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11. 发明授权

US5756806A Cyanobenzenesulfenyl halide and process for preparation of 3-substituted benzisothiazole using the same 失效
标题翻译：氰基苯硫基卤化物及使用其制备3-取代苯并异噻唑的方法
公开(公告)号：US5756806A
公开(公告)日：1998-05-26
申请号：US861426
申请日：1997-05-21
申请人： Hiroshi Goda , Junichi Sakamoto , Shigeki Sakaue , Sakae Kajihara , Miki Todo
发明人： Hiroshi Goda , Junichi Sakamoto , Shigeki Sakaue , Sakae Kajihara , Miki Todo
IPC分类号： C07C313/08 , C07C313/16 , C07D275/04 , C07C255/49
CPC分类号： C07D275/04 , C07C313/08 , C07C313/16
摘要： The present invention provides a compound represented by the general formula (I): ##STR1## wherein X represents Cl or Br, a process for preparation of the same and a process for preparation of 3-substituted benzisothiazole by reaction of the compound (I) with a piperazine compound.
摘要翻译：本发明提供由通式（I）表示的化合物：其中X表示Cl或Br，其制备方法和通过化合物的反应制备3-取代的苯并异噻唑的方法（I）与哌嗪化合物。

12. 发明授权

US5679827A Cyanobenzenesulfenyl halide and process for preparation of 3-substituted benzisothiazole using the same 失效
标题翻译：氰基苯硫基卤化物及使用其制备3-取代苯并异噻唑的方法
公开(公告)号：US5679827A
公开(公告)日：1997-10-21
申请号：US630730
申请日：1996-04-10
申请人： Hiroshi Goda , Junichi Sakamoto , Shigeki Sakaue , Sakae Kajihara , Miki Todo
发明人： Hiroshi Goda , Junichi Sakamoto , Shigeki Sakaue , Sakae Kajihara , Miki Todo
IPC分类号： C07C313/08 , C07C313/16 , C07D275/04 , C07C255/49
CPC分类号： C07D275/04 , C07C313/08 , C07C313/16
摘要： The present invention provides a compound represented by the general formula (I): ##STR1## wherein X represents Cl or Br, a process for preparation of the same and a process for preparation of 3-substituted benzisothiazole by reaction of the compound (I) with a piperazine compound.
摘要翻译：本发明提供由通式（I）表示的化合物：其中X表示Cl或Br，其制备方法和通过化合物的反应制备3-取代的苯并异噻唑的方法（I）与哌嗪化合物。

13. 发明授权

US5821388A Process for preparing .alpha.-haloacetophenone derivative 失效
标题翻译： α-卤代乙酰苯衍生物的制备方法
公开(公告)号：US5821388A
公开(公告)日：1998-10-13
申请号：US834544
申请日：1997-03-27
申请人： Junichi Sakamoto , Hideaki Nishiguchi , Hiroshi Goda
发明人： Junichi Sakamoto , Hideaki Nishiguchi , Hiroshi Goda
IPC分类号： B01J23/30 , C07B61/00 , C07C315/02 , C07C317/24 , C07C319/20 , C07C323/22
CPC分类号： C07C319/20 , C07C315/02
摘要： The present invention provides processes for preparing .alpha.-halo(methylthio)acetophenone and .alpha.-halo (methylsulfonyl)acetophenone in an industrially simple and economically advantageous manner. In the invention, methylthioacetophenone is halogenated with a halogenating agent in the presence of an alcohol, giving .alpha.-halo(methylthio) acetophenone. Then the compound is oxidized with an oxidizing agent, giving .alpha.-halo(methylsulfonyl)acetophenone.
摘要翻译：本发明提供了工业上简单且经济有利的方法制备α-卤代（甲硫基）苯乙酮和α-卤代（甲基磺酰基）苯乙酮的方法。在本发明中，甲基硫代苯乙酮用卤化剂在醇的存在下卤化，得到α-卤代（甲硫基）苯乙酮。然后用氧化剂氧化化合物，得到α-卤代（甲基磺酰基）苯乙酮。

