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111. 发明授权

US5101000A Process for the preparation of binders for cathodically depositable paints, the binders produced, and to the use thereof in paints 失效
标题翻译：用于制作阴离子涂层的粘合剂的方法，生产的粘合剂及其在涂料中的用途
公开(公告)号：US5101000A
公开(公告)日：1992-03-31
申请号：US570624
申请日：1990-08-21
申请人： Willibald Paar , Helmut Honig , Georg Pampouchidis
发明人： Willibald Paar , Helmut Honig , Georg Pampouchidis
IPC分类号： C08G59/14 , C08G59/18 , C08G59/56 , C08G59/58 , C09D5/44 , C09D163/00 , C09D171/00
CPC分类号： C08G59/56 , C08G59/184 , C08G59/58 , C09D5/4434
摘要： A process for the preparation of water-dilutable binders for cathodically depositable electrodeposition paints wherein 5 to 60 mol % of the epoxy groups of a resinous compound having at least two 1,2-epoxy groups per molecule are reacted with disecondary diamines obtained by the reaction of polypropylene glycol diglycidylethers or polypropylene glycol diacrylates with compounds containing a primary amino group is described. The binders prepared in accordance with the invention are suitable, in particular, for formulating electrodeposition paints, to provide films having a greater layer thickness under normal deposition conditions.
摘要翻译：制备用于阴极沉积的电沉积涂料的水可稀释粘合剂的方法，其中每分子具有至少两个1,2-环氧基的树脂化合物的5至60摩尔％的环氧基与通过反应获得的二中二胺反应的聚丙二醇二缩水甘油醚或聚丙二醇二丙烯酸酯与含有伯氨基的化合物进行了描述。根据本发明制备的粘合剂特别适用于配制电沉积涂料，以在正常沉积条件下提供具有更大层厚度的膜。

112. 发明授权

US4713406A Binders for cathodic electrocoating 失效
标题翻译：阴极电泳用粘合剂
公开(公告)号：US4713406A
公开(公告)日：1987-12-15
申请号：US934623
申请日：1986-11-25
申请人： Eberhard Schupp , Rolf Osterloh , Werner Loch , Klaas Ahlers
发明人： Eberhard Schupp , Rolf Osterloh , Werner Loch , Klaas Ahlers
IPC分类号： C08G59/50 , C08G59/58 , C09D5/44 , C09D163/00 , C08L63/02
CPC分类号： C09D5/4438 , C08G59/50 , C08G59/58
摘要： Binders for cathodic electrocoating which are based on polyadducts/polycondensates which carry basic nitrogen groups and are rendered water-dilutable by protonation with an acid, and one or more crosslinking agents for these polyadducts/polycondensates, their use and electrocoating baths prepared from them.These binders essentially consist of a mixture of(A) from 50 to 90% by weight of a polyadduct/polycondensate which carries basic nitrogen groups and is obtainable by reacting(a) an essentially epoxide-free adduct of a secondary amine and polyepoxide compound with(b) a condensate of a diamine/polyepoxide adduct which is prepared in the presence of excess diamine and separated off from excess diamine after complete conversion of the epoxide groups, with one or more mono- and/or dicarboxylic acids of not less than 6 carbon atoms.(B) from 10 to 50% by weight of a crosslinking agent which does not react with component (A) at room temperature but reacts with the latter at elevated temperatures with crosslinking.These binders are particularly useful for the cathodic electrocoating of electrically conductive substrates.
摘要翻译：用于阴极电泳的粘合剂，其基于承载碱性氮基并通过用酸质子化而被水稀释的聚加合物/缩聚物，以及一种或多种用于这些聚加合物/缩聚物的交联剂，它们的用途和由它们制备的电泳浴。这些粘合剂基本上由（A）50-90％重量的承载碱性氮基团的聚加合物/缩聚物组成，可通过使（a）仲胺和聚环氧化物化合物的基本上不含环氧化物的加合物与（b）二胺/聚环氧化物加合物的缩合物，其在过量二胺存在下制备并在完全转化环氧基之后与过量二胺分离，与一种或多种不少于6个的单 - 和/或二羧酸碳原子。（B）10至50重量％的交联剂，其在室温下不与组分（A）反应，但在高温下与交联反应。这些粘结剂特别适用于导电基材的阴极电涂层。

