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1. 发明授权

US5623013A Xonotlite-reinforced organic polymer composition 失效
标题翻译：黑云母增强有机聚合物组合物
公开(公告)号：US5623013A
公开(公告)日：1997-04-22
申请号：US510224
申请日：1995-08-02
申请人： Hideho Tanaka , Yukihiko Asano , Kunio Watanabe , Hisataka Uchimura
发明人： Hideho Tanaka , Yukihiko Asano , Kunio Watanabe , Hisataka Uchimura
IPC分类号： C08K7/10 , C08J5/10 , C08K3/34 , C08L23/00
CPC分类号： C08K7/10
摘要： A Xonotlite-reinforced organic polymer composition obtained by mixing (A) an organic polymer and (B) fibrous Xonotlite, in which the fibrous Xonotlite (1) satisfies conditions (a), (b), and (c):(a) 0.1 .mu.m.ltoreq.D.ltoreq.0.4 .mu.m(b) 1 .mu.m.ltoreq.L
摘要翻译：通过混合（A）有机聚合物和（B）纤维黑云母，其中纤维性雪钛石（1）满足条件（a），（b）和（c））得到的硬粒子增强有机聚合物组合物：（a）0.1 （c）10 / L / D其中D和L代表平均纤维直径，和纤维黑云母（B）的平均纤维长度分别为（2）通过氮吸附测定的BET比表面积不小于21m 2 / g; （3）用表面活性剂和/或偶联剂进行表面处理; 和（4）已经形成颗粒。该组合物表现出改进的机械特性和改善的耐热性和抗冲击性之间的平衡。

2. 发明授权

US08877870B2 Fluorinated elastic copolymer and process for its production, and crosslinked rubber article 有权
标题翻译：氟化弹性共聚物及其制备方法，交联橡胶制品
公开(公告)号：US08877870B2
公开(公告)日：2014-11-04
申请号：US13183852
申请日：2011-07-15
申请人： Hiroshi Funaki , Kunio Watanabe , Keigo Matsuura , Ng Soon Yeng
发明人： Hiroshi Funaki , Kunio Watanabe , Keigo Matsuura , Ng Soon Yeng
IPC分类号： C08F214/18 , C08F214/26
CPC分类号： C08F214/18 , C08F214/26
摘要： A fluorinated elastic copolymer which has iodine atoms, bromine atoms, or both iodine and bromine atoms, at its molecular terminals and which includes repeating units (a) based on tetrafluoroethylene, repeating units (b) based on a fluorinated monomer having one polymerizable unsaturated bond (provided that tetrafluoroethylene is excluded), and repeating units (c) based on a fluorinated monomer having at least two polymerizable unsaturated bonds, wherein the ratio (molar ratio) of the repeating units (a) to the repeating units (b) is (a)/(b)=40/60 to 90/10, and the proportion of the repeating units (c) based on the total amount of the repeating units (a) and the repeating units (b) is from 0.01 to 1 mol %.
摘要翻译：在其分子末端具有碘原子，溴原子或碘原子或碘原子的含氟弹性共聚物，其包含基于四氟乙烯的重复单元（a），基于具有一个可聚合不饱和键的氟化单体的重复单元（b）（不包括四氟乙烯）和基于具有至少两个可聚合不饱和键的氟化单体的重复单元（c），其中重复单元（a）与重复单元（b）的比率（摩尔比）为（ a）/（b）= 40/60〜90/10，重复单元（c）相对于重复单元（a）和重复单元（b）的总量的比例为0.01〜％。

