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11. 发明授权

US4404417A Isomerization 失效
标题翻译：异构化
公开(公告)号：US4404417A
公开(公告)日：1983-09-13
申请号：US286643
申请日：1981-07-24
申请人： John R. Adams , Abraham P. Gelbein , Robert Hansen , Jimmy Y. Peress , Martin B. Sherwin
发明人： John R. Adams , Abraham P. Gelbein , Robert Hansen , Jimmy Y. Peress , Martin B. Sherwin
IPC分类号： B01J21/04 , B01J23/00 , B01J27/00 , B01J31/00 , B01J35/10 , B01J37/24 , C07B61/00 , C07C1/00 , C07C5/27 , C07C11/02 , C07C67/00
CPC分类号： B01J37/24 , B01J21/04 , B01J35/10 , C07C5/2772 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/1085
摘要： A process is provided for the skeletal isomerization of straight chain olefins to branched chain olefins by contact at an elevated temperature with a chlorine- or fluorine-containing compound activated alumina catalyst, the alumina having an average particle size of from about 0.5.times.10.sup.-3 cm to about 160.times.10.sup.-3 cm and from 3 to 9% of the pore volume being attributable to pores having radii from about 100 to about 10,000 Angstroms.
摘要翻译：提供了一种通过在高温下与含氯或含氟化合物活性氧化铝催化剂接触将直链烯烃骨架异构化成支链烯烃的方法，该氧化铝的平均粒度为约0.5×10 -3 cm至约160×10 -3 cm和3至9％的孔体积可归因于具有约100至约10,000埃的半径的孔。

12. 发明申请

US20100317906A1 PROCESS AND CATALYST FOR SELECTIVE HYDROGENATION OF DIENES AND ACETYLENES 有权
标题翻译：用于选择性加氢的乙烯和乙烯的方法和催化剂
公开(公告)号：US20100317906A1
公开(公告)日：2010-12-16
申请号：US12859975
申请日：2010-08-20
申请人： Hugh M. Putman , John R. Adams
发明人： Hugh M. Putman , John R. Adams
IPC分类号： C07C5/03
CPC分类号： C10G45/38 , B01J23/755 , B01J23/78 , B01J23/80 , B01J23/8437 , B01J23/883 , B01J23/892 , B01J35/1014 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G45/36 , C10G45/40 , C10G2300/1088 , C10G2300/1096 , C10G2300/4087 , C10G2400/20
摘要： A process for the selective hydrogenation of dienes and acetylenes in a mixed hydrocarbon stream from a pyrolysis steam cracker in which a front end a one step acetylene hydrogenation is carried out using catalyst comprising (A) 1 to 30 wt. % based on the total weight of the catalyst of a catalytic component of nickel only or nickel and one or more elements selected from the group consisting of copper, rhenium, palladium, zinc, gold, silver, magnesium, molybdenum, calcium and bismuth deposited on (B) a support having the a BET surface area of from 1 to about 100 m2/gram, total nitrogen pore volume of from 0.2 to about 0.9 cc/gram and an average pore diameter of from about 110 to 450 Å under conditions of temperature and pressure to selectively hydrogenate acetylenes and dienes. The process hydrogenates the dienes and acetylenes to olefins without loss of ethylene and propylene in the light and heavy products which eliminates the need for further processing of the heavier stream. In addition the amount of polymerization in the lower part of the distillation column reactor is reduced.
摘要翻译：在来自热解蒸汽裂化器的混合烃流中二烯和乙炔的选择性加氢的方法，其中前端使用包含（A）1-30重量％的催化剂进行一步乙炔氢化。基于仅镍或镍的催化组分的催化剂的总重量和选自铜，铼，钯，锌，金，银，镁，钼，钙和铋的一种或多种元素的％（B）具有1至约100m 2 / g的BET表面积，0.2至约0.9cc / g的总氮孔体积和约110至450的平均孔径的载体在温度条件下以及选择性氢化炔烃和二烯烃的压力。该方法将二烯和乙炔氢化成烯烃，而在轻质和重质产物中不损失乙烯和丙烯，这消除了对较重物流的进一步加工的需要。此外，蒸馏塔反应器下部的聚合量降低。

