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91. 发明授权

US5892123A Process for reproducing a mixture containing cyclododecanone and cyclododecanol 失效
标题翻译：用于再现含有十二烷酮和环十二烷醇的混合物的方法
公开(公告)号：US5892123A
公开(公告)日：1999-04-06
申请号：US17784
申请日：1998-02-03
申请人： Howard Wayne Anderson , James Bernard Sieja
发明人： Howard Wayne Anderson , James Bernard Sieja
IPC分类号： C07C27/12 , C07B61/00 , C07C27/00 , C07C29/132 , C07C29/50 , C07C35/205 , C07C45/33 , C07C45/53 , C07C49/413 , C07C407/00 , C07C409/14 , C07C35/08
CPC分类号： C07C29/132 , C07C29/50 , C07C45/53 , C07C2101/20
摘要： A method is disclosed for catalytically decomposing cyclododecyl hydroperoxide into cyclododecanone and cyclododecanol using a chromium catalyst.
摘要翻译：公开了一种使用铬催化剂将环十二烷基氢过氧化物催化分解成环十二烷酮和环十二烷醇的方法。

92. 发明授权

US5892122A Method for making cyclohexanol and cyclohexanone 失效
标题翻译：制备环己醇和环己酮的方法
公开(公告)号：US5892122A
公开(公告)日：1999-04-06
申请号：US918779
申请日：1997-08-25
申请人： John Joseph Ostermaier , George Crumbaugh Russell, III
发明人： John Joseph Ostermaier , George Crumbaugh Russell, III
IPC分类号： C07B61/00 , C07C27/12 , C07C27/34 , C07C29/132 , C07C29/50 , C07C29/86 , C07C35/08 , C07C45/33 , C07C45/53 , C07C45/80 , C07C49/403 , C07C45/32
CPC分类号： C07C45/53 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/80 , C07C2101/14
摘要： An improved method for making cyclohexanone and cyclohexanol from oxidation of cyclohexane in which a polyprotic acid is used to neutralize caustic to prevent oligomerization of cyclohexanone during fractional distillation.
摘要翻译：一种用于使环己酮和环己醇氧化成环己烷的改进方法，其中使用多聚酸中和苛性碱，以防止分馏过程中环己酮的低聚反应。

93. 发明授权

US5767328A Cyclic alcohol and process for producing the same 失效
标题翻译：循环酒精和生产过程
公开(公告)号：US5767328A
公开(公告)日：1998-06-16
申请号：US770051
申请日：1996-12-19
申请人： Shigeru Ono , Mineyuki Iwasaki
发明人： Shigeru Ono , Mineyuki Iwasaki
IPC分类号： B01J29/08 , B01J29/18 , B01J29/40 , B01J29/50 , B01J29/60 , C07B61/00 , C07C29/04 , C07C29/76 , C07C29/80 , C07C35/08 , C07C29/20
CPC分类号： C07C29/04 , C07C2101/14
摘要： A process for producing a cyclic alcohol which comprises subjecting a cyclic olefin represented by the formula: C.sub.n H.sub.2n-2-m R.sub.m (wherein R represents a hydrogen atom, an alkyl group of 1-4 carbon atoms, a phenyl group or a cyclohexyl group, n represents an integer of 5-12, and m represents an integer of 1-4) to a catalytic hydration reaction with water in the presence of a crystalline aluminosilicate having a primary particle diameter of 0.5 .mu.m or less as a catalyst, extracting the resulting liquid of an oil phase containing a cyclic alcohol and the crystalline aluminosilicate, evaporating the liquid and feeding the vapor to a rectifying column and/or filtering the liquid and feeding the filtrate to the rectifying column, thereby to adjust the concentration of the crystalline aluminosilicate contained in the liquid in the rectifying column to 1000 ppm by weight or less, and subjecting the liquid to distillation to separate the cyclic alcohol.
摘要翻译：一种制备环状醇的方法，该方法包括使式C n H 2n-2-m R m（其中R表示氢原子，1-4个碳原子的烷基，苯基或环己基，n 表示在一次粒径为0.5μm以下的结晶性硅铝酸盐作为催化剂进行与水的催化水合反应的5〜12的整数，m表示1-4的整数），萃取所得含有环状醇的油相的液体和结晶硅铝酸盐，蒸发液体并将蒸气送入精馏塔和/或过滤液体，并将滤液送入精馏塔，从而调节所含的结晶铝硅酸盐的浓度在精馏塔中的液体至1000重量ppm以下，并使液体蒸馏分离出环状醇。

