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    • 9. 发明授权
    • Dehydrogenation and cracking of C.sub.3 and C.sub.4 hydrocarbons
    • C3和C4烃的脱氢和裂解
    • US4620052A
    • 1986-10-28
    • US758936
    • 1985-07-25
    • John H. KoltsGary A. Delzer
    • John H. KoltsGary A. Delzer
    • B01J23/00B01J23/34B01J23/84B01J23/86C07B61/00C07C1/00C07C4/06C07C4/10C07C5/32C07C5/333C07C11/02C07C11/04C07C67/00
    • C07C5/322C07C4/06C07C4/10C07C2521/10C07C2523/02C07C2523/10C07C2523/14C07C2523/18C07C2523/20C07C2523/26C07C2523/34Y02P20/52
    • Novel compositions of matter include: mixed oxides of (a) at least one oxide of chromium, at least one oxide of manganese and at least one oxide of magnesium, Lanthanum Series metals, preferably lanthanum and cerium, and/or niobium; (b) at least one oxide of chromium, at least one oxide of calcium, strontium, tin and/or antimony, at least one oxide of manganese and at least one oxide of magnesium, Lanthanum Series metals and/or niobium; (c) at least one oxide of chromium, at least one oxide of iron and at least one oxide of magnesium, Lanthanum Series metals and/or niobium; and (d) at least one oxide of chromium, at least one oxide of iron, at least one oxide of manganese and at least one oxide of magnesium, Lanthanum Series metals and/or niobium. These compositions are particularly effective as catalyst compositions for the conversion of C.sub.3 and C.sub.4 hydrocarbons to less saturated hydrocarbons, with high selectivities to ethylene and ethane and particularly ethylene, and the addition of the chromium significantly extends the activity of the catalyst for such selective conversion before regeneration is necessary. A method of converting C.sub.3 and C.sub.4 hydrocarbons to less saturated hydrocarbons, and selectively to ethylene and ethane and particularly ethylene, is also disclosed. Carrying out the process in the presence of steam is essential to the process when the catalyst contains iron and is optional when the catalyst does not contain iron. Limiting the amount of bound or fixed sulfur in the catalyst also improves the catalyst.
    • 物质的新组合物包括:(a)至少一种铬的氧化​​物,至少一种锰的氧化物和至少一种镁的氧化物,镧系金属,优选镧和铈和/或铌的混合氧化物; (b)至少一种铬的氧化​​物,钙,锶,锡和/或锑的至少一种氧化物,至少一种锰的氧化物和至少一种镁,镧系金属和/或铌的氧化物; (c)至少一种铬的氧化​​物,至少一种铁的氧化物和至少一种镁的氧化物,镧系金属和/或铌; 和(d)至少一种铬的氧化​​物,至少一种铁的氧化物,至少一种锰的氧化物和至少一种镁的氧化物,镧系金属和/或铌。 这些组合物作为用于将C3和C4烃转化为较少饱和烃的催化剂组合物是特别有效的,对乙烯和乙烷特别是乙烯具有高选择性,并且加入铬显着延长了催化剂在这种选择性转化之前的活性 再生是必要的。 还公开了将C3和C4烃转化为较少饱和烃,并选择性地转化成乙烯和乙烷,特别是乙烯的方法。 当催化剂含有铁时,在蒸汽存在下进行该过程是必不可少的,当催化剂不含铁时是必需的。 限制催化剂中结合或固定硫的量也可改善催化剂。