13. 发明授权

US5942456A Multi-functional catalytic distillation structure 失效
标题翻译：多功能催化蒸馏结构
公开(公告)号：US5942456A
公开(公告)日：1999-08-24
申请号：US762323
申请日：1996-12-09
申请人： Clifford S. Crossland , John R. Adams
发明人： Clifford S. Crossland , John R. Adams
IPC分类号： B01D3/00 , B01J8/00 , B01J8/02 , B01J8/06 , B01J19/32 , B01J35/02 , B01J35/04 , B01J33/02
CPC分类号： B01J8/02 , B01D3/009 , B01J19/32 , B01J35/02 , B01J35/04 , B01J8/008 , B01J8/06 , B01J2208/0069 , B01J2208/00814 , B01J2219/32279 , B01J2219/32282 , B01J2219/32466
摘要： A catalytic distillation structure containing (1) a solid catalytic material comprising a catalyst component and (2) a structure. The total volume of open space for the catalytic distillation structure should be at least 10 volume % and preferably at least 20 volume % up to about 65 volume %. The catalytic material may be a mixture of two or more catalysts or the individual catalyst may occupy separate and distinct areas of the structure without physical mixing of the catalysts. The structural element may contain substantially rigid elements and porous containers which contain the catalytic material. The structural element may be comprised of the porous containers. Other catalytic distillation structures may comprises the porous containers for the catalysts and a resilient material such as demister wire.
摘要翻译：一种催化蒸馏结构，其包含（1）包含催化剂组分的固体催化材料和（2）结构。催化蒸馏结构的开放空间的总体积应为至少10体积％，优选至少20体积％至多约65体积％。催化材料可以是两种或更多种催化剂的混合物，或者单独的催化剂可以占据该结构的单独且不同的区域，而不会使催化剂物理混合。结构元件可以包含基本上刚性的元件和含有催化材料的多孔容器。结构元件可以由多孔容器组成。其他催化蒸馏结构可以包括用于催化剂的多孔容器和诸如除雾丝的弹性材料。

14. 发明授权

US5019669A Alkylation of organic aromatic compounds 失效
标题翻译：有机芳族化合物的烷基化
公开(公告)号：US5019669A
公开(公告)日：1991-05-28
申请号：US321359
申请日：1989-03-10
申请人： John R. Adams , Lawrence A. Smith
发明人： John R. Adams , Lawrence A. Smith
IPC分类号： C07C2/70 , B01D3/00 , B01D3/34 , C07B61/00 , C07C2/66 , C07C7/04 , C07C15/02 , C07C17/275 , C07C17/37 , C07C25/02 , C07C25/22 , C07C37/14 , C07C39/06
CPC分类号： C07C37/14 , B01D3/009 , C07C2/66 , C07C2529/00 , C07C2531/08 , Y02P20/127
摘要： Organic aromatic compounds are alkylated in a Reactive Distillation.TM. reactor, wherein the solid particulate catalyst is slurried in the aromatic feed stream and fed to a reaction zone containing inert distillation packing. Olefin is vaporized and fed to the bottom of the reaction zone and agitates the catalyst while reacting the olefin with the aromatic to form an alkylation product. The alkylation product is removed from the lower end of the reaction zone and recovered. Any unreacted aromatic is distilled overhead and recycled or recovered. Recycling the aromatic controls the molar ratio of aromatic to olefin to the extent that substantially all of the olefin is reacted.

15. 发明授权

US06620965B1 Process for vinyl acetate 有权
标题翻译：乙酸乙烯酯的工艺
公开(公告)号：US06620965B1
公开(公告)日：2003-09-16
申请号：US10093708
申请日：2002-03-08
申请人： John R. Adams , Willibrord A. Groten , Speros P. Nemphos
发明人： John R. Adams , Willibrord A. Groten , Speros P. Nemphos
IPC分类号： C07C67055
CPC分类号： C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for producing vinyl acetate comprising reacting ethylene, acetic acid and oxygen together in at least partially liquid phase in the presence of a catalyst comprising a noble metal component.
摘要翻译：一种生产乙酸乙烯酯的方法，包括在包含贵金属组分的催化剂的存在下，使至少部分液相中的乙烯，乙酸和氧一起反应。

16. 发明授权

US5840259A Boiling point reactor with heat removal 失效
公开(公告)号：US5840259A
公开(公告)日：1998-11-24
申请号：US42524
申请日：1993-04-05
申请人： John R. Adams
发明人： John R. Adams
IPC分类号： B01D3/00 , B01J8/02 , B01J8/04
CPC分类号： B01J8/025 , B01D3/009 , B01J8/0285 , B01J8/0453 , B01J8/0496 , B01J2208/00141 , B01J2208/00513 , B01J2208/00539 , B01J2219/00083
摘要： In a boiling point reactor wherein reactants react exothermically to vaporize a portion of the reaction mixture in a fixed catalyst bed, a cooling coil is provided within the bed which condenses a portion of the vaporized reaction mixture. The condensing heat transfer coefficient within the bed is thus increased dramatically and efficient heat removal is achieved.

