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121. 发明授权

US06887819B2 Compositions that can produce polymers 有权
公开(公告)号：US06887819B2
公开(公告)日：2005-05-03
申请号：US10751619
申请日：2004-01-05
申请人： Max P. McDaniel , Shirley J. Martin , Kathy S. Collins , Marvin M. Johnson
发明人： Max P. McDaniel , Shirley J. Martin , Kathy S. Collins , Marvin M. Johnson
IPC分类号： C08F4/02 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/02 , C08F110/02 , C08F4/64 , C08F4/622
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F4/65916 , C08F4/025
摘要： This invention provides compositions that are useful for polymerizing at least one monomer into at least one polymer.

122. 发明申请

US20050090383A1 Metal complex compositions and their use as catalysts to produce polydienes 审中-公开
标题翻译：金属络合物组合物及其作为制备聚二烯的催化剂的用途
公开(公告)号：US20050090383A1
公开(公告)日：2005-04-28
申请号：US10489370
申请日：2002-10-07
申请人： Sven Thiele , Victor Monroy , Hartmut Stoye , David Wilson
发明人： Sven Thiele , Victor Monroy , Hartmut Stoye , David Wilson
IPC分类号： C08F36/00 , B01J31/00 , C08F4/02 , C08F4/54 , C08F4/60 , C08F4/605 , C08F36/04
CPC分类号： C08F36/04 , C08F4/545
摘要： This invention relates to metal complex compositions, their preparation and their use as catalysts to produce polymers of conjugate dienes through polymerization of conjugated diene monomers. The used metal complex compositions are transition metal compounds in combination with an activator compound, optionally with a transition metal halide compound and optionally a catalyst modifier and optionally an inorganic or organic support material. The metal complexes comprises metals of group 3 to 10 of the Periodic System of the Elements in combination with activators, and optionally transition metal halide compounds of groups 3 to 10 of the Periodic Table of the Elements including lanthanide metals and actinide metals and optionally, catalyst modifiers, especially Lewis acids and optionally an inorganic or organic support material. More in particular the invention relates metal complex compositions, their preparation and their use as catalysts to produce homopolymers of conjugated dienes, preferably, but not limited to, through polymerization of 1,3-butadiene or isoprene.
摘要翻译：本发明涉及金属络合物组合物及其制备及其作为通过共轭二烯单体聚合生成共轭二烯聚合物的催化剂的用途。所使用的金属络合物组合物是与活化剂化合物，任选地与过渡金属卤化物化合物和任选的催化剂改性剂和任选的无机或有机载体材料组合的过渡金属化合物。金属络合物包括与活化剂组合的元素周期系统3至10族的金属，以及任选的元素周期表第3至10族的过渡金属卤化物化合物，包括镧系金属和锕系金属以及任选的催化剂改性剂，尤其是路易斯酸和任选的无机或有机载体材料。更具体地，本发明涉及金属络合物组合物及其制备及其用作催化剂以制备共轭二烯的均聚物，优选但不限于通过1,3-丁二烯或异戊二烯的聚合。

123. 发明授权

US06875816B2 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：US06875816B2
公开(公告)日：2005-04-05
申请号：US10100687
申请日：2002-03-15
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
IPC分类号： C08F2/00 , C08F4/02 , C08F4/64 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F290/04 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/02 , C08F4/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要翻译：聚合物组合物包含：（a）高分子量的支化组分; 和（b）低分子量支化组分。一些聚合物组合物的特征在于基本上不存在戊基或甲基支链和满足以下关系的熔体强度（MS）：其中x大于或等于约12.5，y大于或等于约3.一些聚合物其特征在于熔体强度（MS）满足以下关系：其中x大于或等于约3，y大于或等于约4.5，分子量分布大于3.一种制备聚合物的方法也被披露。

