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11. 发明授权

US06903145B2 Method for producing a multicomponent system which can be thermally hardened and hardened by actinic radiation and the use thereof 失效
标题翻译：用于制造可以通过光化辐射热硬化和硬化的多组分体系的方法及其用途
公开(公告)号：US06903145B2
公开(公告)日：2005-06-07
申请号：US10363751
申请日：2001-10-01
申请人： Egbert Nienhaus , Bernhard Lettmann
发明人： Egbert Nienhaus , Bernhard Lettmann
IPC分类号： C08F2/46 , C08G18/62 , C08G18/81 , C09D5/46 , C09D175/16 , C08F2/50
CPC分类号： C09D175/16 , C08G18/6254 , C08G18/8175 , Y10T428/31547 , Y10T428/31551 , Y10T428/31554
摘要： A process for preparing a multicomponent system curable thermally and with actinic radiation (dual cure), where (A) at least one component comprising at least one constituent (A1) containing per molecule at least two isocyanate-reactive functional groups, and (B) one component containing one polyisocyanate (B1), are mixed with one another, which comprises mixing component (A) and/or component (B), shortly before their mixing, with one further liquid component (C) comprising (C1) one constituent which is curable with actinic radiation and contains per molecule at least two functional groups which contain bond which can be activated with actinic radiation, and/or (C2) one constituent which is curable thermally and with actinic radiation and contains per molecule at least one functional group which contains at least one bond which can be activated with actinic radiation, and containing per molecule at least one isocyanate-reactive functional group or containing at least one isocyanate group, and subsequently mixing and homogenizing components (A/C) and (B), (A) and (B/C) or (A/C) and (B/C).
摘要翻译：一种制备可热固化并具有光化辐射（双重固化）的多组分体系的方法，其中（A）至少一种组分包含至少一种每分子含有至少两个异氰酸酯反应性官能团的组分（A1），和（B）含有一种多异氰酸酯（B1）的一种组分彼此混合，其中包括在混合之前不久将混合组分（A）和/或组分（B）与一种另外的液体组分（C），其包含（C1）一种组分，可以用光化辐射固化，并且每分子含有至少两个含有可以用光化辐射活化的键的官能团，和/或（C2）可热固化并具有光化辐射的组分，并且每分子含有至少一个官能团其包含至少一个可以用光化辐射活化的键，并且每分子含有至少一个异氰酸酯反应性官能团或含有至少一个异氰酸酯基团（A / C）和（B），（A）和（B / C）或（A / C）和（B / C）混合均化。

12. 发明申请

US20080090935A1 Uv-A-Curable, Solvent-Containing Composition, Process For Preparing It, And Use Thereof 有权
标题翻译： Uv-A-可固化，含溶剂的组合物，其制备方法及其用途
公开(公告)号：US20080090935A1
公开(公告)日：2008-04-17
申请号：US11816776
申请日：2006-01-28
申请人： Bernhard Lettmann , Klaus-Udo Reize , Egbert Nienhaus
发明人： Bernhard Lettmann , Klaus-Udo Reize , Egbert Nienhaus
IPC分类号： C08G18/02 , C08F2/46
CPC分类号： C08L33/062 , C08K5/101 , C09D4/00
摘要： A UV-A-curable, solvent-containing composition composed of (A) 1% to 50% by weight of a UV-A-curable constituent containing isocyanate-reactive groups; (B) 0.01% to 10% by weight of a colorless photoinitiator having an absorption maximum in the wavelength range of λ=300 to 400 nm; (C) 10% to 70% by weight of an alkyl and/or cycloalkyl acetate having 3 to 10 carbon atoms in the alkyl radical and/or in the cycloalkyl radical; (D) 10% to 70% by weight of an alkoxyalkyl, alkoxycycloalkyl, cycloalkoxyalkyl and/or cycloalkoxycycloalkyl acetate; (E) 0.01% to 5% by weight of a constituent that lowers the interfacial tension; (F) 0 to 50% by weight of an alkylaromatic having at least two alkyl radicals having 1 to 6 carbon atoms in the molecule; and (G) 0 to 50% by weight of an additive different from constituents (A) to (F); processes for preparing it, and its use as a spot blender in automotive refinishing, especially in spot repair, or for preparation thereof.
摘要翻译：包含（A）1重量％至50重量％的含有异氰酸酯反应性基团的UV-A可固化组分的UV-A固化的含溶剂组合物; （B）在λ= 300〜400nm的波长范围内具有吸收最大值的0.01〜10重量％的无色光引发剂; （C）10％至70％重量的烷基和/或烷基和/或环烷基中具有3至10个碳原子的烷基和/或环烷基乙酸酯; （D）10重量％至70重量％的烷氧基烷基，烷氧基环烷基，环烷氧基烷基和/或环烷氧基环烷基乙酸酯; （E）0.01〜5重量％的降低界面张力的组分; （F）0至50重量％的分子中具有至少两个具有1至6个碳原子的烷基的烷基芳族化合物; 和（G）0至50重量％的不同于组分（A）至（F）的添加剂; 其制备方法，以及其作为汽车修补中的现场搅拌器的使用，特别是在现场维修中或用于制备。

