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1. 发明申请

US20070083064A1 NOVEL FLUORINATED ADAMANTANE DERIVATIVE 失效
标题翻译：新型氟化物衍生物
公开(公告)号：US20070083064A1
公开(公告)日：2007-04-12
申请号：US11611183
申请日：2006-12-15
申请人： Kazuya OHARU , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
发明人： Kazuya OHARU , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
IPC分类号： C07C57/64
CPC分类号： C07C61/15 , C07C51/58 , C07C2603/74
摘要： A compound represented by the formula AF(—COF)n, provided that AF and n have the following meanings. AF: a fluorinated adamantane residue which is an n-valent group having an n number of hydrogen atoms removed from adamantane (provided that when n is at least 2, the removed hydrogen atoms are hydrogen atoms bonded to different carbon atoms), wherein at least one of the remaining hydrogen atoms is substituted by a fluorine atom, and the remaining hydrogen atoms may be substituted by a C1-6 alkyl group or fluoroalkyl group, and n: an integer of from 1 to 4, provided the when n is 1, AF has at least one hydrogen atom.
摘要翻译：由式A -F（ - COF）n N表示的化合物，条件是A和N具有下列含义。氟化金刚烷残基，其是从金刚烷中除去n个氢原子的n价基团（条件是当n至少为2时，除去的氢原子是与氢原子键合的氢原子不同的碳原子），其中剩余的氢原子中的至少一个被氟原子取代，剩余的氢原子可以被C 1-6烷基或氟代烷基取代，n ：1〜4的整数，n为1时，A为至少1个氢原子。

2. 发明申请

US20050288528A1 Fluorinated adamantane and its derivatives 有权
公开(公告)号：US20050288528A1
公开(公告)日：2005-12-29
申请号：US11153438
申请日：2005-06-16
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
IPC分类号： C07C51/60 , C07C53/38 , C07C67/14 , C07C67/287 , C07C67/307
CPC分类号： C07C51/60 , C07C67/14 , C07C67/287 , C07C67/307 , C07C2603/74 , C07C55/40 , C07C53/50 , C07C69/54 , C07C69/63 , C07C69/708 , C07C69/753 , C07C69/734
摘要： The present invention provides a process A1 for producing a compound (5A), which comprises fluorinating a compound (3A-1) by liquid phase fluorination to a compound (4A-1), followed by a decomposition reaction of an ester bond; a process A2 for producing a compound (5A), which comprises fluorinating a compound (3A-2) by liquid phase fluorination to a compound (4A-2), followed by a decomposition reaction of an ester bond; and a process B for producing a compound (5B), which comprises fluorinating a compound (3B) by liquid phase fluorination to a compound (4B), followed by hydrolysis or alcoholysis. Further, the present invention provides a compound (5A) wherein n is 2 to 4, and a compound (5B) wherein n is 3 or 4. A(-CH2—OCO—R)n (3A-1) Af(-CF2—OCO—Rf)n (4A-1) A(-COOR)n (3A-2) Af(-COORf)n (4A-2) Af(-COF)n (5A) A(-OCO—R)n (3B) Af(-OCO—Rf)n (4B) Af(-OH)n (5B) provided that the carbon atom in adamantane to which —OCO—Rf is bonded, is a tertiary carbon atom, A is a n-valent group having n hydrogen atoms in adamantane converted to connecting bonds, R is a fluorinated monovalent organic group, n is an integer of from 1 to 4, Af is a group having at least one of hydrogen atoms in the group A substituted by a fluorine atom, and Rf is a fluorinated monovalent organic group.

