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111. 发明授权

US5077412A Substituted thioureas, isothioureas and carbodiimides 失效
标题翻译：取代的硫酸盐，同位素和碳水化合物
公开(公告)号：US5077412A
公开(公告)日：1991-12-31
申请号：US414998
申请日：1989-09-29
申请人： Josef Ehrenfreund , Manfred Boger , Odd Kristiansen , Jozef Drabek , Haukur Kristinsson
发明人： Josef Ehrenfreund , Manfred Boger , Odd Kristiansen , Jozef Drabek , Haukur Kristinsson
IPC分类号： A01N47/30 , A01N47/32 , A01N47/40 , A01N47/42 , C07D207/34 , C07D209/32 , C07D231/20 , C07D233/70 , C07D235/26 , C07D249/12 , C07D257/04 , C07D263/38 , C07D263/58 , C07D271/10 , C07D271/113 , C07D277/20 , C07D277/34 , C07D277/68 , C07D285/08 , C07D285/12 , C07D285/13 , C07D307/58 , C07D333/32 , C07D333/34
CPC分类号： C07D271/113 , A01N47/30 , A01N47/32 , A01N47/40 , A01N47/42 , C07D233/70 , C07D249/12 , C07D277/34 , C07D277/68 , C07D285/08 , C07D285/13
摘要： The invention relates to novel substituted phenylthioureas, phenylisothioureas and phenylcarbodiimides of formula I ##STR1## wherein Z is ##STR2## or --N.dbd.C.dbd.N--; R.sub.1 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.10 alkenyl, C.sub.3 -C.sub.10 alkynyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.3 alkyl substituted by 1 or 2 C.sub.3 -C.sub.6 cycloalkyl radicals, or is alkoxyalkyl containing a total of 3 to 10 carbon atoms, halogen-substituted C.sub.1 -C.sub.12 alkyl, polycyclic C.sub.7 -C.sub.10 cycloalkyl, or phenyl(C.sub.1 -C.sub.5)alkyl which may be substituted in the phenyl moiety by 1 or 2 identical or different members selected from the group consisting of halogen, methoxy, ethoxy and C.sub.1 -C.sub.5 alkyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.3 is C.sub.1 -C.sub.5 alkyl or C.sub.3 -C.sub.6 cycloalkyl,R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sub.5 is a 5-membered heterocyclic radical containing 1 to 4 hetero atoms selected from the group consisting of N, O and S, which radical may be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8, or is a 5-membered heterocyclic radical which may be fused with benzene nuclei and which contains 1 or 2 hetero atoms selected from the group consisting of N, O and S and can be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8,R.sub.6 and R.sub.7 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, halogen-substituted C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy; halogen-substituted C.sub.1 -C.sub.4 alkoxy, phenyl, or C.sub.1 -C.sub.4 alkylthio,R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl, andR.sub.9 is C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.3 -C.sub.4 alkynyl, alkoxyalkyl containing a total of 10 carbon atoms, or alkylthioalkyl containing a total of 10 carbon atomsand to the salts thereof with acids and bases. The invention further relates to the preparation of these compounds and to the use thereof in pest control, and to novel intermediates.

