy T. A. Van Driessche
发明人： Nicolaas A. De Munck , Eddy T. A. Van Driessche
IPC分类号： C07C69/76 , C07C69/78 , C07C67/08
CPC分类号： C07C69/78 , B01J2219/0025 , C07C67/08 , Y02P20/582 , C07C69/80
摘要： A process for production of C4 to C15 esters by the esterification of a carboxylic acid or anhydride with a C4 to C15 alcohol including forming a reaction mixture of the acid or anhydride and the C4 to C15 alcohol including a stoichiometric excess of the alcohol is provided.

2. 发明授权

US08962541B2 Processes relating to alcohols for the production of esters 有权
标题翻译：与醇类生产酯相关的方法
公开(公告)号：US08962541B2
公开(公告)日：2015-02-24
申请号：US13139949
申请日：2009-12-03
申请人： Allen D. Godwin , Philippe L. Buess , Raphael F. Caers , Arie Van Vliet , Eddy T. A. Van Driessche , Alfons Cuyckens
发明人： Allen D. Godwin , Philippe L. Buess , Raphael F. Caers , Arie Van Vliet , Eddy T. A. Van Driessche , Alfons Cuyckens
IPC分类号： C10M105/32 , C07C31/125 , C07C69/75 , C07C69/78 , C08K5/10 , C07C29/141 , C07C29/17
CPC分类号： C07C29/175 , C07C29/141 , C07C2601/14 , C08K5/10 , C07C31/125 , C08L27/06
摘要： The present invention relates to alcohols and in particular to C4 to C15 alcohols that are used in the production of esters.
摘要翻译：本发明涉及醇，特别涉及用于生产酯的C4至C15醇。

3. 发明授权

US08247618B2 Oxidative demetalling 有权
标题翻译：氧化脱金属
公开(公告)号：US08247618B2
公开(公告)日：2012-08-21
申请号：US12532646
申请日：2008-03-31
申请人： Kenneth J. Buturla , James T. Ritchie , Ronald D. Garton , Eddy T. A. Van Driessche
发明人： Kenneth J. Buturla , James T. Ritchie , Ronald D. Garton , Eddy T. A. Van Driessche
IPC分类号： C07C45/50 , C07C45/78
CPC分类号： B01J31/403 , B01J31/20 , B01J31/4092 , B01J2231/321 , B01J2531/845 , C07C45/50 , C07C45/85 , C07C51/235 , C07C67/08 , C07C67/303 , Y02P20/584 , C07C47/00 , C07C69/80 , C07C69/78 , C07C69/75 , C07C47/02
摘要： Oxidative recovery methods that use oxygen or air for recovery of homogeneous metal catalysts, such as cobalt catalysts, used in for example hydroformylation processes, can be hazardous. Explosive or flammable gas mixtures may be generated inside the process equipment, which can deflagrate upon any ignition source such as a static electricity discharge. The use of a flammable diluent has been found to be a very effective way of optimizing the recovery method, by bringing the resulting gas mixtures above their upper flammability limit. The offgas produced is then also easier to dispose of as a fuel, as compared to when a non-flammable diluent is used.
摘要翻译：使用氧气或空气回收均质金属催化剂（例如用于例如加氢甲酰化方法的钴催化剂）的氧化回收方法可能是危险的。可能会在工艺设备内部产生爆炸性或易燃气体混合物，这些混合物可能会在任何点火源（如静电放电）上发生爆炸。已经发现使用可燃性稀释剂是通过将所得气体混合物高于其上限燃烧极限来优化回收方法的非常有效的方法。与使用不易燃稀释剂相比，生产的废气也更容易作为燃料处置。

4. 发明授权

US5410090A Airless cobalt demetalling in the cobalt flash combination catalyst cycle 失效
标题翻译：无气钴脱钴在钴闪光组合催化剂循环中
公开(公告)号：US5410090A
公开(公告)日：1995-04-25
申请号：US224911
申请日：1994-04-08
申请人： Stephen W. Beadle , William H. Summerlin , Eddy T. A. Van Driessche
发明人： Stephen W. Beadle , William H. Summerlin , Eddy T. A. Van Driessche
IPC分类号： C07C45/50 , C07C45/80 , C07C45/85 , C07C45/78
CPC分类号： C07C45/50 , C07C45/80 , C07C45/85
摘要： A method for removing cobalt values from the crude product of a cobalt-catalyzed hydroformylation reaction by the application of an airless cobalt demetalling step upstream of the stripping step of a Cobalt Flash hydroformylation catalyst recovery process for C.sub.4 to C.sub.14 olefins, whereby no oxygen is required to oxidize cobalt carbonyls to their cobaltous form. This airless demetalling step may also be used downstream of the stripping step in the case of C.sub.7 to C.sub.20 olefins to remove carbonyls from a water soluble cobaltous salt and carbon carbonyl stream which is taken as bottoms from the stripper reactor.
摘要翻译：通过在C4至C14烯烃的钴闪加氢甲酰化催化剂回收方法的汽提步骤的上游施加无气体脱钴步骤来从钴催化的加氢甲酰化反应的粗产物中除去钴值的方法，由此不需要氧气以将羰基钴氧化成它们的钴耳托形式。在C7至C20烯烃的情况下，该无气体脱金属步骤也可用于汽提步骤的下游，以从水溶性钴铵盐中除去羰基，并将碳羰基物流从汽提塔反应器中作为塔底产物。

