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1. 发明申请

US20130137908A1 PROCESS FOR DEHYDRATION AND ISOMERIZATION OF C4 ALCOHOLS USING AN AMORPHOUS SOLID WITH SUITABLE POROSITY 有权
标题翻译：使用具有适当孔隙率的无定形固体的C4酒精的脱水和异构化方法
公开(公告)号：US20130137908A1
公开(公告)日：2013-05-30
申请号：US13703107
申请日：2011-05-27
申请人： Vincent Coupard , Sylvie Maury , Karine Surla
发明人： Vincent Coupard , Sylvie Maury , Karine Surla
IPC分类号： B01J21/04 , C07C1/24
CPC分类号： B01J21/04 , C07C1/24 , C07C5/2772 , C07C5/2775 , C07C11/08 , C07C11/09 , C07C2521/04 , C07C2521/06 , C07C2523/04 , C07C2523/06 , C07C2523/20 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/30
摘要： The present invention relates to a method of producing C4 olefins, from a feed of C4 monohydric alcohol, in which a reaction of dehydration of the monohydric alcohol to at least one olefin, and a reaction of skeletal isomerization of at least one of the olefins produced in one and the same reaction vessel, are carried out in the presence of an alumina-based catalyst with adapted porosity.
摘要翻译：本发明涉及从一元醇的进料中生产C4烯烃的方法，其中一元醇与至少一种烯烃的脱水反应和至少一种烯烃的骨架异构化的反应在同一反应容器中，在具有适应孔隙率的氧化铝基催化剂的存在下进行。

2. 发明授权

US07304199B2 Solid acid catalyst and method of using same 有权
标题翻译：固体酸催化剂及其使用方法
公开(公告)号：US07304199B2
公开(公告)日：2007-12-04
申请号：US10824390
申请日：2004-04-14
申请人： Jinsuo Xu , Chuen Y. Yeh , Philip J. Angevine
发明人： Jinsuo Xu , Chuen Y. Yeh , Philip J. Angevine
IPC分类号： C07C5/22 , C07C6/08 , C07C2/58 , C01G11/00 , B01J27/053
CPC分类号： B01J23/6527 , B01J21/063 , B01J21/066 , B01J23/24 , B01J23/30 , B01J23/652 , B01J27/053 , B01J27/057 , B01J37/0009 , B01J37/08 , C07C5/2772 , C07C2523/652 , C10G45/60 , C10G45/62 , C10G47/02 , C10G49/04 , C10G2300/1081 , C10G2300/4018 , C07C9/00
摘要： A catalyst composition includes an oxygen compound of an element selected from Group IVB or Group IVA of the Periodic Table of the Elements; an oxygen compound of an element selected from Group VIB or Group VIA of the Periodic Table of the Elements; and at least about 1% by weight based upon total catalyst weight of fumed silica particles. The catalyst composition is advantageously employed in hydrocarbon conversion processes such as isomerization.
摘要翻译：催化剂组合物包括选自元素周期表的IVB族或IVA族元素的元素的氧化合物; 选自元素周期表的VIB族或VIA族的元素的氧化合物; 和基于热解二氧化硅颗粒的总催化剂重量的至少约1重量％。催化剂组合物有利地用于烃转化过程如异构化。

3. 发明授权

US5811630A PSA process with reaction for reversible reactions 失效
标题翻译： PSA方法与可逆反应有反应
公开(公告)号：US5811630A
公开(公告)日：1998-09-22
申请号：US638705
申请日：1996-04-29
申请人： Hemant W. Dandekar , Gregory A. Funk
发明人： Hemant W. Dandekar , Gregory A. Funk
IPC分类号： C07C5/27 , C07C7/13 , C07C29/151 , C07C29/152 , C07C5/22 , B01D53/047 , C07C7/12 , C07C9/14
CPC分类号： C07C5/2772 , C07C5/2789 , C07C5/2791 , C07C7/13 , C12C11/02 , C07C2521/04 , C07C2521/06 , C07C2523/42 , C07C2527/126 , C07C2529/22
摘要： A process is disclosed for the production of a high octane product from a feed mixture comprising C.sub.5 -C.sub.6 normal paraffins in which an equilibrium reaction to produce mono and dimethyl branched paraffins is achieved by conducting the reaction and the product separation in a pressure swing adsorption and reaction zone containing a uniformly distributed adsorbent for the selective adsorption of normal paraffins and a catalyst for the equilibrium conversion of normal paraffins to mono and dimethyl branched paraffins. More specifically, the process achieves the isomerization of the normal paraffins by the reaction of the normal paraffins in the presence of hydrogen with the simultaneous removal of the mono and dimethyl branched paraffin product at the same temperature and pressure. In one embodiment, the passing of the feed mixture to the bed is terminated and the bed is purged with one of the reactants which in turn further reacts to displace heavier paraffin and enhance the overall product octane. The advantage of the present invention over the conventional process is the higher octane of the product produced and that this higher octane can be achieved at lower severity since the product is removed from the reaction zone as soon as it is produced. The lower operating severity provides longer catalyst life, and reduces the amount of heavy paraffins lost to side reactions such as cracking.
摘要翻译：公开了一种从包含C5-C6正构链烷烃的进料混合物生产高辛烷值产物的方法，其中通过在变压吸附中进行反应和产物分离来实现产生单和二甲基支链烷烃的平衡反应，反应区含有均匀分布的吸附剂，用于选择性吸附正构烷烃和用于将正链烷烃平衡转化为单和二甲基支链烷烃的催化剂。更具体地，该方法通过正链烷烃在氢气存在下的反应，同时在相同的温度和压力下同时除去单支和二甲基支链的石蜡产物，来实现正链烷烃的异构化。在一个实施方案中，将进料混合物通入床中止，并且用一种反应物吹扫床，反应物又进一步反应以置换较重的石蜡并增强总产物辛烷值。本发明优于常规方法的优点是所生产的产物中较高的辛烷值，并且可以在较低的苛刻度下实现更高的辛烷值，因为一旦生产产物就从反应区域中除去。较低的操作苛刻度提供更长的催化剂寿命，并且减少了副反应（例如开裂）所损失的重链烷烃的量。

