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11. 发明授权

US4666880A Catalysts 失效
标题翻译：催化剂
公开(公告)号：US4666880A
公开(公告)日：1987-05-19
申请号：US831553
申请日：1986-02-20
申请人： Bruce G. Baker , Neville J. Clark , Hamish McArthur , Edward Summerville
发明人： Bruce G. Baker , Neville J. Clark , Hamish McArthur , Edward Summerville
IPC分类号： B01J21/04 , B01J23/30 , B01J23/83 , B01J23/888 , B01J37/02 , B01J37/08 , C07C1/04 , C07C5/27 , B01J23/10 , B01J23/76
CPC分类号： C07C1/0445 , B01J21/04 , B01J23/30 , B01J23/83 , B01J23/888 , B01J37/0207 , B01J37/08 , C07C1/044 , C07C5/2772 , C07C2521/04 , C07C2523/10 , C07C2523/30 , C07C2523/745 , C07C2523/83
摘要： A method of forming a support for use with a primary catalyst for conversion of a feed stream comprising carbon monoxide and hydrogen into hydrocarbons is disclosed.A primary catalyst and a method of manufacturing the catalyst is also disclosed.Furthermore, a secondary catalyst for the production of branched chain alkenes from straight chain alkenes is also disclosed, together with methods of manufacturing the secondary catalyst.

12. 发明授权

US4663305A Cobalt catalysts for the conversion of methanol and for Fischer-Tropsch synthesis to produce hydrocarbons 失效
标题翻译：用于甲醇转化和费 - 托合成以生产碳氢化合物的钴催化剂
公开(公告)号：US4663305A
公开(公告)日：1987-05-05
申请号：US813918
申请日：1985-12-27
申请人： Charles H. Mauldin , Stephen M. Davis , Kym B. Arcuri
发明人： Charles H. Mauldin , Stephen M. Davis , Kym B. Arcuri
IPC分类号： B01J23/75 , B01J23/83 , B01J23/889 , C07C1/04 , C07C1/20 , C10G3/00 , B01J21/06 , B01J23/10 , B01J23/12 , B01J23/76
CPC分类号： C07C1/0435 , B01J23/75 , B01J23/83 , B01J23/8896 , C07C1/20 , C10G3/45 , C10G3/48 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/36 , C07C2523/75 , C07C2523/83 , C07C2523/889 , C10G2300/1022 , Y02P20/52 , Y02P30/20
摘要： A zirconium, hafnium, cerium or uranium promoted cobalt catalyst and process for the conversion of methanol or synthesis gas to hydrocarbons. Methanol is contacted, preferably with added hydrogen, over said catalyst, or synthesis gas is contacted over said catalyst to produce, at reaction conditions, an admixture of C.sub.10 + linear paraffins and olefins. These hydrocarbons can be further refined to high quality middle distillate fuels, and other valuable products such as mogas, diesel fuel, and jet fuel, particularly premium middle distillate fuels of carbon number ranging to about C.sub.20.
摘要翻译：锆，铪，铈或铀促进了钴催化剂和将甲醇或合成气转化为烃的方法。甲醇在所述催化剂上接触，优选与加入的氢气接触，或者合成气在所述催化剂上接触，以在反应条件下产生C10 +直链烷烃和烯烃的混合物。这些碳氢化合物可以进一步精制成高质量的中间馏分燃料，以及其他有价值的产品，如摩尔瓦，柴油和喷气燃料，特别是碳数高于约C20的优质中间馏分燃料。

