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1. 发明授权

US09255053B2 Treatment of bisphenol-A residue streams 有权
标题翻译：双酚A残留物流的处理
公开(公告)号：US09255053B2
公开(公告)日：2016-02-09
申请号：US13487872
申请日：2012-06-04
申请人： David P. Palmer , Steven D. Evitt , Stephen W. Fetsko , Chung-Ming Chi
发明人： David P. Palmer , Steven D. Evitt , Stephen W. Fetsko , Chung-Ming Chi
IPC分类号： C07C37/72 , C07C37/52 , C07C37/20 , C07C45/51
CPC分类号： C07C37/52 , C07C37/20 , C07C37/72 , C07C45/51 , C07C39/04 , C07C39/16 , C07C49/08
摘要： In a method of treating a residue stream from the production of bisphenol-A, the residue stream is contacted with an aqueous solution of a base under conditions effective to hydrolyze at least part of said residue stream into acetone and phenol and produce an effluent stream. Acetone is recovered from the effluent stream to produce a phenol-containing mixed phase stream which is substantially free of acetone and which contains water and unhydrolyzed heavy organic compounds. The phenol-containing mixed phase stream is then treated with a water-immiscible organic solvent to extract phenol and unhydrolyzed heavy organic compounds into said solvent and produce an organic phase containing the solvent, phenol and unhydrolyzed heavy aromatic compounds and an aqueous phase with reduced concentrations of phenol and unhydrolyzed heavy organic compounds. At least part of the phenol and the organic solvent are subsequently recovered from the organic phase.
摘要翻译：在从生产双酚A处理残余物流的方法中，将残余物流与碱的水溶液接触，在有效地将至少部分所述残余物流水解成丙酮和苯酚并产生流出物流的条件下进行。从流出物流中回收丙酮以产生基本上不含丙酮并含有水和未水解的重质有机化合物的含苯酚混合物流。然后用与水不混溶的有机溶剂处理含苯酚的混合物流，将苯酚和未水解的重质有机化合物提取到所述溶剂中，并产生含有溶剂，苯酚和未水解的重芳族化合物的有机相和浓度降低的水相的酚和未水解的重质有机化合物。随后从有机相中回收至少部分的苯酚和有机溶剂。

2. 发明授权

US08039679B2 Bisphenol-A plant yield enhancement 有权
标题翻译：双酚A植物产量提高
公开(公告)号：US08039679B2
公开(公告)日：2011-10-18
申请号：US12066630
申请日：2006-08-24
申请人： Steven D. Evitt , Stephen W. Fetsko , Chung-Ming Chi
发明人： Steven D. Evitt , Stephen W. Fetsko , Chung-Ming Chi
IPC分类号： C07C37/74 , C07C37/20
CPC分类号： C07C45/53 , C07C2/66 , C07C37/20 , C07C37/72 , C07C37/74 , C07C37/84 , C07C407/00 , C07C409/10 , Y02P20/127 , C07C15/085 , C07C49/08 , C07C39/16
摘要： An improved process is provided for producing bisphenol-A (BPA) comprising steps of (1) contacting benzene and a C3 alkylating agent to produce an alkylation effluent comprising cumene; (2) oxidizing the cumene to produce the corresponding hydroperoxide; (3) cleaving the hydroperoxide to produce product comprising phenol and acetone; (4) reacting acetone with phenol to form a reaction product stream comprising crude bisphenol-A product; (5) distilling the reaction product stream, while sending downstream to a BPA-phenol adduct crystallization and purification step, the resulting concentrated BPA phenolic feed stream; (6) producing BPA-phenol adduct crystals by crystallization of the concentrated BPA phenolic feed stream; (7) separating the BPA-phenol adduct crystals by solid-liquid separationr; (8) cracking a stream comprising at least a portion of said final mother liquor to recover a product; and (9) recovering and feeding the phenol product of step (8) to step (4) and/or step (7).
摘要翻译：提供用于生产双酚-A（BPA）的改进方法，包括以下步骤：（1）使苯和C3烷基化剂接触以产生包含枯烯的烷基化流出物; （2）氧化枯烯以产生相应的氢过氧化物; （3）切割氢过氧化物以产生包含苯酚和丙酮的产物; （4）使丙酮与苯酚反应形成包含粗双酚-A产物的反应产物流; （5）蒸馏反应产物流，同时向下游送入BPA-苯酚加合物结晶和纯化步骤，得到浓缩的BPA酚类进料流; （6）通过浓缩的BPA酚类进料流的结晶生产BPA-苯酚加合物晶体; （7）通过固液分离器分离BPA-苯酚加合物晶体; （8）裂化含有至少一部分所述最终母液的物流以回收产物; 和（9）将步骤（8）的苯酚产物回收和进料至步骤（4）和/或步骤（7）。