17. 发明授权

US5756872A Process for the treatment of FCCU off gas 失效
标题翻译： FCCU废气处理工艺
公开(公告)号：US5756872A
公开(公告)日：1998-05-26
申请号：US789650
申请日：1997-01-27
申请人： Lawrence A. Smith, Jr. , John R. Adams
发明人： Lawrence A. Smith, Jr. , John R. Adams
IPC分类号： B01D53/72 , C07C15/073 , C10G11/18 , C10G29/20 , C07C2/70 , C07C2/66 , C07C7/148
CPC分类号： B01D53/72 , C07C15/073 , C10G11/18 , C10G29/205 , C07C2527/173 , C07C2529/70
摘要： A process wherein an FCCU off gas is treated by first subjecting the off gas to an alkylation with a heavy reformat to remove the propylene and contaminants after which the gas is separated from the reformat and alkylated products by distillation to produce an ethylene feed suitable for the reaction with benzene to produce ethyl benzene.
摘要翻译：一种方法，其中通过首先使废气进行烷基化处理以除去丙烯和污染物，然后通过蒸馏将气体从重整塔和烷基化产物中分离出来，以生产适合于与苯反应生成乙苯。

18. 发明申请

US20120158310A1 METHOD OF DETERMINING RESERVOIR PRESSURE 有权
标题翻译：确定储层压力的方法
公开(公告)号：US20120158310A1
公开(公告)日：2012-06-21
申请号：US13327182
申请日：2011-12-15
申请人： John R. Adams , Siyavash Motealleh , Herbert M. Sebastian , Yuanlin Jiang , Bryan Dotson
发明人： John R. Adams , Siyavash Motealleh , Herbert M. Sebastian , Yuanlin Jiang , Bryan Dotson
IPC分类号： G06F19/00 , G01V9/02
CPC分类号： E21B47/06 , E21B49/003 , E21B49/008 , E21B2049/085 , G01V9/02
摘要： A new approach is disclosed for measuring the pressure of tight gas reservoirs, using information obtain from continuous injection prior to hydraulic fracture stimulation. The technique can be obtained utilizing either bottom-hole or surface pressure gauges and properly instrumented surface injection pumps. The analysis is completed by plotting injection and rate data in a specialized form from terms arranged in Darcy's radial flow equation to obtain a curve or trend. The key component to proper application of this technique is to obtain both baseline and one or more calibration data sets. These calibration data sets are obtained by either increasing or decreasing the injection pressure and/or rate from the baseline data. Initial reservoir pressure is assumed, but the calibration data indicates if the guess was too high or low. Accurate estimates of reservoir pressure may be obtained in a few iterations.
摘要翻译：公开了一种新的方法来测量紧密气藏的压力，使用在水力压裂刺激之前从连续注射获得的信息。该技术可以利用底孔或表面压力表和适当仪表的表面注射泵来获得。通过以Darcy的径向流方程式排列的术语以专门的形式绘制注射和速率数据，以获得曲线或趋势，从而完成分析。正确应用该技术的关键部分是获得基线和一个或多个校准数据集。这些校准数据集是通过从基线数据增加或减少注入压力和/或速率获得的。假设初始储层压力，但校准数据表明猜测是否过高或过低。油藏压力的准确估计可以在几次迭代中获得。

19. 发明授权

US07319176B2 Selective hydrogenation of acetylenes 有权
标题翻译：乙炔的选择氢化
公开(公告)号：US07319176B2
公开(公告)日：2008-01-15
申请号：US11010907
申请日：2004-12-13
申请人： J. Yong Ryu , John R. Adams , Willibrord A. Groten
发明人： J. Yong Ryu , John R. Adams , Willibrord A. Groten
IPC分类号： C07C7/163
CPC分类号： C07C7/167 , C07C5/09 , C07C2523/755 , C07C2523/80 , C07C2523/89
摘要： A process for removing acetylenic compounds using unsulfided metallic nickel or unsulfided metallic nickel modified with metallic Mo, Re, Bi or mixtures in which the catalyst is used alone or is used in combination with other acetylenic selective catalysts. The unsulfided metallic nickel catalyst or modified catalyst must be the first catalyst to contact the hydrocarbon stream.
摘要翻译：使用用金属Mo，Re，Bi改性的未硫化金属镍或未硫化金属镍除去炔属化合物的方法或其中催化剂单独使用或与其它炔属选择性催化剂组合使用的混合物。未硫化的金属镍催化剂或改性催化剂必须是与烃流接触的第一催化剂。

20. 发明授权

US6033633A Boiling point reactor with heat removal 有权
标题翻译：沸点反应器除热
公开(公告)号：US6033633A
公开(公告)日：2000-03-07
申请号：US178925
申请日：1998-10-26
申请人： John R. Adams
发明人： John R. Adams
IPC分类号： B01D3/00 , B01J8/02 , B01J8/04
CPC分类号： B01J8/025 , B01D3/009 , B01J8/0285 , B01J8/0453 , B01J8/0496 , B01J2208/00141 , B01J2208/00513 , B01J2208/00539 , B01J2219/00083
摘要： In a boiling point reactor wherein reactants react exothermically to vaporize a portion of the reaction mixture in a fixed catalyst bed, a cooling coil is provided within the bed which condenses a portion of the vaporized reaction mixture. The condensing heat transfer coefficient within the bed is thus increased dramatically and efficient heat removal is achieved.
摘要翻译：在其中反应物放热反应以在固定的催化剂床中蒸发一部分反应混合物的沸点反应器中，在床内提供冷凝盘管，其冷凝蒸发的反应混合物的一部分。因此，床内的冷凝传热系数显着提高，实现了有效的除热。

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