94. 发明授权

US5726321A Process for carrying out gas/liquid reactions under avoidance of a continuous gas phase 失效
标题翻译：避免连续气相进行气/液反应的方法
公开(公告)号：US5726321A
公开(公告)日：1998-03-10
申请号：US620940
申请日：1996-03-22
申请人： Klaus Bittins , Marc Heider , Martin Schmidt-Radde , Jochen Kellenbenz , Kurt Josef Wagner , Peter Zehner , Stefan Berg
发明人： Klaus Bittins , Marc Heider , Martin Schmidt-Radde , Jochen Kellenbenz , Kurt Josef Wagner , Peter Zehner , Stefan Berg
IPC分类号： B01J3/00 , B01J10/00 , C07B61/00 , C07C29/36 , C07C29/44 , C07C29/48 , C07C31/12 , C07C31/13 , C07C31/20 , C07C31/27 , C07C35/08 , C07C41/05 , C07C41/08 , C07C43/16 , C07C51/235 , C07C53/122 , C07D233/54 , C07C31/18 , C07C35/18 , C07C41/00 , C07C43/00
CPC分类号： C07D233/54 , B01J10/002 , B01J3/00 , C07C29/36 , C07C29/44 , C07C41/08 , C07C51/235 , B01J2219/00162 , C07C2101/14 , Y10S585/951
摘要： Process for carrying out gas/liquid reactions at from (-50.degree.) to 300.degree. C. and from 0.1 to 100 bar by carrying out the reaction in the absence of a continuous gas phase, and, as a special case, a process for the batchwise reaction of acetylene in the liquid phase at from 0.degree. to 300.degree. C. and from 2 to 30 bar, in which acetylene is introduced a) in the absence of a continuous gas phase and b) under isobaric conditions to a degree of saturation of from 5 to 100%.
摘要翻译：通过在不存在连续气相的情况下进行反应，在（-50℃）〜300℃，0.1〜100巴下进行气/液反应的方法，作为特殊情况，在不存在连续气相的条件下，在0-300℃和2-30巴条件下将乙炔在液相中进行间歇反应，其中引入乙炔a）a）在不存在连续气相的情况下，和b）在等压条件下以一定程度饱和度为5〜100％。

95. 发明授权

US5672778A Process for increased yields of oxygenated products in two-step oxidation of hydrocarbons 失效
标题翻译：在两步氧化烃中增加氧化产物产率的方法
公开(公告)号：US5672778A
公开(公告)日：1997-09-30
申请号：US703423
申请日：1996-08-26
申请人： James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
发明人： James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
IPC分类号： A62D3/00 , A62D3/37 , A62D101/28 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12 , C07C35/08 , C07C45/53 , C07C407/00 , C07C29/48 , C07C27/10 , C07C31/02
CPC分类号： C07C45/53 , A62D3/37 , C07C29/132 , C07C31/12 , C07C35/08 , C07C407/003 , A62D2101/28 , C07C2101/14
摘要： The invention comprises a method for the catalytic conversion of alkanes and alkylhydroperoxides to oxygenates, particularly alcohols, comprising the oxidation of alkanes to yield alkylhydroperoxides, alcohols, other reaction products and unreacted alkane, and the decomposition of said alkylhydroperoxides to form alcohols and oxygen. Decomposition of the alkylhydroperoxide in the presence of unreacted alkane increases the yield of alcohol. The process further comprises drying of the reaction mixture comprising alkylhydroperoxide. Suitable catalysts for the process of the invention comprise metal containing catalysts, including metal organic ligand catalysts such as unsubstituted and substituted metal complexes of porphyrins, phthalocyanines and acetylacetonates.
摘要翻译：本发明包括将烷烃和烷基氢过氧化物催化转化为含氧化合物，特别是醇的方法，其包括烷烃的氧化以产生烷基氢过氧化物，醇，其它反应产物和未反应的烷烃，以及所述烷基氢过氧化物分解形成醇和氧。在未反应的烷烃存在下分解烷基氢过氧化物可提高醇的产率。该方法还包括干燥包含烷基过氧化氢的反应混合物。用于本发明方法的合适的催化剂包括含金属的催化剂，包括金属有机配体催化剂，例如卟啉，酞菁和乙酰丙酮化合物的未取代和取代的金属络合物。