4. 发明授权

US5659104A Olefin isomerisation process 失效
标题翻译：烯烃异构化过程
公开(公告)号：US5659104A
公开(公告)日：1997-08-19
申请号：US537924
申请日：1996-01-22
申请人： Christine Travers , Jean-Pierre Burzynski , Albert Chaillard
发明人： Christine Travers , Jean-Pierre Burzynski , Albert Chaillard
IPC分类号： B01J21/04 , B01J21/06 , B01J32/00 , C07C5/27 , C07C11/02 , C07C11/09 , C07C11/10 , C07C5/22
CPC分类号： B01J21/063 , C07C5/2772 , C07C2521/02 , C07C2521/04 , C07C2521/06
摘要： The invention concerns an isomerisation process for n-olefins containing at most 20 carbon atoms, consisting of bringing a feed containing the olefins into contact with an alumina based catalyst impregnated with 0.03% to 0.6% by weight of titanium and 0.05% to 5% by weight of an oxide of an element from group IIIA. The process can then be carried out in the presence of a small quantity of steam or it can be carried out in the absence of steam.
摘要翻译： PCT No.PCT / FR95 / 00190 Sec。 371日期1996年1月22日 102（e）日期1996年1月22日PCT提交1995年2月17日PCT公布。出版物WO95 / 23777 日期1995年9月8日本发明涉及含有至多20个碳原子的正烯烃的异构化方法，其包括使含有烯烃的进料与浸渍有0.03重量％至0.6重量％钛和0.05重量％的氧化铝基催化剂接触％至5重量％的IIIA族元素的氧化物。该方法然后可以在少量蒸汽的存在下进行，或者可以在没有蒸汽的情况下进行。

5. 发明授权

US5510309A Method for preparing a modified solid oxide 失效
标题翻译：制备改性固体氧化物的方法
公开(公告)号：US5510309A
公开(公告)日：1996-04-23
申请号：US236073
申请日：1994-05-02
申请人： Clarence D. Chang , Charles T. Kresge , Jose G. Santiesteban , James C. Vartuli
发明人： Clarence D. Chang , Charles T. Kresge , Jose G. Santiesteban , James C. Vartuli
IPC分类号： B01J23/30 , B01J21/06 , B01J23/882 , B01J23/888 , B01J37/03 , B01J37/08 , C07B61/00 , C07C2/58 , C07C5/27 , C07C9/14 , C10G50/00
CPC分类号： B01J23/30 , B01J23/882 , B01J23/888 , C07C2/58 , C07C5/2772 , C10G50/00 , B01J37/03 , C07C2521/06 , C07C2523/30
摘要： There is provided a method for preparing an acidic solid comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. An example of this acidic solid is zirconia, modified with tungstate. This modified solid oxide may be used as a catalyst, for example, to isomerize C.sub.4 to C.sub.8 paraffins. The modified solid oxide is prepared by co-precipitating the Group IVB metal oxide along with the oxyanion of the Group VIB metal.
摘要翻译：提供了一种制备酸性固体的方法，该酸性固体包含用VIB族金属的氧阴离子改性的ⅣB族金属氧化物。这种酸性固体的一个例子是用钨酸盐改性的氧化锆。该改性的固体氧化物可以用作催化剂，例如使C4至C8链烷烃异构化。通过将IVB族金属氧化物与VIB族金属的氧阴离子共沉淀来制备改性的固体氧化物。