124. 发明授权

US06875718B2 Olefin polymerization catalysts, transition metal compounds, processes for olefin polymerization, and α-olefin/conjugated diene copolymers 有权
标题翻译：烯烃聚合催化剂，过渡金属化合物，烯烃聚合方法和α-烯烃/共轭二烯共聚物
公开(公告)号：US06875718B2
公开(公告)日：2005-04-05
申请号：US09942706
申请日：2001-08-31
申请人： Terunori Fujita , Yasushi Tohi , Makoto Mitani , Shigekazu Matsui , Junji Saito , Masatoshi Nitabaru , Kiyoaki Sugi , Haruyuki Makio , Toshiyuki Tsutsui
发明人： Terunori Fujita , Yasushi Tohi , Makoto Mitani , Shigekazu Matsui , Junji Saito , Masatoshi Nitabaru , Kiyoaki Sugi , Haruyuki Makio , Toshiyuki Tsutsui
IPC分类号： C08F210/04 , C07F7/00 , C07F7/08 , C07F9/00 , C08F4/602 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/12 , C08F210/16 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/44
CPC分类号： C08F210/02 , C07F7/003 , C07F7/0803 , C07F9/005 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/17 , C08F2500/01 , C08F2500/03 , C08F236/06 , C08F210/06 , C08F4/64189 , C08F4/64048 , C08F4/7022 , C08F4/6812
摘要： The invention provides olefin polymerization catalysts exhibiting excellent polymerization activities, a process for olefin polymerization using the catalysts, a novel transition metal compound useful for the catalysts, and α-olefin/conjugated diene copolymers having specific properties. The olefin polymerization catalysts of the invention contain (A) a transition metal compound of formula (I), and (B) an organometallic compound, an organoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compounds of the invention are compounds of formula (I) wherein M is a transition metal atom of Group 3 or 4 of the periodic table; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc
摘要翻译：本发明提供了表现出优异聚合活性的烯烃聚合催化剂，使用该催化剂的烯烃聚合方法，用于该催化剂的新型过渡金属化合物和具有特定性质的α-烯烃/共轭二烯共聚物。本发明的烯烃聚合催化剂含有（A）式（I）的过渡金属化合物和（B）有机金属化合物，有机铝氧化合物或离子化离子化合物。本发明的新型过渡金属化合物是式（I）的化合物，其中M是周期表第3或4族的过渡金属原子; R 1是烃基等; R 2〜R 5各自为H，卤素，烃基等; R 6是卤素，烃基等; n是满足M价的数; X为卤素，烃基等

125. 发明申请

US20050065019A1 Catalytic systems for the polimerisation and copolimerisation of alpha-olefins 失效
标题翻译：用于α-烯烃聚合和共聚合的催化体系
公开(公告)号：US20050065019A1
公开(公告)日：2005-03-24
申请号：US10893754
申请日：2004-07-16
申请人： Jose Royo , Gerardo Llinas , Antonio Lafuente , M. Francisca Nunez , Carlos Marcos , Pilar Canas , Begona Garcia
发明人： Jose Royo , Gerardo Llinas , Antonio Lafuente , M. Francisca Nunez , Carlos Marcos , Pilar Canas , Begona Garcia
IPC分类号： C07F17/00 , C08F4/02 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/04 , C08F110/02 , C08F210/16 , B01J31/00 , C08F4/44
CPC分类号： C07F17/00 , C08F4/61912 , C08F4/61916 , C08F4/61922 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/6192 , C08F210/14
摘要： Catalyst component for the polymerization of alpha-olefins in solution, in suspension, in gas phase at low and high pressure and temperature or in mass at high pressures and high or low temperatures, characterised in that is defined by general formulas I or II wherein: R, equal to or different from each other, is hydrogen or a radical which contains from 1 to 20 carbon atoms; this group optionally contains heteroatoms of groups 14 to 16 of the periodic table of the elements and boron; at least one group R contains a group OSiR″3, Q is selected from a group comprising: boron or an element from groups 14 or 16 of the periodic table; m value can change from 1 to 4 and it preferably is 1 or 2; L, equal to or different from each other, is a cyclic organic group united to M through a π bond, or it is an atom from groups 15 or 16 of the periodic table; L1 and L2, equal to or different from each other, have the same meaning of L; M is a metal from groups 3, 4, 10 of the periodic table, lanthanide or actinide. X, equal to or different from each other, is selected from a group comprising: halogen, hydrogen, OR′″, N(R′″)2, C1-C20 alkyl or C6-C20 aryl; wherein R′″ is selected from the group comprising: C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkenyl, C7-C20 arylalkyl, C7-C20arylalkenyl or alkylaryl, linear or branched; x is 1 or 2, y is 2 or 3 in such a way that x+y=4 d ranges from 0 to 2; a, b and c are integers from 0 to 10, in such a way that a+b+c≧1 Incorporated herein by this reference is Spanish Appln. No. P9602310, filed on Oct. 31, 1996. This U.S. application claims priority under 35 U.S.C. 119 to Spanish Appln. No. P9602310, filed on Oct. 31, 1996.
摘要翻译：催化剂组分用于在溶液中，悬浮液中，在低压和高压和高温下或在高压和高温或低温下的质量的气相中聚合α-烯烃，其特征在于由通式I或II定义，其中： R 3相同或不同，为氢或含有1至20个碳原子的基团; 该基团任选地含有元素周期表第14至16族的杂原子和硼; 至少一个基团R包含基团OSiR'3，Q选自包括：硼或元素周期表第14或16族的元素; m值可以从1变为4，优选为1或2; L彼此相同或不同，是通过π键与M结合的环状有机基团，或其是来自元素周期表的第15或16族的原子; L1和L2彼此相同或不同，具有相同的L含义; M是周期表第3,4,10族的金属，镧系元素或锕系元素。 X，等于或不同，选自卤素，氢，OR“，N（R”'）2，C 1 -C 20烷基或C 6 -C 20芳基; 其中R“'选自C 1 -C 20烷基，C 3 -C 20环烷基，C 6 -C 20芳基，C 7 -C 20链烯基，C 7 -C 20芳基烷基，C 7 -C 20芳基烯基或烷基芳基，其为直链或支链; x为1或2，y为2或3，x + y = 4d的范围为0至2; a，b和c是0至10的整数，以这样一种方式使得+ b + c> = 1在此引用的本文引用的是西班牙语Appl。美国专利申请No.P9602310，1996年10月31日提交。美国申请根据35U.S.C. 119到西班牙文 1996年10月31日提交的P9602310号。