14. 发明授权

US5210287A 2,5-dichlorophenylthioglycolic acid derivative and method for its production 失效
标题翻译： 2,5-二氯乙酰胆酸衍生物及其生产方法
公开(公告)号：US5210287A
公开(公告)日：1993-05-11
申请号：US824313
申请日：1992-01-23
申请人： Hiroshi Goda , Nario Kimura , Naohiro Yoshikawa , Katsuhiko Yoshida
发明人： Hiroshi Goda , Nario Kimura , Naohiro Yoshikawa , Katsuhiko Yoshida
IPC分类号： C07C323/66
CPC分类号： C07C323/66
摘要： The present invention is directed to novel 2,5-dichlorophenylthioglycolic acid derivative, a process for their production and a process for producing the desired product 2,5-dichlorophenylthioglycolic acid derived from said novel compounds. 2,5-dichlorophenylthioglycolic acid derivative of the present invention can be obtained by reacting 2,4,5-trichlorobenzensulfonates and thioglycolic acid in the presence of base, and said desired product can be obtained by desulfonating said compound in an aqueous solution of mineral acid. Novel 4-carboxymethylthio-2,5-dichlorobenzenesulfonates of the present invention can be used advantageously as an intermediate for the production of 2,5-dichlorophenylthioglycolic acid. The use of said intermediate makes it possible to obtain the desired product in a decreased process steps with high yield. In addition, it poses no problem of environmental pollution as pointed out with conventional methods because it uses no heavy metals.

15. 发明授权

US4853158A Process for preparing N,N-dialkylaniline salt of 5-acetyl-2-alkylbenzene sulfonic acid 失效
标题翻译：制备5-乙酰基-2-烷基苯磺酸的N，N-二烷基苯胺盐的方法
公开(公告)号：US4853158A
公开(公告)日：1989-08-01
申请号：US178833
申请日：1988-03-25
申请人： Kunioki Kato , Masao Kawamura , Hiroshi Goda , Kiyoshi Sawada , Kazuhiro Hamatani
发明人： Kunioki Kato , Masao Kawamura , Hiroshi Goda , Kiyoshi Sawada , Kazuhiro Hamatani
IPC分类号： C07C20060101 , C07C309/30 , C07C311/15
CPC分类号： C07C309/00
摘要： Process for preparing 2-alkyl-5-haloacetylbenzenesulfonamide represented by the general formula (1), ##STR1## (wherein R.sup.1 is an alkyl group having 1 to 5 carbon atoms; and X is a chlorine atom, bromine atom or iodine atom), characterized by halogenating a 5-acetyl-2-alkylbenzenesulfonamide represented by the general formula (2), ##STR2## (wherein R.sup.1 is the same as defined above) in a lower alcohol represented by the general formula (3),R.sup.4 --OH(wherein R.sup.4 is an alkyl group having 1 to 5 carbon atoms).
摘要翻译：用于制备由通式（1）表示的2-烷基-5-卤代乙酰基苯磺酰胺的方法，其中R1是具有1-5个碳原子的烷基; X是氯原子，溴原子或碘原子），其特征在于在通式（3）表示的低级醇中卤化由通式（2）表示的5-乙酰基-2-烷基苯磺酰胺，（IMAG）（2）（其中R 1与上述相同）），R4-OH（其中R4是具有1至5个碳原子的烷基）。

16. 发明授权

US5352821A 2,5-dichlorophenylthioglycolic acid derivative and method for its production 失效
标题翻译： 2,5-二氯苯硫基乙酸衍生物及其制备方法
公开(公告)号：US5352821A
公开(公告)日：1994-10-04
申请号：US19906
申请日：1993-02-19
申请人： Hiroshi Goda , Nario Kimura , Naohiro Yoshikawa , Katsuhiko Yoshida
发明人： Hiroshi Goda , Nario Kimura , Naohiro Yoshikawa , Katsuhiko Yoshida
IPC分类号： C07C323/66 , C07C323/62
CPC分类号： C07C323/66
摘要： The present invention is directed to novel 2,5-dichlorophenylthioglycolic acid derivative, a process for their production and a process for producing the desired product 2,5-dichlorophenylthioglycolic acid derived from said novel compounds. 2,5-dichlorophenylthioglycolic acid derivative of the present invention can be obtained by reacting 2,4,5-trichlorobenzensulfonates and thioglycolic acid in the presence of base, and said desired product can be obtained by desulfonating said compound in an aqueous solution of mineral acid. Novel 4-carboxymethylthio-2,5-dichlorobenzenesulfonates of the present invention can be used advantageously as an intermediate for the production of 2,5-dichlorophenylthioglycolic acid. The use of said intermediate makes it possible to obtain the desired product in a decreased process steps with high yield. In addition, it poses no problem of environmental pollution as pointed out with conventional methods because it uses no heavy metals.
摘要翻译：本发明涉及新的2,5-二氯苯基硫代乙醇酸衍生物，其制备方法和由所述新化合物衍生的所需产物2,5-二氯苯基乙氧基乙酸的制备方法。本发明的2,5-二氯苯硫代乙酸衍生物可以通过使2,4,5-三氯苯磺酸盐和巯基乙酸在碱存在下反应而获得，所需要的产物可通过将无机酸水溶液中的所述化合物脱磺酸。本发明的新型4-羧甲基硫代-2,5-二氯苯磺酸盐可以有利地用作生产2,5-二氯苯乙硫醇的中间体。使用所述中间体使得可以以降低的工艺步骤以高产率获得所需产物。另外，由于不使用重金属，因此常规方法指出了环境污染问题。

