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111. 发明授权

US5936012A Cationic electrocoating compositions, method of making, and use 失效
标题翻译：阳离子电涂组合物，制备方法和使用
公开(公告)号：US5936012A
公开(公告)日：1999-08-10
申请号：US167687
申请日：1998-10-07
申请人： Marvin L. Kaufman , Patrick O'Neill , Richard F. Karabin , Gregory J. McCollum
发明人： Marvin L. Kaufman , Patrick O'Neill , Richard F. Karabin , Gregory J. McCollum
IPC分类号： C08G18/58 , C08G18/64 , C09D5/44 , C09D163/00 , C09D175/04 , C09D179/02 , C08K3/20
CPC分类号： C08G18/643 , C09D5/4434 , Y10T428/31511 , Y10T428/31551
摘要： An electrodepositable composition that has: (A) an active hydrogen-containing cationic resin, electrodepositable on a cathode, having: (1) a polyepoxide; (2) an oxygen-substituted diamine compound having the following formula: ##STR1## where n is an integer from 2 to 4; and where R.sup.1 or R.sup.2 are the same or different and either one or both contain at least one oxygen and are alkyl, cycloalkyl, substituted alkyl, or substituted cycloalkyl having from 1 to 6 carbon atoms, or R.sup.1 and R.sup.2 are alkanol groups having from 2 to 6 carbon atoms, or R.sup.1, R.sup.2, and the N atom form a cyclic group which is substituted or unsubstituted such as morpholine and 1-(3-aminopropyl) imidazole; and (B) at least partially blocked isocyanate or polyisocyanate curing agent. The diamine compound of Formula I can be used alone or in conjunction with one or more secondary amines, nonhydroxy group containing amines and/or amines with ring structures. Optionally, the polyepoxide can be chain extended with active hydrogen-containing compounds other than polyoxyalkylene polyamines. Also provided is a method of producing an active hydrogen-containing cationic resin composition, electrodepositable on a cathode, comprised of (a) mixing together in a suitable reaction vessel a polyepoxide, or the precursors of the polyepoxide, a polycarboxylic acid, a blocked isocyanate curing agent; (b) adding to the mixture of (a) a base catalyst and the diamine compound of Formula I; (c) polymerizing the mixture of (b) to form a resinous composition; and (d) neutralizing the resinous composition of (c) by adding the resinous composition to a dilute mixture of acid and water to form an aqueous dispersed electrodepositable cationic resin composition.
摘要翻译：一种电沉积组合物，其具有：（A）可阴离子电解的活性含氢阳离子树脂，其具有：（1）聚环氧化物; （2）具有下式的氧取代二胺化合物：其中n是2至4的整数; 并且其中R 1或R 2相同或不同，并且一个或两者含有至少一个氧，并且是具有1至6个碳原子的烷基，环烷基，取代的烷基或取代的环烷基，或者R 1和R 2是具有2个至6个碳原子，或R 1，R 2和N原子形成取代或未取代的环状基团，例如吗啉和1-（3-氨基丙基）咪唑; 和（B）至少部分封端的异氰酸酯或多异氰酸酯固化剂。式I的二胺化合物可以单独使用或与一种或多种仲胺，含羟基的胺和/或具有环结构的胺结合使用。任选地，聚环氧化物可以用除聚氧化烯多胺以外的活性含氢化合物链延伸。还提供了一种生产可阴离子电沉积的含活性氢的阳离子树脂组合物的方法，其包括（a）在合适的反应容器中在聚环氧化物或聚环氧化物的前体，多元羧酸，封端异氰酸酯固化剂（b）向（a）碱催化剂和式I的二胺化合物的混合物中加入; （c）使（b）的混合物聚合以形成树脂组合物; 和（d）通过将树脂组合物加入酸和水的稀混合物中和（c）的树脂组合物，形成水分散的可电沉积阳离子树脂组合物。