112. 发明授权

US5026730A Anilinophenylthioureas, compositions containing them, and the use thereof in pest control 失效
标题翻译：苯胺基苯硫脲，含有它们的组合物及其在害虫防治中的用途
公开(公告)号：US5026730A
公开(公告)日：1991-06-25
申请号：US230814
申请日：1988-08-11
申请人： Manfred Boger , Jozef Drabek , Josef Ehrenfreund
发明人： Manfred Boger , Jozef Drabek , Josef Ehrenfreund
IPC分类号： A01N47/30 , A01N47/32 , A01N47/40 , A01N47/42 , C07C67/00 , C07C241/00 , C07C267/00 , C07C325/00 , C07C335/20 , C07C335/32 , C07C335/36
CPC分类号： A01N47/42 , A01N47/30 , A01N47/32 , A01N47/40 , C07C335/20 , C07C335/36 , C07C2101/08 , C07C2101/14
摘要： The invention relates to novel substituted anilinophenylthioureas, anilinophenylisothioureas and anilinophenylcarbodiimides of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.12 alkyl, unsubstituted or substituted by one or more halogen atoms and/or C.sub.1 -C.sub.6 alkoxy groups; C.sub.3 -C.sub.8 cycloalkyl, unsubstituted or substituted by one or more C.sub.1 -C.sub.3 alkyl groups; or C.sub.3 -C.sub.8 cycloalkyl-C.sub.1 -C.sub.4 alkyl,R.sub.2 and R.sub.3 are each C.sub.1 -C.sub.5 alkyl or C.sub.5 -C.sub.6 cycloalkyl,R.sub.4 is hydrogen, methyl or --CHO,R.sub.5 is halogen; C.sub.1 -C.sub.4 alkyl, unsubstituted or substituted by one or more halogen atoms; C.sub.1 -C.sub.4 alkoxy, unsubstituted or substituted by one or more halogen atoms; or is a --CH.dbd.CH--.sub.2, --CH.sub.2--3 or --CH.sub.2--4 bridge in 2,3- or 3,4-position,n is 0, 1, 2, 3 or 4,Z is --NH--CS--NH--, --N.dbd.C(SR.sub.6)--NH-- or --N.dbd.C.dbd.N--; andR.sub.6 is C.sub.1 -C.sub.6 alkyl or allyl,to salts thereof with organic or inorganic acids, to the preparation of these compounds and to intermediates for their synthesis. The invention further relates to the use of the novel compound in pest control and to pesticidal compositions which contain at least one compound of formula I as active component. The preferred utility is the control of pests of animals and plants.
摘要翻译：本发明涉及式I的新型取代的苯胺基苯硫脲，苯胺基异硫脲和苯胺基碳化二亚胺其中R1是未被取代或被一个或多个卤素原子和/或C 1 -C 6烷氧基取代的C 1 -C 12烷基; 未被取代或被一个或多个C 1 -C 3烷基取代的C 3 -C 8环烷基; 或C 3 -C 8环烷基-C 1 -C 4烷基，R 2和R 3各自为C 1 -C 5烷基或C 5 -C 6环烷基，R 4为氢，甲基或-CHO，R 5为卤素; 未被取代或被一个或多个卤素原子取代的C 1 -C 4烷基; 未被取代或被一个或多个卤素原子取代的C 1 -C 4烷氧基; 或在2,3-或3,4-位是-CH = CH-2，-CH2-3或-CH2-4桥，n为0,1,2,3或4，Z为-NH-CS -NH-，-N = C（SR 6）-NH-或-N = C = N-; 并且R 6是C 1 -C 6烷基或烯丙基，与其与有机或无机酸的盐相关，用于制备这些化合物及其合成中间体。本发明还涉及新型化合物在害虫防治中的用途以及含有至少一种式I化合物作为活性成分的农药组合物。优选的效用是控制动物和植物的害虫。

113. 发明授权

US5004826A Substituted propane-phosphonous acid compounds 失效
标题翻译：取代的丙烷 - 膦酸化合物
公开(公告)号：US5004826A
公开(公告)日：1991-04-02
申请号：US444466
申请日：1989-12-01
申请人： John G. Dingwall , Josef Ehrenfreund , Roger G. Hall , James Jack
发明人： John G. Dingwall , Josef Ehrenfreund , Roger G. Hall , James Jack
IPC分类号： C07F9/38 , A61K31/66 , A61P21/00 , A61P25/04 , A61P25/24 , A61P25/26 , A61P25/28 , C07F9/32 , C07F9/40 , C07F9/48
CPC分类号： C07F9/48 , C07F9/3211 , C07F9/4816
摘要： The compounds of the formula ##STR1## in which one of the groups R.sup.1, R.sup.2 and R.sup.3 represents hydrogen, C.sub.1-8 -alkyl, C.sub.3-6 -cycloalkyl, phenyl optionally substituted by halogeno, C.sub. 1-4 -alkyl, C.sub. -4 -alkoxy and/or trifluoromethyl, or C.sub.7-10 -phenylalkyl optionally substituted in the phenyl moiety by halogeno, C.sub.1-4 -alkyl C.sub.1-4 -alkoxy and/or trifluormethyl, and the other two are hydrogen, or salts thereof.These compounds have valuable pharmaceutical properties.

