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111. 发明授权

US07985929B2 Circuit board and method of manufacturing the same 失效
标题翻译：电路板及其制造方法
公开(公告)号：US07985929B2
公开(公告)日：2011-07-26
申请号：US11896204
申请日：2007-08-30
申请人： Yasuto Watanabe , Hiroyuki Fujita , Kunio Watanabe
发明人： Yasuto Watanabe , Hiroyuki Fujita , Kunio Watanabe
IPC分类号： H05K1/11
CPC分类号： H05K3/4046 , H05K3/0047 , H05K3/325 , H05K3/3447 , H05K2201/09845 , H05K2201/10401 , H05K2201/10409 , H05K2201/10962 , Y10T29/49126 , Y10T29/49165
摘要： A circuit board and a method of manufacturing the same are provided. The circuit board includes: a multilayer board in which a plurality of conductive layers with desired patterns formed therein, and a plurality of insulating layers are stacked; a plurality of through holes penetrating the multilayer board; cylindrical recesses each formed around a through hole corresponding thereto, having a diameter larger than that of the through hole, having a depth from an outermost surface of the insulating layer to a surface of the conductive layer for electrical connection, and partially exposing the surface of the predetermined conductive layer; and a plurality of conductive terminals fitted into the through holes.
摘要翻译：提供一种电路板及其制造方法。电路板包括：多层板，其中形成有所需图案的多个导电层，并且堆叠多个绝缘层; 贯穿多层基板的多个通孔; 圆柱形凹部各自围绕与其对应的通孔形成，其直径大于通孔的直径，具有从绝缘层的最外表面到用于电连接的导电层的表面的深度，并且部分地暴露所述预定导电层; 以及配置在通孔中的多个导电端子。

112. 发明授权

US07906821B2 Semiconductor device 有权
标题翻译：半导体器件
公开(公告)号：US07906821B2
公开(公告)日：2011-03-15
申请号：US12129191
申请日：2008-05-29
申请人： Masahiro Hayashi , Takahisa Akiba , Kunio Watanabe , Tomo Takaso , Susumu Kenmochi
发明人： Masahiro Hayashi , Takahisa Akiba , Kunio Watanabe , Tomo Takaso , Susumu Kenmochi
IPC分类号： H01L29/76 , H01L29/94 , H01L29/788 , H01L27/148 , H01L29/768
CPC分类号： H01L29/7834 , H01L23/5225 , H01L23/585 , H01L29/0638 , H01L29/0653 , H01L29/0692 , H01L29/1083 , H01L29/402 , H01L29/7833 , H01L2924/0002 , H01L2924/00
摘要： A semiconductor device including: a semiconductor layer; a gate insulating layer; a gate electrode; a channel region; a source region and a drain region; a guard ring region; an offset insulating layer; a first interlayer dielectric; a first shield layer formed above the first interlayer dielectric and the guard ring region and electrically connected to the guard ring region; a second interlayer dielectric; and a second shield layer formed above the second interlayer dielectric, wherein the first shield layer is provided outside of both ends of the gate electrode in a channel width direction when viewed from the top side; and wherein the second shield layer is provided in at least part of a first region and/or at least part of a second region, the first region being a region between one edge of the gate electrode and an edge of the first shield layer opposite to the edge of the gate electrode in the channel width direction when viewed from the top side, and the second region being a region between the other edge of the gate electrode and an edge of the first shield layer opposite to the other edge of the gate electrode in the channel width direction when viewed from the top side.
摘要翻译：一种半导体器件，包括：半导体层; 栅极绝缘层; 栅电极; 一个通道区; 源区和漏区; 护环区; 偏移绝缘层; 第一层间电介质; 第一屏蔽层，其形成在所述第一层间电介质和所述保护环区域上方并电连接到所述保护环区域; 第二层间电介质; 以及形成在所述第二层间电介质上方的第二屏蔽层，其中当从所述顶侧观察时，所述第一屏蔽层设置在所述栅电极的两端的沟道宽度方向的外侧; 并且其中所述第二屏蔽层设置在第一区域和/或第二区域的至少一部分的至少一部分中，所述第一区域是所述栅电极的一个边缘与所述第一屏蔽层的与所述第一屏蔽层的边缘相反的边缘之间的区域所述栅电极的边缘在从所述顶侧观察时在所述沟道宽度方向上，所述第二区域是所述栅电极的另一边缘与所述第一屏蔽层的与所述栅电极的另一边缘相反的边缘之间的区域在从顶侧观察的通道宽度方向上。

