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1. 发明授权

US4780114A Molten salt hydrate membranes for the separation of gases 失效
标题翻译：用于分离气体的熔融盐水合物膜
公开(公告)号：US4780114A
公开(公告)日：1988-10-25
申请号：US108501
申请日：1987-10-14
申请人： Robert Quinn , Guido P. Pez , John B. Appleby
发明人： Robert Quinn , Guido P. Pez , John B. Appleby
IPC分类号： B01D53/22 , B01D61/00 , B01D61/38 , B01D69/00 , B01D69/14 , C01B32/50 , C07C1/00 , C07C7/144 , C07C9/04 , C07C11/02 , C07C67/00
CPC分类号： B01D69/142 , B01D61/38
摘要： The present invention is a membrane and a process for separating at least one component from at least one other component in a gas mixture. A gaseous mixture is passed over a membrane having a thin film of a molten salt hydrate which is selectively permeable to at least one component in the gaseous mixture.

2. 发明授权

US4409411A Process of hydrogenating benzenes and group IVa metal hydride catalysts therefor 失效
标题翻译：氢化苯和IVa族金属氢化物催化剂的方法
公开(公告)号：US4409411A
公开(公告)日：1983-10-11
申请号：US303261
申请日：1981-09-17
申请人： Guido P. Pez
发明人： Guido P. Pez
IPC分类号： C07C5/10 , B01J31/00 , B01J31/12 , C01B6/00 , C01B6/02 , C07B61/00 , C07C1/00 , C07C5/11 , C07C13/20 , C07C67/00 , C07C5/02 , C07C5/03
CPC分类号： C01B6/02 , B01J31/121 , C07C5/11 , B01J2231/646 , C07C2101/16 , C07C2531/12
摘要： Benzene, or an alkylbenzene, is hydrogenated by reaction with hydrogen in the presence of a Group IVa (titanium family) or Va metal hydride catalyst. The catalyst may be a simple hydride such as ZrH.sub.2 or a hydride of an alloy such as Cu.sub.3 Zr or may be a complex material. One complex material is the reaction product of a Group IVa or Va metal halide, such as ZrCl.sub.4 with an alkyllithium or aryllithium, such as n-butyllithium, in a hydrocarbon solvent.
摘要翻译：苯或烷基苯通过与IVa（钛族）或Va金属氢化物催化剂的存在下与氢反应而被氢化。催化剂可以是简单的氢化物，例如ZrH 2或合金如Cu 3 Zr的氢化物，或者可以是复合材料。一种复合材料是在烃溶剂中的IVa或Va族金属卤化物如ZrCl 4与烷基锂或芳基锂如正丁基锂的反应产物。

3. 发明授权

US4336162A Alkali metal amide catalyst 失效
标题翻译：碱金属酰胺催化剂
公开(公告)号：US4336162A
公开(公告)日：1982-06-22
申请号：US288273
申请日：1981-07-30
申请人： Guido P. Pez
发明人： Guido P. Pez
IPC分类号： C07C209/60 , B01J27/24 , B01J31/12
CPC分类号： C07C209/60
摘要： Monolefins such as ethylene are reacted with ammonia using alkali metal amide catalysts such as cesium or rubidium amides, or low melting mixtures of amides such as cesium/potassium, cesium/sodium or sodium/potassium amides. Conversions are improved compared to reactions using sodium or potassium amide alone. Conversions of ethylene are improved also when liquid ammonia is present.
摘要翻译：使用碱金属酰胺催化剂如铯或铷酰胺或诸如铯/钾，铯/钠或钠/钾的酰胺的低熔点混合物，使乙烯等单烯与氨反应。与使用单独使用钠或钾的反应相比，转化率有所改善。当液氨存在时，乙烯的转化也得到改善。

4. 发明授权

US4231948A Lithium dicyclopentadienyl titanium hydride compositions 失效
标题翻译：锂二环戊二烯基氢化钛组合物
公开(公告)号：US4231948A
公开(公告)日：1980-11-04
申请号：US957392
申请日：1978-11-03
申请人： Guido P. Pez
发明人： Guido P. Pez
IPC分类号： B01J31/00 , C07B61/00 , C07C2/34 , C07F7/28 , C07F17/00
CPC分类号： C07F17/00 , C07C2/34 , C07F7/28 , C07C2531/22
摘要： Novel lithium dicyclopentadienyl titanium hydride type compositions are described, useful as catalysts in converting ethylene to 1-butene, which is used in producing "polymer gasoline" for increasing the octane number of automotive gasolines. Methods for synthesizing the novel compositions are also described.
摘要翻译：描述了新型的二环戊二烯基钛氢化锂型组合物，其可用作将乙烯转化为1-丁烯的催化剂，其用于生产“聚合物汽油”以增加汽车汽油的辛烷值。还描述了合成新组合物的方法。