3. 发明授权

US08431749B2 Recovery of phenol and acetone from bisphenol-A streams 有权
标题翻译：从双酚A流中回收苯酚和丙酮
公开(公告)号：US08431749B2
公开(公告)日：2013-04-30
申请号：US13153909
申请日：2011-06-06
申请人： David P. Palmer , Steven D. Evitt , Stephen W. Fetsko , Chung-Ming Chi
发明人： David P. Palmer , Steven D. Evitt , Stephen W. Fetsko , Chung-Ming Chi
IPC分类号： C07C45/78 , C07C37/68 , C07C37/20
CPC分类号： C07C37/20 , C07C37/52 , C07C37/70 , C07C39/16 , C07C39/04
摘要： In a method of recovering phenol and acetone from a feed stream containing bisphenol-A and isomers thereof, the feed stream is contacted with water and a source of hydroxyl ions under conditions effective to decompose at least part of said bisphenol-A and isomers thereof to phenol and acetone. The conditions include a temperature of about 150° C. to about 300° C., a pressure sufficient to keep the water substantially in the liquid phase at said temperature, and a molar ratio of hydroxyl ions to hydroxyphenyl groups in the residue stream from about 0.3:1 to about 0.9:1.
摘要翻译：在从含有双酚A及其异构体的进料流中回收苯酚和丙酮的方法中，在有效分解至少部分所述双酚A及其异构体的条件下，将进料流与水和羟基离子源接触，苯酚和丙酮。条件包括约150℃至约300℃的温度，足以将水保持在所述温度下的液相中的压力以及来自约的残留物流中羟基离子与羟基苯基的摩尔比 0.3：1至约0.9：1。

4. 发明申请

US20110201858A1 PROCESS FOR PRODUCING CUMENE 审中-公开
标题翻译：生产过程的方法
公开(公告)号：US20110201858A1
公开(公告)日：2011-08-18
申请号：US13119789
申请日：2009-09-23
申请人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
发明人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
IPC分类号： C07C2/00
CPC分类号： C07C409/10 , C07C2/66 , C07C2/864 , C07C29/145 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C15/085 , C07C31/10 , C07C49/08 , C07C39/04
摘要： In a process for producing cumene from acetone and benzene, a feed stream comprising acetone is contacted with hydrogen in the presence of a hydrogenation catalyst in a first reaction zone under hydrogenation conditions sufficient to convert at least part of the acetone to isopropanol and produce a first liquid effluent stream rich in isopropanol and a first vapor stream rich in unreacted hydrogen. Benzene is then added to at least part of the first liquid effluent stream, without intermediate purification of the first liquid effluent stream, and optionally to at least part of the first vapor stream, to form a second feed stream. The second feed stream is then contacted with an alkylation catalyst in a second reaction zone separate from the first reaction zone under alkylation conditions sufficient to maintain at least part of the second feed stream in the liquid phase and to cause at least part of the isopropanol in the second feed stream to react with the benzene to form cumene and water and produce a second effluent stream comprising at least cumene, water and unreacted benzene. Hydrogen is separated from the first vapor stream and/or the second effluent stream. At least part of the hydrogen is recycled to the first reaction zone and/or purged from the system.
摘要翻译：在从丙酮和苯生产异丙基苯的方法中，在氢化条件下，在氢化催化剂存在下，将含丙酮的进料流与氢气接触，在氢化条件下，将至少部分丙酮转化成异丙醇，并产生第一富含异丙醇的液体流出物流和富含未反应氢的第一蒸气流。然后将苯添加到至少部分第一液体流出物流中，而不用第一液体流出物流的中间纯化，以及任选地至少部分第一蒸气流，形成第二进料流。然后在足以将至少部分第二进料流保持在液相中并使至少部分异丙醇在烷基化条件下与第一反应区分离的第二反应区中的第二进料流与烷基化催化剂接触所述第二进料流与苯反应以形成异丙基苯和水，并产生包含至少异丙基苯，水和未反应的苯的第二流出物流。氢气与第一蒸气流和/或第二流出物流分离。至少部分氢被再循环到第一反应区和/或从系统中清除。

