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1. 发明授权

US5811571A Process for preparing aromatic or heteroaromatic sulfonyl halides 失效
标题翻译：制备芳族或杂芳族磺酰卤的方法
公开(公告)号：US5811571A
公开(公告)日：1998-09-22
申请号：US765246
申请日：1996-12-13
申请人： Hitoshi Karino , Hiroshi Goda , Jun-ichi Sakamoto , Katsuhiko Yoshida , Hideaki Nishiguchi
发明人： Hitoshi Karino , Hiroshi Goda , Jun-ichi Sakamoto , Katsuhiko Yoshida , Hideaki Nishiguchi
IPC分类号： C07C303/18 , C07C303/02 , C07C303/16 , C07C309/86 , C07C309/89 , C07C315/04 , C07C317/14 , C07C319/20 , C07C323/66 , C07D213/71 , C07D241/18 , C07D251/22 , C07D263/46 , C07D275/02 , C07D275/03 , C07D277/36 , C07C255/10
CPC分类号： C07D275/03 , C07C303/02 , C07C303/16 , C07C315/04 , C07C319/20 , C07D213/71 , C07D241/18 , C07D251/22 , C07D263/46
摘要： The present invention is directed to a process for preparing an aromatic or heteroaromatic sulfonyl halide represented by the formula (3), the process comprising halogenating an aromatic or heteroaromatic methyl sulfide represented by the formula (1) or an aromatic or heteroaromatic methyl sulfoxide represented by the formula (2) with a halogenating agent in the presence of water Ar.paren open-st.SCH.sub.3-m X.sub.m).sub.n (1) Ar.paren open-st.SOCH.sub.3-m X.sub.m).sub.n (2) Ar.paren open-st.SO.sub.2 Y).sub.n (3) wherein Ar is an aromatic ring or a heteroaromatic ring which is unsubstituted or which has an optional substituent or substituents, X and Y are halogen atoms, m is an integer of 0 to 3 and n is 1 or 2. According to the present invention, aromatic or heteroaromatic sulfonyl halides can be produced industrially cheaply and easily.
摘要翻译： PCT No.PCT / JP95 / 02675 Sec。 371日期1996年12月13日第 102（e）日期1996年12月13日PCT 1995年12月25日PCT PCT。公开号WO96 / 33167 日期：1996年10月24日本发明涉及一种由式（3）表示的芳族或杂芳族磺酰卤的制备方法，该方法包括将由式（1）表示的芳族或杂芳族甲基硫醚或芳族或（2）Ar + 545 SO 2 Y）n（3）其中，式（2）表示的杂芳香族甲基亚砜与卤化剂在水存在下反应，式中，Ar + 545 SCH3-mXm）n（1）Ar + 545 SOCH3-mXm） Ar是未取代的或具有任选的取代基的芳香环或杂芳环，X和Y是卤素原子，m是0-3的整数，n是1或2.根据本发明，芳香族或杂芳族磺酰卤可以在工业上廉价且容易地制备。

2. 发明授权

US5741933A Process for preparing aromatic or heteroaromatic sulfur compound 失效
标题翻译：制备芳族或杂芳族硫化合物的方法
公开(公告)号：US5741933A
公开(公告)日：1998-04-21
申请号：US687556
申请日：1996-07-24
申请人： Hiroshi Goda , Mikio Yamamoto , Jun-ichi Sakamoto , Hitoshi Karino
发明人： Hiroshi Goda , Mikio Yamamoto , Jun-ichi Sakamoto , Hitoshi Karino
IPC分类号： C07C319/06 , C07C321/24 , C07D213/70 , C07D241/18 , C07D249/02 , C07D263/46 , C07D275/02 , C07D275/03 , C07D277/20 , C07D277/36 , C07D521/00
CPC分类号： C07D275/03 , C07C319/06 , C07D213/70 , C07D241/18 , C07D249/02 , C07D263/46
摘要： The present invention provides a process for preparing an aromatic or heteroaromatic thiol represented by the formula (2), the process comprising hydrolyzing an aromatic or heteroaromatic halogenated methyl sulfide represented by the formula (1) Ar.paren open-st.SCH.sub.3-m X.sub.m).sub.n (1) Ar.paren open-st.SH).sub.n (2) wherein Ar is an aromatic or heteroaromatic ring which has no substituent or which has an optional substituent or substituents, X is a halogen atom, m is an integer of 1 to 3 and n is 1 or 2. According to the present invention, an aromatic or heteroaromatic thiol can be prepared at a commercially low cost and with ease.
摘要翻译： PCT No.PCT / JP95 / 02315 Sec。 371日期：1996年7月24日 102（e）日期1996年7月24日PCT提交1995年11月13日PCT公布。出版物WO96 / 16034 日期：1996年5月30日本发明提供由式（2）表示的芳族或杂芳族硫醇的制备方法，该方法包括水解由式（1）Ar + 545 SCH3-mXm表示的芳族或杂芳族卤代甲基硫化物， n（1）Ar + 545 SH）n（2）其中Ar是没有取代基或具有任选的取代基的芳香族或杂芳族环，X是卤素原子，m是1〜3的整数，n 是1或2.根据本发明，芳族或杂芳族硫醇可以商业上低成本且容易地制备。

