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1. 发明授权

US4678835A Coating composition containing an ungelled reaction product as a curative 失效
标题翻译：含有未凝胶化反应产物作为治疗剂的涂料组合物
公开(公告)号：US4678835A
公开(公告)日：1987-07-07
申请号：US824040
申请日：1986-01-30
申请人： Wen-Hsuan Chang , Edward L. Dufford , J. Alden Erikson , Paul J. Prucnal
发明人： Wen-Hsuan Chang , Edward L. Dufford , J. Alden Erikson , Paul J. Prucnal
IPC分类号： C09D7/12 , C07F7/00 , C08G77/54 , C09D183/04 , C09D183/05 , C09D183/14 , C09D201/02 , C08F8/00
CPC分类号： C08G77/54 , C09D183/14
摘要： A coating composition contains at least 15 percent by weight of an ungelled reaction product of:(i) at least 2 percent by weight of an amine having in a molecule thereof at least one amino hydrogen atom, and at least one silicon atom directly bonded to a hydrolyzable group;(ii) at least 4 percent by weight of a material containing at least one epoxide group, at least 30 percent of said material being essentially free of hydroxyl groups; and(iii) a material selected from vinyl alkoxysilanes; nonfunctional organosilanes; organosilicates; and partial hydrolysis products thereof; the percentages by weight being based on the total weight of the resin solids of the coating composition including (i), (ii) and (iii).
摘要翻译：涂料组合物含有至少15重量％的未凝胶化反应产物：（i）至少2重量％的分子中至少有一个氨基氢原子的胺和至少一个直接连接到可水解基团; （ii）至少4重量％的含有至少一个环氧基团的材料，至少30％的所述材料基本上不含羟基; 和（iii）选自乙烯基烷氧基硅烷的材料; 非功能性有机硅烷; 有机硅酸盐及其部分水解产物; 重量百分比基于包括（i），（ii）和（iii）的涂料组合物的树脂固体的总重量。

2. 发明授权

US4684697A Compositions based on silane hydrolyzates and vinyl polymers containing hydrolyzable silyl groups 失效
标题翻译：基于硅烷水解物和含有可水解甲硅烷基的乙烯基聚合物的组合物
公开(公告)号：US4684697A
公开(公告)日：1987-08-04
申请号：US881434
申请日：1986-07-02
申请人： Wen-Hsuan Chang , William P. Blackburn , Paul J. Prucnal , Edward L. Dufford
发明人： Wen-Hsuan Chang , William P. Blackburn , Paul J. Prucnal , Edward L. Dufford
IPC分类号： C08G77/06 , C09D4/00 , C08F8/00
CPC分类号： C08G77/06 , C09D4/00
摘要： Disclosed are moisture-curable compositions based on (A) ungelled, partial hydrolyzates or organosilicon-containing materials in combination with (B) acrylic addition interpolymers containing hydrolyzable silyl groups.The organosilicon-containing material for preparation of the ungelled partial hydrolysis product has an average functionality based on easily hydrolyzable Y groups attached to silicon atoms of greater than or equal to 2.4 and contains greater than or equal to 10 mole percent of at least one organosilane compound corresponding to the formula R-Si-Y.sub.3. The partial hydrolysis product is prepared using a controlled amount of water.The acrylic addition interpolymer is not particularly limited provided that it contains at least one silicon atom directly bonded to a hydrolyzable group and is compatible with the ungelled partial hydrolysis product.
摘要翻译：公开了基于（A）未凝胶化，部分水解产物或含有机硅材料与（B）含有可水解甲硅烷基的丙烯酸加成互聚物的组合物的可湿固化组合物。用于制备未凝胶化部分水解产物的含有机硅材料具有基于与硅原子连接的容易水解的Y基团大于或等于2.4的平均官能度，并且含有大于或等于10摩尔％的至少一种有机硅烷化合物对应于式R-Si-Y3。使用受控量的水制备部分水解产物。丙烯酸类加成互聚物没有特别限制，只要其含有至少一个直接键合到可水解基团上的硅原子并与未凝胶化的部分水解产物相容即可。