5. 发明授权

US07777086B2 Production of alkyl aromatic compounds 有权
标题翻译：烷基芳族化合物的生产
公开(公告)号：US07777086B2
公开(公告)日：2010-08-17
申请号：US10505787
申请日：2003-02-27
申请人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard F. Guarino , Dana E Johnson
发明人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard F. Guarino , Dana E Johnson
IPC分类号： C07C2/66 , C07C7/04
CPC分类号： C07C2/66 , C07C7/04 , C07C7/10 , C07C7/12 , C07C7/13 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/82 , Y02P20/125 , C07C15/085 , C07C11/06 , C07C15/04
摘要： Improved integrated processes for the production of alkyl aromatic compounds are disclosed wherein aromatic compounds which may be treated for removal of deleterious substances are reacted with olefin compounds, which may also be treated for contaminant removal, in the presence of acidic zeolite catalyst(s) to produce the desired alkyl aromatic compound(s). The aromatic and preferably also the olefin feeds are treated substantially to remove contaminants, particularly the nitrogen compounds contained therein, before they are brought together for reaction in the presence of the zeolite catalyst(s). In accordance with the present invention, it has been found that feed pretreatment for removal of nitrogen compounds significantly improves the run length and life of the acidic zeolite catalyst(s). The feed pretreatment of this invention may include the steps of distillation, extraction, and/or adsorption by solid adsorbent, which may be regenerated in accordance with further embodiments of this invention.
摘要翻译：公开了用于生产烷基芳族化合物的改进的一体化方法，其中可以处理去除有害物质的芳族化合物与烯烃化合物反应，烯烃化合物也可以在酸性沸石催化剂存在下进行处理以除去污染物，产生所需的烷基芳族化合物。在沸石催化剂的存在下，芳族化合物和烯烃进料基本上被处理以除去污染物，特别是其中所含的氮化合物，然后将它们聚集在一起进行反应。根据本发明，已经发现用于除去氮化合物的进料预处理显着地改善了酸性沸石催化剂的运行长度和使用寿命。本发明的进料预处理可以包括根据本发明的其它实施方案可以再生的固体吸附剂的蒸馏，萃取和/或吸附的步骤。

6. 发明授权

US07745676B2 Alkylaromatics production 有权
标题翻译：烷基芳烃生产
公开(公告)号：US07745676B2
公开(公告)日：2010-06-29
申请号：US11881921
申请日：2007-07-30
申请人： Michael C. Clark , Vijay Nanda , Maruti Bhandarkar , Joseph C. Peters , Chung-Ming Chi , Brian Maerz
发明人： Michael C. Clark , Vijay Nanda , Maruti Bhandarkar , Joseph C. Peters , Chung-Ming Chi , Brian Maerz
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C15/073 , C07C15/02
摘要： A process is described for producing an alkylaromatic compound, in which a first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into a first alkylation reaction zone comprising a first alkylation catalyst. The first alkylation reaction zone is operated under conditions effective to cause alkylation of the alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the vapor phase. A first effluent comprising the alkylaromatic compound and unreacted alkylatable aromatic compound is withdrawn from the first alkylation reaction zone and at least part of the unreacted alkylatable aromatic compound is treated to remove catalyst poisons therefrom and produce a treated unreacted alkylatable aromatic stream. At least part of the unreacted alkylatable aromatic compound and a third feed comprising said alkene is introduced into a second alkylation reaction zone comprising a second alkylation catalyst. The second alkylation reaction zone is operated under conditions effective to cause alkylation of the unreacted alkylatable aromatic compound by the alkene to produce said alkylaromatic compound, the conditions being such that the alkylatable aromatic compound is at least predominantly in the liquid phase. A second effluent comprising said alkylaromatic compound is withdrawn from the second alkylation reaction zone.
摘要翻译：描述了用于生产烷基芳族化合物的方法，其中将包含可烷基化芳族化合物的第一种进料和包含烯烃的第二种进料引入到包含第一烷基化催化剂的第一烷基化反应区中。第一烷基化反应区在有效使烷基化芳族化合物被烯烃烷基化以产生所述烷基芳族化合物的条件下运行，条件是使可烷基化芳族化合物至少主要在气相中。包含烷基芳族化合物和未反应的可烷基化芳族化合物的第一流出物从第一烷基化反应区取出，并且处理至少部分未反应的可烷基化芳族化合物以除去其中的催化剂毒物并产生经处理的未反应的可烷基化芳族物流。将至少部分未反应的可烷基化芳族化合物和包含所述烯烃的第三进料引入到包含第二烷基化催化剂的第二烷基化反应区中。第二烷基化反应区在有效使得未反应的可烷基化芳族化合物被烯烃烷基化以产生所述烷基芳族化合物的条件下运行，条件是使可烷基化芳族化合物至少主要在液相中。从第二烷基化反应区取出包含所述烷基芳族化合物的第二流出物。