3. 发明授权

US5932731A Process for preparing aromatic or heteroaromatic sulfur compound 失效
标题翻译：制备芳族或杂芳族硫化合物的方法
公开(公告)号：US5932731A
公开(公告)日：1999-08-03
申请号：US996074
申请日：1997-12-22
申请人： Hiroshi Goda , Mikio Yamamoto , Jun-ichi Sakamoto , Hitoshi Karino
发明人： Hiroshi Goda , Mikio Yamamoto , Jun-ichi Sakamoto , Hitoshi Karino
IPC分类号： C07C319/06 , C07C321/24 , C07D213/70 , C07D241/18 , C07D249/02 , C07D263/46 , C07D275/02 , C07D275/03 , C07D277/20 , C07D277/36 , C07D521/00 , C07D213/28 , C07D231/18 , C07D239/36
CPC分类号： C07D275/03 , C07C319/06 , C07D213/70 , C07D241/18 , C07D249/02 , C07D263/46
摘要： The present invention provides a process for preparing an aromatic or heteroaromatic thiol represented by the formula (2), the process comprising hydrolyzing an aromatic or heteroaromatic halogenated methyl sulfide represented by the formula (1)Ar.paren open-st.SCH.sub.3-m X.sub.m).sub.n (1)Ar.paren open-st.SH).sub.n (2)wherein Ar is an aromatic or heteroaromatic ring which has no substituent or which has an optional substituent or substituents, X is a halogen atom, m is an integer of 1 to 3 and n is 1 or 2.
摘要翻译：本发明提供一种制备由式（2）表示的芳族或杂芳族硫醇的方法，该方法包括水解式（1）Ar + 545 SCH3-mXm）n（1）表示的芳族或杂芳族卤化甲基硫化物 Ar + 545 SH）n（2）其中Ar是没有取代基或具有任选的取代基的芳族或杂芳族环，X是卤素原子，m是1〜3的整数，n是1或2 。

4. 发明授权

US08715516B2 Optical element and method of manufacturing optical element with each of first and second layers having a repetition structure 有权
标题翻译：光学元件和制造光学元件的方法，每个第一和第二层具有重复结构
公开(公告)号：US08715516B2
公开(公告)日：2014-05-06
申请号：US13013882
申请日：2011-01-26
申请人： Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai , Kazuhiro Arai
发明人： Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai , Kazuhiro Arai
IPC分类号： B29D11/00 , B44C1/22
CPC分类号： G02B1/002 , B82Y20/00 , G02B5/1809 , G02B6/126 , G02B6/136 , G02B27/42 , G02B27/4261
摘要： An optical element having a three-dimensional structure which can function in a visible range and can improve adherence at a structural interface of the element, and a method of manufacturing the optical element. The optical element includes a substrate, and at least a first layer and a second layer on the substrate are manufactured such that each of the first layer and the second layer has a repetition structure of spaces and structural parts at a pitch equal to or less than a wavelength of visible light, and at an interface between the first layer and the second layer, overlapped structures are provided in which the repetition structure of the first layer and the repetition structure of the second layer overlap in a stack direction of the layers.
摘要翻译：具有三维结构的光学元件，其可以在可见光范围内起作用并且能够提高元件的结构界面处的粘附性，以及制造该光学元件的方法。所述光学元件包括基板，并且所述基板上的至少第一层和第二层被制造为使得所述第一层和所述第二层中的每一个具有空间的重复结构和等于或小于可见光的波长，并且在第一层和第二层之间的界面处，提供重叠结构，其中第一层的重复结构和第二层的重复结构在层的堆叠方向上重叠。

