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11. 发明授权

US06265602B1 Method for hydrogenating aliphatic alpha-, omega-dinitriles 失效
标题翻译：脂肪族α-，ω-二腈的氢化方法
公开(公告)号：US06265602B1
公开(公告)日：2001-07-24
申请号：US09622800
申请日：2000-08-23
申请人： Guido Voit , Frank Ohlbach , Hermann Luyken , Martin Merger , Alwin Rehfinger , Rolf Hartmuth Fischer , Peter Bassler , Andreas Ansmann
发明人： Guido Voit , Frank Ohlbach , Hermann Luyken , Martin Merger , Alwin Rehfinger , Rolf Hartmuth Fischer , Peter Bassler , Andreas Ansmann
IPC分类号： C07C25500
CPC分类号： C07C253/30 , B01J23/02 , B01J23/78 , C07C209/48 , C07C211/12 , C07C255/24
摘要： A process for hydrogenation of aliphatic alpha, omega-dinitriles in the presence of a heterogeneous fixed bed catalyst comprises using a reaction mixture comprising from 2 &mgr;mol to 30 mmol NA, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, based on 10 mol of aliphatic alpha, omega-dinitrile used.
摘要翻译：在异相固定床催化剂存在下，脂肪族α，ω-二腈的氢化方法包括使用包含2μmol-30mmol NA，K，Rb，Cs，Mg，Ca，Sr，Ba或Mn的反应混合物或基于10摩尔所用的脂肪族α，ω-二腈的碱性盐形式的混合物。

12. 发明授权

US06815388B1 Method for activating passivated iron 失效
标题翻译：激活钝化铁的方法
公开(公告)号：US06815388B1
公开(公告)日：2004-11-09
申请号：US10088406
申请日：2002-03-19
申请人： Frank Ohlbach , Rolf Fischer , Hermann Luyken , Johann-Peter Melder , Martin Merger , Andreas Ansmann , Peter Bassler
发明人： Frank Ohlbach , Rolf Fischer , Hermann Luyken , Johann-Peter Melder , Martin Merger , Andreas Ansmann , Peter Bassler
IPC分类号： B01J3808
CPC分类号： B01J37/18 , B01J23/745
摘要： Passivated iron useful as catalytically active component after activation is activated by hydrogen at elevated temperature and elevated pressure in the presence of a nitrile.
摘要翻译：活化后可用作催化活性组分的钝化铁在高温和高压下在腈的存在下由氢活化。

13. 发明授权

US6140545A Preparation of alcohols 失效
标题翻译：醇的制备
公开(公告)号：US6140545A
公开(公告)日：2000-10-31
申请号：US251462
申请日：1999-02-17
申请人： Martin Merger , Shelue Liang , Rolf Fischer , Joachim Wulff-Doring
发明人： Martin Merger , Shelue Liang , Rolf Fischer , Joachim Wulff-Doring
IPC分类号： C07C29/149 , C07C37/08
CPC分类号： C07C29/149 , C07C2101/14
摘要： In a process for preparing alcohols by gas phase hydrogenation of carboxylic acids or esters thereof at elevated temperature and elevated pressure in the presence of catalysts consisting of or comprising, as hydrogenating components, oxides of main group VI and/or subgroup IV, the hydrogenation is carried outa) at from 250.degree. C. to 400.degree. C. and from 5 bar to 100 bar in the presence ofb) primary or secondary alcohols, the molar hydrogen/alcohol ratio being at most 800.
摘要翻译：在通过在升高的温度和升高的压力下，在由主要VI族和/或第IV族的氧化物组成或包含氢化组分的催化剂存在下，在羧酸或其酯的气相氢化制备醇的方法中，氢化是在b）伯醇或仲醇的存在下，在250℃至400℃和5巴至100巴下进行a），氢/醇摩尔比为至多800。