113. 再颁专利

USRE41806E1 Process for producing a fluorine atom-containing sulfonyl fluoride compound 失效
标题翻译：含氟原子的磺酰氟化合物的制造方法
公开(公告)号：USRE41806E1
公开(公告)日：2010-10-05
申请号：US11812533
申请日：2007-06-19
申请人： Masahiro Ito , Kunio Watanabe , Takashi Okazoe , Isamu Kaneko , Daisuke Shirakawa
发明人： Masahiro Ito , Kunio Watanabe , Takashi Okazoe , Isamu Kaneko , Daisuke Shirakawa
IPC分类号： C07C309/00
CPC分类号： C07C309/82 , C07C51/60 , C07C303/22 , C07C59/135
摘要： The present invention provides a process whereby fluorine atom-containing sulfonyl fluoride compound(s) useful as e.g. materials for ion-exchange membranes, can be produced efficiently and at low cost without structural limitations while solving the difficulties in production. Namely, the present invention provides a process which comprises reacting XSO2RA-E1 (1) with RB-E2 (2) to form XSO2R4-E-RB (3), then reacting (3) with fluorine in a liquid phase to form FSO2RAF-EF-RBF (4), and further, decomposing the compound to obtain FSO2RAF-EFl (5), wherein RA is a bivalent organic group, E1 is a monovalent reactive group, RB is a monovalent organic group, E2 is a monovalent reactive group which is reactive with E1, E is a bivalent connecting group formed by the reaction of E1 with E2, RAF is a bivalent organic group formed by the fluorination of RA, etc., RBF is the same group as RB, etc., EF1 is a bivalent connecting group formed by the fluorination of E, etc., EF1 is a monovalent group formed by the decomposition of EF, and X is a halogen atom.
摘要翻译：本发明提供了一种可用于例如氟原子的磺酰氟化合物的方法。用于离子交换膜的材料可以在没有结构限制的情况下有效且低成本地生产，同时解决生产上的困难。即，本发明提供一种方法，其包括使XSO2RA-E1（1）与RB-E2（2）反应形成XSO 2 R 4 -E-RB（3），然后使（3）与氟在液相中反应形成FSO2RAF- EF-RBF（4），进一步分解化合物，得到FSO2RAF-EF1（5），其中RA为二价有机基团，E1为单价反应性基团，RB为一价有机基团，E2为单价反应基团 E与E1反应，E是通过E1与E2的反应形成的二价连接基团，RAF是通过RA的氟化形成的二价有机基团等，RBF与RB等同，EF1是通过E的氟化形成的二价连接基团等，EF1是通过EF的分解形成的一价基团，X是卤素原子。

114. 发明申请

US20100029878A1 METHOD FOR PRODUCING FLUOROPOLYMER USING FLUOROCARBOXYLIC ACID COMPOUND 审中-公开
标题翻译：使用氟代羧酸化合物生产氟聚合物的方法
公开(公告)号：US20100029878A1
公开(公告)日：2010-02-04
申请号：US12577785
申请日：2009-10-13
申请人： Yasuhiko MATSUOKA , Kunio Watanabe , Kiroki Kamiya
发明人： Yasuhiko MATSUOKA , Kunio Watanabe , Kiroki Kamiya
IPC分类号： C08F2/22
CPC分类号： C08F14/18 , C08F14/26 , C08F114/26 , C08F2/24 , C08F2/22
摘要： To provide a method for efficiently producing a fluoropolymer by an aqueous emulsion polymerization in which a fluorocarboxylic acid compound is used.A method for producing a fluoropolymer, which comprises polymerizing a fluoromonomer by emulsion polymerization in the presence of a polymerization catalyst in an aqueous medium containing a fluorocarboxylic acid, wherein the aqueous medium in the polymerization has a pH of at most 4.
摘要翻译：提供通过使用氟代羧酸化合物的水性乳液聚合来有效生产含氟聚合物的方法。一种含氟聚合物的制造方法，其特征在于，在聚合催化剂的存在下，在含有氟代羧酸的水性介质中，通过乳液聚合使含氟单体聚合，其中聚合中的水性介质的pH为4以下。