3. 发明申请

US20050277785A1 Fluorinated adamantane derivatives 有权
标题翻译：氟化金刚烷衍生物
公开(公告)号：US20050277785A1
公开(公告)日：2005-12-15
申请号：US11143978
申请日：2005-06-03
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
IPC分类号： C07C35/52 , C07C69/00 , C07C69/74 , C07C35/22 , C07C69/63
CPC分类号： C07C69/753 , C07C35/52 , C07C69/708 , C07C2603/74
摘要： The present invention provides novel compounds which are useful for the production of fluorinated adamantane derivatives excellent in etching resistance and useful as photolithographic material and so on. Namely, the present invention provides compounds represented by the following formulae (3) and (4): A(-G-Q-R)n (3) Af(-Gf-Q-Rf)n (4)provided that the symbols in the formula have the following meanings: A: a n-valent group having n hydrogen atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, R: a fluorinated monovalent organic group, n: an integer of from 1 to 4, G: —CH2— or a single bond, Q: —COO— or —OCO—, Af: a n-valent group (A) having n hydrogen atoms bonded to carbon atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, in which at least one of hydrogen atoms forming C—H bonds is substituted by a fluorine atom, Rf: a fluorinated monovalent organic group, Gf: —CF2— or a single bond.
摘要翻译：本发明提供了可用于制备耐腐蚀性优异且用作光刻材料等的氟化金刚烷衍生物的新化合物。即，本发明提供由下式（3）和（4）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> A（-GQR）（3）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead” （4）<？------------------（（（（（（（（（（-（（----------------- 公式描述=“直列公式”end =“tail”？>条件是式中的符号具有以下含义：A：具有转化为连接键的金刚烷的n个氢原子的n价基团，其中氢原子不转化成连接键，可以各自被烷基取代，R：氟化一价有机基团，n：1〜4的整数，G：-CH 2 - 或单键， Q：-COO-或-OCO-，A0：具有与键合到金刚烷的碳原子上的n个氢原子的n价基团（A）转化为连接键，其中未转化为连接键的氢原子可以各自被烷基取代，其中至少一个形成CH键的氢原子被氟原子取代：氟化一价有机基团， -CF 2 - 或单键。

4. 发明申请

US20060194936A1 Novel fluorinated compound and fluoropolymer 审中-公开
标题翻译：新型氟化合物和含氟聚合物
公开(公告)号：US20060194936A1
公开(公告)日：2006-08-31
申请号：US11414300
申请日：2006-05-01
申请人： Takeshi Eriguchi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
发明人： Takeshi Eriguchi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
IPC分类号： C08F16/24
CPC分类号： C07D317/42 , C08F24/00 , G02B6/02033 , G02B2006/1219
摘要： The present invention provides a fluoropolymer having excellent mechanical strength and transparency, having a high glass transition point suitable for high-temperature use, and having a high refractive index. The present invention provides a novel compound represented by the following formula (1) and a fluoropolymer comprising monomer unit (2) formed by the polymerization of such a compound. RAF, RBF, RCF, RDF: each independently is a fluorine atom, a chlorine atom, a perfluoro monovalent saturated hydrocarbon group or a perfluoro(partially chlorinated monovalent saturated hydrocarbon) group, provided that at least one of RAF, RBF, RCF and RDF is a perfluoro(partially chlorinated monovalent saturated hydrocarbon) group.
摘要翻译：本发明提供一种具有优异的机械强度和透明性的氟聚合物，具有适合于高温使用的高玻璃化转变点，并具有高折射率。本发明提供由下式（1）表示的新化合物和通过这种化合物的聚合形成的含有单体单元（2）的含氟聚合物。 R AF，BF，R CF，R DF各自独立地是氟原子，氯原子，全氟一价饱和烃基或全氟（部分氯化的一价饱和烃）基团中的至少一个，条件是R AF，BF 2，R CF，和/或DF是全氟（部分氯化的一价饱和烃）基团。

5. 发明授权

US07511177B2 Fluoroadamantane derivative 失效
标题翻译：氟金刚烷衍生物
公开(公告)号：US07511177B2
公开(公告)日：2009-03-31
申请号：US12020863
申请日：2008-01-28
申请人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
发明人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
IPC分类号： C07C35/22
CPC分类号： C07C69/653 , C07C29/095 , C07C35/52 , C07C67/14 , C07C67/287 , C07C2603/74 , C07C69/708
摘要： Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials.A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are —CFH— or —CF2—; RF is a perfluoroalkyl group or the like; X10 is F or the like; Y2 is H or OH; Y3 is H or RFCOO—; Y4 is H, F or RFCOO—; Y5 is H, F, RFCOO— or OH; Y0 is H, F, —OCOCR1═CH2 or OH: R1 is a hydrogen atom, a methyl group or the like; and X11 is OH or a halogen atom:
摘要翻译：金刚烷衍生物可以通过从容易获得的材料的经济上有利的方法产生耐蚀性优异且具有改善的具有短波长的光的透射率的聚合物的材料化合物。化合物（10）与化合物（11）进行酯化反应，得到化合物（12），将其进行液相氟化，得到化合物（13），然后进行水解或醇解得到化合物（2），然后与化合物（15）反应，得到化合物（1）。这里，A至J为-CFH-或-CF2-; RF是全氟烷基等; X10为F等; Y2是H或OH; Y3为H或RFCOO-; Y4是H，F或RFCOO-; Y5为H，F，RFCOO-或OH; Y0是H，F，-OCOCR1-CH2或OH：R1是氢原子，甲基等; X 11为OH或卤原子：