7. 发明申请

US20100069693A1 Liquid Phase Alkylation with Multiple Catalysts 有权
标题翻译：多相催化剂的液相烷基化
公开(公告)号：US20100069693A1
公开(公告)日：2010-03-18
申请号：US12624118
申请日：2009-11-23
申请人： Michael C. Clark , Vijay Nanda , Chung-Ming Chi , Maruti Bhamdarkar , Brian Maerz , Matthew J. Vincent
发明人： Michael C. Clark , Vijay Nanda , Chung-Ming Chi , Maruti Bhamdarkar , Brian Maerz , Matthew J. Vincent
IPC分类号： C07C2/00
CPC分类号： C10G29/205 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C10G2300/1092 , C10G2300/1096 , C10G2400/30 , Y02P20/52 , C07C15/073 , C07C15/02 , C07C15/085
摘要： A process is disclosed for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones, each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into the first alkylation reaction zone. The first and second alkylation reaction zones are operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is at least partly in the liquid phase. The alkylation catalyst in the first alkylation reaction zone, which may be a reactor guard bed, has more acid sites per unit volume of catalyst than the alkylation catalyst in the second reaction zone.
摘要翻译：公开了一种在多级反应体系中生产烷基芳族化合物的方法，其包含至少第一和第二串联连接的烷基化反应区，每个含有烷基化催化剂。将包含可烷基化芳族化合物和包含烯烃的第二进料的第一进料引入第一烷基化反应区。第一烷基化反应区和第二烷基化反应区在温度和压力有效的条件下运行，以在烷基化催化剂存在下使芳族化合物与烯烃进行烷基化，温度和压力使芳族化合物至少部分在液相。在第一烷基化反应区（其可以是反应器保护床）中的烷基化催化剂与第二反应区中的烷基化催化剂相比，每单位体积催化剂具有更多的酸性位点。

8. 发明授权

US07645913B2 Liquid phase alkylation with multiple catalysts 有权
公开(公告)号：US07645913B2
公开(公告)日：2010-01-12
申请号：US11655452
申请日：2007-01-19
申请人： Michael C. Clark , Vijay Nanda , Chung-Ming Chi , Maruti Bhandarkar , Brian Maerz , Matthew J. Vincent
发明人： Michael C. Clark , Vijay Nanda , Chung-Ming Chi , Maruti Bhandarkar , Brian Maerz , Matthew J. Vincent
IPC分类号： C07C2/66
CPC分类号： C10G29/205 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C10G2300/1092 , C10G2300/1096 , C10G2400/30 , Y02P20/52 , C07C15/073 , C07C15/02 , C07C15/085
摘要： A process is disclosed for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones, each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into the first alkylation reaction zone. The first and second alkylation reaction zones are operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is at least partly in the liquid phase. The alkylation catalyst in the first alkylation reaction zone, which may be a reactor guard bed, has more acid sites per unit volume of catalyst than the alkylation catalyst in the second reaction zone.

