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    • 5. 发明授权
    • Triazine containing fluoropolyether elastomers having low glass transition temperature
    • 具有低玻璃化转变温度的含氟聚醚弹性体的三嗪
    • US09290619B2
    • 2016-03-22
    • US14003141
    • 2012-02-24
    • Miguel A. GuerraRudolf J. DamsSteven G. Corveleyn
    • Miguel A. GuerraRudolf J. DamsSteven G. Corveleyn
    • C08G67/02C08K5/16B01J8/36C08G73/24C08G65/00C08L71/00
    • C08G65/00C08G65/007C08G2650/48C08L71/00
    • There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
    • 提供了一种可固化组合物,其包含:a)具有约400g / mol至约20,000g / mol的分子量的含氟聚醚,并且含有选自( - (CF 2)4 O-),( - (CF 2) ),(-CF 2 O-)或其组合,并且在末端位置或与末端位置相邻的位置还含有至少一个腈基; 和b)一种或多种选自含有一个或多个与普通残基连接的官能团的非氟化合物的固化剂,所述残基含有至少三个碳原子,其中官能团选自伯胺,仲胺和官能团,其中 在热处理时产生伯胺或仲胺,其中组合物可以通过产生具有三嗪结构的基团来固化。 还提供固化组合物,固化组合物的制备方法,固化组合物固化的制品以及使用该可固化组合物制造制品的方法。
    • 10. 发明申请
    • DEGRADABLE MATERIALS
    • 可降解材料
    • US20130338271A1
    • 2013-12-19
    • US13994331
    • 2011-12-08
    • Michael D. CrandallRudolf J. DamsMichelle M. HewittIgnatius A. KadomaSiegmund PappYong K. WuJay M. JennenSasha B. Myers
    • Michael D. CrandallRudolf J. DamsMichelle M. HewittIgnatius A. KadomaSiegmund PappYong K. WuJay M. JennenSasha B. Myers
    • C08L67/04
    • C08L67/04C08K5/0016C08L2201/06C08L2205/02
    • The present disclosure relates to a degradable material comprising (a) from about 60 weight percent to about 97 weight percent of a first material based on the total weight of the degradable material, and (b) from about 3 weight percent to about 40 weight percent of a second material based on the total weight of the degradable material, where the second material is an oligomer comprising lactate and giycolate. In another aspect, the present disclosure provides a degradable material comprising (a) poly lactic acid, and (b) an oligomer comprising lactate and giycolate, wherein the degradable material has a Tg less than 56° C. In still another aspect, the present disclosure provides a degradable material comprising (a) poly lactic acid, and (b) an oligomer comprising lactate and giycolate, wherein the degradable material has a tan delta peak of less than 65° C. It has been surprisingly found that the degradable materials according to the present disclosure provide physical properties that are not inherent to poly lactic acid alone. It has also been surprisingly found that the degradable materials disclosed herein provide improvements with respect to the processability, production costs, flexibility and ductility without decreasing their degradability.
    • 本公开内容涉及可降解材料,其包含(a)基于可降解材料的总重量的约60重量%至约97重量%的第一材料,和(b)约3重量%至约40重量% 基于可降解材料的总重量的第二种材料,其中第二种材料是包含乳酸盐和双羟萘酸盐的低聚物。 另一方面,本公开提供了一种可降解材料,其包含(a)聚乳酸和(b)包含乳酸盐和木糖苷的低聚物,其中所述可降解材料的Tg小于56℃。另一方面,本发明 公开提供了一种可降解材料,其包含(a)聚乳酸和(b)包含乳酸盐和木糖醇的低聚物,其中所述可降解材料具有小于65℃的tanδ峰值。令人惊奇地发现, 本公开提供了单独聚乳酸不固有的物理性质。 还惊奇地发现,本文公开的可降解材料提供了相对于可加工性,生产成本,柔韧性和延展性而不降低其降解性的改进。