6. 发明授权

US07425646B2 Fluorinated adamantane derivative 失效
标题翻译：氟化金刚烷衍生物
公开(公告)号：US07425646B2
公开(公告)日：2008-09-16
申请号：US11611183
申请日：2006-12-15
申请人： Kazuya Oharu , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
发明人： Kazuya Oharu , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
IPC分类号： C07C69/63
CPC分类号： C07C61/15 , C07C51/58 , C07C2603/74
摘要： A compound represented by the formula AF(—COF)n, provided that AF and n have the following meanings.AF: a fluorinated adamantane residue which is an n-valent group having an n number of hydrogen atoms removed from adamantane (provided that when n is at least 2, the removed hydrogen atoms are hydrogen atoms bonded to different carbon atoms), wherein at least one of the remaining hydrogen atoms is substituted by a fluorine atom, and the remaining hydrogen atoms may be substituted by a C1-6 alkyl group or fluoroalkyl group, and n: an integer of from 1 to 4, provided the when n is 1, AF has at least one hydrogen atom.
摘要翻译：由式A -F（ - COF）n N表示的化合物，条件是A和N具有下列含义。氟化金刚烷残基，其是从金刚烷中除去n个氢原子的n价基团（条件是当n至少为2时，除去的氢原子是与氢原子键合的氢原子不同的碳原子），其中剩余的氢原子中的至少一个被氟原子取代，剩余的氢原子可以被C 1-6烷基或氟代烷基取代，n ：1〜4的整数，n为1时，A为至少1个氢原子。

7. 发明授权

US07488847B2 Fluorinated adamantane and its derivatives 有权
公开(公告)号：US07488847B2
公开(公告)日：2009-02-10
申请号：US11153438
申请日：2005-06-16
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
IPC分类号： C07C63/00
CPC分类号： C07C51/60 , C07C67/14 , C07C67/287 , C07C67/307 , C07C2603/74 , C07C55/40 , C07C53/50 , C07C69/54 , C07C69/63 , C07C69/708 , C07C69/753 , C07C69/734
摘要： The present invention provides a process A1 for producing a compound (5A), which comprises fluorinating a compound (3A-1) by liquid phase fluorination to a compound (4A-1), followed by a decomposition reaction of an ester bond; a process A2 for producing a compound (5A), which comprises fluorinating a compound (3A-2) by liquid phase fluorination to a compound (4A-2), followed by a decomposition reaction of an ester bond; and a process B for producing a compound (5B), which comprises fluorinating a compound (3B) by liquid phase fluorination to a compound (4B), followed by hydrolysis or alcoholysis. Further, the present invention provides a compound (5A) wherein n is 2 to 4, and a compound (5B) wherein n is 3 or 4. A(—CH2—OCO—R)n (3A-1) Af(—CF2—OCO—Rf)n (4A-1) A(—COOR)n (3A-2) Af(—COORf)n (4A-2) Af(—COF)n (5A) A(—OCO—R)n (3B) Af(—OCO—Rf)n (4B) Af(—OH)n (5B) provided that the carbon atom in adamantane to which —OCO—Rf is bonded, is a tertiary carbon atom, A is a n-valent group having n hydrogen atoms in adamantane converted to connecting bonds, R is a fluorinated monovalent organic group, n is an integer of from 1 to 4, Af is a group having at least one of hydrogen atoms in the group A substituted by a fluorine atom, and Rf is a fluorinated monovalent organic group.

8. 发明申请

US20080132736A1 FLUOROADAMANTANE DERIVATIVE 失效
标题翻译：荧光素衍生物
公开(公告)号：US20080132736A1
公开(公告)日：2008-06-05
申请号：US12020863
申请日：2008-01-28
申请人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
发明人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
IPC分类号： C07C35/22
CPC分类号： C07C69/653 , C07C29/095 , C07C35/52 , C07C67/14 , C07C67/287 , C07C2603/74 , C07C69/708
摘要： Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials.A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are —CFH— or —CF2—; RF is a perfluoroalkyl group or the like; X10 is F or the like; Y2 is H or OH; Y3 is H or RFCOO—; Y4 is H, F or RFCOO—; Y5 is H, F, RFCOO— or OH; Y0 is H, F, —OCOCR1═CH2 or OH: R1 is a hydrogen atom, a methyl group or the like; and X11 is OH or a halogen atom:
摘要翻译：金刚烷衍生物可以通过从容易获得的材料的经济上有利的方法产生耐蚀性优异且具有改善的具有短波长的光的透射率的聚合物的材料化合物。化合物（10）与化合物（11）进行酯化反应，得到化合物（12），将其进行液相氟化，得到化合物（13），然后进行水解或醇解得到化合物（2），然后与化合物（15）反应，得到化合物（1）。这里，A至J为-CFH-或-CF 2 - R F是全氟烷基等; X 10是F等; Y 2是H或OH; Y 3是H或R 0 COO-; Y 4是H，F或R“COO-; H 5是H，F，R F CO或O-; Y 0是H，F，-OCOCR 1 -CH 2或OH：R 1是氢原子，甲基等; 并且X 11是OH或卤素原子：