115. 发明授权

US07501540B2 Process for producing perfluorodiacyl fluorinated compounds 失效
标题翻译：制备全氟二碘氟化合物的方法
公开(公告)号：US07501540B2
公开(公告)日：2009-03-10
申请号：US11770889
申请日：2007-06-29
申请人： Shu-zhong Wang , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Daisuke Shirakawa , Kazuya Oharu
发明人： Shu-zhong Wang , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Daisuke Shirakawa , Kazuya Oharu
IPC分类号： C07C21/18 , C07C53/38 , C07C55/36
CPC分类号： C07C59/60 , C07C51/09 , C07C59/315 , C07C67/14 , C07C67/31 , C07C69/708 , C07C69/734
摘要： The present invention provides a process for producing compounds useful as raw materials for various fluororesins in high yields in few steps from inexpensive and readily available starting materials.The following compound (1) and the following compound (2) are reacted to form the following compound (3), then the compound (3) is fluorinated in a liquid phase to form the following compound (4), and the ester bonds in the compound (4) are dissociated to form the compound (5), or the compound (5) and the compound (6). HOCH2-Q-O—(CH2)3—OH (1), CRBCOX (2), RBCOOCH2-Q-O—(CH2)3—OCORB (3), RBFCOOCF2-QF-O—(CF2)3—OCORBF (4), FCO-QF-O—(CF2)2—COF (5), RBFCOF (6).
摘要翻译：本发明提供了从廉价且易于获得的起始原料以几步的方式高产率地生产用作各种氟树脂的原料的化合物的方法。使下列化合物（1）和下列化合物（2）反应形成下列化合物（3），然后将化合物（3）在液相中氟化，形成下列化合物（4）解离化合物（4）以形成化合物（5）或化合物（5）和化合物（6）。 HO-2-QO-（CH2）3-OH（1），<？in-line-formula description =“In-line formula”end =“lead” “end =”tail“？> <？in-line-formula description =”In-line formula“end =”lead“？> CRBCOX（2），<？in-line-formula description =”In-line Formulas“ end =“tail”？> <？in-line-formula description =“In-line formula”end =“lead”？> RBCOOCH2-QO-（CH2）3-OCORB（3），<？in-line-formula 描述=“在线公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> RBFCOOCF2-QF-O-（CF2）3-OCORBF 4），<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> FCO-QF -O-（CF2）2-COF（5），<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas” end =“lead”？> RBFCOF（6）。<？in-line-formula description =“In-line Formulas”end =“tail”？>

116. 发明授权

US07488847B2 Fluorinated adamantane and its derivatives 有权
公开(公告)号：US07488847B2
公开(公告)日：2009-02-10
申请号：US11153438
申请日：2005-06-16
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
IPC分类号： C07C63/00
CPC分类号： C07C51/60 , C07C67/14 , C07C67/287 , C07C67/307 , C07C2603/74 , C07C55/40 , C07C53/50 , C07C69/54 , C07C69/63 , C07C69/708 , C07C69/753 , C07C69/734
摘要： The present invention provides a process A1 for producing a compound (5A), which comprises fluorinating a compound (3A-1) by liquid phase fluorination to a compound (4A-1), followed by a decomposition reaction of an ester bond; a process A2 for producing a compound (5A), which comprises fluorinating a compound (3A-2) by liquid phase fluorination to a compound (4A-2), followed by a decomposition reaction of an ester bond; and a process B for producing a compound (5B), which comprises fluorinating a compound (3B) by liquid phase fluorination to a compound (4B), followed by hydrolysis or alcoholysis. Further, the present invention provides a compound (5A) wherein n is 2 to 4, and a compound (5B) wherein n is 3 or 4. A(—CH2—OCO—R)n (3A-1) Af(—CF2—OCO—Rf)n (4A-1) A(—COOR)n (3A-2) Af(—COORf)n (4A-2) Af(—COF)n (5A) A(—OCO—R)n (3B) Af(—OCO—Rf)n (4B) Af(—OH)n (5B) provided that the carbon atom in adamantane to which —OCO—Rf is bonded, is a tertiary carbon atom, A is a n-valent group having n hydrogen atoms in adamantane converted to connecting bonds, R is a fluorinated monovalent organic group, n is an integer of from 1 to 4, Af is a group having at least one of hydrogen atoms in the group A substituted by a fluorine atom, and Rf is a fluorinated monovalent organic group.