13. 发明申请

US20070142545A1 Multicomponent systems; method for producing the same and use thereof 审中-公开
标题翻译：多组分体系其制备方法及其用途
公开(公告)号：US20070142545A1
公开(公告)日：2007-06-21
申请号：US10598195
申请日：2005-01-26
申请人： Bernhard Lettmann , Egbert Nienhaus
发明人： Bernhard Lettmann , Egbert Nienhaus
IPC分类号： C08G18/08
CPC分类号： C08G18/0866 , C08G18/6254 , C09D175/04
摘要： Disclosed herein are multicomponent systems, processes for preparing them, and their use for preparing water-in-oil dispersions curable thermally or both thermally and with actinic radiation, and also their use as coating materials, adhesives, and sealants for producing coatings, adhesive layers, and seals. In one embodiment, a multicomponent system compries: (I) at least one water-in-oil dispersion comprising water and at least one water-soluble and/or water-dispersible, oligomeric and/or polymeric binder (A) having at least two isocyanate-reactive functional groups in solution and/or dispersion in at least one organic solvent; (II) at least one water-free liquid component comprising at least one polyisocyanate (B); and (III) water or at least one aqueous component comprising at least one binder (A) in dispersion and/or solution in water.
摘要翻译：本文公开了多组分体系，其制备方法以及它们用于制备热或热和光化辐射可固化的油包水分散体的用途，以及它们作为用于生产涂料，粘合剂层的涂料，粘合剂和密封剂的用途，和密封。在一个实施方案中，多组分体系包括：（I）至少一种包含水和至少一种水溶性和/或水分散性低聚物和/或聚合物粘合剂（A）的油包水分散体，其具有至少两个溶液中的异氰酸酯反应性官能团和/或在至少一种有机溶剂中的分散体; （II）至少一种包含至少一种多异氰酸酯（B）的无水液体组分; 和（III）水或至少一种包含至少一种在分散体和/或水溶液中的粘合剂（A）的水性组分。

14. 发明授权

US07037972B2 Multicomponent system which can be hardened by means of heat and actinic radiation, and use of the same 失效
标题翻译：可以通过热和光化辐射硬化的多组分体系，以及使用它们
公开(公告)号：US07037972B2
公开(公告)日：2006-05-02
申请号：US10398126
申请日：2001-09-26
申请人： Egbert Nienhaus , Bernhard Lettmann
发明人： Egbert Nienhaus , Bernhard Lettmann
IPC分类号： C08G18/00 , C08G18/04 , C08G18/28
CPC分类号： C09D175/16 , C08G18/6212 , C08G18/6229 , C08G18/8116
摘要： A multicomponent system curable thermally and with actinic radiation (dual cure), comprising (A) at least one component comprising at least one constituent containing at least one isocyanate-reactive functional group and at least one functional group having at least one bond which can be activated with actinic radiation, and at least one vinylaromatic-allyl alcohol copolymer, and (B) at least one component comprising at least one polyisocyanate, and its use as a coating material, adhesive and sealing compound.
摘要翻译：一种可热固化并具有光化辐射（双重固化）的多组分体系，其包含（A）至少一种包含至少一种含有至少一个异氰酸酯反应性官能团的组分和至少一个具有至少一个键的官能团的组分，以及至少一种乙烯基芳族 - 烯丙醇共聚物，和（B）至少一种包含至少一种多异氰酸酯的组分，以及其用作涂料，粘合剂和密封剂的用途。