112. 发明授权

US5733479A Positive photoactive compounds based on 2,6-dinitro benzyl groups 失效
标题翻译：基于2,6-二硝基苄基的阳性光活性化合物
公开(公告)号：US5733479A
公开(公告)日：1998-03-31
申请号：US685062
申请日：1996-07-22
申请人： Charles F. Kahle, II , Neil D. McMurdie , Raphael O. Kollah , Daniel E. Rardon , Gregory J. McCollum
发明人： Charles F. Kahle, II , Neil D. McMurdie , Raphael O. Kollah , Daniel E. Rardon , Gregory J. McCollum
IPC分类号： C07C201/08 , A61K9/00 , A61K9/32 , C07C201/12 , C07C205/11 , C07C205/19 , C07C205/23 , C07C205/26 , C07C205/34 , C07C205/42 , C07C215/14 , C07C271/08 , C07C301/00 , C07C309/67 , C07C309/73 , C07C319/14 , C07C323/16 , C07C323/25 , C07C323/29 , C08G18/38 , C08G59/50 , C08G63/685 , C08L101/00 , C09D163/00 , G03F7/00 , G03F7/004 , G03F7/039 , G03F7/16 , C09K15/16
CPC分类号： C07C323/25 , A61K9/0004 , C07C205/11 , C07C205/19 , C07C205/26 , C07C215/14 , C08G18/384 , C08G59/50 , C08G59/504 , C08G63/6856 , C09D163/00 , G03F7/0045 , G03F7/039 , G03F7/164
摘要： Photoreactive compounds are synthesized from 2,5- or 2,6-dinitrobenzyl groups. Also disclosed are methods of synthesizing reactive monomers containing 2,5- or 2,6-dinitrobenzyl groups.
摘要翻译：光反应性化合物由2,5-或2,6-二硝基苄基合成。还公开了合成含有2,5-或2,6-二硝基苄基的反应性单体的方法。

113. 发明授权

US5582704A Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition 失效
标题翻译：阳离子树脂和封端的多异氰酸酯固化剂适用于电沉积
公开(公告)号：US5582704A
公开(公告)日：1996-12-10
申请号：US334712
申请日：1994-11-04
申请人： Joseph T. Valko , Philippe Faucher , Richard F. Karabin , Thomas C. Moriarity , V. Eswarakrishnan , Ellor J. Van Buskirk , Gregory J. McCollum , Raphael O. Kollah
发明人： Joseph T. Valko , Philippe Faucher , Richard F. Karabin , Thomas C. Moriarity , V. Eswarakrishnan , Ellor J. Van Buskirk , Gregory J. McCollum , Raphael O. Kollah
IPC分类号： C09D163/00 , C08G18/08 , C08G18/32 , C08G18/42 , C08G18/58 , C08G18/64 , C08G18/80 , C09D5/08 , C09D5/44 , C09D175/04 , C09D175/12 , C25D13/04
CPC分类号： C08G18/3256 , C08G18/0814 , C08G18/0823 , C08G18/4294 , C08G18/581 , C08G18/584 , C08G18/6407 , C08G18/643 , C08G18/80 , C08G18/8009 , C08G18/8048 , C08G18/8064 , C09D5/4434 , C09D5/4453 , C09D5/4457
摘要： An electrodepositable composition is provided comprising:(A) a non-gelled cationic resin which is derived from a polyepoxide and which contains in the resin molecule cationic salt groups and active hydrogen groups selected from aliphatic hydroxyl and primary and secondary amino; and present as a separate component(B) a fully capped polyisocyanate curing agent containing substantially no free isocyanate groups, The electrodepositable composition contains from about 0.02 to 1.0 milliequivalents phenolic hydroxyl groups per gram of resin solids, and from about 0.1 to 2.0 milliequivalents beta-hydroxy ester groups per gram of resin solids. The composition provides excellent corrosion resistance when electrodeposited over steel substrates, and does not require lead in the formulation nor the use of a conventional chrome rinse for the steel substrate pretreatment before electrodeposition.
摘要翻译：提供了一种可电沉积的组合物，其包含：（A）衍生自聚环氧化物的非胶凝阳离子树脂，其在树脂分子中含有阳离子盐基团和选自脂族羟基和伯和仲氨基的活性氢基团; 并且作为单独的组分（B）存在基本上不含游离异氰酸酯基团的完全封端的多异氰酸酯固化剂。该可电沉积组合物每克树脂固体含有约0.02-1.0毫当量酚羟基，和约0.1-2.0毫当量β- 羟基酯基团/克树脂固体。当电沉积在钢基材上时，该组合物提供优异的耐腐蚀性，并且在电沉积之前不需要配方中的铅，也不使用常规的铬漂洗用于钢基材预处理。