117. 发明授权

US07394137B2 Semiconductor device 有权
标题翻译：半导体器件
公开(公告)号：US07394137B2
公开(公告)日：2008-07-01
申请号：US11519169
申请日：2006-09-11
申请人： Masahiro Hayashi , Takahisa Akiba , Kunio Watanabe , Tomo Takaso , Susumu Kenmochi
发明人： Masahiro Hayashi , Takahisa Akiba , Kunio Watanabe , Tomo Takaso , Susumu Kenmochi
IPC分类号： H01L29/76 , H01L29/94 , H01L31/062
CPC分类号： H01L29/7834 , H01L23/5225 , H01L23/585 , H01L29/0638 , H01L29/0653 , H01L29/0692 , H01L29/1083 , H01L29/402 , H01L29/7833 , H01L2924/0002 , H01L2924/00
摘要： A semiconductor device including: a semiconductor layer; a gate insulating layer; a gate electrode; a channel region; a source region and a drain region; a guard ring region; an offset insulating layer; a first interlayer dielectric; a first shield layer formed above the first interlayer dielectric and the guard ring region and electrically connected to the guard ring region; a second interlayer dielectric; and a second shield layer formed above the second interlayer dielectric, wherein the first shield layer is provided outside of both ends of the gate electrode in a channel width direction when viewed from the top side; and wherein the second shield layer is provided in at least part of a first region and/or at least part of a second region, the first region being a region between one edge of the gate electrode and an edge of the first shield layer opposite to the edge of the gate electrode in the channel width direction when viewed from the top side, and the second region being a region between the other edge of the gate electrode and an edge of the first shield layer opposite to the other edge of the gate electrode in the channel width direction when viewed from the top side.
摘要翻译：一种半导体器件，包括：半导体层; 栅极绝缘层; 栅电极; 一个通道区; 源区和漏区; 护环区; 偏移绝缘层; 第一层间电介质; 第一屏蔽层，其形成在所述第一层间电介质和所述保护环区域上方并电连接到所述保护环区域; 第二层间电介质; 以及形成在所述第二层间电介质上方的第二屏蔽层，其中当从所述顶侧观察时，所述第一屏蔽层设置在所述栅电极的两端的沟道宽度方向的外侧; 并且其中所述第二屏蔽层设置在第一区域和/或第二区域的至少一部分的至少一部分中，所述第一区域是所述栅电极的一个边缘与所述第一屏蔽层的与所述第一屏蔽层的边缘相反的边缘之间的区域所述栅电极的边缘在从所述顶侧观察时在所述沟道宽度方向上，所述第二区域是所述栅电极的另一边缘与所述第一屏蔽层的与所述栅电极的另一边缘相反的边缘之间的区域在从顶侧观察的通道宽度方向上。