5. 发明申请

US20120176676A1 METHOD OF PRODUCING WIRE-GRID POLARIZER AND WIRE-GRID POLARIZER 审中-公开
标题翻译：生产网状极化器和电网偏振器的方法
公开(公告)号：US20120176676A1
公开(公告)日：2012-07-12
申请号：US13339278
申请日：2011-12-28
申请人： Jun-ichi Sakamoto
发明人： Jun-ichi Sakamoto
IPC分类号： G02B5/30 , B05D5/06
CPC分类号： G02B5/3058
摘要： A line-and-space structure having a line portion and a space portion is formed by applying a sol-gel coating on a substrate and transferring a structure of a mold to the coating, and an embedded metal portion is formed by filling the space portion with a molten metal. As the metal to be molten, a metal material having a melting point of not higher than 650° C. and showing, after the solidification, an average extinction coefficient of higher than 5.0 or an average extinction coefficient of higher than 4.5 and an average refractive index of less than 1, at a wavelength range of 400 to 700 nm, is selected to improve optical characteristics.
摘要翻译：具有线部分和空间部分的线间空间结构通过在基底上施加溶胶 - 凝胶涂层并将模具的结构转移到涂层而形成，并且通过填充空间部分形成嵌入的金属部分与熔融金属。作为熔融金属，熔点不高于650℃的金属材料，凝固后的平均消光系数高于5.0，平均消光系数高于4.5，平均折射率在400〜700nm的波长范围内小于1的指数被选择以改善光学特性。

6. 发明授权

US5035010A Reciprocating shower device for human usage when showering 失效
标题翻译：淋浴间用于人体使用的往复式淋浴设备
公开(公告)号：US5035010A
公开(公告)日：1991-07-30
申请号：US398836
申请日：1989-08-14
申请人： Jun-ichi Sakamoto , Tetsuya Onkura , Kouichi Yoshida
发明人： Jun-ichi Sakamoto , Tetsuya Onkura , Kouichi Yoshida
IPC分类号： E03C1/06
CPC分类号： E03C1/063
摘要： A shower device includes a housing having a longitudinally elongated slit substantially in center part of the housing, substantially all constituents of the device being accommodated within the housing, so that a guide rail is disposed along the slit and a slider carrying a shower nozzle is displaced by a drive means for reciprocation along the guide rail with the shower nozzle disposed at the slit. The device is thus made excellent in the appearance and also in the safety with all water hoses disposed inside the housing.
摘要翻译：淋浴装置包括具有基本上位于壳体的中心部分的纵向细长狭缝的壳体，该装置的基本上所有构件被容纳在壳体内，使得沿着狭缝设置导轨，并且带有淋浴喷嘴的滑块被移位通过用于沿着导轨往复运动的驱动装置，淋浴喷嘴设置在狭缝处。因此，所述装置的外观以及设置在壳体内部的所有水软管的安全性均优异。

7. 发明申请

US20130241090A1 METHOD OF MANUFACTURING AN OPTICAL ELEMENT 审中-公开
标题翻译：制造光学元件的方法
公开(公告)号：US20130241090A1
公开(公告)日：2013-09-19
申请号：US13989451
申请日：2011-12-08
申请人： Jun-ichi Sakamoto , Junji Terada , Masaya Hisamatsu
发明人： Jun-ichi Sakamoto , Junji Terada , Masaya Hisamatsu
IPC分类号： G02B5/00
CPC分类号： B29D11/0073 , G02B1/118 , G02B5/00 , G02B5/1809 , G02B5/1852 , G02B27/283
摘要： Provided is a method of manufacturing an optical element having a structure, which is represented by a one-dimensional lattice, with high yield with the use of a sol-gel material. A titanium based sol-gel material is applied onto a substrate (1), and then is subjected to vacuum drying to form a titania sol layer (2) corresponding to a dried sol-gel film. Onto the titania sol layer (2), a line-and-space structure is transferred by embossing using a mold (3), and then the mold (3) is separated. Thus, a titania sol layer (4) having the structure is formed. Next, heating is performed to accelerate the dehydration condensation reaction of the sol-gel material to cure the sol-gel material, and thus a titanium oxide structure portion (5) having the line-and-space structure is formed.
摘要翻译：提供了使用溶胶 - 凝胶材料以高产率制造具有由一维网格表示的结构的光学元件的方法。将钛基溶胶 - 凝胶材料施加到基材（1）上，然后进行真空干燥以形成对应于干燥的溶胶 - 凝胶膜的二氧化钛溶胶层（2）。在二氧化钛溶胶层（2）上，通过使用模具（3）通过压花转移线间距结构，然后分离模具（3）。因此，形成具有该结构的二氧化钛溶胶层（4）。接下来，进行加热以加速溶胶 - 凝胶材料的脱水缩合反应以固化溶胶 - 凝胶材料，因此形成具有线间距结构的氧化钛结构部分（5）。