15. 发明授权

US6025031A Coating agent consisting of at least 3 components 失效
标题翻译：涂层剂由至少3种组分组成
公开(公告)号：US6025031A
公开(公告)日：2000-02-15
申请号：US180083
申请日：1998-12-11
申请人： Bernhard Lettmann , Heinz-Peter Rink , Bernd Mayer , Egbert Nienhaus , Sunitha Grandhee
发明人： Bernhard Lettmann , Heinz-Peter Rink , Bernd Mayer , Egbert Nienhaus , Sunitha Grandhee
IPC分类号： C08G18/40 , C08G18/62 , C08G59/62 , C09D133/06 , C09D151/08 , C09D167/00 , C09D175/04 , B05D7/14
CPC分类号： C09D167/00 , C08G18/4063 , C08G18/4081 , C08G18/6254 , C09D151/08 , C09D175/04
摘要： The present invention relates to a coating composition consisting of at least three components (I), (II) and (III), component (I) containing as binder (A) at least one acrylate copolymer (A1) which is dispersed or dissolved in organic, optionally water-dilutable solvent and/or one polyester resin (A2) which is dispersed or dissolved in organic, optionally water-dilutable solvent and/or one polyurethane resin (A3) which is dispersed or dissolved in organic, optionally water-dilutable solvent and/or optionally a further binder (A4),component (II) contains at least one nonblocked polyisocyanate as crosslinking agent, andcomponent (III) contains as constituent essential to the invention an aqueous dispersion, prepared in a single- or multistage method, of a hydrophilicized polymer resin HP based on a hydrophobic polymer resin HP' and also, if desired, contains components (A1) and/or (A2) and/or (A3) and/or (A4) in aqueous dispersion.Also described is the use of the novel coating compositions for the finishing of automobile bodies and plastics parts and for automotive refinishing.
摘要翻译： PCT No.PCT / EP97 / 02024 Sec。 371 1998年12月11日第 102（e）日期1998年12月11日PCT 1997年4月22日PCT PCT。出版物WO97 / 42247 日本公开日1997年11月13日本发明涉及由至少三种成分（I），（II）和（III）组成的涂料组合物，含有至少一种丙烯酸酯共聚物（A1）作为粘合剂（A）的组分（I）分散或溶解在分散或溶解在有机，任选的水可稀释溶剂和/或一种聚氨酯树脂（A3）的有机，任选的水可稀释溶剂和/或一种聚酯树脂（A2）中，其分散或溶解在有机，任选的水可稀释溶剂和/或任选的另外的粘合剂（A4），组分（II）含有至少一种非封端多异氰酸酯作为交联剂，组分（III）含有本发明所必需的组分，基于疏水性聚合物树脂HP'的亲水化聚合物树脂HP以及如果需要，还含有组分（A1）和/或（A2）和/或（A3）和/或（A4）的单级或多级方法水分散体。还描述了新型涂料组合物用于汽车车身和塑料部件的整理以及用于汽车修补的用途。

16. 发明授权

US09889466B2 Method for coating a metal or plastic substrate, coating that can be obtained therefrom, and coated substrate 有权
公开(公告)号：US09889466B2
公开(公告)日：2018-02-13
申请号：US13636023
申请日：2011-03-18
申请人： Michael Grabbe , Bernhard Lettmann , Günther Ott
发明人： Michael Grabbe , Bernhard Lettmann , Günther Ott
IPC分类号： B05D1/36 , B05D3/02 , B05D7/14 , B05D7/00 , C08G18/08 , C08G18/58 , C09D5/08 , C09D5/44
CPC分类号： B05D3/0254 , B05D1/36 , B05D7/14 , B05D7/542 , B05D2202/10 , B05D2202/25 , C08G18/0814 , C08G18/581 , C09D5/08 , C09D5/4438 , Y10T428/31511
摘要： A method for coating an uncoated or precoated metallic or plastics substrate by (a) applying an aqueous coating composition (W) whose constituents are free or substantially free from blocked isocyanate groups, which comprises an aqueous dispersion of an epoxide-amine adduct, and which comprises either no crosslinking agent or one or more nonblocked polyisocyanate crosslinking agents, to the substrate, (b) optionally applying one or more further coating compositions, and (c) curing the coating composition (W) and, where appropriate, the further coating composition(s) at temperatures of below 90° C.