126. 发明授权

US06864209B2 Organometallic complexes comprising phosphonite ligands, and their use in catalyzing olefin oligomerization 失效
标题翻译：包含亚膦酸酯配体的有机金属络合物及其在催化烯烃低聚中的用途
公开(公告)号：US06864209B2
公开(公告)日：2005-03-08
申请号：US10402153
申请日：2003-03-31
申请人： Fredy Speiser , Pierre Braunstein , Lucien Saussine
发明人： Fredy Speiser , Pierre Braunstein , Lucien Saussine
IPC分类号： C08F4/70 , B01J23/755 , B01J31/12 , B01J31/14 , B01J31/18 , C07C2/30 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/44 , C08F4/60
CPC分类号： B01J31/1865 , B01J23/755 , B01J31/143 , B01J2231/20 , B01J2531/847 , C07C2/30 , C07C2531/14 , C07C2531/22 , C07C11/02
摘要： A catalytic composition for oligomerizing olefins, in particular ethylene, comprises mixing at least one nickel complex, prepared by reacting a nickel salt with a phosphonite ligapd, with at least one hydrocarbylaluminum compound in a molar proportion with respect to the nickel of not more than 8″ and selected from the group formed by tris(hydrocarbyl)aluminum compounds, chlorinated or brominated hydrocarbylaluminum compounds and aluminoxanes.
摘要翻译：用于使烯烃，特别是乙烯低聚的催化组合物包括将至少一种镍络合物（其通过使镍盐与亚膦酸酯接触反应制得）与至少一种相对于镍的摩尔比例的烃基铝化合物混合在不超过8 并选自三（烃基）铝化合物，氯化或溴化烃基铝化合物和铝氧烷形成的基团。

127. 发明授权

US06864207B2 Ziegler-Natta catalyst for polyolefins 有权
标题翻译：齐格勒 - 纳塔催化剂用于聚烯烃
公开(公告)号：US06864207B2
公开(公告)日：2005-03-08
申请号：US10667546
申请日：2003-09-22
申请人： David W. Knoeppel , Tim J. Coffy , Henry Enriquez , Steven D. Gray
发明人： David W. Knoeppel , Tim J. Coffy , Henry Enriquez , Steven D. Gray
IPC分类号： C08F4/654 , C08F4/658 , C08F10/00 , C08F10/02 , C08F110/02 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6546 , C08F4/651 , C08F4/6567 , C08F4/6557 , C08F2500/12 , C08F2500/02 , C08F2500/23 , C08F2500/07 , C08F2500/18 , C08F2500/04
摘要： A process for making a polyolefin catalyst component, catalyst and polymer resin is disclosed. Controlling the viscosity of a catalyst synthesis solution with the addition of aluminum alkyl alters the precipitation of the catalyst component from a catalyst synthesis solution. The average particle size of the catalyst component increases with an increased concentration of aluminum alkyl in the synthesis solution. The catalyst component can be produced by a process comprising contacting a magnesium alkyl compound with an alcohol and an aluminum alkyl to form a magnesium dialkoxide. Catalyst components, catalysts, catalyst systems, polyolefin, products made therewith, and methods of forming each are disclosed. The reaction products can be washed with a hydrocarbon solvent to reduce titanium species [Ti] content to less than about 100 mmol/L.
摘要翻译：公开了一种制备聚烯烃催化剂组分，催化剂和聚合物树脂的方法。通过添加烷基铝来控制催化剂合成溶液的粘度改变了催化剂组分从催化剂合成溶液中的沉淀。催化剂组分的平均粒度随着合成溶液中烷基铝浓度的增加而增加。催化剂组分可以通过包括使烷基镁化合物与醇和烷基铝接触以形成二烷氧基镁的方法来制备。公开了催化剂组分，催化剂，催化剂体系，聚烯烃，由其制备的产品，以及各自形成的方法。可以用烃溶剂洗涤反应产物以将钛物质[Ti]含量降低至小于约100mmol / L。