3. 发明授权

US4604443A Partial hydrolyzates containing hydrolyzable moieties from organosilane compounds 失效
标题翻译：部分水解产物含有有机硅烷化合物的可水解部分
公开(公告)号：US4604443A
公开(公告)日：1986-08-05
申请号：US728968
申请日：1985-04-30
申请人： Wen-Hsuan Chang , Edward L. Dufford
发明人： Wen-Hsuan Chang , Edward L. Dufford
IPC分类号： C08G77/00 , C07F7/18 , C08G77/06 , C08G77/14 , C08G77/22 , C09D4/00 , C09D183/04 , C08G77/04
CPC分类号： C08G77/06 , C09D4/00
摘要： Disclosed is an ungelled partial hydrolysis product of an organosilicon-containing material, a method for preparing the partial hydrolysis product, and a composition such as a coating composition containing the partial hydrolysis product. The organosilicon-containing material for preparation of the ungelled partial hydrolysis product has an average functionality based on easily hydrolyzable Y groups attached to silicon atoms of greater than or equal to 2.4. The organosilicon-containing material for preparation of the ungelled partial hydrolysis product contains greater than or equal to 10 mole percent of at least one organosilane compound corresponding to the formula, R--Si--Y.sub.3. In the aforesaid formula, R represents hydrogen or a C.sub.1 -C.sub.10 group joined to Si through an Si--C linkage. Each Y in the aforesaid formula represents an easily hydrolyzable group. The partial hydrolysis product is prepared by hydrolyzing a portion of the easily hydrolyzable groups of the organosilane compound with a controlled amount of water. The amount of water employed in the controlled hydrolysis is determined according to the following formula,(E.sub.1,2 .times.0.5)+(E.sub.3,4 .times.Z)=W,whereinW represents the total moles H.sub.2 O employed calculated based on the total equivalents of the easily hydrolyzable groups employed,E.sub.1,2 represents the total number of equivalents of Y employed from organosilane compounds containing one or two Y groups,E.sub.3,4 represents the total number of equivalents of Y employed from organosilane compounds containing three or four Y groups, andZ is a number in the range of from 0.023 to 0.43.
摘要翻译：公开了含有机硅材料的未凝胶化部分水解产物，制备部分水解产物的方法，以及包含部分水解产物的涂料组合物的组合物。用于制备未凝胶化部分水解产物的含有机硅材料具有基于与硅原子连接的容易水解的Y基团大于或等于2.4的平均官能度。用于制备未凝胶化部分水解产物的含有机硅材料含有大于或等于10摩尔％的至少一种对应于式R-Si-Y 3的有机硅烷化合物。在上述式中，R表示氢或通过Si-C键与Si连接的C1-C10基。上述式中的每个Y表示易水解基团。部分水解产物通过用受控量的水水解部分有机硅烷化合物的易水解基团来制备。在受控水解中使用的水量根据下式确定：（E1,2x0.5）+（E3,4xZ）= W，其中W表示基于容易计算的总当量计算的H 2 O的总摩尔数可水解基团，E1,2表示从含有一个或两个Y基团的有机硅烷化合物中使用的Y的当量总数，E3,4表示从含有三个或四个Y基团的有机硅烷化合物中使用的Y的当量总数，Z 是从0.023到0.43的范围内的数字。