13. 发明授权

US4657885A Cerium promoted Fischer-Tropsch catalysts 失效
标题翻译：铈促进费 - 托催化剂
公开(公告)号：US4657885A
公开(公告)日：1987-04-14
申请号：US754004
申请日：1985-07-11
申请人： Rocco A. Fiato , Ronny Bar-Gadda , Sabato Miseo
发明人： Rocco A. Fiato , Ronny Bar-Gadda , Sabato Miseo
IPC分类号： B01J23/80 , B01J23/889 , C07C1/04 , B01J21/00 , B01J23/24
CPC分类号： C07C1/044 , B01J23/80 , B01J23/889 , C07C1/0445 , C07C2521/06 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/34 , C07C2523/745 , C07C2523/83 , C07C2523/889 , Y10S502/524
摘要： New Fischer-Tropsch catalysts containing a Lanthanide Group element, such as cerium, exhibit improved activity over conventional catalysts and exhibit a reversal in the olefin/paraffin ratio of low molecular weight hydrocarbons. The catalyst comprises:(a) a Group VIII metal oxide;(b) a Group IIB metal oxide;(c) a Group IVB and/or VIIB metal oxide;(d) a Group IA metal oxide; and,(e) a Lanthanide group metal oxide.
摘要翻译：含有镧系元素元素（如铈）的新的费 - 托催化剂显示出比常规催化剂更好的活性，并表现出低分子量烃的烯烃/石蜡比例的逆转。催化剂包括：（a）第Ⅷ族金属氧化物; （b）IIB族金属氧化物; （c）IVB族和/或VIIB族金属氧化物; （d）IA族金属氧化物; 和（e）镧系元素金属氧化物。

14. 发明授权

US4624968A Multi-stage Fischer-Tropsch process 失效
标题翻译：多级费 - 托法
公开(公告)号：US4624968A
公开(公告)日：1986-11-25
申请号：US814402
申请日：1985-12-30
申请人： Chang J. Kim , Rocco A. Fiato
发明人： Chang J. Kim , Rocco A. Fiato
IPC分类号： C07C1/04 , C07C2/00 , C07C9/00 , C07C1/02
CPC分类号： C10G2/331 , C07C1/044 , C07C1/0485 , C07C2/00 , C07C9/00 , C10G2/33 , C10G2/332 , C10G2/333 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/34 , C07C2523/745 , C07C2523/75 , C07C2523/78 , C07C2523/83 , C07C2523/889
摘要： A multi-stage catalyst system is disclosed for the production of waxes in a Fischer-Tropsch process while producing relatively low quantities of methane. A first catalyst converts CO and H.sub.2 into olefins, while a second catalyst converts the olefin, additional hydrogen and CO into higher molecular weight paraffin.
摘要翻译：公开了一种多阶段催化剂体系，用于在费 - 托方法中生产蜡，同时产生相对低量的甲烷。第一催化剂将CO和H 2转化为烯烃，而第二催化剂将烯烃，另外的氢和CO转化成更高分子量的链烷烃。

15. 发明授权

US4595703A Preparation of hydrocarbons from synthesis gas 失效
标题翻译：从合成气中制备碳氢化合物
公开(公告)号：US4595703A
公开(公告)日：1986-06-17
申请号：US626023
申请日：1984-06-29
申请人： Virgil L. Payne , Charles H. Mauldin
发明人： Virgil L. Payne , Charles H. Mauldin
IPC分类号： B01J23/75 , B01J23/83 , C07C1/04
CPC分类号： B01J23/75 , B01J23/83 , C07C1/0435 , C07C2521/06 , C07C2523/12 , C07C2523/75 , C07C2523/83 , Y10S208/95
摘要： A process wherein an admixture of carbon monoxide and hydrogen is contacted over a cobalt catalyst, especially a thoria promoted cobalt catalyst, formed by dispersing the cobalt, or cobalt and thoria, upon a titania or titania-containing support wherein the titania support is one having a rutile:anatase ratio of at least about 2:3, and preferably at least about 3:2 to produce, at reaction conditions, a distillate fuel constituted principally of an admixture of linear paraffin and olefins, particularly a C.sub.10 + distillate which can be further refined and upgraded to high quality fuels, and other products such as mogas, diesel fuel, jet fuel, lubes and specialty solvents, particularly premium middle distillate fuels of carbon numbers ranging from about C.sub.10 to about C.sub.20.
摘要翻译：一种方法，其中将一氧化碳和氢气的混合物与钴催化剂，特别是通过将钴或钴和氧化钍分散而形成的氧化钍促进的钴催化剂接触在二氧化钛或二氧化钛载体上，其中二氧化钛载体是具有金红石：锐钛矿比率为至少约2:3，优选至少约3:2，以在反应条件下产生主要由线型石蜡和烯烃，特别是C10 +馏出物的混合物构成的馏出物燃料，其可以进一步精炼和升级为高质量燃料，以及其他产品，如摩尔卡，柴油，喷气燃料，润滑剂和特种溶剂，特别是碳数为约C10至约C20的优质中间馏分燃料。