5. 发明授权

US5338521A Process for reversibly absorbing acid gases from gaseous mixtures 失效
标题翻译：从气态混合物中可逆地吸收酸性气体的方法
公开(公告)号：US5338521A
公开(公告)日：1994-08-16
申请号：US973897
申请日：1992-11-10
申请人： Robert Quinn , Guido P. Pez , John B. Appleby
发明人： Robert Quinn , Guido P. Pez , John B. Appleby
IPC分类号： B01D53/14 , C01B17/16 , B01D47/00 , B01J8/00 , C01C3/00
CPC分类号： C01B17/167 , B01D53/1493
摘要： A process is disclosed for reversibly absorbing acid gases from gaseous mixtures wherein a salt hydrate is heated to a temperature above its melting point and exposed to an acid gas which is absorbed by the salt hydrate to form a salt hydrate melt. This melt is thereafter cooled to a temperature sufficient to solidify the melt and to desorb the acid gas from the solidified salt hydrate. Preferred salt hydrates include tetramethylammonium fluoride tetrahydrate and tetraethylammonium acetate tetrahydrate.
摘要翻译：公开了一种可逆地吸收来自气态混合物的酸性气体的方法，其中将盐水合物加热至高于其熔点的温度并暴露于由盐水合物吸收形成盐水合物熔体的酸性气体。然后将该熔体冷却至足以固化熔体并从固化的盐水合物解吸酸性气体的温度。优选的盐水合物包括四水合四水合四水合物和四乙基四乙酸铵四水合物。

6. 发明授权

US5126466A Cyanocobaltate oxygen adducts 失效
标题翻译：氰钴酸盐氧加合物
公开(公告)号：US5126466A
公开(公告)日：1992-06-30
申请号：US672711
申请日：1991-03-19
申请人： Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
发明人： Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
IPC分类号： B01D53/04 , B01J20/02 , B01J20/04 , B01J20/22 , C01B13/02 , C01C3/11 , C07B61/00
CPC分类号： C01C3/11 , B01J20/0225 , B01J20/024 , B01J20/04 , B01J20/223 , B01J20/3071 , B01J20/3425 , B01J20/3483 , B01J20/3491
摘要： A process is provided for selectively separating oxygen from an oxygen-containing fluid stream by bringing said fluid stream into contact with a high capacity solid state cyanocobaltate complex in a non-aluminosilicate environment represented by the chemical formula:A.sub.X/Z.sup.Z+ [Co(CN).sub.n ].sup.X- .cndot.pSwhere:A is an alkali, alkaline earth, transition, or Group 12 metal atom;Z is 1, 2 or 3;n is any number from 3 to 5;X is n-2;p is any number from greater than zero to 6; andS is a ligand which is capable of coordinating with A.sup.Z+, Co or both.These complexes chemically bind oxygen to form novel oxygen adducts, thereby selectively removing oxygen from the fluid stream. The bound oxygen may be recovered by increasing the temperature or by reducing the partial pressure of O.sub.2 above the adduct.

7. 发明授权

US4418227A Improved process for hydrogenating aldehydes and ketones by employing anionic group VIII metal hydride compositions as hydrogenation catalysts 失效
标题翻译：通过使用阴离子VIII族金属氢化物组合物作为氢化催化剂来改进醛和酮的氢化方法
公开(公告)号：US4418227A
公开(公告)日：1983-11-29
申请号：US200165
申请日：1980-10-20
申请人： Guido P. Pez , Roger A. Grey
发明人： Guido P. Pez , Roger A. Grey
IPC分类号： B01J31/12 , B01J31/18 , B01J31/24 , C07C5/03 , C07C5/08 , C07C5/09 , C07C29/141 , C07C29/145 , C07C29/17 , C07C45/62 , C07F15/00 , C07F15/02 , C07C27/00 , C07C29/00 , C07C31/18
CPC分类号： C07F15/02 , B01J31/121 , B01J31/2404 , C07C29/141 , C07C29/145 , C07C29/175 , C07C45/62 , C07C5/03 , C07C5/08 , C07C5/09 , C07F15/0013 , B01J2231/643 , B01J2531/80 , B01J2531/821 , C07C2101/14 , C07C2531/24
摘要： A novel class of compounds, anionic Group VIII metal hydrides containing phosphorus, arsenic and antimony organoligands is described, such as potassium tris and bis(triphenylphosphine) ruthenium hydride. The compounds are useful as homogeneous catalysts in the hydrogenation of aldehydes, ketones, olefins or alkynes. Processes for producing the compounds are also described.
摘要翻译：描述了一类新颖的化合物，含有磷，砷和锑有机液体的阴离子Ⅷ族金属氢化物，如三（三苯基膦）三钌钾和氢化钌。该化合物可用作醛，酮，烯烃或炔烃氢化中的均相催化剂。还描述了用于生产化合物的方法。