17. 发明授权

US07932317B1 Aqueous coating material and modular system for producing same 有权
标题翻译：水性涂料及其制造方法
公开(公告)号：US07932317B1
公开(公告)日：2011-04-26
申请号：US10018336
申请日：2000-04-13
申请人： Bernhard Lettmann
发明人： Bernhard Lettmann
IPC分类号： C09B67/00 , C08F8/30 , C08F218/04 , C08G18/08 , C08L39/00 , C08L75/00
CPC分类号： C09D5/02 , C09D7/80 , Y10T428/31873
摘要： An aqueous coating material preparable by mixing with one another (A1) at least one substantially water-free base color comprising (a11) at least one optionally water-soluble or -dispersible binder, (a12) at least one color and/or effect pigment, and (a13) at least one optionally water-miscible organic solvent; (A2) at least one aqueous base color comprising (a21) at least one water-soluble or -dispersible binder, (a22) at least one color pigment, and (a23) water; and (B) at least one aqueous pigment-free mixing varnish comprising (b1) at least one water-soluble or -dispersible binder and (b2) water; and also, if desired, comprising (C) an aqueous medium comprising (c1) a rheology control additive; and also a modular system for preparing aqueous coating materials, comprising (I) at least one substantially water-free color and/or effect module, comprising at least one base color (A1), (II) at least one aqueous color module comprising at least one base color (A2), and (III) at least one aqueous, pigment-free mixing varnish module comprising at least one aqueous, pigment-free mixing varnish (B), and if desired (IV) at least one rheology module.
摘要翻译：可通过彼此混合制备的水性涂料（A1）至少一种基本上无水的基色，其包含（a11）至少一种任选的水溶性或可分散的粘合剂，（a12）至少一种颜色和/或效果颜料和（a13）至少一种任选的水混溶性有机溶剂; （A2）至少一种水性基色，其包含（a21）至少一种水溶性或可分散粘合剂，（a22）至少一种着色颜料和（a23）水; 和（B）至少一种含水不含颜料的混合清漆，其包含（b1）至少一种水溶性或可分散的粘合剂和（b2）水; 并且如果需要，还包含（C）包含（c1）流变控制添加剂的水性介质; 还包括用于制备水性涂料的模块化系统，其包含（I）至少一种基本上无水的颜色和/或效果模块，其包含至少一种碱颜色（A1），（II）至少一种水性颜色模块，其包含至少一种碱颜色（A2）和（III）至少一种含颜料的无水混合清漆组合物，其包含至少一种无水颜料的混合清漆（B），如果需要（IV）至少一种流变模块。

18. 发明授权

US07812088B2 Aqueous multi-constituent coating material, method for the production thereof and use of the same 有权
标题翻译：水性多组分涂料，其制备方法和用途
公开(公告)号：US07812088B2
公开(公告)日：2010-10-12
申请号：US10250639
申请日：2002-02-13
申请人： Bernhard Lettmann , Andreas Jansen , Christella Pudelski
发明人： Bernhard Lettmann , Andreas Jansen , Christella Pudelski
IPC分类号： C08G18/42 , C08G18/66 , C08G18/12
CPC分类号： C09D175/04 , C08G18/6254
摘要： An aqueous multicomponent coating material comprising (I) an aqueous component preparable by mixing at least the following starting products: (A) at least one secondary aqueous dispersion of at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group, (B) at least one primary aqueous dispersion of at least one (meth)acrylate copolymer containing no isocyanate-reactive functional group, and (C) at least one pigment and/or one filler; and also (II) a component comprising at least one polyisocyanate as crosslinking agent, and also a process for preparing it, and its use.
摘要翻译：一种水性多组分涂料，其包含（I）通过混合至少以下起始产物可制备的水性组分：（A）至少一种至少一种（甲基）丙烯酸酯共聚物的第二水性分散体，其每分子平均含有至少一个异氰酸酯 - 反应性官能团，（B）至少一种不含异氰酸酯反应性官能团的至少一种（甲基）丙烯酸酯共聚物的主要水分散体，和（C）至少一种颜料和/或一种填料; 以及（II）包含至少一种多异氰酸酯作为交联剂的组分，以及其制备方法及其用途。

