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    • 2. 发明授权
    • Exhaust gas purification device for an engine
    • 发动机废气净化装置
    • US5746052A
    • 1998-05-05
    • US525892
    • 1995-09-08
    • Yukio KinugasaKouhei IgarashiTakaaki ItouTakehisa YaegashiToshifumi Takaoka
    • Yukio KinugasaKouhei IgarashiTakaaki ItouTakehisa YaegashiToshifumi Takaoka
    • B01D53/94F01N3/20F01N3/22F01N3/24F01N13/02F01N13/04F02D41/04
    • B01D53/9454B01D53/9431B01D53/9477B01D53/9495F01N13/009F01N13/011F01N3/20F01N3/206F01N2240/25F01N2570/14F01N2610/02Y02T10/22
    • In the present invention, the exhaust gas from the engine is divided into a first and a second branch exhaust passages after it passes through a three-way reducing and oxidizing catalyst, and the two branch exhaust passages merge into an exhaust gas outlet passage. In the first branch exhaust passage, an oxidizing catalyst is disposed, and in the exhaust gas outlet passage, a denitrating and oxidizing catalyst is disposed. NO.sub.x in the exhaust gas from the engine is all converted to N.sub.2 and NH.sub.3 by the three-way reducing and oxidizing catalyst and a part of the NH.sub.3 generated by the three-way catalyst flows into the first branch exhaust passage and is converted to NO.sub.x again by the oxidizing catalyst. The amount of NO.sub.x produced by the oxidizing catalyst and the amount of NO.sub.x flowing through the second branch exhaust passage is determined by the flow distribution ratio of the first and the second branch exhaust passages. In this invention, the flow ratio is determined in such a manner that the amount of the NO.sub.x produced by the oxidizing catalyst and the amount of the NH.sub.3 passing through the second branch exhaust passage are stoichiometric to produce N.sub.2 and H.sub.2 O. Therefore, when these exhaust gases flow into the denitrating and oxidizing catalyst after they mix with each other in the exhaust gas outlet passage, all the NO.sub.x and the NH.sub.3 are converted to N.sub.2 and H.sub.2 O by the denitrating and oxidizing catalyst without producing any surplus NO.sub.x or NH.sub.3.
    • 在本发明中,来自发动机的废气在通过三通还原氧化催化剂后被分成第一和第二分支排气通道,两个分支排气通道合流到废气出口通道中。 在第一分支排气通道中设置氧化催化剂,并且在排气出口通道中设置脱硝和氧化催化剂。 来自发动机的废气中的NOx通过三元还原氧化催化剂全部转化为N 2和NH 3,并且由三元催化剂产生的一部分NH 3流入第一分支排气通道并再次转化为NOx 通过氧化催化剂。 由氧化催化剂产生的NOx的量和流过第二分支排气通道的NOx的量由第一和第二分支排气通道的流量分配比确定。 在本发明中,流量比以如下方式确定:氧化催化剂产生的NOx的量和通过第二分支排气通道的NH 3的量是化学计量的,以产生N 2和H 2 O. 因此,当这些废气在废气出口通道中彼此混合后流入脱硝和氧化催化剂时,所有的NOx和NH 3都被脱硝和氧化催化剂转化为N 2和H 2 O,而不产生任何剩余的NOx或 NH3。
    • 5. 发明授权
    • Exhaust gas purification device for an internal combustion engine
    • 内燃机用废气净化装置
    • US6109024A
    • 2000-08-29
    • US75358
    • 1998-05-08
    • Yukio KinugasaTakaaki ItouKoichi Takeuchi
    • Yukio KinugasaTakaaki ItouKoichi Takeuchi
    • F01N3/08B01D53/86B01D53/94F01N3/24F01N3/28F01N13/02F01N13/04F02B75/12F02D41/02F02D41/40F01N3/00
    • F01N3/0842F01N13/009F01N13/011F01N3/101F02D41/0275F02D41/405F01N2900/0418F02B2075/125F02D2041/389Y02T10/123Y02T10/22Y02T10/44
    • In an exhaust gas purification device, a three-way catalyst, an NO.sub.x absorbing-reducing catalyst and an NH.sub.3 adsorbing-denitrating catalyst are disposed in an exhaust gas passage of the internal combustion engine. The engine is provided with direct cylinder injection valves which inject fuel directly into the respective cylinders. A control circuit controls the amount of fuel injected from the injection valve so that the air-fuel ratio of the combustion in the cylinders becomes a lean air-fuel ratio during the normal operation of the engine. Therefore, a lean air-fuel ratio exhaust gas is discharged from the cylinders during the normal operation and NO.sub.x, in the exhaust gas is absorbed by the NO.sub.x absorbing-reducing catalyst. When the amount of NO.sub.x absorbed in the NO.sub.x absorbing-reducing catalyst increases to a predetermined level, the control circuit performs an additional fuel injection during the expansion stroke or exhaust stroke of cylinders in order to adjust the air-fuel ratio of the exhaust gas leaving the cylinders to a rich air-fuel ratio. The rich air-fuel ratio exhaust gas leaving the cylinders flows into the three-way catalyst and NO.sub.x in the exhaust gas is converted into NH.sub.3 at the three-way catalyst. When the rich air-fuel ratio exhaust gas flows through the NO.sub.x absorbing-reducing catalyst, NO.sub.x is released from the NO.sub.x absorbing-reducing catalyst and is reduced to N.sub.2 by NH.sub.3 in the exhaust gas.
    • 在排气净化装置中,在内燃机的废气通道中设置三元催化剂,NOx吸收还原催化剂和NH 3吸附脱硝催化剂。 发动机配有直接气缸喷射阀,其将燃料直接喷射到相应的气缸中。 控制电路控制从喷射阀喷射的燃料量,使得在发动机的正常运行期间气缸中的燃烧空燃比变为稀空燃比。 因此,在正常操作期间,从空气中排出贫空燃比废气,并且排气中的NOx被NOx吸收还原催化剂吸收。 当NOx吸收还原催化剂吸收的NOx的量增加到预定水平时,控制电路在气缸的膨胀冲程或排气冲程期间执行额外的燃料喷射,以便调节离开废气的空燃比 气缸以较高的空燃比。 离开气缸的富空燃比废气流入三元催化剂,废气中的NOx在三元催化剂下转化为NH3。 当富空燃比废气流过NOx吸收还原催化剂时,NOx从NOx吸收还原催化剂释放,并通过排气中的NH 3还原为N2。