14. 发明授权

US06362333B1 Method for simultaneously producing a cyclic lactam and a cyclic amine 失效
标题翻译：同时制备环状内酰胺和环胺的方法
公开(公告)号：US06362333B1
公开(公告)日：2002-03-26
申请号：US09786940
申请日：2001-03-12
申请人： Martin Merger , Rolf Fischer , Andreas Ansmann
发明人： Martin Merger , Rolf Fischer , Andreas Ansmann
IPC分类号： C07D20108
CPC分类号： C07D201/02 , C07D201/08 , C07D295/023
摘要： A cyclic lactam and a cyclic amine are coproduced by coreacting an aliphatic alpha, omega-diamine and an aliphatic alpha, omega-aminonitrile with water in the gas phase in the presence of a heterogeneous catalyst.
摘要翻译：通过在非均相催化剂的存在下，在气相中与脂肪族α，ω-二胺和脂族α，ω-氨基腈与水共核反应来共同制备环状内酰胺和环胺。

15. 发明授权

US06362332B1 Coproduction of a cyclic lactam and a cyclic amine 失效
标题翻译：环内酰胺和环胺的共同生产
公开(公告)号：US06362332B1
公开(公告)日：2002-03-26
申请号：US09786914
申请日：2001-03-12
申请人： Martin Merger , Rolf Fischer , Andreas Ansmann
发明人： Martin Merger , Rolf Fischer , Andreas Ansmann
IPC分类号： C07D22310
CPC分类号： C07D201/02 , C07D295/023
摘要： A cyclic lactam and a cyclic amine are coproduced by reacting an aliphatic alpha, omega-diamine with water in the gas phase in the presence of a heterogeneous catalyst.
摘要翻译：在非均相催化剂存在下，通过在气相中使脂族α，ω-二胺与水反应来共同制备环状内酰胺和环胺。

16. 发明申请

US20120232309A1 PROCESS FOR THE PREPARATION OF PRIMARY AMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 有权
标题翻译：通过均相催化的醇醇胺化制备主要胺的方法
公开(公告)号：US20120232309A1
公开(公告)日：2012-09-13
申请号：US13415174
申请日：2012-03-08
申请人： Thomas SCHAUB , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
发明人： Thomas SCHAUB , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
IPC分类号： C07C209/16 , C07C211/02
CPC分类号： C07C213/02 , C07C215/08 , C07C217/08
摘要： Preparing a primary amine by alcohol amination of alcohol with ammonia and elimination of water includes reacting, in a homogeneously catalyzed reaction, a mixture of alcohol, ammonia, nonpolar solvent, and catalyst, in a liquid phase, to obtain a product mixture. The process then includes phase separating the product mixture into a polar product phase and a nonpolar product phase, and separating off the nonpolar product phase. At least some of the nonpolar phase returns to the homogenously catalyzed reaction. The process further includes separating off amination product from the polar product phase. At least some of the catalyst is in the nonpolar phase, and the catalyst accumulates in the nonpolar phase.
摘要翻译：通过醇与醇的氨基化反应制备伯胺并除去水包括在均相催化的反应中，将醇，氨，非极性溶剂和催化剂的混合物在液相中反应，得到产物混合物。然后，该方法包括将产物混合物相分离成极性产物相和非极性产物相，并将非极性产物相分离。至少一些非极性相返回均匀催化反应。该方法还包括从极性产物相分离胺化产物。至少一些催化剂处于非极性相，并且催化剂积聚在非极性相中。

