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1. 发明申请

US20090192330A1 FLUOROCOMPOUND HAVING HIGHLY FLUORINATED NORBORNANE STRUCTURE, FLUOROPOLYMER, AND THEIR PRODUCTION PROCESSES 失效
标题翻译：具有高度氟化的诺贝恩结构，荧光体及其生产工艺的氟化合物
公开(公告)号：US20090192330A1
公开(公告)日：2009-07-30
申请号：US12351905
申请日：2009-01-12
申请人： Yasuhisa MATSUKAWA , Daisuke SHIRAKAWA , Eisuke MUROTANI , Naoko SHIROTA , Yoko TAKEBE
发明人： Yasuhisa MATSUKAWA , Daisuke SHIRAKAWA , Eisuke MUROTANI , Naoko SHIROTA , Yoko TAKEBE
IPC分类号： C07C43/192 , C07C35/29 , C07C49/115 , C07C61/28 , C07C35/48 , C07C49/323
CPC分类号： C07C49/477 , C07C29/143 , C07C29/147 , C07C31/44 , C07C35/52 , C07C45/54 , C07C61/40 , C07C67/14 , C07C69/653 , C07C69/753 , C07C2602/42 , C08F220/24
摘要： To provide a novel polymerizable fluorocompound having a highly fluorinated norbornane structure, and a polymer obtained from the compound. Further, their production processes and a novel intermediate useful for the processes.A novel compound (1) such as a compound (11) or a compound (12), and its polymer. A compound (2) such as a compound (21) or (22), and a compound (3) such as a compound (31) or (32M), which are useful as an intermediate for the production of the compound (1), and its production process. However, each of ZA to ZE represents such as —CH(—OC(O)C(CH3)═CH2)— or —CF2, Each of WA and WB represents such as F, each of YA to YE represents such as —CH(—OH)— or —CF(CH2OH), and each of XA to XE represents such as —C(O)— or —CF2—.
摘要翻译：提供具有高氟化降冰片烷结构的新型可聚合氟化合物和由该化合物获得的聚合物。此外，它们的制备方法和用于该方法的新型中间体。新化合物（1）如化合物（11）或化合物（12）及其聚合物。作为化合物（1）的制造中间体的化合物（21）或（22）的化合物（2）和化合物（31）或（32M）等化合物（3），及其生产工艺。然而，ZA至ZE各自表示-CH（-OC（O）C（CH 3）-CH 2） - 或-CF 2，WA和WB各自表示F，YA至YE各自表示-CH （-OH） - 或-CF（CH 2 OH），XA至XE各自表示-C（O） - 或-CF 2 - 。

2. 发明申请

US20070083064A1 NOVEL FLUORINATED ADAMANTANE DERIVATIVE 失效
标题翻译：新型氟化物衍生物
公开(公告)号：US20070083064A1
公开(公告)日：2007-04-12
申请号：US11611183
申请日：2006-12-15
申请人： Kazuya OHARU , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
发明人： Kazuya OHARU , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
IPC分类号： C07C57/64
CPC分类号： C07C61/15 , C07C51/58 , C07C2603/74
摘要： A compound represented by the formula AF(—COF)n, provided that AF and n have the following meanings. AF: a fluorinated adamantane residue which is an n-valent group having an n number of hydrogen atoms removed from adamantane (provided that when n is at least 2, the removed hydrogen atoms are hydrogen atoms bonded to different carbon atoms), wherein at least one of the remaining hydrogen atoms is substituted by a fluorine atom, and the remaining hydrogen atoms may be substituted by a C1-6 alkyl group or fluoroalkyl group, and n: an integer of from 1 to 4, provided the when n is 1, AF has at least one hydrogen atom.
摘要翻译：由式A -F（ - COF）n N表示的化合物，条件是A和N具有下列含义。氟化金刚烷残基，其是从金刚烷中除去n个氢原子的n价基团（条件是当n至少为2时，除去的氢原子是与氢原子键合的氢原子不同的碳原子），其中剩余的氢原子中的至少一个被氟原子取代，剩余的氢原子可以被C 1-6烷基或氟代烷基取代，n ：1〜4的整数，n为1时，A为至少1个氢原子。