114. 发明授权

US5324789A Azetidinol reaction products 失效
标题翻译：氮杂环丁烷反应产物
公开(公告)号：US5324789A
公开(公告)日：1994-06-28
申请号：US814656
申请日：1991-12-30
申请人： Shanti Swarup , Padmanabhan Sundararaman , Gregory J. McCollum , Charles M. Kania , James A. Claar
发明人： Shanti Swarup , Padmanabhan Sundararaman , Gregory J. McCollum , Charles M. Kania , James A. Claar
IPC分类号： C07D205/04 , C08F8/30 , C08L57/00 , C08L57/12 , C09D133/02 , C09D133/04 , C09D157/12 , C09D175/04
CPC分类号： C08F8/30
摘要： An ungelled reaction product is prepared from a carboxylic acid group containing polymeric material and an azetidinol containing material having one azetidinol moiety per molecule. The ungelled reaction product is particularly useful as a grind vehicle for pigment grind compositions.
摘要翻译：由含羧酸基的聚合物材料和含有氮杂环丁烷的材料每分子制备一个氮杂环丁烷部分制备未凝胶化的反应产物。未凝胶化的反应产物特别可用作用于颜料研磨组合物的研磨载体。

115. 发明授权

US5296541A Polyazetidinol containing materials 失效
标题翻译：含聚氮杂环丁烷的材料
公开(公告)号：US5296541A
公开(公告)日：1994-03-22
申请号：US109895
申请日：1993-08-23
申请人： Shanti Swarup , Gregory J. McCollum
发明人： Shanti Swarup , Gregory J. McCollum
IPC分类号： C07D205/04 , C08F8/30 , C09D5/02
CPC分类号： C08F8/30 , C07D205/04 , C09D5/024
摘要： A reaction product is prepared from a polycarboxylic acid group containing polymeric material and a polyazetidinol of a specific structural formula. The polyazetidinol can also be formulated into curable compositions both as film forming vehicle or alternatively as an additive to improve mar and humidity resistance.
摘要翻译：反应产物由具有特定结构式的含聚合物材料和聚氮杂环丁烷醇的多元羧酸基团制备。聚氮杂环丁醇也可以配制成可固化组合物，既可以作为成膜载体，也可以配制成添加剂，以改善耐湿性和耐湿性。

116. 发明授权

US5276166A Polyazetidinol containing materials 失效
标题翻译：含聚氮杂环丁烷的材料
公开(公告)号：US5276166A
公开(公告)日：1994-01-04
申请号：US814655
申请日：1991-12-30
申请人： Shanti Swarup , Gregory J. McCollum
发明人： Shanti Swarup , Gregory J. McCollum
IPC分类号： C07D205/04 , C08F8/30 , C09D5/02 , C07D205/00
CPC分类号： C08F8/30 , C07D205/04 , C09D5/024
摘要： An organic compound having at least two azetidinol moieties per molecule is prepared from a polyamine and an epihalohydrin. A reaction product is prepared by reacting a polycarboxylic acid group containing polymeric material with the organic compound having at least two azetidinol moieties. The organic compound and reaction product can be formulated into curable compositions both as a film forming vehicle or alternatively as an additive to improve mar and humidity resistance.
摘要翻译：每个分子具有至少两个氮杂环丁烷部分的有机化合物由多胺和表卤代醇制备。通过使含有聚羧酸基团的聚合物材料与具有至少两个氮杂环丁烷部分的有机化合物反应来制备反应产物。有机化合物和反应产物可以配制成可固化的组合物，既可以作为成膜载体，也可以作为添加剂，以改善耐湿性和耐湿性。

117. 发明授权

US4824925A Novel blocked isocyanates and curable compositions containing the same 失效
标题翻译：新型封闭的异氰酸酯和含有它们的可固化组合物
公开(公告)号：US4824925A
公开(公告)日：1989-04-25
申请号：US131889
申请日：1987-12-11
申请人： Peter Kamarchik, Jr. , Gregory J. McCollum , George W. Mauer
发明人： Peter Kamarchik, Jr. , Gregory J. McCollum , George W. Mauer
IPC分类号： C08G18/08 , C08G18/10 , C08G18/64 , C08G18/76 , C08G18/80 , C09D5/44 , C08G18/30
CPC分类号： C09D5/4496 , C08G18/0814 , C08G18/10 , C08G18/643 , C08G18/7628 , C08G18/8029 , C08G18/8077
摘要： Disclosed herein are novel blocked isocyanate curing agents prepared by reacting meta-xylylene diisocyanate with a select group of ketoximes and curable compositions containing the same.
摘要翻译：本文公开了通过使间二甲苯二异氰酸酯与选择性酮肟基团和含有它们的可固化组合物反应制备的新型封端异氰酸酯固化剂。