17. 发明授权

US07091375B2 Method for the production of 2=-keto-l-gulonic acid C4C10 alkyl esters 失效
标题翻译：制备2 =酮-1-古洛糖酸C 4 C 10烷基酯的方法
公开(公告)号：US07091375B2
公开(公告)日：2006-08-15
申请号：US10534334
申请日：2003-11-07
申请人： Thomas Domschke , Martin Merger , Georg Grossmann , Tillmann Faust
发明人： Thomas Domschke , Martin Merger , Georg Grossmann , Tillmann Faust
IPC分类号： C07D305/12
CPC分类号： C07H7/027 , Y02P20/127
摘要： The invention relates to a method for producing 2-keto-L-gulonic acid-C4–C10 alkyl ester by esterifying 2-keto-L-gulonic acid (KGS) with an unsaturated, branched or unbranched C4–C10 alcohol. The inventive method is characterized by the fact that an aqueous KGS solution is reacted with a C4–C10 alcohol up to an esterification degree of 20 to 70 percent in a pre-esterification process carried out under acidic catalysis conditions; and the obtained product is dehydrogenated with an unsaturated, branched or unbranched C4–C10 alcohol in a continuous rectification device, whereby the esterification reaction continues, n-butanol preferably being used as the alkyl alcohol. In a preferred embodiment, the aqueous KGS solution is concentrated up to or beyond the limit of solubility prior to the esterification process, preferably by catalyzing a homogeneous or heterogeneous catalyst, especially sulfonic acid, at temperatures of 50 to 120° C. In another embodiment, the produced KGS ester is reacted in one or several additional steps so as to obtain L-ascorbic acid.
摘要翻译：本发明涉及通过酯化2-酮-L-古洛糖酸（KGS）制备2-酮-L-古洛糖酸-C 4 -C 10烷基酯的方法）与不饱和，支链或非支链C 4 -C 10醇。本发明的方法的特征在于，将KGS水溶液与C 4 -C 10 - 醇反应，直到酯化程度为20至70％在酸性催化条件下进行酯化过程; 并将得到的产物用连续精馏装置中的不饱和支链或非支链C 4 -C 10醇脱氢，由此继续进行酯化反应，正丁醇优选为用作烷基醇。在优选的实施方案中，在酯化过程之前，优选通过在50至120℃的温度下催化均相或多相催化剂，特别是磺酸，将KGS水溶液浓缩至或超过溶解度的极限。在另一个实施方案中，所制备的KGS酯在一个或几个附加步骤中反应，以获得L-抗坏血酸。

18. 发明授权

US09193666B2 Process for preparing alkanolamines by homogeneously catalyzed alcohol amination 有权
标题翻译：通过均匀催化醇胺化制备链烷醇胺的方法
公开(公告)号：US09193666B2
公开(公告)日：2015-11-24
申请号：US13415409
申请日：2012-03-08
申请人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
发明人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
IPC分类号： C07C209/66 , C07F15/00 , C07C209/16 , C07C213/02 , C07D207/02 , C07D207/20 , C07D295/027 , C07D307/52
CPC分类号： C07C209/16 , C07C213/02 , C07D207/02 , C07D207/20 , C07D295/027 , C07D307/52 , C07C211/09 , C07C215/08 , C07C217/08 , C07C211/10 , C07C211/12
摘要： Process for preparing alkanolamines which have a primary amino group (—NH2) and a hydroxyl group (—OH) by alcohol amination of diols having two hydroxyl groups (—OH) by means of ammonia with elimination of water, wherein the reaction is carried out homogeneously catalyzed in the presence of at least one complex catalyst comprising at least one element selected from groups 8, 9 and 10 of the Periodic Table and also at least one donor ligand.
摘要翻译：制备具有伯氨基（-NH 2）和羟基（-OH）的链烷醇胺的方法，其通过用氨除去水而具有两个羟基（-OH）的二醇醇胺化，其中反应进行在包含至少一种选自元素周期表第8,9和10族的元素的复合催化剂的存在下，以及至少一种供体配体均匀催化。