16. 发明授权

US2517036A Supported catalysts for the conversion of carbon-monoxide-containing reactants 失效
标题翻译：用于转化一氧化碳的反应物的负载型催化剂
公开(公告)号：US2517036A
公开(公告)日：1950-08-01
申请号：US75402647
申请日：1947-06-11
申请人： TEXAS CO
发明人： SENSEL EUGENE E , STEWART MEREDITH M
IPC分类号： B01J23/83 , C07C1/04 , C07C29/156
CPC分类号： B01J23/83 , C07C1/0435 , C07C29/156 , C07C2521/12 , C07C2521/16 , C07C2523/12 , C07C2523/75 , C07C2523/83 , C07C31/02

17. 再颁专利

USRE23145E Two-stage synthesis of 失效
公开(公告)号：USRE23145E
公开(公告)日：1949-09-06
申请号：US23145D
IPC分类号： C07C1/04
CPC分类号： C07C1/0485 , C07C2521/08 , C07C2523/12 , C07C2523/75 , C07C2523/83

18. 发明授权

US2286814A Manufacture of motor fuel 失效
标题翻译：制造汽油
公开(公告)号：US2286814A
公开(公告)日：1942-06-16
申请号：US30173939
申请日：1939-10-28
申请人： TEXAS CO
发明人： KEMP LEBBEUS C
IPC分类号： C07C1/04 , C10G2/00
CPC分类号： C07C1/0485 , C07C2521/08 , C07C2521/10 , C07C2523/12 , C07C2523/75 , C07C2523/83 , C10G2/00 , Y10S208/95

20. 发明授权

US09617196B2 Catalyst for methanation of carbon oxides, preparation method of the catalyst and process for the methanation 有权
公开(公告)号：US09617196B2
公开(公告)日：2017-04-11
申请号：US12184493
申请日：2008-08-01
申请人： Koji Hashimoto , Hiroyuki Takano , Kouichi Izumiya , Naokazu Kumagai , Zenta Kato , Hiroyuki Shinomiya
发明人： Koji Hashimoto , Hiroyuki Takano , Kouichi Izumiya , Naokazu Kumagai , Zenta Kato , Hiroyuki Shinomiya
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , C07C1/04 , B01J23/78 , B01J23/83 , B01J37/02 , C07C1/12 , C10G2/00 , C10L3/08
CPC分类号： C07C1/12 , B01J23/002 , B01J23/78 , B01J23/83 , B01J37/0236 , B01J37/04 , B01J37/08 , B01J2523/00 , C07C1/0435 , C07C1/044 , C07C2521/06 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/78 , C07C2523/83 , C10G2/332 , C10L3/08 , Y02P20/52 , C07C9/04 , B01J2523/23 , B01J2523/3706 , B01J2523/3737 , B01J2523/48 , B01J2523/847 , B01J2523/842 , B01J2523/3718 , B01J2523/845 , B01J2523/3762 , B01J2523/3725 , B01J2523/36 , B01J2523/22 , B01J2523/3712 , B01J2523/375
摘要： Disclosed is a catalyst for methanation reaction producing methane with high conversion by reaction of hydrogen with carbon dioxide, or a gas mixture of carbon dioxide and carbon monoxide, or a gas mixture containing these compounds as the main components. The catalyst is prepared by the steps of mixing (A) aqueous zirconia sol with salts of (B) stabilizing element(s), which is selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Ca and Mg, and (C) iron group element(s), drying and calcining the mixture to obtain a catalyst precursor, and subsequent reduction of the precursor. The catalyst comprises, by atomic %, A: 18-70%, B: 1-20% and C: 25-80% based on the elemental states of the metals. The catalyst is characterized by multiple oxide of tetragonal zirconia structure, in which not only the stabilizing element(s) but also a part of the iron group element(s) is incorporated, and on which the iron group element(s) in the metallic state is supported.

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