113. 发明授权

US4644036A Curing component for synthetic resins which contain groups capable of amide formation or ester formation with carboxylic acids 失效
标题翻译：含有能够酰胺形成的基团或用羧酸形成酯的合成树脂的固化组分
公开(公告)号：US4644036A
公开(公告)日：1987-02-17
申请号：US604084
申请日：1984-04-26
申请人： Gerd Walz , Ernst-August Theiling
发明人： Gerd Walz , Ernst-August Theiling
IPC分类号： C08F8/00 , C08G59/40 , C08G59/42 , C08G59/50 , C08G59/58 , C08G85/00 , C08K5/00 , C08K5/10 , C08K5/20 , C08L33/00 , C08L33/02 , C08L77/00 , C09D5/44 , C09D201/00 , C09D201/02 , C08G59/14
CPC分类号： C08G59/42 , C08G59/4014 , C08G59/58 , C08K5/0025 , C09D5/4496
摘要： Michael addition products of monocarboxylic or dicarboxylic acid esters, capable of undergoing Michael addition, with compounds containing double bonds capable of undergoing Michael addition are suitable for use as a curing component for synthetic resins containing groups capable of amide formation and/or ester formation with carboxylic acids. In particular, the Michael addition products of acetoacetic esters or malonic esters with esters, amides or urea derivatives of .alpha., .beta.-unsaturated monocarboxylic or dicarboxylic acids are used. The structure and the functionality of the curing component can be varied in many ways. It can be attached directly to the synthetic resin molecule, so that self-curing synthetic resins are obtained.
摘要翻译：能够进行迈克尔加成的单羧酸或二羧酸酯与含有能够进行迈克尔加成的双键的化合物的迈克尔加成产物适合用作含有能够与羧酸形成酰胺和/或与酯形成的基团的合成树脂的固化组分酸。特别地，使用乙酰乙酸酯或丙二酸酯与α，β-不饱和一元羧酸或二羧酸的酯，酰胺或脲衍生物的迈克尔加成产物。固化组分的结构和功能可以以许多方式变化。它可以直接连接到合成树脂分子上，从而获得自固化合成树脂。

114. 发明授权

US4622117A Self-crosslinking, heat-curable grinding resin 失效
标题翻译：自交联，热固化研磨树脂
公开(公告)号：US4622117A
公开(公告)日：1986-11-11
申请号：US699149
申请日：1985-02-07
申请人： Michael Geist , Gunther Ott
发明人： Michael Geist , Gunther Ott
IPC分类号： C08G59/00 , C08G59/50 , C08G59/52 , C08G59/58 , C08G59/62 , C09D5/44 , C09D17/00 , C09D163/00 , C09D201/02 , C09D201/06 , C25D13/06 , C08G59/14 , C08G59/16
CPC分类号： C08G59/625 , C08G59/58 , C09D163/00 , C09D17/00 , C09D5/4446 , C09D5/4488 , Y10T428/31529 , Y10T428/31681 , Y10T428/31699
摘要： The invention relates to a self-crosslinking heat-curable binder, in particular for electrocoating finishes, based on an organic synthetic resin which contains primary and/or secondary hydroxyl groups, esterified carboxyl groups and quaternary ammonium groups and can be diluted with water as a result of partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which has a negative inductive effect.
摘要翻译：本发明涉及一种自交联热固化性粘合剂，特别是电泳涂料，其基于含有伯和/或仲羟基，酯化羧基和季铵基团的有机合成树脂，并且可以用水稀释部分或完全用酸中和的结果。酯化的羧基在醇组分中通过具有负诱导作用的取代基活化。

115. 发明授权

US4477642A Selfcrosslinking heat-hardenable binder 失效
标题翻译：自交联热硬化粘合剂
公开(公告)号：US4477642A
公开(公告)日：1984-10-16
申请号：US526071
申请日：1983-08-24
申请人： Michael Geist , Horst Diefenbach
发明人： Michael Geist , Horst Diefenbach
IPC分类号： C08G18/08 , C08G18/32 , C08G59/42 , C08G59/56 , C08G59/58 , C09D5/44 , C09D163/00 , C09D175/00 , C09D201/02 , C08G18/34
CPC分类号： C08G18/0814 , C08G18/3221 , C08G59/4284 , C08G59/56 , C08G59/58 , C09D5/4446 , C09D5/4488 , Y10T428/31529 , Y10T428/31605
摘要： The invention relates to a selfcrosslinking heat-hardenable binder, in particular for electropaints, which is based on an organic synthetic resin which contains hydroxyl groups and esterified carboxyl groups in the form of carbalkoxymethyl ester groups and is water-dilutable by partial or complete acid-neutralization of amino groups present in the resin.
摘要翻译：本发明涉及一种自交联热硬化性粘合剂，特别是用于电极的自交联热粘合剂，其基于含有羟基的有机合成树脂和以烷氧基甲基酯基形式的酯化羧基，并且可通过部分或完全酸 - 中和树脂中存在的氨基。