19. 发明申请

US20060058550A1 Method for the production of 2 =-keto-l-gulonic acid c4-c10 alkyl esters 失效
标题翻译：制备2 =酮-1-古洛糖酸c4-c10烷基酯的方法
公开(公告)号：US20060058550A1
公开(公告)日：2006-03-16
申请号：US10534334
申请日：2003-11-07
申请人： Thomas Domschke , Martin Merger , Georg Grobmann , Tillmann Faust
发明人： Thomas Domschke , Martin Merger , Georg Grobmann , Tillmann Faust
IPC分类号： C07C69/66
CPC分类号： C07H7/027 , Y02P20/127
摘要： The invention relates to a method for producing 2-keto-L-gulonic acid-C4-C10 alkyl ester by esterifying 2-keto-L-gulonic acid (KGS) with an unsaturated, branched or unbranched C4-C10 alcohol. The inventive method is characterized by the fact that an aqueous KGS solution is reacted with a C4-C10 alcohol up to an esterification degree of 20 to 70 percent in a pre-esterification process carried out under acidic catalysis conditions; and the obtained product is dehydrogenated with an unsaturated, branched or unbranched C4-C10 alcohol in a continuous rectification device, whereby the esterification reaction continues, n-butanol preferably being used as the alkyl alcohol. In a preferred embodiment, the aqueous KGS solution is concentrated up to or beyond the limit of solubility prior to the esterification process, preferably by catalyzing a homogeneous or heterogeneous catalyst, especially sulfonic acid, at temperatures of 50 to 120 ° C. In another embodiment, the produced KGS ester is reacted in one or several additional steps so as to obtain L-ascorbic acid.
摘要翻译：本发明涉及通过酯化2-酮-L-古洛糖酸（KGS）制备2-酮-L-古洛糖酸-C 4 -C 10烷基酯的方法）与不饱和，支链或非支链C 4 -C 10醇。本发明的方法的特征在于，将KGS水溶液与C 4 -C 10 - 醇反应，直到酯化程度为20至70％在酸性催化条件下进行酯化过程; 并将得到的产物用连续精馏装置中的不饱和支链或非支链C 4 -C 10醇脱氢，由此继续进行酯化反应，正丁醇优选为用作烷基醇。在优选的实施方案中，在酯化过程之前，优选通过在50至120℃的温度下催化均相或多相催化剂，特别是磺酸，将KGS水溶液浓缩至或超过溶解度的极限。在另一个实施方案中，所制备的KGS酯在一个或几个附加步骤中反应，以获得L-抗坏血酸。

20. 发明授权

US06677486B2 Hydrogenation of nitriles over Raney catalysts 失效
标题翻译：在阮内催化剂上氢化腈
公开(公告)号：US06677486B2
公开(公告)日：2004-01-13
申请号：US09985982
申请日：2001-11-07
申请人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
发明人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
IPC分类号： C07C2948
CPC分类号： C07D295/13 , B01J25/00 , B01J37/0018 , C07C209/48 , C07C211/14 , C07C211/36
摘要： Nitriles are hydrogenated to primary amines over an activated, alpha-Al2O3-containing, macroporous Raney catalyst based on an alloy of aluminum and at least one transition metal selected from the group consisting of iron, cobalt and nickel, and, if desired, one or more further transition metals selected from the group consisting of titanium, zirconium, chromium and manganese, which is obtainable by a process comprising the steps in the order (a)-(f): (a) preparing a kneadable composition comprising the alloy, a shaping aid, water and a pore former; (b) shaping the kneadable composition to form a shaped body; (c) calcining the shaped body; (d) activating the calcined shaped body by treatment with aqueous alkali metal hydroxide solution; (e) rinsing the shaped catalyst body with aqueous alkali metal hydroxide solution; (f) rinsing the shaped catalyst body with water.
摘要翻译：基于铝和至少一种选自铁，钴和镍的过渡金属的合金，并且如果需要，腈在一种活化的含α-Al 2 O 3的大孔阮内催化剂上氢化成伯胺，如果需要，（a） - （f）：（a）制备包含该合金的可捏合组合物的方法可以获得更多的选自钛，锆，铬和锰的过渡金属，成型助剂，水和成孔剂;（b）使捏合组合物成形以形成成形体;（c）煅烧成形体;（d）用碱金属氢氧化物水溶液处理活化煅烧成形体;（e）用碱金属氢氧化物水溶液冲洗成型的催化剂体;（f）用水冲洗成型的催化剂体。

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