114. 发明授权

US4897424A Aryloxyphenylthioureas, aryloxyphenylisothioureas and aryloxyphenylcarbodiimides and pesticidal compositions containing them 失效
标题翻译：丙烯酰氧基苯硫脲，芳氧基苯硫基脲和芳氧基苯基碳二亚胺和含有它们的杀虫组合物
公开(公告)号：US4897424A
公开(公告)日：1990-01-30
申请号：US205260
申请日：1988-06-09
申请人： Manfred Boger , Jozef Drabek , Josef Ehrenfreund
发明人： Manfred Boger , Jozef Drabek , Josef Ehrenfreund
IPC分类号： A01N47/30 , A01N47/32 , A01N47/40 , A01N47/42 , C07C67/00 , C07C213/00 , C07C217/90 , C07C241/00 , C07C267/00 , C07C325/00 , C07C331/28 , C07C335/18 , C07C335/32 , C07C335/36
CPC分类号： C07C335/36 , A01N47/30 , A01N47/32 , A01N47/40 , A01N47/42 , C07C331/28 , C07C335/18 , C07C2101/08 , C07C2102/04
摘要： Novel substituted aryloxyphenyl-thioureas, -isothioureas and -carbodiimides of formula I ##STR1## in which R.sub.1 represents C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkyl mono- or poly-substituted by halogen and/or by C.sub.1 -C.sub.6 alkoxy, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.8 cycloalkyl mono- or poly-substituted by C.sub.1 -C.sub.3 alkyl, or C.sub.3 -C.sub.8 cycloalkyl-C.sub.1 -C.sub.4 alkyl;R.sub.2 represents hydroben or C.sub.1 -C.sub.5 alkyl;R.sub.3 represents a C.sub.1 -C.sub.5 alkyl or C.sub.5 -C.sub.6 cycloalkyl;R.sub.4 represents hydrogen or methyl;R.sub.5 represents a --CH.dbd.CH--.sub.2, --CH.sub.2 --.sub.3 or --CH.sub.2 --.sub.4 bridge in the 2,3- or 3,4-position;Z represents --NH--CS--NH--, --N.dbd.C(SR.sub.6)--NH-- or --N.dbd.C.dbd.N-- andR.sub.6 represents C.sub.1 -C.sub.10 alkyl or allyl,and the salts thereof with organic or inorganic acids, processes and intermediates for their preparation, their use in the control of pests, and pesticidal compositions that contain at least one compound of formula I as active ingredient are disclosed. The preferred field of use is the control of pests in and on animals and plants.
摘要翻译：式I的新型取代的芳氧基苯基硫脲， - 异硫脲和碳二亚胺其中R1代表C1-C12烷基，被卤素单取代或多取代的C1-C12烷基和/或被C1-C6烷氧基，C3-C8环烷基 C 1 -C 3烷基或C 3 -C 8环烷基-C 1 -C 4烷基单或多取代的C 3 -C 8环烷基; R 2表示氢或C 1 -C 5烷基; R3表示C1-C5烷基或C5-C6环烷基; R4代表氢或甲基; R5表示2,3或3,4位的-CH = CH-2，-CH2-3或-CH2-4桥; Z表示-NH-CS-NH-，-N = C（SR6）-NH-或-N = C = N-，R6表示C1-C10烷基或烯丙基，其与有机酸或无机酸的盐，方法和中间体公开了其用于控制害虫的用途，以及含有至少一种式I化合物作为活性成分的杀虫组合物。优选的使用领域是控制动物和植物中的有害生物。

115. 发明授权

US4859783A 2,2-Difluoro-4-amino-1,3-benzodioxole 失效
标题翻译： 2,2-二氟-4-氨基-1,3-苯并间二氧杂环戊烯
公开(公告)号：US4859783A
公开(公告)日：1989-08-22
申请号：US106303
申请日：1987-10-09
申请人： Josef Ehrenfreund
发明人： Josef Ehrenfreund
IPC分类号： A01N43/30 , C07D317/46
CPC分类号： A01N43/30 , C07D317/46
摘要： 2,2-Difluoro-4-amino-1,3-benzodioxole is useful as an intermediate for the synthesis of 2,2-difluoro-4-(2',4'-dinitro-6'-trifluoromethylanilino)-1,3-benzodioxole of the formula ##STR1## which is suitable as a pesticide. In combination with carriers and further adjuvants, said compound can be employed for controlling pests, in particular phytopathogenic fungi or bacteria, and also insects and acarids.
摘要翻译： 2,2-二氟-4-氨基-1,3-苯并间二氧杂环戊烯可用作合成2,2-二氟-4-（2'，4'-二硝基-6'-三氟甲基苯胺基）-1,3 - 苯并二氧杂环戊烯，其适合作为农药。与载体和进一步的佐剂组合，所述化合物可用于防治害虫，特别是植物病原真菌或细菌，以及昆虫和螨虫。

