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    • 7. 发明授权
    • Coating composition of aziridinyl polymer and epoxy polymer(s)
    • 氮丙啶基聚合物和环氧聚合物的涂料组合物
    • US5241001A
    • 1993-08-31
    • US904083
    • 1992-06-25
    • Charles M. KaniaPadmanabhan SundararamanJoseph M. CarneyStephen J. Thomas
    • Charles M. KaniaPadmanabhan SundararamanJoseph M. CarneyStephen J. Thomas
    • C08G59/28C08G59/32C08G59/50C08L63/06C09D133/06C09D163/00
    • C09D163/00C08G59/28C08G59/3245C08G59/5066C09D133/062C08L63/06
    • Isocyanate-free coating compositions, capable of forming a durable coating under ambient conditions, are claimed comprising(A) at least one polymer, oligomer or combinations thereof selected from the group consisting of acrylic, urethane and urea polymers and oligomers having a number average molecular weight of at least about 100 and bearing at least two aziridinyl groups defined by the following structural formula: ##STR1## wherein X represents O, S, NH, NR, wherein R represents an alkyl having from one to 12 carbon atoms, or higher, or phenyl,R.sub.1 represents (CH.sub.2)m.sub.1, m.sub.1 being an integer ranging from 1 to 3 andR.sub.2 represents H, CH.sub.3 or combinations thereof; and a member selected from the group consisting of (B) and (C) wherein(B) is at least one polymer, oligomer or combinations thereof selected from the group consisting of acrylic, urethane and urea polymers and oligomers having a number average molecular weight of at least about 100 and bearing at least two groups selected from epoxy groups defined by one of the following structural formulas: ##STR2## wherein R.sub.3 represents (CH.sub.2)m.sub.2, m.sub.2 being an integer ranging from 1 to 2; and wherein R.sub.3 represents (CH.sub.2)m.sub.2, m.sub.2 being an integer ranging from 1 to 2; and(C) is a polymer or oligomer represented by the following structural formula: ##STR3## wherein R represents alkyl having from one to 20 carbon atoms and n=0-20. Processes for coating a substrate using such compositions are also claimed.
    • 要求包含(A)至少一种选自丙烯酸,氨基甲酸酯和脲聚合物的聚合物,低聚物或其组合的聚合物和具有数均分子量的低聚物 至少约100重量%,并具有由以下结构式定义的至少两个氮丙啶基:其中X表示O,S,NH,NR,其中R表示具有1至12个碳原子或更高的烷基, 或苯基,R 1表示(CH 2)m1,m1为1〜3的整数,R 2表示H,CH 3或其组合; 和选自(B)和(C)的成员,其中(B)为至少一种选自丙烯酸,氨基甲酸酯和脲聚合物的聚合物,低聚物或其组合,并且具有数均分子量 至少约100个并具有至少两个选自以下结构式之一的环氧基的基团:其中R 3表示(CH 2)m 2,m 2为1至2的整数; 并且其中R 3表示(CH 2)m 2,m 2为1至2的整数; 和(C)是由以下结构式表示的聚合物或低聚物:其中R表示具有1至20个碳原子且n = 0-20的烷基。 还要求保护使用这种组合物涂覆基底的方法。