96. 发明授权

US5420366A Process for the preparation of optically active 2-arylcyclohexanols 失效
标题翻译：光学活性2-芳基环己醇的制备方法
公开(公告)号：US5420366A
公开(公告)日：1995-05-30
申请号：US241322
申请日：1994-05-11
申请人： Shu-Hai Zhao
发明人： Shu-Hai Zhao
IPC分类号： C07C29/60 , C07C35/21 , C07C35/08 , C07C35/00
CPC分类号： C07C29/60 , C07C35/21 , C07B2200/07 , C07C2101/14
摘要： The present invention provides a process for preparing optically active 2-arylcyclohexanol and its esters and ethers and which process comprises the step of subjecting 1-aryl-cyclohexane-1,2 diol and its diethers and diesters to hydrogenolysis conditions to form said cyclohexanol and its esters and ethers.
摘要翻译：本发明提供了制备光学活性2-芳基环己醇及其酯和醚的方法，该方法包括使1-芳基 - 环己烷-1,2-二醇及其二醚和二酯进行氢解条件以形成所述环己醇及其酯和醚。

97. 发明授权

US5406001A Method for the continuous preparation of a mixture of a cycloalkanone, a cycloalkanol and a cycloalkylhydroperoxide 失效
标题翻译：连续制备环烷酮，环烷醇和环烷基氢过氧化物的混合物的方法
公开(公告)号：US5406001A
公开(公告)日：1995-04-11
申请号：US166344
申请日：1993-12-15
申请人： Johannes G. H. M. Housmans , Ubaldus F. Kragten
发明人： Johannes G. H. M. Housmans , Ubaldus F. Kragten
IPC分类号： C07C27/12 , C07C29/48 , C07C29/50 , C07C35/08 , C07C45/33 , C07C49/385 , C07C407/00 , C07C409/14 , C07C409/18
CPC分类号： C07C45/33 , C07C29/50 , C07C407/00 , C07C409/14 , C07C2101/14 , C07C2101/20
摘要： The present invention relates to a method for the continuous preparation of a mixture of a cycloalkanone, a cycloalkanol and a cycloalkylhydroperoxide. In the method, a cycloalkane, corresponding to the cycloalkenone, cycloalkenol and cycloalkylhydroperoxide, is oxidized in a continuous process, with the aid of an oxygen-containing gas, in the absence of a metal catalyst, at a temperature of between 130.degree. C. and 200.degree. C. The oxidation is at least partly carried out in the presence of between 0.002 and 2 mmol of a phenolic compound per kg of reaction mixture (mmol/kg).
摘要翻译：本发明涉及一种连续制备环烷酮，环烷醇和环烷基氢过氧化物的混合物的方法。在该方法中，对应于环烯酮，环烯醇和环烷基氢过氧化物的环烷烃在130℃的温度下，借助于含氧气体，在不存在金属催化剂的情况下，在连续的方法中被氧化。在每千克反应混合物（mmol / kg）下，在0.002至2mmol酚类化合物的存在下至少部分地进行氧化。

98. 发明授权

US5294739A Catalyttic oxidation of hydrocarbons 失效
标题翻译：碳氢化合物的催化氧化
公开(公告)号：US5294739A
公开(公告)日：1994-03-15
申请号：US897151
申请日：1992-06-11
申请人： Bettina Kraushaar-Czarnetzki , Willemina G. M. Hoogervorst
发明人： Bettina Kraushaar-Czarnetzki , Willemina G. M. Hoogervorst
IPC分类号： B01J29/83 , B01J29/84 , C07B61/00 , C07C27/12 , C07C29/50 , C07C35/08 , C07C45/33 , C07C49/403 , C07C51/215 , C07C51/31 , C07C55/14 , C07C67/035 , C07C15/10
CPC分类号： C07C67/035 , C07C27/12 , C07C45/33 , C07C51/215 , C07C51/313
摘要： The invention relates to a process for the catalytic oxidation of hydrocarbons with molecular oxygen using a cobalt-containing molecular sieve material having the cobalt ions substantially incorporated in the crystal lattice of the molecular sieve. Preferably, the oxidation is carried out with a molecular sieve containing from about 0.1% to about 10% by weight of cobalt and wherein the cobalt ions are substantially trivalent when the reaction starts. Preferably, the catalyst is a cobalt containing phosphate based molecular sieve material of the structure type 5, 31, 36, 37, 40, 50 and mixtures thereof and the hydrocarbons oxidized are from the group consisting of straight chain alkanes, alkenes, cycloalkanes and cycloalkenes which contain from about 3 to about 20 carbon atoms.
摘要翻译：本发明涉及一种使用具有钴离子基本上并入分子筛的晶格中的含钴分子筛材料用分子氧催化氧化烃的方法。优选地，用包含约0.1重量％至约10重量％的钴的分子筛进行氧化，并且其中当反应开始时钴离子基本上为三价。优选地，催化剂是结构类型为5,31,36,37,40,50的含磷酸钴基分子筛材料及其混合物，氧化的烃来自直链烷烃，烯烃，环烷烃和环烯烃其含有约3至约20个碳原子。