116. 发明授权

US4780551A Microbicidal compositions 失效
标题翻译：杀菌组合物
公开(公告)号：US4780551A
公开(公告)日：1988-10-25
申请号：US79985
申请日：1987-07-31
申请人： Robert Nyfeler , Josef Ehrenfreund
发明人： Robert Nyfeler , Josef Ehrenfreund
IPC分类号： A01N43/28 , A01N43/36 , A01P3/00 , B01J27/122 , C07B61/00 , C07D20060101 , C07D207/325 , C07D207/34 , C07D317/00 , C07D317/46 , C07D317/60 , C07D405/04 , C07D405/10 , C07D405/14 , C07D407/04 , C07D407/14
CPC分类号： C07D317/60 , C07D405/04 , C07D405/14
摘要： The invention relates to novel 3-phenyl-4-cyanopyrrole derivatives of the general formula ##STR1## wherein X has the following meanings: A: hydrogen or CO--R.sub.1, wherein R.sub.1 is C.sub.1 -C.sub.6 alkyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy; or is C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 alkynyl, or C.sub.1 -C.sub.6 alkoxy which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy; or is C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 cycloalkyl or tetrahydrofur-2-yl;B: S--R.sub.2, wherein R.sub.2 is C.sub.1 -C.sub.3 haloalkyl;C: CH(Y)R.sub.3, wherein R.sub.3 is hydrogen or C.sub.1 -C.sub.8 haloalkyl and Y is hydroxy, halogen or OC(O)R.sub.4, wherein R.sub.4 is C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 -haloalkyl, C.sub.2 -C.sub.6 alkenyl, tetrahydrofur-2-yl, tetrahydropyran-2-yl or C.sub.1 -C.sub.6 alkoxycarbonyl;D: CH.sub.2 --Z, wherein Z is one of the groups ##STR2## in which formula each of R.sub.5 and R.sub.6 independently of the other is hydrogen, C.sub.1 -C.sub.6 alkyl which is unsubstituted or substituted by cyano or C.sub.1 -C.sub.6 alkoxycarbonyl; or is C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, or phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl and/or C.sub.1 -6alkoxy, with the proviso that only R.sub.5 or R.sub.6 may be hydrogen; each of R.sub.7 and R.sub.8 independently of the other is hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl, or both together form a fused aromatic ring; each of R.sub.9 and R.sub.10 independently of the other is hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and X is oxygen, sulfur, ##STR3## wherein R.sub.11 is hydrogen, C.sub.1 -C.sub.6 alkyl, formyl, C.sub.1 -C.sub.6 alkanoyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and n is O or 1.The novel compounds are used for controlling harmful micoorganisms, in particular phytopathogenic fungi. They can be employed together with suitable formulation adjuvants as compositions and are also suitable for protecting cultivated plants from attack by harmful microorganisms.
摘要翻译：本发明涉及通式为“IMAGE”的新型3-苯基-4-氰基吡咯衍生物，其中X具有以下含义：A：氢或CO-R 1，其中R 1为未被取代或被卤素或C 1取代的C 1 -C 6烷基 -C3烷氧基; 或是未被取代或被卤素或C 1 -C 3烷氧基取代的C 3 -C 6 - 烯基，C 3 -C 6炔基或C 1 -C 6烷氧基; 或者是C 3 -C 6烯氧基，C 3 -C 6环烷基或四氢呋喃-2-基; B：S-R2，其中R2是C1-C3卤代烷基; C：CH（Y）R 3，其中R 3是氢或C 1 -C 8卤代烷基，Y是羟基，卤素或OC（O）R 4，其中R 4是C 1 -C 8烷基，C 1 -C 8卤代烷基，C 2 -C 6烯基，四氢吡喃-2-基或C 1 -C 6烷氧基羰基; D：CH 2 -Z，其中Z是基团，其中R 5和R 6各自独立地是氢，C 1 -C 6烷基，未被取代或被氰基或C1-C6烷氧基羰基取代的C6烷基; 或者是未被取代或被卤素，C 1 -C 6烷基，C 1 -C 6卤代烷基和/或C 1-6烷氧基取代的C 3 -C 6烯基，C 3 -C 6炔基，C 3 -C 7环烷基或苯基，条件是仅R5或R6可以是氢; R 7和R 8各自独立地为氢，C 1 -C 6烷基或C 1 -C 6烷氧基羰基，或两者一起形成稠合芳环; R 9和R 10各自独立地是氢，C 1 -C 6烷基或C 1 -C 6烷氧基羰基; 并且X是氧，硫，其中R 11是氢，C 1 -C 6烷基，甲酰基，C 1 -C 6烷酰基或C 1 -C 6烷氧基羰基; 并且n为O或1.新化合物用于控制有害微生物，特别是植物病原真菌。它们可以与合适的制剂佐剂一起用作组合物，并且也适用于保护栽培植物免受有害微生物侵袭。

