专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

11. 发明授权

US4346240A Hydrogenation of esters using alkali doped heterogeneous group VIII transition metal catalysts 失效
标题翻译：使用碱掺杂的异质基团VIII过渡金属催化剂氢化酯
公开(公告)号：US4346240A
公开(公告)日：1982-08-24
申请号：US307031
申请日：1981-09-29
申请人： Roger A. Grey , Guido P. Pez
发明人： Roger A. Grey , Guido P. Pez
IPC分类号： B01J23/58 , B01J31/28 , C07C29/149 , C07C31/38
CPC分类号： B01J31/0204 , B01J23/58 , B01J31/0212 , B01J31/122 , B01J31/26 , B01J31/28 , B01J31/30 , C07C29/149 , B01J21/18 , B01J2231/641 , B01J31/1616 , Y02P20/52
摘要： A novel class of heterogeneous catalysts, containing Group VIII transition metals in combination with alkali organic compounds is prepared, such as potassium naphthalene on ruthenium on carbon. The catalysts are useful as heterogeneous catalysts in the hydrogenation of carboxylic acid esters. A process for producing the materials is described. The catalysts permit the process of the hydrogenation of carboxylic acid esters to primary alcohols to be conducted with the ester in the liquid phase at a temperature not exceeding about 150.degree. C. with high selectivity. Catalysts of Group VIII transition metals and alkali metal on carbon are also useful in such processes.
摘要翻译：制备了一类新颖的非均相催化剂，其中含有与碱性有机化合物组合的第VIII族过渡金属，例如萘上钌碳上的萘。催化剂可用作羧酸酯氢化中的非均相催化剂。对材料的制造方法进行说明。催化剂允许羧酸酯与伯醇的氢化在液相中以不超过约150℃的温度以高选择性进行。第VIII族过渡金属和碱金属碳的催化剂在这些方法中也是有用的。

12. 发明授权

US4060499A Copper chloride/boron nitride catalyst for substitution chlorination 失效
标题翻译：氯化铜/氮化硼催化剂用于取代氯化
公开(公告)号：US4060499A
公开(公告)日：1977-11-29
申请号：US761561
申请日：1977-01-24
申请人： Wim J. M. Pieters , Emery J. Carlson , Guido P. Pez
发明人： Wim J. M. Pieters , Emery J. Carlson , Guido P. Pez
IPC分类号： B01J27/24 , C07B39/00 , C07C17/10 , B01J21/00 , B01J27/06 , C07C17/00
CPC分类号： C07C17/10 , B01J27/24 , C07B39/00
摘要： A catalyst consisting essentially of cuprous chloride intercalated in crystalline boron nitride, containing at least 10% copper, useful for substitution chlorination of organic substances in vapor phase at elevated temperature by action of chlorine or HCL and oxygen. Highly selective for chlorination versus oxidation and hydrolysis even at high conversions, using partially chlorinated organic material as reactant, in particular methyl chloride.
摘要翻译：一种主要由氯化亚铜组成的催化剂，其插入结晶氮化硼中，含有至少10％的铜，可用于通过氯或HCL和氧的作用在升高的温度下进行有机物质的取代氯化。即使在高转化率下，也可选择性地进行氯化与氧化和水解，使用部分氯化有机材料作为反应物，特别是氯甲烷。

13. 发明授权

US07101530B2 Hydrogen storage by reversible hydrogenation of pi-conjugated substrates 有权
标题翻译：通过π-共轭底物的可逆氢化来储存氢
公开(公告)号：US07101530B2
公开(公告)日：2006-09-05
申请号：US10430246
申请日：2003-05-06
申请人： Guido P. Pez , Aaron R. Scott , Alan C. Cooper , Hansong Cheng
发明人： Guido P. Pez , Aaron R. Scott , Alan C. Cooper , Hansong Cheng
IPC分类号： C01B3/00 , F17C11/00
CPC分类号： C01B3/0015 , Y02E60/328
摘要： Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.
摘要翻译：提供了通过扩展的π-共轭底物的基本可逆的催化氢化来提供氢的方法，其包括大的多环芳烃，具有氮杂原子的多环芳烃，具有氧杂原子的多环芳烃，具有烷基的多环芳烃烷氧基，酮，醚或聚醚取代基，包含5元环的π-共轭分子，包含具有氮或氧杂原子的六元和五元环的π-共轭分子和延伸的π-共轭有机聚合物。包含在延伸的π-共轭体系的至少部分氢化形式中的氢可以通过在脱氢催化剂的存在下通过催化脱氢来容易地释放使用，所述脱氢催化剂可以通过降低氢气压力来实现，通常压力大于0.1巴或将温度升高到小于250℃或更低，或通过这两个工艺参数的组合。