8. 发明申请

US20110123765A1 METHOD OF PRODUCING OPTICAL ELEMENT AND OPTICAL ELEMENT 有权
标题翻译：生产光学元件和光学元件的方法
公开(公告)号：US20110123765A1
公开(公告)日：2011-05-26
申请号：US13055663
申请日：2009-07-07
申请人： Kazuhiro Arai , Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai
发明人： Kazuhiro Arai , Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai
IPC分类号： B32B3/10 , B32B7/02 , B32B3/00 , B29D11/00
CPC分类号： G02B5/1809 , G02B5/30 , G02B27/28 , Y10T428/24322 , Y10T428/24562 , Y10T428/24942
摘要： Provided are an optical element and a method of producing an optical element in which sufficient adhesion with an upper layer can be secured without damaging spectral characteristics. The production method includes the step of forming a first structural body in which a space part and a structural part are alternately and repeatedly arranged, the step of forming an etching stopper layer on an upper part of the structural part, and the step of forming a second structural body on the etching stopper layer by etching.
摘要翻译：提供一种光学元件和制造光学元件的方法，其中可以确保与上层具有足够的粘合性而不损害光谱特性。制造方法包括形成空间部和结构部交替重复排列的第一结构体的工序，在结构部的上部形成蚀刻停止层的工序，以及形成工序蚀刻停止层上的第二结构体。

9. 发明授权

US08941920B2 Method of producing optical element and optical element 有权
标题翻译：制造光学元件和光学元件的方法
公开(公告)号：US08941920B2
公开(公告)日：2015-01-27
申请号：US13055663
申请日：2009-07-07
申请人： Kazuhiro Arai , Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai
发明人： Kazuhiro Arai , Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai
IPC分类号： G02B5/30 , G02B5/18 , G02B27/28
CPC分类号： G02B5/1809 , G02B5/30 , G02B27/28 , Y10T428/24322 , Y10T428/24562 , Y10T428/24942
摘要： Provided are an optical element and a method of producing an optical element in which sufficient adhesion with an upper layer can be secured without damaging spectral characteristics. The production method includes the step of forming a first structural body in which a space part and a structural part are alternately and repeatedly arranged, the step of forming an etching stopper layer on an upper part of the structural part, and the step of forming a second structural body on the etching stopper layer by etching.
摘要翻译：提供一种光学元件和制造光学元件的方法，其中可以确保与上层具有足够的粘合性而不损害光谱特性。制造方法包括形成空间部和结构部交替重复排列的第一结构体的工序，在结构部的上部形成蚀刻停止层的工序，以及形成工序蚀刻停止层上的第二结构体。

10. 发明申请

US20110114598A1 OPTICAL ELEMENT AND METHOD OF MANUFACTURING OPTICAL ELEMENT WITH EACH OF FIRST AND SECOND LAYERS HAVING A REPETITION STRUCTURE 有权
标题翻译：光学元件和制造具有重复结构的第一层和第二层的光学元件的方法
公开(公告)号：US20110114598A1
公开(公告)日：2011-05-19
申请号：US13013882
申请日：2011-01-26
申请人： Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai , Kazuhiro Arai
发明人： Jun-ichi Sakamoto , Junji Terada , Noriyuki Nakai , Kazuhiro Arai
IPC分类号： B29D11/00
CPC分类号： G02B1/002 , B82Y20/00 , G02B5/1809 , G02B6/126 , G02B6/136 , G02B27/42 , G02B27/4261
摘要： An optical element having a three-dimensional structure which can function in a visible range and can improve adherence at a structural interface of the element, and a method of manufacturing the optical element. The optical element includes a substrate, and at least a first layer and a second layer on the substrate are manufactured such that each of the first layer and the second layer has a repetition structure of spaces and structural parts at a pitch equal to or less than a wavelength of visible light, and at an interface between the first layer and the second layer, overlapped structures are provided in which the repetition structure of the first layer and the repetition structure of the second layer overlap in a stack direction of the layers.
摘要翻译：具有三维结构的光学元件，其可以在可见光范围内起作用并且能够提高元件的结构界面处的粘附性，以及制造该光学元件的方法。所述光学元件包括基板，并且所述基板上的至少第一层和第二层被制造为使得所述第一层和所述第二层中的每一个具有空间的重复结构和等于或小于可见光的波长，并且在第一层和第二层之间的界面处，提供重叠结构，其中第一层的重复结构和第二层的重复结构在层的堆叠方向上重叠。

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