117. 发明授权

US4677212A Intermediate 1,2-benzoxathiin derivatives 失效
标题翻译：中间体1,2-苯并恶嗪衍生物
公开(公告)号：US4677212A
公开(公告)日：1987-06-30
申请号：US658003
申请日：1984-10-04
申请人： Josef Ehrenfreund , Werner Fory , Willy Meyer , Werner Topfl
发明人： Josef Ehrenfreund , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： A01N47/36 , C07D209/08 , C07D215/00 , C07D215/36 , C07D239/00 , C07D251/00 , C07D307/00 , C07D307/79 , C07D307/82 , C07D307/83 , C07D307/88 , C07D311/00 , C07D311/18 , C07D311/20 , C07D311/22 , C07D311/58 , C07D311/70 , C07D311/76 , C07D317/00 , C07D317/46 , C07D317/62 , C07D319/00 , C07D319/18 , C07D327/00 , C07D327/04 , C07D327/06 , C07D333/00 , C07D333/54 , C07D333/62 , C07D335/00 , C07D335/06 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D411/12 , C07D417/12 , C07D521/00
CPC分类号： C07D307/79 , A01N47/36 , C07D209/08 , C07D215/36 , C07D307/83 , C07D307/88 , C07D311/18 , C07D311/22 , C07D311/58 , C07D311/70 , C07D311/76 , C07D317/46 , C07D317/62 , C07D319/18 , C07D327/06 , C07D333/54 , C07D335/06 , C07D521/00
摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein Q is selected from a radical ##STR2## Z is oxygen or sulfur, E is nitrogen or .dbd.CH--,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.3 alkoxy, andR.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.2 -C.sub.5 alkoxyalkoxy or --NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 are hydrogen or C.sub.1 -C.sub.4 alkyl,and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
摘要翻译：本发明涉及通式为（I）的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N-三嗪基脲，其中Q选自基团Z是氧或硫，E是氮或= CH-，R 2是氢，C 1 -C 4烷基或C 1 -C 3烷氧基，R 3和R 4各自独立地是氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4 卤代烷氧基，C 1 -C 4卤代烷硫基，C 1 -C 4烷硫基，卤素，C 2 -C 5烷氧基烷基，C 2 -C 5烷氧基烷氧基或-NR 5 R 6，其中R 5和R 6是氢或C 1 -C 4烷基，以及这些化合物与胺，碱金属碱或碱土金属碱或季铵碱。这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。