14. 发明授权

US4580404A Method for adsorbing and storing hydrogen at cryogenic temperatures 失效
标题翻译：在低温下吸附和储存氢的方法
公开(公告)号：US4580404A
公开(公告)日：1986-04-08
申请号：US764150
申请日：1985-08-09
申请人： Guido P. Pez , William A. Steyert
发明人： Guido P. Pez , William A. Steyert
IPC分类号： F04B37/04 , B01D8/00
CPC分类号： F04B37/04 , Y10S417/901
摘要： Hydrogen is stored at cryogenic temperatures by adsorption on porous carbon having a nitrogen BET apparent surface area above about 1500 m.sup.2 /g. Hydrogen can be adsorbed and desorbed in the context of a cryopump, having as the pumping element a panel, having large particles of pressed porous carbon thereon.
摘要翻译：通过在具有大于约1500m 2 / g的氮BET表观表面积的多孔碳上吸附将氢储存在低温温度下。可以在低温泵的上下文中吸附和解吸氢，其具有作为泵送元件的面板，其上具有大的压制多孔碳颗粒。

15. 发明授权

US4254059A Process for hydrogenation of nitriles 失效
标题翻译：腈水解方法
公开(公告)号：US4254059A
公开(公告)日：1981-03-03
申请号：US62874
申请日：1979-08-01
申请人： Roger A. Grey , Guido P. Pez
发明人： Roger A. Grey , Guido P. Pez
IPC分类号： B01J31/18 , B01J31/24 , C07C209/48 , C07C85/20
CPC分类号： C07C209/48 , B01J31/2404 , B01J2231/643 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/842 , B01J31/1895
摘要： A novel process is described for the homogeneous hydrogenation of nitriles to primary amines utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the high yield hydrogenation of nitriles to primary amines to be conducted under mild conditions of temperature and pressure with high selectivity and eliminates the need for the presence of ammonia to suppress the formation of significant amounts of secondary and tertiary amines.
摘要翻译：描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂将腈均相氢化成伯胺的新方法。使用这些阴离子催化剂允许腈在高温选择性条件下在温和条件下进行的腈的高产率氢化，并且不需要氨的存在来抑制显着量的仲胺和叔胺的形成。

16. 发明授权

US4232170A Process for homogeneous hydrogenation of esters 失效
标题翻译：酯类均相加氢方法
公开(公告)号：US4232170A
公开(公告)日：1980-11-04
申请号：US007876
申请日：1979-01-31
申请人： Roger A. Grey , Guido P. Pez
发明人： Roger A. Grey , Guido P. Pez
IPC分类号： C07C29/149 , C07C69/675 , C07C27/04 , C07C31/38
CPC分类号： C07C29/149 , Y02P20/52
摘要： A novel process is described for the homogeneous hydrogenation of carboxylic acid esters to primary alcohols utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted in solution under mild conditions of temperature and pressure with high selectivity and eliminates the disadvantages of utilizing heterogeneous catalysts. A process is also described for decarbonylating formate esters utilizing said compositions as catalysts.
摘要翻译：描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的羧酸酯与伯醇的均相氢化的新方法。使用这些阴离子催化剂允许该方法在温和和高温的温和条件下在溶液中进行，并且消除了利用非均相催化剂的缺点。还描述了使用所述组合物作为催化剂的甲酸酯脱羧酸酯的方法。

17. 发明授权

US4224458A Process for homogeneous hydrogenation of polycyclic aromatic hydrocarbons 失效
标题翻译：多环芳烃均相氢化方法
公开(公告)号：US4224458A
公开(公告)日：1980-09-23
申请号：US7877
申请日：1979-01-31
申请人： Roger A. Grey , Guido P. Pez
发明人： Roger A. Grey , Guido P. Pez
IPC分类号： C07C5/11 , C07C13/28 , C07C15/24 , C07C15/28
CPC分类号： C07C5/11 , C07C2102/10 , C07C2531/22
摘要： An improved process is described for the homogeneous hydrogenation of polycyclic aromatic hydrocarbons utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted under mild conditions of temperature and pressure with high selectivity for the production of partially hydrogenated derivatives of polycyclic aromatic hydrocarbons such as 1,2,3,4-tetrahydronaphthalene, and eliminates the need for the presence of base or carbon monoxide atmosphere in the process.
摘要翻译：描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的多环芳烃的均相氢化的改进方法。使用这些阴离子催化剂允许该方法在温和的温度和压力条件下进行，并且高选择性地生产多环芳烃如1,2,3,4-四氢化萘的部分氢化衍生物，并且不需要在该过程中存在碱或一氧化碳气氛。