6. 发明授权

US4827075A Catalysts 失效
标题翻译：催化剂
公开(公告)号：US4827075A
公开(公告)日：1989-05-02
申请号：US208094
申请日：1988-06-17
申请人： Bruce G. Baker , Neville J. Clark , Hamish McArthur , Edward Summerville
发明人： Bruce G. Baker , Neville J. Clark , Hamish McArthur , Edward Summerville
IPC分类号： B01J21/04 , B01J23/30 , B01J23/83 , B01J23/888 , B01J37/02 , B01J37/08 , C07C1/04 , C07C5/27 , C07C5/22
CPC分类号： C07C1/0445 , B01J21/04 , B01J23/30 , B01J23/83 , B01J23/888 , B01J37/0207 , B01J37/08 , C07C1/044 , C07C5/2772 , C07C2521/04 , C07C2523/10 , C07C2523/30 , C07C2523/745 , C07C2523/83
摘要： A method of forming a support for use with a primary catalyst for conversion of a feed stream comprising carbon monoxide and hydrogen into hydrocarbons is disclosed.A primary catalyst and a method of manufacturing the catalyst is also disclosed.Furthermore, a secondary catalyst for the production of branched chain alkenes from straight chain alkenes is also disclosed, together with methods of manufacturing the secondary catalyst.
摘要翻译：公开了形成用于将包含一氧化碳和氢气的进料流转化为烃的初级催化剂的载体的方法。还公开了主催化剂和制造催化剂的方法。此外，还公开了用于从直链烯烃生产支链烯烃的二次催化剂以及制备二次催化剂的方法。

7. 发明授权

US4666880A Catalysts 失效
标题翻译：催化剂
公开(公告)号：US4666880A
公开(公告)日：1987-05-19
申请号：US831553
申请日：1986-02-20
申请人： Bruce G. Baker , Neville J. Clark , Hamish McArthur , Edward Summerville
发明人： Bruce G. Baker , Neville J. Clark , Hamish McArthur , Edward Summerville
IPC分类号： B01J21/04 , B01J23/30 , B01J23/83 , B01J23/888 , B01J37/02 , B01J37/08 , C07C1/04 , C07C5/27 , B01J23/10 , B01J23/76
CPC分类号： C07C1/0445 , B01J21/04 , B01J23/30 , B01J23/83 , B01J23/888 , B01J37/0207 , B01J37/08 , C07C1/044 , C07C5/2772 , C07C2521/04 , C07C2523/10 , C07C2523/30 , C07C2523/745 , C07C2523/83
摘要： A method of forming a support for use with a primary catalyst for conversion of a feed stream comprising carbon monoxide and hydrogen into hydrocarbons is disclosed.A primary catalyst and a method of manufacturing the catalyst is also disclosed.Furthermore, a secondary catalyst for the production of branched chain alkenes from straight chain alkenes is also disclosed, together with methods of manufacturing the secondary catalyst.

8. 发明授权

US3730958A Skeletal isomerization of olefins over halogen-containing zirconia catalyst 失效
标题翻译：通过含卤素的ZIRCONIA催化剂的烯烃的骨架异构化
公开(公告)号：US3730958A
公开(公告)日：1973-05-01
申请号：US3730958D
申请日：1972-02-22
申请人： PHILLIPS PETROLEUM CO
发明人： MYERS J
IPC分类号： B01J27/06 , C07C5/27 , C07C5/22 , C07C5/24
CPC分类号： B01J27/06 , C07C5/2772 , C07C11/02
摘要： Olefins undergo skeletal isomerization by contact with a catalyst containing a zirconium compound and a halogen.
摘要翻译：烯烃通过与含有锆化合物和卤素的催化剂接触进行骨架异构化。

9. 发明授权

US3538173A C8-alkylaromatic isomerization process 失效
公开(公告)号：US3538173A
公开(公告)日：1970-11-03
申请号：US3538173D
申请日：1969-05-05
申请人： UNIVERSAL OIL PROD CO
发明人： BERGER CHARLES V , DONALDSON GEORGE R
IPC分类号： C07C5/27 , C07C5/24
CPC分类号： C07C5/2772 , C07C5/2791 , Y02P20/582 , Y10S585/901 , C07C15/08

10. 发明授权

US3531542A Olefin isomerization process 失效
标题翻译： OLEFIN异构化过程
公开(公告)号：US3531542A
公开(公告)日：1970-09-29
申请号：US3531542D
申请日：1968-09-04
申请人： PHILLIPS PETROLEUM CO
发明人： MYERS JOHN W , DOANE ELLIOTT P
IPC分类号： C07C5/27 , C07C11/09 , C07C5/22
CPC分类号： C07C11/09 , C07C5/2772 , C07C5/2791

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