116. 发明授权

US4448912A Heat hardenable binders comprising aqueous dispersions of solid epoxy resins, processes for the preparation thereof and the use thereof 失效
标题翻译：热硬化性粘合剂，其包含固体环氧树脂的水性分散体，其制备方法及其用途
公开(公告)号：US4448912A
公开(公告)日：1984-05-15
申请号：US349840
申请日：1982-02-18
申请人： Wilhelm Becker , Albrecht Manz
发明人： Wilhelm Becker , Albrecht Manz
IPC分类号： C08G59/58 , C08G59/64 , C09D163/00 , C08L63/02
CPC分类号： C09D163/00 , C08G59/58 , C08G59/64 , Y10T428/1352 , Y10T428/31529
摘要： Heat hardenable binders comprising aqueous dispersions of solid epoxy resins of a special structure, wherein some of the glycidyl groups are converted into quaternary ammonium groups by means of primary and/or secondary amines and quaternization, and further containing hardeners and possibly other conventional additives, characterized in that they contain, as hardeners, polybasic water-soluble polycarboxylic acid units or the anhydrides or acid esters thereof having a COOH functionality of at least 3, and the use of the binders for the preparation of hardened products, particularly coatings.
摘要翻译：热硬化性粘合剂，其包含特殊结构的固体环氧树脂的水分散体，其中一些缩水甘油基基团通过伯胺和/或仲胺和季铵化转化成季铵基团，并且进一步含有硬化剂和可能的其它常规添加剂，其特征在于因为它们含有作为硬化剂的多元水溶性多羧酸单元或其COOH官能度至少为3的酸酐或其酸酯，以及粘合剂用于制备硬化产物，特别是涂料的用途。

117. 发明授权

US4174333A Carboxylated amide polymers and coating compositions containing same 失效
标题翻译：羧化酰胺聚合物和含有它们的涂料组合物
公开(公告)号：US4174333A
公开(公告)日：1979-11-13
申请号：US957118
申请日：1978-11-02
申请人： Marvis E. Hartman , Thomas R. Hockswender
发明人： Marvis E. Hartman , Thomas R. Hockswender
IPC分类号： B65D65/42 , C08G59/00 , C08G59/16 , C08G59/58 , C08G69/00 , C09D163/00 , C08G59/14 , C08L63/00
CPC分类号： C08G59/58 , C08G69/00
摘要： Carboxylated amide polymers and coating compositions containing same are especially useful for the coating of food and beverage containers. The carboxylated amide polymers are the reaction product of (1) a compound of formula: ##STR1## wherein A is the organic residue resulting from a ring opening reaction of a 1,2-epoxy group on a polyepoxide with ammonia or amine, R.sub.1 is hydrogen or a C.sub.1-4 alkyl group, R.sub.2 is a C.sub.2-12 alkylene group, x is 0 or 1, y is from 0 to 4, R.sub.3 is hydrogen or a C.sub.1-6 alkyl group, R.sub.4 is hydrogen or a C.sub.1-6 alkyl group, provided at least one R.sub.1, R.sub.3 or R.sub.4 is hydrogen, and n is at least 1.0 with (2) a cyclic anhydride of a dibasic carboxylic acid. The carboxylated amide polymers can be made water reducible by neutralizing the polymer with an organic or inorganic base and used in aqueous coating compositions.
摘要翻译：羧酸酰胺聚合物和含有它们的涂料组合物对于食品和饮料容器的涂覆特别有用。羧化酰胺聚合物是（1）下式化合物的反应产物：其中A是由聚环氧化物上的1,2-环氧基与氨或胺的开环反应得到的有机残基，R1是氢或C1-4烷基，R2是C2-12亚烷基，x是0或1，y是0-4，R3是氢或C1-6烷基，R4是氢或C1-6 烷基，提供至少一个R 1，R 3或R 4为氢，n为至少1.0，（2）二元羧酸的环状酸酐。羧化酰胺聚合物可以通过用有机或无机碱中和聚合物制成水可稀释并用于水性涂料组合物中。

