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    • 15. 发明授权
    • Exhaust gas purification device for an internal combustion engine
    • 内燃机用废气净化装置
    • US6109024A
    • 2000-08-29
    • US75358
    • 1998-05-08
    • Yukio KinugasaTakaaki ItouKoichi Takeuchi
    • Yukio KinugasaTakaaki ItouKoichi Takeuchi
    • F01N3/08B01D53/86B01D53/94F01N3/24F01N3/28F01N13/02F01N13/04F02B75/12F02D41/02F02D41/40F01N3/00
    • F01N3/0842F01N13/009F01N13/011F01N3/101F02D41/0275F02D41/405F01N2900/0418F02B2075/125F02D2041/389Y02T10/123Y02T10/22Y02T10/44
    • In an exhaust gas purification device, a three-way catalyst, an NO.sub.x absorbing-reducing catalyst and an NH.sub.3 adsorbing-denitrating catalyst are disposed in an exhaust gas passage of the internal combustion engine. The engine is provided with direct cylinder injection valves which inject fuel directly into the respective cylinders. A control circuit controls the amount of fuel injected from the injection valve so that the air-fuel ratio of the combustion in the cylinders becomes a lean air-fuel ratio during the normal operation of the engine. Therefore, a lean air-fuel ratio exhaust gas is discharged from the cylinders during the normal operation and NO.sub.x, in the exhaust gas is absorbed by the NO.sub.x absorbing-reducing catalyst. When the amount of NO.sub.x absorbed in the NO.sub.x absorbing-reducing catalyst increases to a predetermined level, the control circuit performs an additional fuel injection during the expansion stroke or exhaust stroke of cylinders in order to adjust the air-fuel ratio of the exhaust gas leaving the cylinders to a rich air-fuel ratio. The rich air-fuel ratio exhaust gas leaving the cylinders flows into the three-way catalyst and NO.sub.x in the exhaust gas is converted into NH.sub.3 at the three-way catalyst. When the rich air-fuel ratio exhaust gas flows through the NO.sub.x absorbing-reducing catalyst, NO.sub.x is released from the NO.sub.x absorbing-reducing catalyst and is reduced to N.sub.2 by NH.sub.3 in the exhaust gas.
    • 在排气净化装置中,在内燃机的废气通道中设置三元催化剂,NOx吸收还原催化剂和NH 3吸附脱硝催化剂。 发动机配有直接气缸喷射阀,其将燃料直接喷射到相应的气缸中。 控制电路控制从喷射阀喷射的燃料量,使得在发动机的正常运行期间气缸中的燃烧空燃比变为稀空燃比。 因此,在正常操作期间,从空气中排出贫空燃比废气,并且排气中的NOx被NOx吸收还原催化剂吸收。 当NOx吸收还原催化剂吸收的NOx的量增加到预定水平时,控制电路在气缸的膨胀冲程或排气冲程期间执行额外的燃料喷射,以便调节离开废气的空燃比 气缸以较高的空燃比。 离开气缸的富空燃比废气流入三元催化剂,废气中的NOx在三元催化剂下转化为NH3。 当富空燃比废气流过NOx吸收还原催化剂时,NOx从NOx吸收还原催化剂释放,并通过排气中的NH 3还原为N2。
    • 19. 发明授权
    • Method and a device for purifying combustion exhaust gas
    • 燃烧废气净化方法和装置
    • US5778667A
    • 1998-07-14
    • US876608
    • 1997-06-16
    • Yukio KinugasaTakaaki ItouNaoto Suzuki
    • Yukio KinugasaTakaaki ItouNaoto Suzuki
    • B01D53/94F01N3/08F01N3/20F01N3/24F01N9/00F01N13/02F01N13/04F02D41/14F01N3/36
    • F01N3/2073B01D53/9481B01D53/9495F01N13/009F01N13/011F01N3/0842F01N3/0871F01N3/2053F01N9/00B01D2251/2062B01D53/9418B01D53/945F01N2240/25F01N2250/12F01N2610/02Y02T10/22Y02T10/24Y02T10/47
    • In the present invention, the No. 1 cylinder of an engine is connected to a first exhaust passage and the No. 2 to No. 4 cylinders are connected to a second exhaust passage. A three-way catalyst and a NO.sub.X absorbent are disposed in the first and second exhaust passage, respectively. A denitrating catalyst is disposed in a common exhaust passage to which the first and second exhaust passage merge. The NO.sub.X absorbent absorbs NO.sub.X when the No. 2 to No. 4 cylinders are operated at a lean air-fuel ratio, and is regenerated, i.e., releases and reduces the absorbed NO.sub.X when the No. 2 to No. 4 cylinders are operated at a rich air-fuel ratio. However, NO.sub.X, without being reduced, is released from the NO.sub.X absorbent during a short period at the beginning of the regenerating operation. In the present invention, the No. 1 cylinder is operated at a rich air-fuel ratio during the short period at the beginning of the regenerating operation in order to produce NH.sub.3 at the three-way catalyst. Therefore, when NO.sub.X without being reduced is released from the NO.sub.X absorbent and flows into the denitrating catalyst on the common exhaust passage, NH.sub.3 produced at the three-way catalyst is also supplied to the denitrating catalyst. Thus, NO.sub.X released from the NO.sub.X absorbent at the beginning of the regenerating operation is reduced at the denitrating catalyst by NH.sub.3 produced at the three-way catalyst.
    • 在本发明中,发动机的1号缸与第一排气通路连接,第2〜4缸与第2排气通路连接。 分别在第一和第二排气通道中设置三元催化剂和NOX吸收剂。 脱气催化剂设置在第一和第二排气通道合流的公共排气通道中。 当2号至4号气缸以稀薄的空燃比运行时,NOX吸收剂吸收NOX,并且再生时,即当第2号至第4号气缸运行时释放并减少吸收的NOX 丰富的空燃比。 然而,在再生操作开始时的短时间内,NOX不被还原,从NOX吸收剂中释放出来。 在本发明中,为了在三元催化剂下生成NH 3,在再生运转开始的短时间内,1号气缸以浓空燃比运转。 因此,当没有还原的NO x从NOX吸收剂中释放并流入共用排气通道的脱硝催化剂时,在三元催化剂上生成的NH 3也被供给到脱硝催化剂。 因此,在再生操作开始时从NOX吸收剂释放的NOX在脱氮催化剂下通过在三元催化剂下产生的NH 3而降低。