3. 发明申请

US20060183875A1 Novel fluorinated dioxolan compound and novel fluorinated polymer 审中-公开
标题翻译：新型氟化二氧戊环化合物和新型氟化聚合物
公开(公告)号：US20060183875A1
公开(公告)日：2006-08-17
申请号：US11401371
申请日：2006-04-11
申请人： Norihide Sugiyama , Masahiro Ito , Eisuke Murotani , Takashi Okazoe
发明人： Norihide Sugiyama , Masahiro Ito , Eisuke Murotani , Takashi Okazoe
IPC分类号： C08F224/00 , C07D405/02
CPC分类号： C08F24/00 , C07D317/42
摘要： To provide a novel fluorinated dioxolan compound which can be used as a raw material for a fluorinated polymer excellent in characteristics such as heat resistance, mechanical strength, transparency and rigidity, and a novel polymer. A compound represented by the following formula (1A), a compound represented by the following formula (1B) and a polymer comprising repeating units, wherein these compounds are polymerized. Here, Qf1 represents a single bond, an oxygen atom, a C1-5 perfluoroalkylene group, or a C1-5 perfluoroalkylene group having an etheric oxygen atom inserted between carbon-carbon atoms, X2 is a fluorine atom, or a group represented by —OR (wherein R is a hydrogen atom, a C1-5 is alkyl group, or a C1-5 alkyl group having an etheric oxygen atom inserted between carbon-carbon atoms).
摘要翻译：提供可用作耐热性，机械强度，透明性和刚性等特性优异的氟化聚合物的原料的新的氟化二氧戊环化合物和新型聚合物。由下式（1A）表示的化合物，由下式（1B）表示的化合物和包含重复单元的聚合物，其中这些化合物聚合。这里，Q 1表示单键，氧原子，C 1-5 - 全氟亚烷基或C 1-5 - 全氟亚烷基具有插入碳 - 碳原子之间的醚性氧原子，X 2是氟原子，或由-OR表示的基团（其中R是氢原子，C 1-5 - / SUB>是在碳 - 碳原子之间插入具有醚性氧原子的C 1-5烷基。

4. 发明申请

US20050288528A1 Fluorinated adamantane and its derivatives 有权
公开(公告)号：US20050288528A1
公开(公告)日：2005-12-29
申请号：US11153438
申请日：2005-06-16
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
IPC分类号： C07C51/60 , C07C53/38 , C07C67/14 , C07C67/287 , C07C67/307
CPC分类号： C07C51/60 , C07C67/14 , C07C67/287 , C07C67/307 , C07C2603/74 , C07C55/40 , C07C53/50 , C07C69/54 , C07C69/63 , C07C69/708 , C07C69/753 , C07C69/734
摘要： The present invention provides a process A1 for producing a compound (5A), which comprises fluorinating a compound (3A-1) by liquid phase fluorination to a compound (4A-1), followed by a decomposition reaction of an ester bond; a process A2 for producing a compound (5A), which comprises fluorinating a compound (3A-2) by liquid phase fluorination to a compound (4A-2), followed by a decomposition reaction of an ester bond; and a process B for producing a compound (5B), which comprises fluorinating a compound (3B) by liquid phase fluorination to a compound (4B), followed by hydrolysis or alcoholysis. Further, the present invention provides a compound (5A) wherein n is 2 to 4, and a compound (5B) wherein n is 3 or 4. A(-CH2—OCO—R)n (3A-1) Af(-CF2—OCO—Rf)n (4A-1) A(-COOR)n (3A-2) Af(-COORf)n (4A-2) Af(-COF)n (5A) A(-OCO—R)n (3B) Af(-OCO—Rf)n (4B) Af(-OH)n (5B) provided that the carbon atom in adamantane to which —OCO—Rf is bonded, is a tertiary carbon atom, A is a n-valent group having n hydrogen atoms in adamantane converted to connecting bonds, R is a fluorinated monovalent organic group, n is an integer of from 1 to 4, Af is a group having at least one of hydrogen atoms in the group A substituted by a fluorine atom, and Rf is a fluorinated monovalent organic group.

