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101. 发明授权

US5656748A Process for the preparation of ivermectin 失效
标题翻译：伊维菌素制备方法
公开(公告)号：US5656748A
公开(公告)日：1997-08-12
申请号：US606787
申请日：1996-02-27
申请人： Dieter Arlt , Gerhard Bonse , Friedhelm Reisewitz
发明人： Dieter Arlt , Gerhard Bonse , Friedhelm Reisewitz
IPC分类号： C07H17/08 , A01N43/90 , A61K31/365 , A61K31/70 , A61K31/7042 , A61K31/7048 , A61P33/10 , B01J31/24 , C07B61/00 , C07D493/22 , C07H19/01 , C07H1/00 , C07D311/00 , C07D493/00
CPC分类号： C07H19/01
摘要： The invention relates to a process for the selective hydrogenation of avermectins with the aid of a rhodium-phosphine complex based on a hydrazine.
摘要翻译：本发明涉及一种借助于基于肼的铑 - 膦配合物选择性氢化除虫菌素的方法。

102. 发明授权

US5196441A Compounds useful as antimicrobial agents 失效
标题翻译：化合物作为抗微生物剂有用
公开(公告)号：US5196441A
公开(公告)日：1993-03-23
申请号：US777832
申请日：1991-10-10
申请人： Franz Kunisch , Peter Babczinski , Dieter Arlt , Wilhelm Brandes , Heinz-Wilhelm Dehne , Stefan Dutzmann , Manfred Plempel
发明人： Franz Kunisch , Peter Babczinski , Dieter Arlt , Wilhelm Brandes , Heinz-Wilhelm Dehne , Stefan Dutzmann , Manfred Plempel
IPC分类号： C07D275/06 , A01N37/44 , A01N37/46 , A01N43/38 , A01N43/40 , A01N43/80 , B01J23/46 , C07B61/00 , C07C219/24 , C07C227/16 , C07C229/48 , C07C233/52 , C07C237/04 , C07C237/24 , C07C269/06 , C07C271/24 , C07C323/53 , C07C323/62 , C07C327/24 , C07C327/32 , C07D213/30 , C07F9/165 , C07F9/40
CPC分类号： C07D213/30 , A01N37/44 , A01N37/46 , A01N43/40 , C07C229/48 , C07C233/52 , C07C237/04 , C07C237/24 , C07C271/24 , C07C327/24 , C07C327/32 , C07F9/4021 , C07C2101/08 , Y02P20/55
摘要： There are described new 2-cyclohexan-1-yl-amine derivatives of formula (I) ##STR1## in which A, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the meaning given in the description, and processes for their preparation.The compounds of the formula (I) are used as antimicrobial agents.
摘要翻译：描述了式（I）的新的2-环己烷-1-基 - 胺衍生物其中A，R1，R2，R3和R4具有说明书中给出的含义及其制备方法。式（I）的化合物用作抗微生物剂。

103. 发明授权

US5185454A Process for the preparation of symmetrical diarylacetylenes 失效
标题翻译：制备对称二氨基乙烯的方法
公开(公告)号：US5185454A
公开(公告)日：1993-02-09
申请号：US594265
申请日：1990-10-02
申请人： Axel Bader , Dieter Arlt
发明人： Axel Bader , Dieter Arlt
IPC分类号： B01J23/44 , B01J31/28 , C07B37/04 , C07B61/00 , C07C2/86 , C07C15/54 , C07C45/68 , C07C49/782 , C07C49/796 , C07C49/813 , C07C67/343 , C07C69/76 , C07C69/78 , C07C253/30 , C07C255/50 , C07C315/04 , C07C317/14
CPC分类号： C07C69/78 , C07C317/14 , C07C49/796 , C07C49/813 , C07C67/343 , C07C69/76
摘要： Symmetrical diaryl-acetylenes can be prepared by reacting an aryl halide with acetylene in the presence of a palladium catalyst and a base. If the acetylene is introduced into the liquid reaction mixture using a high intensity gas dispersion means, the aryl halide used can be an aryl bromide.
摘要翻译：对称二芳基 - 乙炔可以通过芳基卤化物与乙炔在钯催化剂和碱的存在下反应来制备。如果使用高强度气体分散装置将乙炔引入液体反应混合物中，则所用的芳基卤可以是芳基溴。