99. 发明授权

US5268356A Cyclic tertiary alcohols and their use as perfuming ingredients 失效
标题翻译：循环叔醇及其用作加香成分
公开(公告)号：US5268356A
公开(公告)日：1993-12-07
申请号：US969909
申请日：1992-11-02
申请人： Rene Decorzant , Ferdinand Naef
发明人： Rene Decorzant , Ferdinand Naef
IPC分类号： C07C35/08 , C07C35/18 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C11D3/50 , C07C35/08 , C07C35/18 , C11B9/0034 , C07C2101/16
摘要： The cyclic tertiary alcohols of formula ##STR1## wherein the dotted line indicates the location of a single or double bond, symbols R.sup.1 and R.sup.3 represent each a hydrogen atom or a methyl radical and symbol R.sup.2 stands for a lower alkyl radical, are useful perfuming ingredients for the preparation of perfuming compositions and perfumed articles, to which they impart odor notes of the patchouli type.
摘要翻译：式（I）的环状叔醇，其中虚线表示单键或双键的位置，符号R 1和R 3各自表示氢原子或甲基，符号R 2表示低级烷基，用于制备加香组合物和香料制品的有用的加香成分，它们赋予广藿香型气味。

100. 发明授权

US5262571A Cycloalkyl-based chiral auxiliaries and method making the same 失效
标题翻译：环烷基型手性助剂及其制备方法
公开(公告)号：US5262571A
公开(公告)日：1993-11-16
申请号：US855721
申请日：1992-03-20
申请人： Daniel L. Comins , James M. Salvador
发明人： Daniel L. Comins , James M. Salvador
IPC分类号： C07C29/40 , C07C35/08 , C12P7/62 , C12P41/00 , C07C29/159
CPC分类号： C12P41/004 , C07C29/40 , C07C35/08 , C12P7/62 , C07B2200/09 , C07C2101/14
摘要： A process of synthesizing enantiomerically pure compounds defined by Formula V, ##STR1## which are useful as chiral auxiliaries is disclosed. The process comprises, first, combining a base of Formula Y.sup.- Z.sup.+ (Formula I), wherein Y.sup.- is an organic anion and Z.sup.+ is an inorganic cation, with a compound of Formula II, ##STR2## wherein R.sub.1 is a C.sub.1 -C.sub.4 alkyl group and R.sub.2 is the same as R.sub.1, or wherein R.sub.1 and R.sub.2 together form cyclopentane or cyclohexane, and wherein R.sub.3 is a substituted or unsubstituted aryl group, to form a compound defined by Formula III, ##STR3## then: (b) reacting the compound of Formula III with a cyclic epoxide defined by Formula IV, ##STR4## wherein n is 1, 2, or 3, to form a racemic mixture of a compound defined by Formula V. ##STR5## In a preferred embodiment, the method further comprises stereospecifically esterifying one of the enantiomers of the racemic mixture of compound (V) and a carboxylic acid with an enzyme in an organic solvent, wherein said acid is a C.sub.2 -C.sub.20 alkyl acid, benzoic acid or a C.sub.2 -C.sub.14 alkyl benzoic acid, and then separating the esterified enantiomer from the non-esterified enantiomer.
摘要翻译：公开了可用作手性助剂的由式V，（VI）定义的对映体纯的化合物的合成方法。该方法包括首先将式Y-Z +（式I）的碱，其中Y-是有机阴离子，Z +是无机阳离子，与式II化合物，其中R1是 C1-C4烷基，R2与R1相同，或者其中R1和R2一起形成环戊烷或环己烷，其中R3是取代或未取代的芳基，形成由式III定义的化合物，然后：（b）使式III的化合物与式IV定义的环状环氧化物反应，其中n为1,2或3，以形成由式V定义的化合物的外消旋混合物。（V）在优选的实施方案中，该方法还包括将有机溶剂中的化合物（V）和羧酸的外消旋混合物的对映异构体立体异构酯化为酶，其中所述酸是C 2 -C 20烷基酸，苯甲酸或C 2 -C 14烷基苯甲酸，然后将酯化的对映异构体与未酯化的对映体 omer。

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