5. 发明申请

US20050277785A1 Fluorinated adamantane derivatives 有权
标题翻译：氟化金刚烷衍生物
公开(公告)号：US20050277785A1
公开(公告)日：2005-12-15
申请号：US11143978
申请日：2005-06-03
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
IPC分类号： C07C35/52 , C07C69/00 , C07C69/74 , C07C35/22 , C07C69/63
CPC分类号： C07C69/753 , C07C35/52 , C07C69/708 , C07C2603/74
摘要： The present invention provides novel compounds which are useful for the production of fluorinated adamantane derivatives excellent in etching resistance and useful as photolithographic material and so on. Namely, the present invention provides compounds represented by the following formulae (3) and (4): A(-G-Q-R)n (3) Af(-Gf-Q-Rf)n (4)provided that the symbols in the formula have the following meanings: A: a n-valent group having n hydrogen atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, R: a fluorinated monovalent organic group, n: an integer of from 1 to 4, G: —CH2— or a single bond, Q: —COO— or —OCO—, Af: a n-valent group (A) having n hydrogen atoms bonded to carbon atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, in which at least one of hydrogen atoms forming C—H bonds is substituted by a fluorine atom, Rf: a fluorinated monovalent organic group, Gf: —CF2— or a single bond.
摘要翻译：本发明提供了可用于制备耐腐蚀性优异且用作光刻材料等的氟化金刚烷衍生物的新化合物。即，本发明提供由下式（3）和（4）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> A（-GQR）（3）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead” （4）<？------------------（（（（（（（（（（-（（----------------- 公式描述=“直列公式”end =“tail”？>条件是式中的符号具有以下含义：A：具有转化为连接键的金刚烷的n个氢原子的n价基团，其中氢原子不转化成连接键，可以各自被烷基取代，R：氟化一价有机基团，n：1〜4的整数，G：-CH 2 - 或单键， Q：-COO-或-OCO-，A0：具有与键合到金刚烷的碳原子上的n个氢原子的n价基团（A）转化为连接键，其中未转化为连接键的氢原子可以各自被烷基取代，其中至少一个形成CH键的氢原子被氟原子取代：氟化一价有机基团， -CF 2 - 或单键。

6. 发明申请

US20120065347A1 FLUOROCOMPOUND HAVING HIGHLY FLUORINATED NORBORNANE STRUCTURE, FLUOROPOLYMER, AND THEIR PRODUCTION PROCESSES 审中-公开
标题翻译：具有高度氟化的诺贝恩结构，荧光体及其生产工艺的氟化合物
公开(公告)号：US20120065347A1
公开(公告)日：2012-03-15
申请号：US13302824
申请日：2011-11-22
申请人： Yasuhisa MATSUKAWA , Daisuke SHIRAKAWA , Eisuke MUROTANI , Naoko SHIROTA , Yoko TAKEBE
发明人： Yasuhisa MATSUKAWA , Daisuke SHIRAKAWA , Eisuke MUROTANI , Naoko SHIROTA , Yoko TAKEBE
IPC分类号： C08F120/68 , C07C69/753 , C07C53/50 , C07C49/477
CPC分类号： C07C49/477 , C07C29/143 , C07C29/147 , C07C31/44 , C07C35/52 , C07C45/54 , C07C61/40 , C07C67/14 , C07C69/653 , C07C69/753 , C07C2602/42 , C08F220/24
摘要： The present invention provides novel polymers obtained by polymerizing a compound of formula (1) which has a highly fluorinated norbornane structure. The invention also provides compounds represented by formulas (3) and (3A-1) below, as well as the following compounds:
摘要翻译：本发明提供了通过聚合具有高度氟化的降冰片烷结构的式（1）化合物获得的新型聚合物。本发明还提供由下式（3）和（3A-1）表示的化合物以及以下化合物：