19. 发明授权

US07683105B2 Mixture containing a solvent, which can be cured with UV-A radiation, method for its production, and use thereof 有权
标题翻译：含有溶剂的混合物，其可以用UV-A辐射固化，其制备方法及其用途
公开(公告)号：US07683105B2
公开(公告)日：2010-03-23
申请号：US11816776
申请日：2006-01-28
申请人： Bernhard Lettmann , Klaus-Udo Reize , Egbert Nienhaus
发明人： Bernhard Lettmann , Klaus-Udo Reize , Egbert Nienhaus
IPC分类号： C08F2/48 , C08J3/28 , C08F2/50
CPC分类号： C08L33/062 , C08K5/101 , C09D4/00
摘要： A UV-A-curable, solvent-containing composition composed of (A) 1% to 50% by weight of a UV-A-curable constituent containing isocyanate-reactive groups; (B) 0.01% to 10% by weight of a colorless photoinitiator having an absorption maximum in the wavelength range of λ=300 to 400 nm; (C) 10% to 70% by weight of an alkyl and/or cycloalkyl acetate having 3 to 10 carbon atoms in the alkyl radical and/or in the cycloalkyl radical; (D) 10% to 70% by weight of an alkoxyalkyl, alkoxycycloalkyl, cycloalkoxyalkyl and/or cycloalkoxycycloalkyl acetate; (E) 0.01% to 5% by weight of a constituent that lowers the interfacial tension; (F) 0 to 50% by weight of an alkylaromatic having at least two alkyl radicals having 1 to 6 carbon atoms in the molecule; and (G) 0 to 50% by weight of an additive different from constituents (A) to (F); processes for preparing it, and its use as a spot blender in automotive refinishing, especially in spot repair, or for preparation thereof.
摘要翻译：包含（A）1重量％至50重量％的含有异氰酸酯反应性基团的UV-A可固化组分的UV-A固化的含溶剂组合物; （B）0.01〜10重量％的λ= 300〜400nm波长范围吸收最大的无色光引发剂; （C）10％至70％重量的烷基和/或烷基和/或环烷基中具有3至10个碳原子的烷基和/或环烷基乙酸酯; （D）10重量％至70重量％的烷氧基烷基，烷氧基环烷基，环烷氧基烷基和/或环烷氧基环烷基乙酸酯; （E）0.01〜5重量％的降低界面张力的组分; （F）0至50重量％的分子中具有至少两个具有1至6个碳原子的烷基的烷基芳族化合物; 和（G）0至50重量％的不同于组分（A）至（F）的添加剂; 其制备方法，以及其作为汽车修补中的现场搅拌器的使用，特别是在现场维修中或用于制备。

20. 发明申请

US20090018254A1 AQUEOUS MULTICOMPONENT SYSTEMS, THEIR PREPARATION AND USE 审中-公开
标题翻译：水质多功能体系，其制备和使用
公开(公告)号：US20090018254A1
公开(公告)日：2009-01-15
申请号：US12162663
申请日：2007-02-08
申请人： Inge Huster , Bernhard Lettmann , Egbert Nienhaus
发明人： Inge Huster , Bernhard Lettmann , Egbert Nienhaus
IPC分类号： C08L75/04 , C08L33/10
CPC分类号： C08G18/6659 , C08G18/12 , C08G18/4063 , C08G18/6216 , C08G18/792 , C08G18/3206
摘要： Disclosed herein is an aqueous multicomponent system comprising (I) at least one aqueous binder component comprising (A) at least one secondary dispersion comprising (A1) at least one water-soluble or water-dispersible (meth)acrylate copolymer which can be prepared by a multistage copolymerization and has at least two isocyanate-reactive functional groups, and (A2) at least one low molecular weight or oligomeric, or at least one low molecular weight and oligomeric, substantially unbranched, hydrophobic polyester having at least two hydroxyl groups in the molecule, an OH number of 56 to 500 mg KOH/g, an acid number less than 10 mg KOH/g, and a number-average molecular weight Mn of 300 to 2000 Daltons, the at least one aqueous binder further comprising (B) at least one additive. The aqueous multicomponent system further comprises at least one water-free crosslinking component comprising at least one hydrophilicized polyisocyanate. Also disclosed is a process for preparing the foregoing aqueous multicomponent system.
摘要翻译：本文公开了一种水性多组分体系，其包含（I）至少一种水性粘合剂组分，其包含（A）至少一种第二分散体，其包含（A1）至少一种水溶性或水分散性（甲基）丙烯酸酯共聚物，其可以由多级共聚合并具有至少两个异氰酸酯反应性官能团，和（A2）至少一种低分子量或低聚物，或至少一种低分子量和低聚，基本上未分支的疏水性聚酯，其在分子，OH值为56〜500mg KOH / g，酸值小于10mg KOH / g，数均分子量Mn为300〜2000道尔顿，所述至少一种含水粘合剂还含有（B）至少一种添加剂。水性多组分体系还包含至少一种包含至少一种亲水化多异氰酸酯的无水交联组分。还公开了制备上述水性多组分体系的方法。

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