118. 发明授权

US4001101A Electrodeposition of epoxy compositions 失效
标题翻译：环氧组合物的电沉积
公开(公告)号：US4001101A
公开(公告)日：1977-01-04
申请号：US167470
申请日：1971-07-29
申请人： Joseph F. Bosso , Marco Wismer
发明人： Joseph F. Bosso , Marco Wismer
IPC分类号： C08G59/40 , C08G59/50 , C08G59/52 , C08G59/58 , C08G59/64 , C09D5/44 , C25D13/06
CPC分类号： C08G59/4078 , C08G59/50 , C08G59/52 , C08G59/58 , C08G59/64 , C09D5/4434 , C09D5/4457
摘要： Synthetic resins which are water-dispersible epoxy resins having epoxy groups, chemically-bound quaternary ammonium base salts, can be dissolved or dispersed in water to provide aqueous coating compositions. Such compositions, in which these resins are the major resinous component, can be applied by electrodeposition and deposit on the cathode to provide coatings of improved properties, including a high degree of resistance to corrosion or staining.
摘要翻译：作为具有环氧基的水分散性环氧树脂，化学键合的季铵碱盐的合成树脂可以溶解或分散在水中以提供水性涂料组合物。这些组合物，其中这些树脂是主要的树脂组分，可以通过电沉积并沉积在阴极上来施加改进性能的涂层，包括高度的抗腐蚀或抗污染性。

119. 发明授权

US3996182A Water-based can coating composition and method of making same 失效
标题翻译：水性罐头涂料组合物及其制备方法
公开(公告)号：US3996182A
公开(公告)日：1976-12-07
申请号：US586785
申请日：1975-06-12
申请人： Myung K. Hong , Edward J. Holzrichter , Edward A. Lasher
发明人： Myung K. Hong , Edward J. Holzrichter , Edward A. Lasher
IPC分类号： C08G59/42 , C08G59/58 , C08L63/00 , C09D163/00 , C09D167/00 , C08K5/06 , C08K5/07 , C08K5/10
CPC分类号： C09D163/00 , C08G59/4292 , C08G59/58 , C08L63/00 , Y10T428/31529 , Y10T428/31678
摘要： A water-reduced coating composition is made by admixing water with a concentrate comprising: (1) a water-reducible, low molecular weight ester compound; (2) a modified epoxy amine salt; (3) a highly functional cross-linking agent; and (4) a coupling solvent for coupling the epoxy amine salt to water. Preferably, a low boiling component is included in the coating composition to facilitate removal of the water therefrom during cure.
摘要翻译：通过将水与浓缩物混合来制备减水涂料组合物，其包含：（1）水可稀释的低分子量酯化合物; （2）改性环氧胺盐; （3）高功能性交联剂; 和（4）用于将环氧胺盐偶联至水的偶联溶剂。优选地，涂料组合物中包含低沸点组分以便于在固化期间从其中除去水。

120. 发明授权

US3877871A Process for rendering wool non-felting 失效
标题翻译：生产羊毛无毛的方法
公开(公告)号：US3877871A
公开(公告)日：1975-04-15
申请号：US29647372
申请日：1972-10-10
申请人： CIBA GEIGY AG
发明人： ABEL HEINZ
IPC分类号： C08G59/58 , D06M13/364 , D06M15/36 , D06M15/60
CPC分类号： D06M13/364 , C08G59/58
摘要： A process for rendering wool non-felting by the exhaustion process is provided. The process is characterized in that the wool first is treated with an aqueous preparation containing small amounts of dichloroisocyanuric acid or of an alkali metal salt thereof. Afterwards the wool is subjected to a non-felting finishing process, wherein synthetic resins having affinity to wool are used. The pretreatment with dichloroisocyanuric acid or its salts produces an improvement in the adhesion of the resin thereby improving the permanence of the non-felting finish.
摘要翻译：提供了通过耗尽过程使羊毛不起毛的过程。该方法的特征在于，首先用含有少量二氯异氰脲酸或其碱金属盐的水性制剂处理羊毛。之后，羊毛经受非毡化整理过程，其中使用对羊毛具有亲和力的合成树脂。用二氯异氰脲酸或其盐的预处理可以提高树脂的粘合性，从而提高非毡化整理剂的耐久性。

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