4. 发明授权

US4808663A Method of preparing acrylic polymers containing hydrolyzable moieties from organosilane compounds 失效
标题翻译：制备含有有机硅烷化合物的可水解部分的丙烯酸聚合物的方法
公开(公告)号：US4808663A
公开(公告)日：1989-02-28
申请号：US88731
申请日：1987-08-24
申请人： Wen H. Chang , Paul J. Prucnal , John R. Peffer , Edward L. Dufford , Ronald R. Ambrose
发明人： Wen H. Chang , Paul J. Prucnal , John R. Peffer , Edward L. Dufford , Ronald R. Ambrose
IPC分类号： C08F8/42 , C08G77/442 , C09D143/04 , C08F8/00
CPC分类号： C09D143/04 , C08F8/42 , C08G77/442
摘要： Disclosed is an ungelled acrylic resin composition containing an acrylic polymer having in a molecule thereof at least one group containing a silicon atom selected from: ##STR1## each R independently is selected from the group of moieties consisting of Y, hydrogen, a C.sub.1 -C.sub.10 group joined to Si through an Si-C linkage, and OR.sup.7 in which R.sup.7 represents alkykl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, wherein Y represents an easily hydrolyzable group.The acrylic resin composition, contains an amount of easily hydrolyzable Y moieties such that the ratio of the number of grams of the ungelled acrylic resin composition to equivalent of easily hydrolyzable Y moieties in the ungelled acrylic resin composition is in the range of from 40 to 667. Preferred acrylic resin compositions of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees Celsius within 3 hours.Disclosed is a method for producing the ungelled acrylic resin composition.Also disclosed is a nonaqueous composition, particularly a nonaqueous coating composition, containing the ungelled acrylic resin composition. Preferred coating compositions containing an ungelled acrylic resin composition can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees C. within 3 hours.
摘要翻译：公开了一种无胶凝的丙烯酸类树脂组合物，其含有丙烯酸类聚合物，其分子中至少含有选自以下的硅原子的基团：每个R独立地选自Y，氢，，通过Si-C键与Si连接的C1-C10基团，其中R7表示具有至少4个碳原子的烷基的OR7，芳基，烷基芳基，芳基烷基，芳氧基烷基或烷氧基烷基，其中Y表示易水解基团。丙烯酸树脂组合物含有一定量的易水解的Y部分，使得未凝胶化丙烯酸树脂组合物的克数与未凝胶化丙烯酸树脂组合物中容易水解的Y部分的当量比例在40至667的范围内本发明优选的丙烯酸树脂组合物可以在大气湿度和合适的催化剂存在下在3小时内在小于或等于121摄氏度的温度下固化。公开了一种制造无凝胶的丙烯酸树脂组合物的方法。还公开了含非凝胶型丙烯酸树脂组合物的非水性组合物，特别是非水性涂料组合物。含有未胶凝的丙烯酸树脂组合物的优选涂料组合物可在大气水分和合适的催化剂存在下在3小时内在小于或等于121℃的温度下固化。

5. 发明授权

US4788107A Substrates coated with nonaqueous compositions comprising acrylic polymers containing hydrolyzable moieties from organosilane compounds 失效
标题翻译：包含非水性组合物的底物，其包含含有来自有机硅烷化合物的可水解部分的丙烯酸聚合物
公开(公告)号：US4788107A
公开(公告)日：1988-11-29
申请号：US88357
申请日：1987-08-24
申请人： Wen H. Chang , Paul J. Prucnal , John R. Peffer , Edward L. Dufford , Ronald R. Ambrose
发明人： Wen H. Chang , Paul J. Prucnal , John R. Peffer , Edward L. Dufford , Ronald R. Ambrose
IPC分类号： C08F8/42 , C08G77/442 , C09D143/04 , B32B9/04
CPC分类号： C09D143/04 , C08F8/42 , C08G77/442 , Y10T428/31663
摘要： Disclosed is an ungelled acrylic resin composition containing an acrylic polymer having in a molecule thereof at least one group containing a silicon atom selected from: ##STR1## wherein each R independently is selected from the group of moieties consisting of Y, hydrogen, a C.sub.1 -C.sub.10 group joined to Si through an Si--C linkage, and OR.sup.7 in which R.sup.7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylaklyl, aryloxyalkyl, or alkyloxyalkyl, wherein Y represents an easily hydrolyzable group.The acrylic resin composition, contains an amount of easily hydrolyzable Y moieties such that the ratio of the number of grams of the ungelled acrylic resin composition to equivalent of easily hydrolyzable Y moieties in the ungelled acrylic resin composition is in a range of from 40 to 667. Prefered acrylic resin compositions of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees Celsius within 3 hours.Disclosed is a method for producing the ungelled acrylic resin composition.Also disclosed is a nonaqueous composition, particularly a nonaqueous coating composition, containing the ungelled acrylic resin composition. Preferred coating compositions containing an ungelled acrylic resin composition can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees C within 3 hours.
摘要翻译：公开了一种含有丙烯酸类聚合物的非凝胶型丙烯酸树脂组合物，其分子内含有至少一个含有选自以下的硅原子的基团：其中每个R独立地选自Y，氢，通过Si-C键与Si连接的C1-C10基团和其中R7表示具有至少4个碳原子的烷基的OR7，芳基，烷基芳基，芳基烷基，芳氧基烷基或烷氧基烷基，其中Y表示易水解基团。丙烯酸树脂组合物含有一定量的易水解的Y部分，使未凝胶化丙烯酸树脂组合物的克数与在非胶凝的丙烯酸树脂组合物中容易水解的Y部分的当量的比例在40至667的范围内本发明优选的丙烯酸树脂组合物可以在大气水分和合适的催化剂存在下在3小时内在小于或等于121摄氏度的温度下固化。公开了一种制造无凝胶的丙烯酸树脂组合物的方法。还公开了含非凝胶型丙烯酸树脂组合物的非水性组合物，特别是非水性涂料组合物。含有无凝胶的丙烯酸树脂组合物的优选涂料组合物可在大气水分和合适的催化剂存在下在3小时内在小于或等于121℃的温度下固化。

