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    • 12. 发明授权
    • Aminoplast curable coating compositions containing sulfonic acid esters
as latent acid catalysts
    • 含有磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物
    • US4477618A
    • 1984-10-16
    • US427402
    • 1982-09-29
    • Debra L. SingerGregory J. McCollumRostyslaw DowbenkoRoger M. ChristensonMichael M. ChauWen-Hsuan Chang
    • Debra L. SingerGregory J. McCollumRostyslaw DowbenkoRoger M. ChristensonMichael M. ChauWen-Hsuan Chang
    • C08F8/36C08K5/42C09D161/20
    • C07C309/00C08K5/42C09D161/20
    • A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.
    • 能够进行酸催化交联的高固体,有机溶剂型可喷涂涂料组合物由含活性氢的树脂,在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成,以及 催化量的磺酸的非离子酯。 磺酸酯由以下结构式表示:其中:Z是选自氨基和有机基团的基团,所述有机基团通过碳原子连接到硫原子上; C3-C20环烷基; 并且R 1,R 2,R 3,R 4,R 5独立地为氢或有机基团。 这些基团可以特别描述如下:R 1是氢,烷氧羰基,C 3 -C 20烷基,C 6 -C 18芳基或C 3 -C 20环烷基; R2是氢,烷氧羰基,C3-C20烷基,C6-C18芳基或C3-C20环烷基; R3是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3-C20烷基,C6-C18芳基或C3-C20环烷基; R4是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3-C20烷基,C6-C18芳基或C3-C20环烷基,R5是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3 -C 20烷基,C 6 -C 18芳基或C 3 -C 20环烷基。
    • 18. 发明授权
    • Water-reduced urethane coating compositions
    • 减水氨酯涂料组合物
    • US4147679A
    • 1979-04-03
    • US853780
    • 1977-11-21
    • Roger L. ScrivenWen-Hsuan Chang
    • Roger L. ScrivenWen-Hsuan Chang
    • C08G18/08C08G18/10C09D175/04C08L75/12
    • C09D175/04C08G18/0804C08G18/0833C08G18/10Y10T428/31678Y10T442/2369
    • A water-diluted, ungelled, non-sedimenting polyurethane and a process for preparing such a polyurethane in an aqueous medium is disclosed. High molecular weight thermoplastic products are obtained by chain extending in aqueous medium an NCO polymer having a salt group equivalent weight of 6000 or less and substantially free of reactive hydrogen. The average functionality and equivalent ratio of the polyisocyanate and active hydrogen-containing materials used in making the NCO polymer, as well as the functionality of the chain extender, are carefully controlled so as to get high molecular weight ungelled products. Thermosetting compositions can be made by adding curing agent to the chain extended material. Curing agents can also be incorporated into the polymer molecule either in the making of the partially reacted NCO-containing prepolymer or by further reaction with the partially reacted NCO-containing prepolymer. The water-dispersed polyurethanes of the present invention are excellent film formers, capable of making coatings with a wide spectrum of desirable properties. In addition, they can be added to other water-compatible compositions to improve flexibility, hardness, drying and other coating properties.
    • 公开了一种水稀释,未凝胶化,非沉降聚氨酯和在水性介质中制备这种聚氨酯的方法。 通过在水性介质中延伸具有当量为6000以下的盐基团且基本上不含反应性氢的NCO聚合物获得高分子量热塑性产物。 用于制备NCO聚合物的多异氰酸酯和含活性氢的材料的平均官能度和当量比以及扩链剂的官能度被小心地控制,以便获得高分子量的未凝胶产物。 热固性组合物可以通过向扩链材料中加入固化剂来制备。 在制备部分反应的含NCO的预聚物中或通过与部分反应的含NCO的预聚物进一步反应,固化剂也可以掺入聚合物分子中。 本发明的水分散性聚氨酯是优异的成膜剂,能够制备具有广泛期望性能的涂层。 此外,它们可以加入到其他与水相容的组合物中以改善柔韧性,硬度,干燥和其它涂料性能。