3. 发明授权

US08354728B2 Semiconductor device 有权
标题翻译：半导体器件
公开(公告)号：US08354728B2
公开(公告)日：2013-01-15
申请号：US12836826
申请日：2010-07-15
申请人： Masahiro Hayashi , Takahisa Akiba , Kunio Watanabe , Tomo Takaso , Susumu Kenmochi
发明人： Masahiro Hayashi , Takahisa Akiba , Kunio Watanabe , Tomo Takaso , Susumu Kenmochi
IPC分类号： H01L29/76 , H01L29/94 , H01L29/788 , H01L27/148 , H01L29/768
CPC分类号： H01L29/7834 , H01L23/5225 , H01L23/585 , H01L29/0638 , H01L29/0653 , H01L29/0692 , H01L29/1083 , H01L29/402 , H01L29/7833 , H01L2924/0002 , H01L2924/00
摘要： A semiconductor device including: a semiconductor layer; a gate insulating layer; a gate electrode; a channel region; a source region and a drain region; a guard ring region; an offset insulating layer; a first interlayer dielectric; a first shield layer formed above the first interlayer dielectric and the guard ring region and electrically connected to the guard ring region; a second interlayer dielectric; and a second shield layer formed above the second interlayer dielectric, wherein the first shield layer is provided outside of both ends of the gate electrode in a channel width direction when viewed from the top side; and wherein the second shield layer is provided in at least part of a first region and/or at least part of a second region, the first region being a region between one edge of the gate electrode and an edge of the first shield layer opposite to the edge of the gate electrode in the channel width direction when viewed from the top side, and the second region being a region between the other edge of the gate electrode and an edge of the first shield layer opposite to the other edge of the gate electrode in the channel width direction when viewed from the top side.
摘要翻译：一种半导体器件，包括：半导体层; 栅极绝缘层; 栅电极; 一个通道区域源区和漏区; 护环区; 偏移绝缘层; 第一层间电介质; 第一屏蔽层，其形成在所述第一层间电介质和所述保护环区域上方并电连接到所述保护环区域; 第二层间电介质; 以及形成在所述第二层间电介质上方的第二屏蔽层，其中当从所述顶侧观察时，所述第一屏蔽层设置在所述栅电极的两端的沟道宽度方向的外侧; 并且其中所述第二屏蔽层设置在第一区域和/或第二区域的至少一部分的至少一部分中，所述第一区域是所述栅电极的一个边缘与所述第一屏蔽层的与所述第一屏蔽层的边缘相反的边缘之间的区域所述栅电极的边缘在从所述顶侧观察时在所述沟道宽度方向上，所述第二区域是所述栅电极的另一边缘与所述第一屏蔽层的与所述栅电极的另一边缘相反的边缘之间的区域在从顶侧观察的通道宽度方向上。

4. 发明申请

US20100080903A1 FLUOROPOLYMER THIN FILM AND METHOD FOR ITS PRODUCTION 审中-公开
标题翻译：氟聚合物薄膜及其生产方法
公开(公告)号：US20100080903A1
公开(公告)日：2010-04-01
申请号：US12581220
申请日：2009-10-19
申请人： Chikaya TAMITSUJI , Kunio Watanabe , Yoshihiko Sakane , Jun Minamidate
发明人： Chikaya TAMITSUJI , Kunio Watanabe , Yoshihiko Sakane , Jun Minamidate
IPC分类号： C23C14/24
CPC分类号： C23C14/12 , B05D1/60 , B05D5/083 , B05D2506/10 , C08F216/1408 , C08F216/38
摘要： To provide a method for producing a fluoropolymer excellent in adhesion to a substrate and film strength.A method for producing a fluoropolymer thin film, which comprises forming a fluoropolymer thin film on a substrate by a physical vapor deposition method using, as an evaporation source, a fluoropolymer having a fluorinated aliphatic ring structure in its main chain and having a weight average molecular weight of from 3,000 to 80,000.
摘要翻译：提供一种制造具有优异的基材粘合性和膜强度的含氟聚合物的方法。一种含氟聚合物薄膜的制造方法，其特征在于，包括在物理气相沉积法的基板上形成含氟聚合物薄膜作为蒸发源，在其主链中具有含氟脂肪族环结构的含氟聚合物，其重均分子量重量从3,000到80,000。