9. 发明授权

US07314952B2 Fluorinated adamantane derivatives 有权
标题翻译：氟化金刚烷衍生物
公开(公告)号：US07314952B2
公开(公告)日：2008-01-01
申请号：US11143978
申请日：2005-06-03
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
IPC分类号： C07C69/63
CPC分类号： C07C69/753 , C07C35/52 , C07C69/708 , C07C2603/74
摘要： The present invention provides novel compounds which are useful for the production of fluorinated adamantane derivatives excellent in etching resistance and useful as photolithographic material and so on. Namely, the present invention provides compounds represented by the following formulae (3) and (4): A(-G-Q-R)n (3) Af(-Gf-Q-Rf)n (4) provided that the symbols in the formula have the following meanings: A: a n-valent group having n hydrogen atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, R: a fluorinated monovalent organic group, n: an integer of from 1 to 4, G: —CH2— or a single bond, Q: —COO— or —OCO—, Af: a n-valent group (A) having n hydrogen atoms bonded to carbon atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, in which at least one of hydrogen atoms forming C—H bonds is substituted by a fluorine atom, Rf: a fluorinated monovalent organic group, Gf: —CF2— or a single bond.
摘要翻译：本发明提供了可用于制备耐腐蚀性优异且用作光刻材料等的氟化金刚烷衍生物的新化合物。即，本发明提供由下式（3）和（4）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> A（-GQR）（3）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead” （4）<？------------------（（（（（（（（（（-（（----------------- 公式描述=“直列公式”end =“tail”？>条件是式中的符号具有以下含义：A：具有转化为连接键的金刚烷的n个氢原子的n价基团，其中氢原子不转化成连接键，可以各自被烷基取代，R：氟化一价有机基团，n：1〜4的整数，G：-CH 2 - 或单键， Q：-COO-或-OCO-，A0：具有与键合到金刚烷的碳原子上的n个氢原子的n价基团（A）转化为连接键，其中未转化为连接键的氢原子可以各自被烷基取代，其中至少一个形成CH键的氢原子被氟原子取代：氟化一价有机基团， -CF 2 - 或单键。

10. 发明申请

US20070129566A1 FLUOROADAMANTANE DERIVATIVE 失效
标题翻译：荧光素衍生物
公开(公告)号：US20070129566A1
公开(公告)日：2007-06-07
申请号：US11567391
申请日：2006-12-06
申请人： Shu-zhong WANG , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
发明人： Shu-zhong WANG , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
IPC分类号： C07C69/52
CPC分类号： C07C69/653 , C07C29/095 , C07C35/52 , C07C67/14 , C07C67/287 , C07C2603/74 , C07C69/708
摘要： Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials. A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are —CFH— or —CF2—; RF is a perfluoroalkyl group or the like; X10 is F or the like; Y2 is H or OH; Y3 is H or RFCOO—; Y4 is H, F or RFCOO—; Y5 is H, F, RFCOO— or OH; Y0 is H, F, —OCOCR1═CH2 or OH: R1 is a hydrogen atom, a methyl group or the like; and X11 is OH or a halogen atom:
摘要翻译：金刚烷衍生物可以通过从容易获得的材料的经济上有利的方法产生耐蚀性优异且具有改善的具有短波长的光的透射率的聚合物的材料化合物。化合物（10）与化合物（11）进行酯化反应，得到化合物（12），将其进行液相氟化，得到化合物（13），然后进行水解或醇解得到化合物（2），然后与化合物（15）反应，得到化合物（1）。这里，A至J为-CFH-或-CF 2 - RF是全氟烷基等; X 10是F等; Y 2是H或OH; Y 3是H或R 0 COO-; Y 4是H，F或R“COO-; H 5是H，F，R F CO或O-; Y 0是H，F，-OCOCR 1 -CH 2或OH：R 1是氢原子，甲基等; 并且X 11是OH或卤素原子：

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