104. 发明授权

US5136114A Process for the preparation of geminal diarylalkanes, new geminal diarylalkanes and alk(en)ylated aromatic compounds 失效
标题翻译：制备二氯化钛的新工艺，新型二烯丙基二胺和碱金属化合物（EN）
公开(公告)号：US5136114A
公开(公告)日：1992-08-04
申请号：US516629
申请日：1990-04-30
申请人： Dieter Arlt
发明人： Dieter Arlt
IPC分类号： B01J27/125 , B01J31/08 , C07B61/00 , C07C2/86 , C07C15/16 , C07C17/26 , C07C22/04 , C07C25/24 , C07C41/30 , C07C43/263 , C07C43/29
CPC分类号： C07C2/861 , C07C15/16 , C07C17/00 , C07C17/266 , C07C17/269 , C07C17/361 , C07C41/30
摘要： The invention relates to a new process for the preparation of geminal diarylalkanes of the formula ##STR1## by Friedel-Crafts alkylation of aromatic compounds with specific aliphatic halogen compounds (addition compounds of CCl.sub.4 , to .alpha.-olefins), to new geminal diarylalkanes and the aralkyl compounds resulting as intermediates.
摘要翻译：本发明涉及一种通过将芳族化合物与特定的脂族卤素化合物（CCl4的加成化合物，与α-烯烃）的芳烃化合物烷基化成新颖的孪晶的方法制备式（ⅰ）的偕二芳基烷烃的新方法二芳基烷烃和作为中间体产生的芳烷基化合物。

105. 发明授权

US4914159A Optically active (meth)acrylamides, a process for their preparation, and their use for racemate resolution 失效
标题翻译：光学活性（甲基）丙烯酰胺，其制备方法及其用于消旋物分解的用途
公开(公告)号：US4914159A
公开(公告)日：1990-04-03
申请号：US162529
申请日：1988-03-01
申请人： Bruno Bomer , Rolf Grosser , Ulrich Schwartz , Dieter Arlt , Karl-Erwin Piejko
发明人： Bruno Bomer , Rolf Grosser , Ulrich Schwartz , Dieter Arlt , Karl-Erwin Piejko
IPC分类号： B01J20/291 , B01J20/281 , B01J20/32 , C08F2/44 , C08F20/52 , C08F20/54 , C08F20/56 , C08L33/24 , C08L33/26 , G01N30/88
CPC分类号： B01J20/29 , B01J20/286 , B01J20/3204 , B01J20/3217 , B01J20/327 , B01J20/3276 , B01J20/3278 , C08F20/54 , B01J2220/54
摘要： The invention relates to optically active homo- and copolymers made from optically active (meth)acrylamides, the polymers being immobilized on silica gel, a process for their preparation, and their use as adsorbents, in particular as the stationary phase for chromatographic racemate resolution.
摘要翻译：本发明涉及由光学活性（甲基）丙烯酰胺制成的光学活性均聚物和共聚物，该聚合物固定在硅胶上，其制备方法及其作为吸附剂的用途，特别是作为色谱外消旋体拆分的固定相。

106. 发明授权

US4748242A Tertiary polyisocyanate derivatives 失效
标题翻译：三元多异氰酸酯衍生物
公开(公告)号：US4748242A
公开(公告)日：1988-05-31
申请号：US930584
申请日：1986-11-12
申请人： Reinhard Halpaap , Josef Pedain , Hans-Joachim Kreuder , Gerhard Klein , Dieter Arlt
发明人： Reinhard Halpaap , Josef Pedain , Hans-Joachim Kreuder , Gerhard Klein , Dieter Arlt
IPC分类号： C08G18/00 , C08G18/02 , C08G18/06 , C08G18/79 , C08G63/52 , C07D251/30 , C07D251/32
CPC分类号： C08G18/792 , C08G2150/20
摘要： The present invention is directed to a process for the production of polyisocyanates containing isocyanurate groups by trimerizing a mixture of aliphatic-cycloaliphatic diisocyanates having a sterically unhindered isocyanate group bound to a primary aliphatic carbon atom and a sterically hindered isocyanate group bound to a tertiary carbon atom which forms a part of a cycloaliphatic ring system and 1,6-diisocyanatohexane. The present invention is also directed to the polyisocyanates containing isocyanurate groups produced according to this process and to their use, optionally in blocked form, as an isocyanate component in the production of polyisocyanate polyaddition products, preferably polyurethane lacquers.
摘要翻译：本发明涉及一种制备含有异氰脲酸酯基团的多异氰酸酯的方法，该方法是将具有与伯脂肪族碳原子结合的空间上不受阻碍的异氰酸酯基团和与叔碳原子结合的位阻异氰酸酯基团的脂族 - 脂环族二异氰酸酯的混合物三聚其形成脂环族环系的一部分和1,6-二异氰酸根合己烷。本发明还涉及根据该方法制备的含有异氰脲酸酯基团的多异氰酸酯基团，以及它们在多异氰酸酯加聚产物（优选聚氨酯漆）生产中作为异氰酸酯组分的用途，任选地以封闭形式使用。