18. 发明授权

US4024169A Titanium complexes with nitrogen 失效
标题翻译：钛与钛配合物
公开(公告)号：US4024169A
公开(公告)日：1977-05-17
申请号：US636197
申请日：1975-11-28
申请人： Guido P. Pez
发明人： Guido P. Pez
IPC分类号： C07F7/28 , C07F17/00
CPC分类号： C07F17/00 , C07F7/28
摘要： Complexes of the titanium cyclopentadienyl compound ##STR1## and nitrogen, having the probable structure: ##STR2## where the symbol N.apprxeq.N represents a bonding state intermediate between the azo-N=N- bond and the hydrazine =N-N= bond; such complex having the simple dimeric form as indicated by molecular weight determination on this form dissolved in tetrahydrofuran, and having a polymeric form wherein a nitrogen atom of one molecule of the dimeric form is coordinated by a dative link with a Ti atom of another molecule of the dimeric form, as suggested by low solubility of this polymeric form in 1,2-dimethoxyethane and breakdown of this form to the dimeric form by action of tetrahydrofuran.Another related complex is a black solid nitrogen-containing reaction product of the above titanium cyclopentadienyl compound in dry state with nitrogen at about 60 atmospheres pressure, having an infrared spectrum typical of a metallocene compound with no N-N or Ti-N vibration absorption bands.The nitrogen in these complexes is reactive, e.g. with reducing agents such as potassium naphthalene, to afford ammonia. Moreover, the complexes are catalytically active for hydrocarbon conversions such as conversion of ethylene to ethane, butane, 1-butene and 1,3-butadiene.
摘要翻译：具有可能结构的钛环戊二烯基化合物＆lt; IMAGE＆gt;和氮的配合物：其中符号N APPROX N表示偶氮-N = N-键和肼= N-N =键之间的键合状态; 这种复合物具有简单的二聚体形式，如该形式的分子量测定所示，溶解在四氢呋喃中，并且具有聚合形式，其中一个分子二聚体形式的氮原子与另一个分子的Ti原子这种二聚体形式，如该聚合物形式在1,2-二甲氧基乙烷中的低溶解度所示，并且通过四氢呋喃的作用将该形式分解成二聚体形式。

19. 发明授权

US5336298A Polyelectrolyte membranes for the separation of acid gases 失效
标题翻译：用于分离酸性气体的聚电解质膜
公开(公告)号：US5336298A
公开(公告)日：1994-08-09
申请号：US38780
申请日：1993-03-29
申请人： Robert Quinn , Daniel V. Laciak , John B. Appleby , Guido P. Pez
发明人： Robert Quinn , Daniel V. Laciak , John B. Appleby , Guido P. Pez
IPC分类号： B01D53/22 , B01D69/12 , B01D71/82
CPC分类号： B01D53/228 , B01D69/12 , B01D71/82
摘要： Acid gases are separated from a gas stream by bringing the gas stream into contact with a multilayer composite membrane comprising a nonselective polymeric support layer and an active separating layer comprising a polyelectrolyte polymer which contains cationic groups which are electrostatically associated with anions for which the pK.sub.a of the conjugate acid is greater than 3.
摘要翻译：通过使气流与包含非选择性聚合物支撑层的多层复合膜和包含聚电解质聚合物的活性分离层接触而将酸性气体与气流分离，该聚电解质聚合物包含阳离子基团，该阳离子基团与阴离子静电相关，其中pKa 共轭酸大于3。

20. 发明授权

US5252733A Volatile crown ligand .beta.-diketonate alkaline earth metal complexes 失效
标题翻译：挥发性冠配体β-二酮碱土金属络合物
公开(公告)号：US5252733A
公开(公告)日：1993-10-12
申请号：US534811
申请日：1990-06-05
申请人： John A. T. Norman , Guido P. Pez
发明人： John A. T. Norman , Guido P. Pez
IPC分类号： C07D323/00 , C07D259/00 , C07D273/00 , C07D285/00 , C07D291/00 , C07D327/00 , C07D341/00 , C07F3/00 , C07F3/04 , C07F5/00 , C23C16/18 , C07D225/00
CPC分类号： C07F3/003 , C07F5/003
摘要： Volatile .beta.-diketonate alkaline earth metal complexes useful in chemical vapor deposition (CVD) operations are formed using a cyclic ligand, such as a macrocyclic crown ether, to increase the degree of coordination and shielding around the individual metal ions in the diketonate structure. The resultant monomeric complexes readily volatize to give a chemically stable vapor.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式