7. 发明授权

US08134033B2 Fluorocompound having highly fluorinated norbornane structure, fluoropolymer, and their production processes 失效
标题翻译：具有高氟化降冰片烷结构的氟化合物，含氟聚合物及其制备方法
公开(公告)号：US08134033B2
公开(公告)日：2012-03-13
申请号：US12351905
申请日：2009-01-12
申请人： Yasuhisa Matsukawa , Daisuke Shirakawa , Eisuke Murotani , Naoko Shirota , Yoko Takebe
发明人： Yasuhisa Matsukawa , Daisuke Shirakawa , Eisuke Murotani , Naoko Shirota , Yoko Takebe
IPC分类号： C07C49/467 , C07C67/14 , C07C69/653 , C08F20/22
CPC分类号： C07C49/477 , C07C29/143 , C07C29/147 , C07C31/44 , C07C35/52 , C07C45/54 , C07C61/40 , C07C67/14 , C07C69/653 , C07C69/753 , C07C2602/42 , C08F220/24
摘要： To provide a novel polymerizable fluorocompound having a highly fluorinated norbornane structure, and a polymer obtained from the compound. Further, their production processes and a novel intermediate useful for the processes.A novel compound (1) such as a compound (11) or a compound (12), and its polymer. A compound (2) such as a compound (21) or (22), and a compound (3) such as a compound (31) or (32M), which are useful as an intermediate for the production of the compound (1), and its production process. However, each of ZA to ZE represents such as —CH(—OC(O)C(CH3)═CH2)— or —CF2, Each of WA and WB represents such as F, each of YA to YE represents such as —CH(—OH)— or —CF(CH2OH), and each of XA to XE represents such as —C(O)— or —CF2—.
摘要翻译：提供具有高氟化降冰片烷结构的新型可聚合氟化合物和由该化合物获得的聚合物。此外，它们的制备方法和用于该方法的新型中间体。新化合物（1）如化合物（11）或化合物（12）及其聚合物。作为化合物（1）的制造中间体的化合物（21）或（22）的化合物（2）和化合物（31）或（32M）等化合物（3），及其生产工艺。然而，ZA至ZE各自表示-CH（-OC（O）C（CH 3)≡CH2） - 或-CF 2，WA和WB各自表示F，YA至YE各自表示-CH （-OH） - 或-CF（CH 2 OH），XA至XE各自表示-C（O） - 或-CF 2 - 。

8. 发明授权

US07501540B2 Process for producing perfluorodiacyl fluorinated compounds 失效
标题翻译：制备全氟二碘氟化合物的方法
公开(公告)号：US07501540B2
公开(公告)日：2009-03-10
申请号：US11770889
申请日：2007-06-29
申请人： Shu-zhong Wang , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Daisuke Shirakawa , Kazuya Oharu
发明人： Shu-zhong Wang , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Daisuke Shirakawa , Kazuya Oharu
IPC分类号： C07C21/18 , C07C53/38 , C07C55/36
CPC分类号： C07C59/60 , C07C51/09 , C07C59/315 , C07C67/14 , C07C67/31 , C07C69/708 , C07C69/734
摘要： The present invention provides a process for producing compounds useful as raw materials for various fluororesins in high yields in few steps from inexpensive and readily available starting materials.The following compound (1) and the following compound (2) are reacted to form the following compound (3), then the compound (3) is fluorinated in a liquid phase to form the following compound (4), and the ester bonds in the compound (4) are dissociated to form the compound (5), or the compound (5) and the compound (6). HOCH2-Q-O—(CH2)3—OH (1), CRBCOX (2), RBCOOCH2-Q-O—(CH2)3—OCORB (3), RBFCOOCF2-QF-O—(CF2)3—OCORBF (4), FCO-QF-O—(CF2)2—COF (5), RBFCOF (6).
摘要翻译：本发明提供了从廉价且易于获得的起始原料以几步的方式高产率地生产用作各种氟树脂的原料的化合物的方法。使下列化合物（1）和下列化合物（2）反应形成下列化合物（3），然后将化合物（3）在液相中氟化，形成下列化合物（4）解离化合物（4）以形成化合物（5）或化合物（5）和化合物（6）。 HO-2-QO-（CH2）3-OH（1），<？in-line-formula description =“In-line formula”end =“lead” “end =”tail“？> <？in-line-formula description =”In-line formula“end =”lead“？> CRBCOX（2），<？in-line-formula description =”In-line Formulas“ end =“tail”？> <？in-line-formula description =“In-line formula”end =“lead”？> RBCOOCH2-QO-（CH2）3-OCORB（3），<？in-line-formula 描述=“在线公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> RBFCOOCF2-QF-O-（CF2）3-OCORBF 4），<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> FCO-QF -O-（CF2）2-COF（5），<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas” end =“lead”？> RBFCOF（6）。<？in-line-formula description =“In-line Formulas”end =“tail”？>