107. 发明授权

US4628118A 5,5-dichloro-3,3-dimethylpentanoic acid 失效
标题翻译： 5,5-二氯-3,3-二甲基戊酸
公开(公告)号：US4628118A
公开(公告)日：1986-12-09
申请号：US786251
申请日：1985-10-10
申请人： Dieter Arlt
发明人： Dieter Arlt
IPC分类号： C07C51/00 , C07C51/093 , C07C51/373 , C07C53/19 , C07C59/147 , C07C59/74 , C07C67/00 , C07D309/30 , C07D309/32
CPC分类号： C07D309/32 , C07C51/093 , C07C51/373 , C07C53/19 , C07C59/74 , C07D309/30
摘要： The following process steps are shown: ##STR1## Intermediates I, II and IV are new. End product III is known, useful as an intermediate in the manufacture of pesticides, pharmaceuticals and dyestuffs.
摘要翻译：显示以下过程步骤： + TR 中间体I，II和IV是新的。终产物III是已知的，可用作制造农药，药物和染料的中间体。

108. 发明授权

US4628112A Amines, processes for their preparation and their use in compositions which can undergo free radical polymerization 失效
标题翻译：胺，它们的制备方法及其在可以进行自由基聚合的组合物中的用途
公开(公告)号：US4628112A
公开(公告)日：1986-12-09
申请号：US675689
申请日：1984-11-28
申请人： Jens Winkel , Gerhard Klein , Helmut-Martin Meier , Carlhans Suling , Dieter Arlt
发明人： Jens Winkel , Gerhard Klein , Helmut-Martin Meier , Carlhans Suling , Dieter Arlt
IPC分类号： C08F20/00 , A61K6/083 , A61L27/00 , C07C67/00 , C07C239/00 , C07C271/16 , C07C275/24 , C08F4/40 , C08F20/34 , C08F20/36 , C07C125/065
CPC分类号： A61K6/083 , C07C275/24 , C08F20/36
摘要： Compounds of the formula ##STR1## in which R represents hydrogen or a methyl group,Y.sup.1 represents an optionally branched alkylene radical with 1 to 6 C atoms,Y.sup.2 represents an optionally branched alkylene radical with 2 to 8 C atoms,X denotes oxygen or an --NH-- group,R.sup.1 and R.sup.2 are identical or different and denote hydrogen, or an alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, aralkyl or alkylaryl group which has 1 to 11 C atoms and is optionally substituted by one or more,hydroxyl, amino, epoxide, urethane, urea, ester or ether groups, orR.sup.1 and R.sup.2 together form a 3-membered to 6-membered ring, which optionally contains nitrogen, oxygen or sulphur as hetero-atoms,R.sup.3 has the meaning of R.sup.1 or represents a group ##STR2## or R.sup.2 and R.sup.3, together with the ##STR3## group, form a 5-membered or 6-membered ring, which optionally contains oxygen as a further hetero-atom, andR.sup.4 and R.sup.5 are identical or different and represent hydrogen, an alkyl or alkenyl group which has 1 to 10 C atoms and is optionally substituted by halogen, or halogen,function as activators in the free radical polymerization of olefinically unsaturated monomers.
摘要翻译：其中R表示氢或甲基的式“IMAGE”的化合物，Y1表示具有1至6个C原子的任选支化的亚烷基，Y2表示具有2至8个C原子的任选支化的亚烷基，X表示氧或 -NH-基团，R 1和R 2相同或不同，表示氢或具有1至11个C原子并且任选被一个或多个羟基取代的烷基，烯基，环烷基，环烯基，芳基，芳烷基或烷芳基，氨基，环氧化物，氨基甲酸酯，脲，酯或醚基团，或R 1和R 2一起形成3元至6元环，其任选地含有氮，氧或硫作为杂原子，R 3具有R 1的含义或表示一组或R2和R3与基团一起形成5元或6元环，其任选地含有氧作为另一个杂原子，并且R 4和R 5相同或不同，并且表示氢，具有1至10个C原子的烷基或烯基，并且是op 被卤素或卤素取代，在烯属不饱和单体的自由基聚合中用作活化剂。

