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    • 122. 发明申请
    • CATALYST COMPOSITION FOR PRODUCTION OF POLYURETHANE RESIN AND METHOD FOR PRODUCING POLYURETHANE RESIN (AS AMENDED)
    • 用于生产聚氨酯树脂的催化剂组合物和生产聚氨酯树脂的方法(如修饰)
    • US20100130629A1
    • 2010-05-27
    • US12377004
    • 2007-08-10
    • Hiroyuki KometaniYutaka Tamano
    • Hiroyuki KometaniYutaka Tamano
    • C08J9/04C08G18/32B01J31/18B01J31/04
    • C08G18/1875A43B13/04C08G18/092C08G18/1808C08G18/1825C08G18/2036C08G18/2063C08G18/2072C08G18/225C08G18/4816C08G2101/0008C08G2101/0066C08G2101/0083C08G2105/02C08G2410/00
    • Disclosed is a catalyst composition for polyurethane resin production which contains (A) triethylenediamine, (B) a specific polyisocyanurating catalyst and/or (C) a specific highly temperature-sensitive catalyst. By using this catalyst composition, a polyurethane resin can be molded with good curability, while suppressing initial reactivity. Consequently, a polyurethane resin having excellent moldability and fluidity can be produced with high productivity by using the catalyst composition. The thus-obtained polyurethane resin is suitably applicable to shoe soles. The component (B) is selected from the group consisting of alkali metal salts of carboxylic acids, quaternary ammonium compounds expressed as R1R2R3R4N+,X−, N,N,N′-trimethylaminoethylethanolamine, and 2,4,6-tris(dimethylaminomethyl)phenol, while the component (C) is selected from the group consisting of triazole salts and benzotriazole salts of 1,8-diazabicyclo[5.4.0]undecene-7 or 1,5-diazabicyclo[4.3.0]nonene-5. The mixing ratio of the component (B) and/or the component (C) to the component (A) is from 2% by weight to 60% by weight.
    • 公开了含有(A)三亚乙基二胺,(B)特定聚异氰脲酸酯化催化剂和/或(C)特定的高温度敏感催化剂的聚氨酯树脂生产用催化剂组合物。 通过使用该催化剂组合物,可以在抑制初始反应性的同时,以良好的固化性成型聚氨酯树脂。 因此,可以通过使用催化剂组合物以高生产率制造具有优异成型性和流动性的聚氨酯树脂。 这样得到的聚氨酯树脂适用于鞋底。 组分(B)选自羧酸的碱金属盐,表示为R1R2R3R4N +,X,N,N,N'-三甲基氨基乙基乙醇胺和2,4,6-三(二甲基氨基甲基)苯酚的季铵化合物 而组分(C)选自1,8-二氮杂双环[5.4.0]十一碳烯-7或1,5-二氮杂双环[4.3.0]壬烯-5的三唑盐和苯并三唑盐。 组分(B)和/或组分(C)与组分(A)的混合比例为2重量%至60重量%。
    • 128. 发明申请
    • RESIN COMPOSITION AND AN ARTICLE FORMED THEREFROM
    • 树脂组合物和其形成的物品
    • US20080051481A1
    • 2008-02-28
    • US11466135
    • 2006-08-22
    • Michael J. KrupaRichard P. HarrisonEdward A. Sliwka
    • Michael J. KrupaRichard P. HarrisonEdward A. Sliwka
    • C08G18/48
    • C08G18/381C08G18/2036C08G18/4018C08G18/4607C08G18/4816C08G2101/0025C08G2101/005
    • A resin composition and an article formed therefrom are disclosed. The resin composition comprises a halogenated polyol, a brominated polyol different from the halogenated polyol, and a flame retardant. The resin composition may further comprise other components, such as supplemental polyols, catalysts, adhesion promoters, surfactants, blowing agents, additives, or combinations thereof. The article comprises the reaction product of an isocyanate, the halogenated polyol, and the brominated polyol in the presence of the flame retardant, a blowing agent, and optionally, one of more of the other components. Typically, the article is defined as a polyurethane foam. The article exceeds Class I flammability requirements, such as flame spread index, smoke density, and convective flame spread parameter according to ASTM E-84 and FM 4880 testing. In addition, the article exhibits excellent dimensional stability and adhesion strength, and may be used to form building materials, such as insulation, wall, and ceiling panels.
    • 公开了一种树脂组合物和由其形成的制品。 树脂组合物包含卤化多元醇,与卤代多元醇不同的溴化多元醇和阻燃剂。 树脂组合物还可以包含其它组分,例如补充多元醇,催化剂,粘合促进剂,表面活性剂,发泡剂,添加剂或其组合。 该制品包含异氰酸酯,卤代多元醇和溴化多元醇在阻燃剂,发泡剂和任选的其它组分之一的存在下的反应产物。 通常,制品被定义为聚氨酯泡沫。 根据ASTM E-84和FM 4880测试,该物品超过I类可燃性要求,如火焰蔓延指数,烟雾密度和对流火焰蔓延参数。 此外,该制品具有优异的尺寸稳定性和粘合强度,并且可用于形成建筑材料,例如绝缘,墙壁和天花板。
    • 130. 发明申请
    • Low-resilience highly air-permeable polyurethane foam and use thereof
    • 低弹性高透气性聚氨酯泡沫及其用途
    • US20070197675A1
    • 2007-08-23
    • US11504089
    • 2006-08-15
    • Hiroyuki Matsumoto
    • Hiroyuki Matsumoto
    • C08G18/00
    • A47C27/14A47G9/10C08G18/0819C08G18/12C08G18/3893C08G18/4816C08G2101/0008C08G2101/0058C08G2101/0083C08G2350/00C08G18/3228
    • A low-resilience highly air-permeable polyurethane foam is prepared by the foaming of a polyurethane raw material containing a polyol component, a polyisocyanate component, a catalyst, and a blowing agent, followed by removal of a foam skin (reticulation). This polyurethane foam has a glass transition point near room temperature and a cell number (cell count) of 25 PPI or less. The polyurethane foam has a large air bubble size as indicated by a cell number of 25 PPI or less. In addition, because the skin of the polyurethane foam is removed, it has high air permeability. Since the polyurethane foam comes into contact with human body at fewer points, unpleasantness, such as “stuffy” feeling, can be reduced. Since the polyurethane foam has large air bubbles, it exhibits excellent drainability and dries in a shorter time.
    • 通过使含有多元醇成分,多异氰酸酯成分,催化剂和发泡剂的聚氨酯原料发泡,然后除去泡沫皮肤(网状)来制备低弹性高透气性聚氨酯泡沫。 该聚氨酯泡沫体的玻璃化转变点接近室温,细胞数(细胞计数)为25PPI以下。 聚氨酯泡沫具有大的气泡尺寸,如细胞数量为25PPI以下所示。 此外,由于去除聚氨酯泡沫的皮肤,因此具有高的透气性。 由于聚氨酯泡沫在较少的点与人体接触,所以可以减少诸如“闷”感的不愉快感。 由于聚氨酯泡沫具有较大的气泡,因此其排出性优异,并且在较短时间内干燥。