5. 发明授权

US08476476B2 Offgas cleanup in olefin hydroformylation 有权
标题翻译：烯烃加氢甲酰化中的废气净化
公开(公告)号：US08476476B2
公开(公告)日：2013-07-02
申请号：US13001930
申请日：2009-08-19
申请人： Eddy T. A. Van Driessche , Ronald D. Garton , Raphael F. Caers
发明人： Eddy T. A. Van Driessche , Ronald D. Garton , Raphael F. Caers
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , C07C29/141 , C07C45/783 , C07C67/08 , C07C67/303 , C07C2601/14 , C07C69/82 , C07C69/75 , C07C47/02 , C07C31/125
摘要： In the hydroformylation of C5-C14 olefins with cobalt catalyst to produce C6-C15 oxygenates, where offgasses from the hydroformylation or cobalt removal step contain volatile cobalt compounds, the cobalt compounds are recovered by scrubbing the offgas with a liquid, and recycling the liquid to the cobalt removal step. Suitable scrubbing liquids are the organic cobalt-depleted hydroformylation reaction product or a downstream derivative thereof, or an aqueous solution of a Co2+ salt, preferably such salt of formic acid.
摘要翻译：在用钴催化剂加氢甲酰化C5-C14烯烃以产生C6-C15含氧化合物，其中来自加氢甲酰化或脱钴步骤的废气含有挥发性钴化合物，通过用液体洗涤废气回收钴化合物，并将液体再循环至钴去除步骤。合适的洗涤液体是有机贫钴加氢甲酰化反应产物或其下游衍生物，或Co2 +盐的水溶液，优选甲酸盐。

6. 发明授权

US08541627B2 Hydroformylation process including catalyst recycle 失效
标题翻译：加氢甲酰化工艺，包括催化剂循环
公开(公告)号：US08541627B2
公开(公告)日：2013-09-24
申请号：US13001922
申请日：2009-08-19
申请人： Eddy T. A. Van Driessche , Ronald D. Garton , Corey W. Reed
发明人： Eddy T. A. Van Driessche , Ronald D. Garton , Corey W. Reed
IPC分类号： C07C45/50 , C07C29/14
CPC分类号： C07C45/50 , C07C45/80 , Y02P20/584 , C07C47/02
摘要： An improved hydroformylation catalyst cycle is disclosed wherein the cobalt catalyst is recycled to the hydroformylation reaction mainly as a water soluble carbonyl salt, obtained from extraction of the acidic form of the homogeneous cobalt carbonyl catalyst from the hydroformylation product with an aqueous solution of a salt of a weaker acid. The organic product after extraction is submitted to a further demetalling step in the presence of a dilute acid and an oxidant. The water from this further demetalling step is suitable for use in the upstream extraction step. A free water phase present in the hydroformylation reaction product may be separated upstream from the extraction step and is suitable for use in the further demetalling step, such that the catalyst cycle has no waste water stream.
摘要翻译：公开了一种改进的加氢甲酰化催化剂循环，其中主要以水溶性羰基盐将钴催化剂再循环至加氢甲酰化反应，该水溶性羰基盐是从加氢甲酰化产物中提取酸性形式的均匀钴羰基催化剂得到的，酸弱。提取后的有机产物在稀酸和氧化剂存在下进一步脱金属步骤。来自该进一步脱金属步骤的水适用于上游萃取步骤。存在于加氢甲酰化反应产物中的游离水相可以从萃取步骤的上游分离，并且适合用于进一步脱金属步骤，使得催化剂循环不含废水流。

7. 发明授权

US07910782B2 Cobalt recovery from cobalt catalysed hydroformylation reactions 有权
标题翻译：从钴催化的羰基化反应中回收钴
公开(公告)号：US07910782B2
公开(公告)日：2011-03-22
申请号：US12532475
申请日：2008-03-28
申请人： Eddy T. A. Van Driessche , Arie Van Vliet , Raphael Frans Caers , Hubertus Joseph Beckers , Ronald Dean Garton , Bertrand Raymond Da Cruz , Michel J. P. Lepagnol , Edwin Kooke
发明人： Eddy T. A. Van Driessche , Arie Van Vliet , Raphael Frans Caers , Hubertus Joseph Beckers , Ronald Dean Garton , Bertrand Raymond Da Cruz , Michel J. P. Lepagnol , Edwin Kooke
IPC分类号： C07C45/50 , C07C29/16 , C07C67/08 , C07C67/303
CPC分类号： C22B23/026 , C01G51/02 , C07C45/50 , C22B23/065 , Y02P10/224 , C07C47/02
摘要： In a hydroformylation reaction, the circulation and recovery of cobalt carbonyl in a cobalt catalyst cycle using carbonylate as an intermediate and acidification thereof, is improved by supplying an aqueous sulfuric acid solution containing less than 16% wt of sulfuric acid to the carbonylate to control sulfuric acid concentration in the carbonylate/acid mixture, before accounting for any acid consuming reaction, to a value of from 2% to 10% by weight. Single step and multistage liquid/liquid extraction techniques as well as vapor/liquid extraction techniques followed by the absorption of cobalt from the vapor in an organic liquid both benefit from this improvement.
摘要翻译：在加氢甲酰化反应中，使用羰基化物作为其中间体和酸化的钴催化剂循环中的羰基钴的循环和回收通过向羰基化物供应含少于16重量％的硫酸的硫酸水溶液来控制硫酸在将碳酸酯/酸混合物中酸消耗反应之前的酸浓度为2重量％至10重量％。单步和多步液/液萃取技术以及蒸汽/液体萃取技术，然后从有机液体中的蒸气中吸收钴，均可从中获益。

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