9. 发明申请

US20050143612A1 Production of alkyl aromatic compounds 有权
标题翻译：烷基芳族化合物的生产
公开(公告)号：US20050143612A1
公开(公告)日：2005-06-30
申请号：US10505787
申请日：2003-02-27
申请人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard Guarino , Dana Johnson
发明人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard Guarino , Dana Johnson
IPC分类号： C07C7/04 , C07B61/00 , C07C2/64 , C07C2/66 , C07C2/70 , C07C7/10 , C07C7/12 , C07C11/04 , C07C11/06 , C07C11/08 , C07C11/09 , C07C15/02 , C07C15/04 , C07C15/06 , C07C15/073 , C07C15/08 , C07C15/085
CPC分类号： C07C2/66 , C07C7/04 , C07C7/10 , C07C7/12 , C07C7/13 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/82 , Y02P20/125 , C07C15/085 , C07C11/06 , C07C15/04
摘要： Improved integrated processes for the production of alkyl aromatic compounds are disclosed wherein aromatic compounds which may be treated for removal of deleterious substances are reacted with olefin compounds, which may also be treated for contaminant removal, in the presence of acidic zeolite catalyst(s) to produce the desired alkyl aromatic compound(s). The aromatic and preferably also the olefin feeds are treated substantially to remove contaminants, particularly the nitrogen compounds contained therein, before they are brought together for reaction in the presence of the zeolite catalyst(s). In accordance with the present invention, it has been found that feed pretreatment for removal of nitrogen compounds significantly improves the run length and life of the acidic zeolite catalyst(s). The feed pretreatment of this invention may include the steps of distillation, extraction, and/or adsorption by solid adsorbent, which may be regenerated in accordance with further embodiments of this invention.
摘要翻译：公开了用于生产烷基芳族化合物的改进的一体化方法，其中可以处理去除有害物质的芳族化合物与烯烃化合物反应，烯烃化合物也可以在酸性沸石催化剂存在下进行处理以除去污染物，产生所需的烷基芳族化合物。在沸石催化剂的存在下，芳族化合物和烯烃进料基本上被处理以除去污染物，特别是其中所含的氮化合物，然后将它们聚集在一起进行反应。根据本发明，已经发现用于除去氮化合物的进料预处理显着地改善了酸性沸石催化剂的运行长度和使用寿命。本发明的进料预处理可以包括根据本发明的其它实施方案可以再生的固体吸附剂的蒸馏，萃取和/或吸附的步骤。

10. 发明授权

US06888035B2 Hydrogenation of cleavage effluents in phenol production 有权
标题翻译：在苯酚生产中氢化裂解废水
公开(公告)号：US06888035B2
公开(公告)日：2005-05-03
申请号：US10363571
申请日：2001-09-25
申请人： Kevin J. Fallon , Chung-Ming Chi , Henry Y. Hwang , Frank A. Demers
发明人： Kevin J. Fallon , Chung-Ming Chi , Henry Y. Hwang , Frank A. Demers
IPC分类号： C07C5/03 , C07C29/145 , C07C39/04 , C07C37/08
CPC分类号： C07C5/03 , C07C29/145 , C07C39/04 , C07C2523/04 , C07C2523/34 , C07C2523/72 , C07C2523/755 , C07C2523/78 , C07C2523/86 , C07C2523/889 , C07C2525/02 , C12C11/02 , C07C15/085 , C07C31/10
摘要： A method for producing phenol is disclosed which includes oxidizing cumene to form cumene hydroperoxide and acid cleavage to form cumene, phenol, acetone, and various byproducts, including alpha methylstyrene, followed by a subsequent hydrogenation of at least a part of the acetone and substantially all of the alpha methylstyrene.
摘要翻译：公开了一种生产苯酚的方法，其包括氧化枯烯以形成氢过氧化枯烯和酸裂解以形成异丙苯，苯酚，丙酮和各种副产物，包括α-甲基苯乙烯，然后随后氢化至少一部分丙酮，基本上全部的α-甲基苯乙烯。

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