109. 发明授权

US4435597A Preparation of caronaldehyde acid and derivatives thereof 失效
标题翻译：丙二酸及其衍生物的制备
公开(公告)号：US4435597A
公开(公告)日：1984-03-06
申请号：US355034
申请日：1982-03-05
申请人： Dieter Arlt
发明人： Dieter Arlt
IPC分类号： C07C17/26 , C07C51/00 , C07C51/04 , C07C51/58 , C07C62/16 , C07C67/00
CPC分类号： C07C62/16 , C07C17/00 , C07C17/269 , C07C51/58
摘要： A process for the preparation of caronaldehyde acid or a derivative thereof of the formula ##STR1## in which R is O.sup.- Me.sup.+, or OH, andMe.sup.+ is an equivalent of an alkali metal, alkaline earth metal or ammonium cation, comprising reacting a 2-halogeno-3,3-dimethyl-5,5-dichloropentanoic acid halide of the formula ##STR2## wherein X and Y each independently is a halogen atom, with a base in the presence of water.
摘要翻译：其中R是O-Me +或OH和Me +的制备式“IMAGE”的丙二酸或其衍生物的方法是碱金属，碱土金属或铵阳离子的当量，包括使2 - 卤代-3,3-二甲基-5,5-二氯戊酸卤化物，其中X和Y各自独立地是卤素原子，在水的存在下与碱反应。

110. 发明授权

US4178279A Permanently stabilized polyurethanes 失效
标题翻译：永久稳定的聚氨酯
公开(公告)号：US4178279A
公开(公告)日：1979-12-11
申请号：US834762
申请日：1977-09-19
申请人： Paul Uhrhan , Harald Oertel , Reinhard Lantzsch , Ernst Roos , Dieter Arlt
发明人： Paul Uhrhan , Harald Oertel , Reinhard Lantzsch , Ernst Roos , Dieter Arlt
IPC分类号： C08G18/00 , C08G18/10 , C08G18/28 , C08G18/30 , C08K5/34 , C08K5/20
CPC分类号： C08G18/2805 , C08G18/10
摘要： The invention is related to modified polyurethanes which have a permanent, wash-fast, acidresistant, dry cleaning-resistant and solvent-resistant stabilization based on 2,2,6,6-tetraalkyl-piperidine light protective agents. These stabilizers are an integral constituent of the polyurethanes, that is to say they take part in the polyurethane synthesis by the reaction of an H-active reactive group (for example NH.sub.2, NH-alkyl, CO--NH--NH.sub.2, NH--CO--NH--NH.sub.2, OH or some other H-active group) of the 2,2,6,6-tetraalkyl-piperidine derivatives with isocyanate groups of polyisocyanates or isocyanate prepolymers.
摘要翻译：本发明涉及基于2,2,6,6-四烷基 - 哌啶光保护剂的具有永久，耐洗，耐酸，耐干性和耐溶剂稳定性的改性聚氨酯。这些稳定剂是聚氨酯的一个组成部分，也就是说，它们通过H活性反应性基团（例如NH 2，NH-烷基，CO-NH-NH 2，NH-CO- NH-NH 2，OH或一些其它H-活性基团）的2,2,6,6-四烷基 - 哌啶衍生物与多异氰酸酯或异氰酸酯预聚物的异氰酸酯基团。

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