128. 发明授权

US06864206B2 Catalyst support method and polymerization with supported catalysts 失效
公开(公告)号：US06864206B2
公开(公告)日：2005-03-08
申请号：US10358951
申请日：2003-02-05
申请人： Thomas Henry Peterson , Eric Lucas
发明人： Thomas Henry Peterson , Eric Lucas
IPC分类号： C08F4/646 , B01J31/14 , B01J31/16 , B01J31/22 , B01J37/02 , C08F4/02 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F210/16 , B01J31/38 , C08F4/44
CPC分类号： C08F210/16 , B01J31/143 , B01J31/1616 , B01J31/2295 , B01J37/0209 , B01J2531/48 , B01J2531/49 , C08F4/659 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/02 , C08F4/65916 , C08F210/14
摘要： This invention relates to a method to support one or more catalyst compounds comprising contacting the catalyst compounds with a pretreatment agent comprising an aluminum alkyl and or an alumoxane in solution and thereafter contacting the combination with a supported activator.

129. 发明授权

US06864205B2 Heterocyclic-amide catalyst compositions for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的杂环酰胺催化剂组合物
公开(公告)号：US06864205B2
公开(公告)日：2005-03-08
申请号：US10023256
申请日：2001-12-18
申请人： Rex Eugene Murray
发明人： Rex Eugene Murray
IPC分类号： C08F4/659 , C08F10/00 , C08F210/16 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , C08F4/65912 , C08F210/16 , C08F4/64013 , C08F4/659 , C08F210/14 , C08F2500/12 , C08F4/64044
摘要： A family of novel hetrocyclic-amide type catalyst precursors useful for the polymerization of olefins, such as ethylene, higher alpha-olefins, dienes, and mixtures thereof.
摘要翻译：可用于烯烃聚合的新型环戊酰胺型催化剂前体家族，如乙烯，高级α-烯烃，二烯及其混合物。

130. 发明申请

US20050043170A1 Catalyst solid comprising pyrogenic silica for olefin polymerization 审中-公开
标题翻译：包含用于烯烃聚合的热解二氧化硅的催化剂固体
公开(公告)号：US20050043170A1
公开(公告)日：2005-02-24
申请号：US10497939
申请日：2002-12-17
申请人： Volker Fraaije , Markus Oberhoff , Nicola Paczkowski , Heike Gregorius , Roland Kratzer , Wolfgang Bidell , Joachim Wulff-Doring
发明人： Volker Fraaije , Markus Oberhoff , Nicola Paczkowski , Heike Gregorius , Roland Kratzer , Wolfgang Bidell , Joachim Wulff-Doring
IPC分类号： C08F4/02 , C08F4/44 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , B01J31/00
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24
摘要： A catalyst solid comprising: A) support particles having a mean particle diameter d50 of from 5 to 200 μm and a specific surface area of from 30 to 1 000 m2/g and obtainable by agglomeration of primary particles of a pyrogenic silica having a mean particle diameter dm of from 1 to 50 nm, and B) at least one organic transition metal compound, can be used for the polymerization or copolymerization of olefins.
摘要翻译：一种催化剂固体，其包括：A）平均粒径d50为5至200μm，比表面积为30至1000m 2 / g的载体颗粒，并且可通过将具有平均粒径dm为1〜50nm，B）至少一种有机过渡金属化合物可用于烯烃的聚合或共聚。

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