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    • 2. 发明授权
    • Water-soluble ester intermediates and water-insoluble coatings made
therefrom
    • 水溶性酯中间体和由其制成的水不溶性涂料
    • US3957709A
    • 1976-05-18
    • US507746
    • 1974-09-20
    • Edward J. HolzrichterEdward A. Lasher
    • Edward J. HolzrichterEdward A. Lasher
    • C09D163/02C08L61/26C08G12/32
    • C09D163/00
    • Water-soluble ester intermediates characterized by having 2 and 3 ester groups per molecule are made by condensing (a) a polyol having 2 to 3 hydroxyl groups per mol and a carbon/oxygen ratio between 5:3 and 7:3 with (b) a polycarboxylic acid having a carboxyl functionality of 2 to 3, using an equivalents ratio of polyol to polycarboxylic acid so that the ester intermediate has a hydroxyl functionality of about 3 and using a ratio of 1 mol of polyol per carboxyl group.The ester intermediates are combined in aqueous media with specific amounts of water-soluble aminoplast resin and the resulting combination is cured at elevated temperatures to produce cross-linked, water-insoluble coatings which are suitable as can and coil coatings.Small amounts of epoxy resin which is soluble in the ester intermediate may be used to provide coatings having improved adhesion, particularly under certain adverse conditions.
    • 其特征在于每分子具有2个和3个酯基的水溶性中间体是通过(a)每摩尔具有2-3个羟基的多元醇和5:3至7:3的碳/氧比与(b) 使用多元醇与多元羧酸的当量比使羧酸官能度为2〜3的多元羧酸,使得酯中间体的羟基官能度为约3,并且使用每摩尔羧酸1摩尔多元醇的比例。
    • 5. 发明授权
    • High solids polyester resin-based coating composition and method of
making same
    • 高固含量聚酯树脂基涂料组合物及其制备方法
    • US4181638A
    • 1980-01-01
    • US903571
    • 1978-05-08
    • Edward A. Lasher
    • Edward A. Lasher
    • C08G63/00C08G63/12C08G63/46C08G63/48C08G63/553C09D167/08C09D3/52C09D3/64C09D3/66
    • C08G63/553C08G63/48C09D167/08
    • A low molecular weight polyester resin is made by condensation reaction of particular polyols and carboxylic acids in a reaction mixture having excess hydroxyls and a system functionality between about 1.6 and 1.8. In one embodiment, an aliphatic diol, a cyclic dicarboxylic acid and a monobasic fatty acid are condensation reacted together to produce the polyester resin, whereas in a second, and preferred, embodiment, the monobasic fatty acid is present as a hydroxyl-bearing, polyol-esterified oil or fatty acid. The polyester resin of either embodiment can be cross-linked with an aminoplast resin, in the presence or absence of pigment, in a coating composition comprising 90% by weight and higher amounts of solids to produce cured coatings exhibiting good hardness, flexibility, chemical resistance and gloss. Pigment can be present in the cured coatings in amounts up to at least 60% by weight of the solids.
    • 低分子量聚酯树脂通过特定多元醇和羧酸在具有过量羟基和系统官能度在约1.6至1.8之间的反应混合物中的缩合反应制备。 在一个实施方案中,脂族二醇,环状二羧酸和一元脂肪酸一起缩合反应以制备聚酯树脂,而在第二个优选的实施方案中,一元脂肪酸作为含羟基的多元醇存在,多元醇 酯化油或脂肪酸。 任何实施方案的聚酯树脂可以在含有颜料存在或不存在的情况下与氨基塑料树脂在包含90重量%和更高固体量的涂料组合物中交联,以产生显示出良好硬度,柔韧性,耐化学性的固化涂料 和光泽。 颜料可以以固体的至少60重量%的量存在于固化涂层中。