118. 发明授权

US4615779A Cationic coating compositions for electrodeposition over rough steel 失效
公开(公告)号：US4615779A
公开(公告)日：1986-10-07
申请号：US698993
申请日：1985-02-07
申请人： Gregory J. McCollum , Roger L. Scriven , Roger M. Christenson , George W. Mauer , Robert R. Zwack
发明人： Gregory J. McCollum , Roger L. Scriven , Roger M. Christenson , George W. Mauer , Robert R. Zwack
IPC分类号： C08G18/08 , C08G18/64 , C08G18/80 , C09D5/44 , C25D13/06
CPC分类号： C08G18/0814 , C08G18/643 , C08G18/8064 , C09D5/4453 , Y10T428/31529
摘要： A method of cationic electrodeposition, electrocoated articles and novel electrocoating compositions are disclosed. The compositions comprise a cationic resin containing blocked isocyanate functionality and are capable of being electrodeposited over rough steel and producing extremely smooth films upon curing.

119. 发明授权

US4501854A Aminoplast curable compositions containing disulfonic acid esters as latent acid catalysts 失效
标题翻译：含有二磺酸酯作为潜酸催化剂的氨基塑料可固化组合物
公开(公告)号：US4501854A
公开(公告)日：1985-02-26
申请号：US551388
申请日：1983-11-14
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko
IPC分类号： C08F4/00 , C08K5/42 , C09D133/00 , C08L61/28
CPC分类号： C07C309/00 , C08K5/42
摘要： An improved curable composition capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent and a sulfonate as latent acid catalyst. The catalyst is represented by the following structural formula: ##STR1## wherein: Z is a radical independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.18 aryl, halogen, alkoxy, hydroxyl, and aryloxy;R is independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, and C.sub.6 to C.sub.18 aryl;R.sup.1 is independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, hydroxyalkyl, and hydroxycycloalkyl;y is an integer from 0 to 4,w is an integer from 0 to 2, andx is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 3.
摘要翻译：能够进行酸催化交联的改进的可固化组合物由含活性氢的树脂，固化剂和作为潜酸催化剂的磺酸盐组成。催化剂由以下结构式表示：其中：Z是独立地选自C 1至C 20烷基，C 3至C 20环烷基，C 6至C 18芳基，卤素，烷氧基，羟基和芳氧基的基团; R独立地选自氢，C1至C20烷基，C3至C20环烷基和C6至C18芳基; R 1独立地选自C 1至C 20烷基，C 3至C 20环烷基，羟基烷基和羟基环烷基; y是0至4的整数，w是0至2的整数，x是1至3的整数，条件是当w为0时，y为1至4的整数，x为整数 2〜3，y为0时，w为1〜2的整数，x为1〜3的整数。

120. 发明授权

US4500680A Aromatic acid catalysts providing improved humidity resistance 失效
标题翻译：提供改善的耐湿性的芳香族酸催化剂
公开(公告)号：US4500680A
公开(公告)日：1985-02-19
申请号：US551389
申请日：1983-11-14
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , James B. O'Dwyer
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , James B. O'Dwyer
IPC分类号： C08K5/42 , C08L61/20 , C08L67/00 , C08L75/00
CPC分类号： C08K5/42
摘要： Curable compositions with improved humidity resistance are composed of an active hydrogen-containing resin which is essentially free of glycidyl groups, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a sulfonic acid having a molecular weight of less than 500 and represented by the following structural formula: ##STR1## wherein: Z is a radical independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.18 aryl, halogen, alkoxy, and aryloxy;R is independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl and C.sub.6 to C.sub.18 aryl;y is an integer from 0 to 4; w is an integer from 0 to 2;x is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 2.
摘要翻译：具有改善的耐湿性的可固化组合物由基本上不含缩水甘油基的活性含氢树脂，外部存在和/或内部作为活性含氢树脂的一部分存在的固化剂和催化量的磺酸分子量小于500并由以下结构式表示的酸：其中：Z是独立地选自C 1至C 20烷基，C 3至C 20环烷基，C 6至C 18芳基，卤素，烷氧基和芳氧基 ; R独立地选自氢，C1至C20烷基，C3至C20环烷基和C6至C18芳基; y为0〜4的整数; w为0〜2的整数; x为1〜3的整数，条件是当w为0时，y为1〜4的整数，x为2〜3的整数，y为0时，w为1〜2的整数， x是1到2的整数。

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