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    • 2. 发明授权
    • Dehydrogenation with a multicomponent catalyst
    • 用多元催化剂脱氢
    • US3761531A
    • 1973-09-25
    • US3761531D
    • 1972-06-01
    • UNIVERSAL OIL PROD CO
    • BLOCH H
    • B01J23/644C07C5/32C07C5/18C07C15/10
    • B01J23/644C07C5/325C07C2521/04C07C2523/02C07C2523/04C07C2523/14C07C2523/18C07C2523/42C07C2523/44C07C2523/644
    • Dehydrogenatable hydrocarbons are dehydrogenated by contacting them at dehydrogenation conditions with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a Group IVA metallic component, a Group VA metallic component and an alkali or alkaline earth metallic component with an alumina carrier material. A specific example of the disclosed method is a method for dehydrogenating a dehydrogenatable hydrocarbon comprising contacting the hydrocarbon at dehydrogenation conditions with a catalyst comprising a combination of catalytically effective amounts of a platinum component, a germanium or tin component, an arsenic component and an alkali or alkaline earth metallic component with an alumina carrier material. Disclosed method is particularly useful for the dehydrogenation of long chain normal paraffins to produce normal mono-olefins of the same carbon number.
    • 可脱氢烃通过在脱氢条件下与催化复合物接触来脱氢,催化复合物包含催化有效量的铂族组分,IVA族金属组分,第VA族金属组分和碱金属或碱土金属组分与氧化铝载体的组合 材料。 所公开的方法的具体实例是使可脱氢烃脱氢的方法,包括使脱氢条件下的烃与包含催化有效量的铂组分,锗或锡组分,砷组分和碱的组合的催化剂接触,或 具有氧化铝载体材料的碱土金属组分。 公开的方法对于长链正构烷烃的脱氢以产生相同碳数的正常单烯烃特别有用。