5. 发明申请

US20080287694A1 PROCESSES FOR PRODUCING A FLUOROSULFONYL GROUP-CONTAINING COMPOUND AND A COMPOUND LED FROM THE FLUOROSULFONYL GROUP-CONTAINING COMPOUND 有权
标题翻译：用于生产含氟聚合物基团的化合物的方法和来自含氟化合物基团的化合物的化合物
公开(公告)号：US20080287694A1
公开(公告)日：2008-11-20
申请号：US11829579
申请日：2007-07-27
申请人： Takashi OKAZOE , Atsushi Watakabe , Masahiro Ito , Kunio Watanabe , Takeshi Eriguchi , Kimiaki Kashiwagi , Shu-zhong Wang
发明人： Takashi OKAZOE , Atsushi Watakabe , Masahiro Ito , Kunio Watanabe , Takeshi Eriguchi , Kimiaki Kashiwagi , Shu-zhong Wang
IPC分类号： C07D317/30 , C07D317/18
CPC分类号： C08F24/00 , C07D317/18 , C07D317/24 , C07D317/42
摘要： A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided.A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. wherein RA is a bivalent organic group such as a fluoroalkylene group, RAF is a group having RA fluorinated, or the same group as RA, each of RB to RD which are independent of one another, is a hydrogen atom, etc., each of RBF to RDF is a fluorine atom, etc., RE is a monovalent organic group, REF is a group having RE fluorinated, or the same group as RE, E is a bivalent connecting group, EF is the same group as E, or a group having E fluorinated, EF1 is a group formed by scission of EF, each of X1 to X3 is a hydrogen atom, etc., and each of X1F to X3F is a fluorine atom, etc.
摘要翻译：提供具有高聚合反应性的含氟磺酰基的化合物，其制备方法，由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过聚合含磺酰基的可聚合单体获得的聚合物。化合物（3）被氟化以形成化合物（4），然后使化合物（4）进行分解反应以制备化合物（5）。将化合物（5）的优选化合物（5-1）热分解，得到聚合反应性高的化合物（7-1）。其中R A是二价有机基团，例如氟代亚烷基，R AF是具有氟代的基团，或与氟代亚烷基相同的基团各自独立的R B，R D，D各自为氢原子等，R a，另一方面，BF> BF 是氟原子等，R E是一价有机基团，R EF是氟化的基团或与R E相同的基团，E是二价连接基团，E是与 E或具有E氟化基团的基团，是通过将X 1和X 2各自分开形成的基团。 > 3是氢原子等，X 1〜X 3各自为氟原子等。

6. 发明申请

US20070096250A1 Semiconductor device and method of manufacturing the same 审中-公开
标题翻译：半导体装置及其制造方法
公开(公告)号：US20070096250A1
公开(公告)日：2007-05-03
申请号：US11529635
申请日：2006-09-28
申请人： Kunio Watanabe , Tomo Takaso , Masahiro Hayashi , Takahisa Akiba , Susumu Kenmochi
发明人： Kunio Watanabe , Tomo Takaso , Masahiro Hayashi , Takahisa Akiba , Susumu Kenmochi
IPC分类号： H01L29/40 , H01L21/44
CPC分类号： H01L23/5258 , H01L23/5256 , H01L2924/0002 , H01L2924/00
摘要： A semiconductor device including: a semiconductor layer; a transistor formed in the semiconductor layer; a first interlayer dielectric formed above the semiconductor layer; a plurality of first interconnect layers formed above the first interlayer dielectric; a second interlayer dielectric formed over the first interlayer dielectric and the first interconnect layers; a plurality of second interconnect layers and an electrode pad which are formed above the second interlayer dielectric, the second interconnect layers being uppermost interconnects; a passivation layer formed over the second interlayer dielectric, the second interconnect layers, and the electrode pad; and an opening formed in the passivation layer to expose at least part of the electrode pad, a minimum distance between the second interconnect layers being greater than a minimum distance between the first interconnect layers.
摘要翻译：一种半导体器件，包括：半导体层; 形成在半导体层中的晶体管; 形成在所述半导体层上方的第一层间电介质; 形成在所述第一层间电介质上方的多个第一互连层; 形成在所述第一层间电介质和所述第一互连层上的第二层间电介质; 多个第二互连层和电极焊盘，形成在第二层间电介质的上方，第二互连层是最上面的互连; 形成在所述第二层间电介质上的钝化层，所述第二互连层和所述电极焊盘; 以及形成在所述钝化层中以暴露所述电极焊盘的至少一部分的开口，所述第二互连层之间的最小距离大于所述第一互连层之间的最小距离。