8. 发明授权

US4346240A Hydrogenation of esters using alkali doped heterogeneous group VIII transition metal catalysts 失效
标题翻译：使用碱掺杂的异质基团VIII过渡金属催化剂氢化酯
公开(公告)号：US4346240A
公开(公告)日：1982-08-24
申请号：US307031
申请日：1981-09-29
申请人： Roger A. Grey , Guido P. Pez
发明人： Roger A. Grey , Guido P. Pez
IPC分类号： B01J23/58 , B01J31/28 , C07C29/149 , C07C31/38
CPC分类号： B01J31/0204 , B01J23/58 , B01J31/0212 , B01J31/122 , B01J31/26 , B01J31/28 , B01J31/30 , C07C29/149 , B01J21/18 , B01J2231/641 , B01J31/1616 , Y02P20/52
摘要： A novel class of heterogeneous catalysts, containing Group VIII transition metals in combination with alkali organic compounds is prepared, such as potassium naphthalene on ruthenium on carbon. The catalysts are useful as heterogeneous catalysts in the hydrogenation of carboxylic acid esters. A process for producing the materials is described. The catalysts permit the process of the hydrogenation of carboxylic acid esters to primary alcohols to be conducted with the ester in the liquid phase at a temperature not exceeding about 150.degree. C. with high selectivity. Catalysts of Group VIII transition metals and alkali metal on carbon are also useful in such processes.
摘要翻译：制备了一类新颖的非均相催化剂，其中含有与碱性有机化合物组合的第VIII族过渡金属，例如萘上钌碳上的萘。催化剂可用作羧酸酯氢化中的非均相催化剂。对材料的制造方法进行说明。催化剂允许羧酸酯与伯醇的氢化在液相中以不超过约150℃的温度以高选择性进行。第VIII族过渡金属和碱金属碳的催化剂在这些方法中也是有用的。

9. 发明授权

US4060499A Copper chloride/boron nitride catalyst for substitution chlorination 失效
标题翻译：氯化铜/氮化硼催化剂用于取代氯化
公开(公告)号：US4060499A
公开(公告)日：1977-11-29
申请号：US761561
申请日：1977-01-24
申请人： Wim J. M. Pieters , Emery J. Carlson , Guido P. Pez
发明人： Wim J. M. Pieters , Emery J. Carlson , Guido P. Pez
IPC分类号： B01J27/24 , C07B39/00 , C07C17/10 , B01J21/00 , B01J27/06 , C07C17/00
CPC分类号： C07C17/10 , B01J27/24 , C07B39/00
摘要： A catalyst consisting essentially of cuprous chloride intercalated in crystalline boron nitride, containing at least 10% copper, useful for substitution chlorination of organic substances in vapor phase at elevated temperature by action of chlorine or HCL and oxygen. Highly selective for chlorination versus oxidation and hydrolysis even at high conversions, using partially chlorinated organic material as reactant, in particular methyl chloride.
摘要翻译：一种主要由氯化亚铜组成的催化剂，其插入结晶氮化硼中，含有至少10％的铜，可用于通过氯或HCL和氧的作用在升高的温度下进行有机物质的取代氯化。即使在高转化率下，也可选择性地进行氯化与氧化和水解，使用部分氯化有机材料作为反应物，特别是氯甲烷。

10. 发明授权

US07101530B2 Hydrogen storage by reversible hydrogenation of pi-conjugated substrates 有权
标题翻译：通过π-共轭底物的可逆氢化来储存氢
公开(公告)号：US07101530B2
公开(公告)日：2006-09-05
申请号：US10430246
申请日：2003-05-06
申请人： Guido P. Pez , Aaron R. Scott , Alan C. Cooper , Hansong Cheng
发明人： Guido P. Pez , Aaron R. Scott , Alan C. Cooper , Hansong Cheng
IPC分类号： C01B3/00 , F17C11/00
CPC分类号： C01B3/0015 , Y02E60/328
摘要： Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.
摘要翻译：提供了通过扩展的π-共轭底物的基本可逆的催化氢化来提供氢的方法，其包括大的多环芳烃，具有氮杂原子的多环芳烃，具有氧杂原子的多环芳烃，具有烷基的多环芳烃烷氧基，酮，醚或聚醚取代基，包含5元环的π-共轭分子，包含具有氮或氧杂原子的六元和五元环的π-共轭分子和延伸的π-共轭有机聚合物。包含在延伸的π-共轭体系的至少部分氢化形式中的氢可以通过在脱氢催化剂的存在下通过催化脱氢来容易地释放使用，所述脱氢催化剂可以通过降低氢气压力来实现，通常压力大于0.1巴或将温度升高到小于250℃或更低，或通过这两个工艺参数的组合。

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