118. 发明授权

US4511571A N-(2-Pyridyloxyphenyl)-N'-benzoyl ureas, pesticidal compositions containing same and pesticidal methods of use 失效
标题翻译： N-（2-吡啶氧基苯基）-N'-苯甲酰脲，含有相同的杀虫组合物和杀虫剂的使用方法
公开(公告)号：US4511571A
公开(公告)日：1985-04-16
申请号：US433763
申请日：1982-10-12
申请人： Manfred Boger , Josef Ehrenfreund , Pierre Martin , Eginhard Steiner
发明人： Manfred Boger , Josef Ehrenfreund , Pierre Martin , Eginhard Steiner
IPC分类号： A01N47/34 , C07D213/64 , C07D213/643 , A01N43/40
CPC分类号： C07D213/643 , A01N47/34
摘要： Novel substituted N-(2-pyridyloxyphenyl)-N'-benzoylureas of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are each hydrogen, methyl or halogen,R.sub.5 is the radical --CHF.sub.2, or a C.sub.2 -C.sub.10 -alkyl group which is uniformly or nonuniformly substituted by 1 to 21 halogen atoms, andR.sub.6 is halogen,processes and starting products for producing these compounds, as well as compositions containing these, for use in combating pests, particularly for combating insects which infest plants and animals. The novel compounds have a specially high ovolarvicidal and ovicidal action against insects that damage plants.
摘要翻译：式（Ia）的新型取代的N-（2-吡啶氧基苯基）-N'-苯甲酰脲其中R 1，R 2，R 3和R 4彼此独立地为氢，甲基或卤素，R 5为基团-CHF 2或C 2 -C 1 -C 10烷基，其被1至21个卤素原子均匀或不均匀地取代，并且R 6是卤素，用于制备这些化合物的方法和起始产物，以及含有这些化合物的组合物，用于防治害虫，特别是用于防治害虫感染植物和动物。这些新型化合物对于损害植物的昆虫具有特别高的抗紫外线和杀卵作用。

119. 发明授权

US4505931A Pesticidal N-(4-alkenylthio)-phenyl-N'-benzoylureas 失效
标题翻译：杀虫N-（4-链烯硫基） - 苯基-N'-苯甲酰脲
公开(公告)号：US4505931A
公开(公告)日：1985-03-19
申请号：US114934
申请日：1980-01-24
申请人： Josef Ehrenfreund
发明人： Josef Ehrenfreund
IPC分类号： A01N47/34 , C07C323/44 , A01N47/28 , C07C127/22
CPC分类号： C07C323/44 , A01N47/34
摘要： Novel N-(4-alkenylthio)-phenyl-N'-benzoylureas of the formula ##STR1## wherein R.sub.1 is a C.sub.3 -alkenyl group, or a C.sub.3 -alkenyl group which is mono- or disubstituted with chlorine or bromine, R.sub.2 and R.sub.3 independently of one another are each hydrogen or chlorine, R.sub.4 is hydrogen, fluorine or chlorine, and R.sub.5 is fluorine or chlorine; processes for producing these compounds, and also compositions containing the compounds, for use in combating pests, particularly in combating insect pests in the field of plant protection, and combating ectoparasites. The compounds have high ovicidal activity.
摘要翻译：式（Ia）的N-（4-链烯基硫代） - 苯基-N'-苯甲酰基脲，其中R 1是C 3链烯基或被氯或溴单或二取代的C 3 - 烯基，R 2和R 3 各自独立地为氢或氯，R4为氢，氟或氯，R5为氟或氯; 用于生产这些化合物的方法，以及含有化合物的组合物，用于防治害虫，特别是防治植物保护领域的害虫，以及对付外寄生虫。该化合物具有高的杀卵活性。

120. 发明授权

US4418066A Phenylbenzoylureas 失效
标题翻译：苯基苯甲酰脲
公开(公告)号：US4418066A
公开(公告)日：1983-11-29
申请号：US263320
申请日：1981-05-13
申请人： Manfred Boger , Josef Ehrenfreund
发明人： Manfred Boger , Josef Ehrenfreund
IPC分类号： A01N43/40 , A01N47/34 , C07D213/64 , C07D213/643
CPC分类号： C07D213/643 , A01N47/34
摘要： Novel substituted N-3-(3-chloro-5-trifluoromethyl-2-pyridyloxy)-phenyl-N'-benzoylureas of the formula ##STR1## wherein R.sub.1 is fluorine, chlorine, bromine or methyl, andR.sub.2 is hydrogen, fluorine, chlorine or bromine, processes for producing these compounds and compositions containing them for use in combating pests, particularly in combating insects which infest plants and animals. The novel compounds are especially effective against larval stages of insects which damage plants by eating.
摘要翻译：新颖的式（I）所示的取代的N-3-（3-氯-5-三氟甲基-2-吡啶氧基） - 苯基-N'-苯甲酰基，其中R1是氟，氯，溴或甲基，R2是氢，氟，氯或溴，用于生产这些化合物的方法和含有它们的组合物用于防治害虫，特别是防治侵染植物和动物的昆虫。这些新颖的化合物对于通过进食损害植物的昆虫的幼虫阶段是特别有效的。

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