17. 发明授权

US5811571A Process for preparing aromatic or heteroaromatic sulfonyl halides 失效
标题翻译：制备芳族或杂芳族磺酰卤的方法
公开(公告)号：US5811571A
公开(公告)日：1998-09-22
申请号：US765246
申请日：1996-12-13
申请人： Hitoshi Karino , Hiroshi Goda , Jun-ichi Sakamoto , Katsuhiko Yoshida , Hideaki Nishiguchi
发明人： Hitoshi Karino , Hiroshi Goda , Jun-ichi Sakamoto , Katsuhiko Yoshida , Hideaki Nishiguchi
IPC分类号： C07C303/18 , C07C303/02 , C07C303/16 , C07C309/86 , C07C309/89 , C07C315/04 , C07C317/14 , C07C319/20 , C07C323/66 , C07D213/71 , C07D241/18 , C07D251/22 , C07D263/46 , C07D275/02 , C07D275/03 , C07D277/36 , C07C255/10
CPC分类号： C07D275/03 , C07C303/02 , C07C303/16 , C07C315/04 , C07C319/20 , C07D213/71 , C07D241/18 , C07D251/22 , C07D263/46
摘要： The present invention is directed to a process for preparing an aromatic or heteroaromatic sulfonyl halide represented by the formula (3), the process comprising halogenating an aromatic or heteroaromatic methyl sulfide represented by the formula (1) or an aromatic or heteroaromatic methyl sulfoxide represented by the formula (2) with a halogenating agent in the presence of water Ar.paren open-st.SCH.sub.3-m X.sub.m).sub.n (1) Ar.paren open-st.SOCH.sub.3-m X.sub.m).sub.n (2) Ar.paren open-st.SO.sub.2 Y).sub.n (3) wherein Ar is an aromatic ring or a heteroaromatic ring which is unsubstituted or which has an optional substituent or substituents, X and Y are halogen atoms, m is an integer of 0 to 3 and n is 1 or 2. According to the present invention, aromatic or heteroaromatic sulfonyl halides can be produced industrially cheaply and easily.
摘要翻译： PCT No.PCT / JP95 / 02675 Sec。 371日期1996年12月13日第 102（e）日期1996年12月13日PCT 1995年12月25日PCT PCT。公开号WO96 / 33167 日期：1996年10月24日本发明涉及一种由式（3）表示的芳族或杂芳族磺酰卤的制备方法，该方法包括将由式（1）表示的芳族或杂芳族甲基硫醚或芳族或（2）Ar + 545 SO 2 Y）n（3）其中，式（2）表示的杂芳香族甲基亚砜与卤化剂在水存在下反应，式中，Ar + 545 SCH3-mXm）n（1）Ar + 545 SOCH3-mXm） Ar是未取代的或具有任选的取代基的芳香环或杂芳环，X和Y是卤素原子，m是0-3的整数，n是1或2.根据本发明，芳香族或杂芳族磺酰卤可以在工业上廉价且容易地制备。

18. 发明授权

US5810907A Continuous melting apparatus for low-melting point metal, improved crucible for such apparatus, and melting method using such apparatus 失效
标题翻译：用于低熔点金属的连续熔化装置，用于这种装置的改进的坩埚以及使用这种装置的熔化方法
公开(公告)号：US5810907A
公开(公告)日：1998-09-22
申请号：US890420
申请日：1997-07-09
申请人： Tamio Okada , Hideo Yoshikawa , Tomohiro Hatanaka , Michio Matsuura , Toshiaki Sano , Masato Yoshida , Hiroshi Goda
发明人： Tamio Okada , Hideo Yoshikawa , Tomohiro Hatanaka , Michio Matsuura , Toshiaki Sano , Masato Yoshida , Hiroshi Goda
IPC分类号： C22B21/00 , F27B14/00 , F27B14/08 , F27B14/14 , F27B19/02 , F27D3/00 , F27D3/14
CPC分类号： F27D3/0025 , C22B21/0084 , F27B14/143 , F27B19/02 , F27D3/14 , F27B2014/008 , F27B2014/0881
摘要： A continuous melting apparatus for a low melting point metal is disclosed. The apparatus includes a melting furnace main body (5) forming a combustion chamber (6) surrounded by a refractory lining, a crucible (1) formed with a tapping orifice (2) at an appropriate position of a body and housed at the center portion of said combustion chamber, a burner (8) provided on a side wall portion of said melting furnace main body (5) for heating said crucible (1) in said combustion chamber (6) and a receptacle (6, 13) for receiving a melt flowing out through said tapping orifice (2) of said crucible (1). In the continuous melting apparatus, with employing a melting method of burner heating type which is inexpensive, easy to handle and maintenance, with successfully minimizing oxidation loss which was the shortcoming of the burner type. Also, generation of corundum on the furnace wall surface due to reaction of the aluminum melt and the furnace wall can be successfully avoided.
摘要翻译：公开了一种用于低熔点金属的连续熔化装置。该装置包括形成由耐火衬里包围的燃烧室（6）的熔炉主体（5），在主体的适当位置处形成有攻丝孔（2）的坩埚（1），并容纳在中心部分，设置在所述熔炉主体（5）的侧壁部分上用于加热所述燃烧室（6）中的所述坩埚（1）的燃烧器（8）和用于接收所述燃烧室熔化物通过所述坩埚（1）的攻丝孔（2）流出。在连续熔融装置中，采用廉价的燃烧器加热型熔融方法，易于处理和维护，成功地使氧化损失最小化，这是燃烧器类型的缺点。此外，可以成功地避免由于铝熔体和炉壁的反应而在炉壁表面产生刚玉。