6. 发明授权

US4714738A Acrylic polymers containing hydrolyzable moieties from organosilane compounds 失效
标题翻译：含有有机硅烷化合物的可水解部分的丙烯酸聚合物
公开(公告)号：US4714738A
公开(公告)日：1987-12-22
申请号：US728973
申请日：1985-04-30
申请人： Wen H. Chang , Paul J. Prucnal , John R. Peffer , Edward L. Dufford , Ronald R. Ambrose
发明人： Wen H. Chang , Paul J. Prucnal , John R. Peffer , Edward L. Dufford , Ronald R. Ambrose
IPC分类号： C09D133/04 , B32B27/30 , C08F8/42 , C08F30/00 , C08F30/08 , C08G77/442 , C08K5/00 , C08L1/08 , C08L5/08 , C08L29/04 , C08L33/00 , C08L33/04 , C09D143/04 , C08F8/00
CPC分类号： C09D143/04 , C08F8/42 , C08G77/442
摘要： Disclosed is an ungelled acrylic resin composition containing an acrylic polymer having in a molecule thereof at least one group containing a silicon atom selected from: ##STR1## wherein each R independently is selected from the group of moieties consisting of Y, hydrogen, a C.sub.1 -C.sub.10 group joined to Si through an Si-C linkage, and OR.sup.7 in which R.sup.7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, wherein Y represents an easily hydrolyzable group.The acrylic resin composition, contains an amount of easily hydrolyzable Y moieties such that the ratio of the number of grams of the ungelled acrylic resin composition to equivalent of easily hydrolyzable Y moieties in the ungelled acrylic resin composition is in a range of from 40 to 667. Preferred acrylic resin compositions of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees Celsius within 3 hours.Disclosed is a method for producing the ungelled acrylic resin composition.Also disclosed is a nonaqueous composition, particularly a nonaqueous coating composition, containing the ungelled acrylic resin composition. Preferred coating compositions containing an ungelled acrylic resin composition can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees C. within 3 hours.
摘要翻译：公开了一种含有丙烯酸类聚合物的非凝胶型丙烯酸树脂组合物，其分子内含有至少一个含有选自以下的硅原子的基团：其中每个R独立地选自Y，氢，通过Si-C键与Si连接的C1-C10基团，和其中R7表示具有至少4个碳原子的烷基的OR7，芳基，烷芳基，芳烷基，芳氧基烷基或烷氧基烷基，其中Y表示易水解基团。丙烯酸树脂组合物含有一定量的易水解的Y部分，使未凝胶化的丙烯酸树脂组合物的克数与在非胶凝的丙烯酸树脂组合物中容易水解的Y部分的当量的比例在40至667的范围内本发明优选的丙烯酸树脂组合物可以在大气湿度和合适的催化剂存在下在3小时内在小于或等于121摄氏度的温度下固化。公开了一种制造无凝胶的丙烯酸树脂组合物的方法。还公开了含非凝胶型丙烯酸树脂组合物的非水性组合物，特别是非水性涂料组合物。含有未胶凝的丙烯酸树脂组合物的优选涂料组合物可在大气水分和合适的催化剂存在下在3小时内在小于或等于121℃的温度下固化。

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