9. 发明授权

US07488847B2 Fluorinated adamantane and its derivatives 有权
公开(公告)号：US07488847B2
公开(公告)日：2009-02-10
申请号：US11153438
申请日：2005-06-16
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
IPC分类号： C07C63/00
CPC分类号： C07C51/60 , C07C67/14 , C07C67/287 , C07C67/307 , C07C2603/74 , C07C55/40 , C07C53/50 , C07C69/54 , C07C69/63 , C07C69/708 , C07C69/753 , C07C69/734
摘要： The present invention provides a process A1 for producing a compound (5A), which comprises fluorinating a compound (3A-1) by liquid phase fluorination to a compound (4A-1), followed by a decomposition reaction of an ester bond; a process A2 for producing a compound (5A), which comprises fluorinating a compound (3A-2) by liquid phase fluorination to a compound (4A-2), followed by a decomposition reaction of an ester bond; and a process B for producing a compound (5B), which comprises fluorinating a compound (3B) by liquid phase fluorination to a compound (4B), followed by hydrolysis or alcoholysis. Further, the present invention provides a compound (5A) wherein n is 2 to 4, and a compound (5B) wherein n is 3 or 4. A(—CH2—OCO—R)n (3A-1) Af(—CF2—OCO—Rf)n (4A-1) A(—COOR)n (3A-2) Af(—COORf)n (4A-2) Af(—COF)n (5A) A(—OCO—R)n (3B) Af(—OCO—Rf)n (4B) Af(—OH)n (5B) provided that the carbon atom in adamantane to which —OCO—Rf is bonded, is a tertiary carbon atom, A is a n-valent group having n hydrogen atoms in adamantane converted to connecting bonds, R is a fluorinated monovalent organic group, n is an integer of from 1 to 4, Af is a group having at least one of hydrogen atoms in the group A substituted by a fluorine atom, and Rf is a fluorinated monovalent organic group.

10. 发明申请

US20080132736A1 FLUOROADAMANTANE DERIVATIVE 失效
标题翻译：荧光素衍生物
公开(公告)号：US20080132736A1
公开(公告)日：2008-06-05
申请号：US12020863
申请日：2008-01-28
申请人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
发明人： Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi , Takashi Okazoe , Eisuke Murotani , Masahiro Ito , Kunio Watanabe
IPC分类号： C07C35/22
CPC分类号： C07C69/653 , C07C29/095 , C07C35/52 , C07C67/14 , C07C67/287 , C07C2603/74 , C07C69/708
摘要： Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials.A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are —CFH— or —CF2—; RF is a perfluoroalkyl group or the like; X10 is F or the like; Y2 is H or OH; Y3 is H or RFCOO—; Y4 is H, F or RFCOO—; Y5 is H, F, RFCOO— or OH; Y0 is H, F, —OCOCR1═CH2 or OH: R1 is a hydrogen atom, a methyl group or the like; and X11 is OH or a halogen atom:
摘要翻译：金刚烷衍生物可以通过从容易获得的材料的经济上有利的方法产生耐蚀性优异且具有改善的具有短波长的光的透射率的聚合物的材料化合物。化合物（10）与化合物（11）进行酯化反应，得到化合物（12），将其进行液相氟化，得到化合物（13），然后进行水解或醇解得到化合物（2），然后与化合物（15）反应，得到化合物（1）。这里，A至J为-CFH-或-CF 2 - R F是全氟烷基等; X 10是F等; Y 2是H或OH; Y 3是H或R 0 COO-; Y 4是H，F或R“COO-; H 5是H，F，R F CO或O-; Y 0是H，F，-OCOCR 1 -CH 2或OH：R 1是氢原子，甲基等; 并且X 11是OH或卤素原子：

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