19. 发明授权

US5741933A Process for preparing aromatic or heteroaromatic sulfur compound 失效
标题翻译：制备芳族或杂芳族硫化合物的方法
公开(公告)号：US5741933A
公开(公告)日：1998-04-21
申请号：US687556
申请日：1996-07-24
申请人： Hiroshi Goda , Mikio Yamamoto , Jun-ichi Sakamoto , Hitoshi Karino
发明人： Hiroshi Goda , Mikio Yamamoto , Jun-ichi Sakamoto , Hitoshi Karino
IPC分类号： C07C319/06 , C07C321/24 , C07D213/70 , C07D241/18 , C07D249/02 , C07D263/46 , C07D275/02 , C07D275/03 , C07D277/20 , C07D277/36 , C07D521/00
CPC分类号： C07D275/03 , C07C319/06 , C07D213/70 , C07D241/18 , C07D249/02 , C07D263/46
摘要： The present invention provides a process for preparing an aromatic or heteroaromatic thiol represented by the formula (2), the process comprising hydrolyzing an aromatic or heteroaromatic halogenated methyl sulfide represented by the formula (1) Ar.paren open-st.SCH.sub.3-m X.sub.m).sub.n (1) Ar.paren open-st.SH).sub.n (2) wherein Ar is an aromatic or heteroaromatic ring which has no substituent or which has an optional substituent or substituents, X is a halogen atom, m is an integer of 1 to 3 and n is 1 or 2. According to the present invention, an aromatic or heteroaromatic thiol can be prepared at a commercially low cost and with ease.
摘要翻译： PCT No.PCT / JP95 / 02315 Sec。 371日期：1996年7月24日 102（e）日期1996年7月24日PCT提交1995年11月13日PCT公布。出版物WO96 / 16034 日期：1996年5月30日本发明提供由式（2）表示的芳族或杂芳族硫醇的制备方法，该方法包括水解由式（1）Ar + 545 SCH3-mXm表示的芳族或杂芳族卤代甲基硫化物， n（1）Ar + 545 SH）n（2）其中Ar是没有取代基或具有任选的取代基的芳香族或杂芳族环，X是卤素原子，m是1〜3的整数，n 是1或2.根据本发明，芳族或杂芳族硫醇可以商业上低成本且容易地制备。

20. 发明授权

US4943655A Salt of 5-acetyl-2-alkylbenzenesulfonic acid 失效
标题翻译： 5-乙酰基-2-烷基苯磺酸盐
公开(公告)号：US4943655A
公开(公告)日：1990-07-24
申请号：US328388
申请日：1989-03-24
申请人： Kunioki Kato , Masao Kawamura , Hiroshi Goda , Kiyoshi Sawada , Kazuhiro Hamatani
发明人： Kunioki Kato , Masao Kawamura , Hiroshi Goda , Kiyoshi Sawada , Kazuhiro Hamatani
IPC分类号： C07C20060101 , C07C309/30 , C07C311/15
CPC分类号： C07C309/00
摘要： Process for preparing 2-alkyl-5-haloacetylbenzenesulfonamide represented by the general formula (1), ##STR1## (wherein R.sup.1 is an alkyl group having 1 to 5 carbon atoms; and X is a chlorine atom, bromine atom or iodine atom), characterized by halogenating a 5-acetyl-2-alkylbenzenesulfonamide represented by the general formula (2), ##STR2## (wherein R.sup.1 is the same as defined above) in a lower alcohol represented by the general formula (3),R.sup.4 --OH(wherein R.sup.4 is an alkyl group having 1 to 5 carbon atoms).

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