118. 发明申请

US20080132736A1 FLUOROADAMANTANE DERIVATIVE 失效
标题翻译：荧光素衍生物
公开(公告)号：US20080132736A1
公开(公告)日：2008-06-05
申请号：US12020863
申请日：2008-01-28
申请人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
发明人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
IPC分类号： C07C35/22
CPC分类号： C07C69/653 , C07C29/095 , C07C35/52 , C07C67/14 , C07C67/287 , C07C2603/74 , C07C69/708
摘要： Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials.A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are —CFH— or —CF2—; RF is a perfluoroalkyl group or the like; X10 is F or the like; Y2 is H or OH; Y3 is H or RFCOO—; Y4 is H, F or RFCOO—; Y5 is H, F, RFCOO— or OH; Y0 is H, F, —OCOCR1═CH2 or OH: R1 is a hydrogen atom, a methyl group or the like; and X11 is OH or a halogen atom:
摘要翻译：金刚烷衍生物可以通过从容易获得的材料的经济上有利的方法产生耐蚀性优异且具有改善的具有短波长的光的透射率的聚合物的材料化合物。化合物（10）与化合物（11）进行酯化反应，得到化合物（12），将其进行液相氟化，得到化合物（13），然后进行水解或醇解得到化合物（2），然后与化合物（15）反应，得到化合物（1）。这里，A至J为-CFH-或-CF 2 - R F是全氟烷基等; X 10是F等; Y 2是H或OH; Y 3是H或R 0 COO-; Y 4是H，F或R“COO-; H 5是H，F，R F CO或O-; Y 0是H，F，-OCOCR 1 -CH 2或OH：R 1是氢原子，甲基等; 并且X 11是OH或卤素原子：

119. 发明授权

US07314952B2 Fluorinated adamantane derivatives 有权
标题翻译：氟化金刚烷衍生物
公开(公告)号：US07314952B2
公开(公告)日：2008-01-01
申请号：US11143978
申请日：2005-06-03
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
IPC分类号： C07C69/63
CPC分类号： C07C69/753 , C07C35/52 , C07C69/708 , C07C2603/74
摘要： The present invention provides novel compounds which are useful for the production of fluorinated adamantane derivatives excellent in etching resistance and useful as photolithographic material and so on. Namely, the present invention provides compounds represented by the following formulae (3) and (4): A(-G-Q-R)n (3) Af(-Gf-Q-Rf)n (4) provided that the symbols in the formula have the following meanings: A: a n-valent group having n hydrogen atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, R: a fluorinated monovalent organic group, n: an integer of from 1 to 4, G: —CH2— or a single bond, Q: —COO— or —OCO—, Af: a n-valent group (A) having n hydrogen atoms bonded to carbon atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, in which at least one of hydrogen atoms forming C—H bonds is substituted by a fluorine atom, Rf: a fluorinated monovalent organic group, Gf: —CF2— or a single bond.
摘要翻译：本发明提供了可用于制备耐腐蚀性优异且用作光刻材料等的氟化金刚烷衍生物的新化合物。即，本发明提供由下式（3）和（4）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> A（-GQR）（3）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead” （4）<？------------------（（（（（（（（（（-（（----------------- 公式描述=“直列公式”end =“tail”？>条件是式中的符号具有以下含义：A：具有转化为连接键的金刚烷的n个氢原子的n价基团，其中氢原子不转化成连接键，可以各自被烷基取代，R：氟化一价有机基团，n：1〜4的整数，G：-CH 2 - 或单键， Q：-COO-或-OCO-，A0：具有与键合到金刚烷的碳原子上的n个氢原子的n价基团（A）转化为连接键，其中未转化为连接键的氢原子可以各自被烷基取代，其中至少一个形成CH键的氢原子被氟原子取代：氟化一价有机基团， -CF 2 - 或单键。

120. 发明授权

US07271229B2 Processes for producing a fluorosulfonyl group-containing compound and a compound led from the fluorosulfonyl group-containing compound 有权
标题翻译：用于制备含氟磺酰基化合物和由含氟磺酰基化合物引发的化合物的方法
公开(公告)号：US07271229B2
公开(公告)日：2007-09-18
申请号：US10830140
申请日：2004-04-23
申请人： Takashi Okazoe , Atsushi Watakabe , Masahiro Ito , Kunio Watanabe , Takeshi Eriguchi , Kimiaki Kashiwagi , Shu-zhong Wang
发明人： Takashi Okazoe , Atsushi Watakabe , Masahiro Ito , Kunio Watanabe , Takeshi Eriguchi , Kimiaki Kashiwagi , Shu-zhong Wang
IPC分类号： G08F228/02
CPC分类号： C08F24/00 , C07D317/18 , C07D317/24 , C07D317/42
摘要： A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer
摘要翻译：具有高聚合反应性的含氟磺酰基的化合物，其制备方法，由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过使含磺酰基的可聚合单体聚合而获得的聚合物

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