7. 发明申请

US20070083064A1 NOVEL FLUORINATED ADAMANTANE DERIVATIVE 失效
标题翻译：新型氟化物衍生物
公开(公告)号：US20070083064A1
公开(公告)日：2007-04-12
申请号：US11611183
申请日：2006-12-15
申请人： Kazuya OHARU , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
发明人： Kazuya OHARU , Takashi Okazoe , Eisuke Murotani , Kunio Watanabe , Masahiro Ito
IPC分类号： C07C57/64
CPC分类号： C07C61/15 , C07C51/58 , C07C2603/74
摘要： A compound represented by the formula AF(—COF)n, provided that AF and n have the following meanings. AF: a fluorinated adamantane residue which is an n-valent group having an n number of hydrogen atoms removed from adamantane (provided that when n is at least 2, the removed hydrogen atoms are hydrogen atoms bonded to different carbon atoms), wherein at least one of the remaining hydrogen atoms is substituted by a fluorine atom, and the remaining hydrogen atoms may be substituted by a C1-6 alkyl group or fluoroalkyl group, and n: an integer of from 1 to 4, provided the when n is 1, AF has at least one hydrogen atom.
摘要翻译：由式A -F（ - COF）n N表示的化合物，条件是A和N具有下列含义。氟化金刚烷残基，其是从金刚烷中除去n个氢原子的n价基团（条件是当n至少为2时，除去的氢原子是与氢原子键合的氢原子不同的碳原子），其中剩余的氢原子中的至少一个被氟原子取代，剩余的氢原子可以被C 1-6烷基或氟代烷基取代，n ：1〜4的整数，n为1时，A为至少1个氢原子。

8. 发明授权

US07053237B2 Process for producing a fluorinated ester, a fluorinated acyl fluoride and a fluorinated vinyl ether 有权
标题翻译：氟化酯，氟化氟化物和氟化乙烯基醚的制造方法
公开(公告)号：US07053237B2
公开(公告)日：2006-05-30
申请号：US10619784
申请日：2003-07-16
申请人： Takashi Okazoe , Kunio Watanabe , Shin Tatematsu , Hidenobu Murofushi , Masakuni Sato , Masahiro Ito , Koichi Yanase , Yasuhiro Suzuki
发明人： Takashi Okazoe , Kunio Watanabe , Shin Tatematsu , Hidenobu Murofushi , Masakuni Sato , Masahiro Ito , Koichi Yanase , Yasuhiro Suzuki
IPC分类号： C07C69/63 , C07C41/00
CPC分类号： C07C67/287 , C07C41/24 , C07C51/60 , C07C67/03 , C07C67/14 , C07C59/135 , C07C69/708 , C07C69/63 , C07C43/17
摘要： A process for producing a fluorinated ester through a small number of steps, is presented. The process for producing a fluorinated ester, comprises a transesterification step in which RAF—COOCF2—RAF and RA—CH2OH are subjected to a transesterification reaction to obtain RAF—COOCH2—RA, and a fluorination step in which the obtained compound is fluorinated to obtain a reaction product containing RAF—COOCF2—RAF. Here, in the formulae, RA is a monovalent organic group, and RAF is the same group as RA or a monovalent organic group obtained by fluorination of RA.
摘要翻译：提出了通过少量步骤生产氟化酯的方法。氟化酯的制备方法包括酯交换步骤，其中R AF -OCOCF 2 -R AF和R A A < / O 2 CH 2 OH进行酯交换反应，得到R AF-COOCH 2 -R A A / O >和氟化步骤，其中所得化合物被氟化以获得含有R AF -OCOCF 2 -R AF的反应产物。这里，在式中，R A A为一价有机基团，R AF为与R A A或单价有机基团相同的基团通过R A A的氟化获得。

9. 发明申请

US20050288528A1 Fluorinated adamantane and its derivatives 有权
公开(公告)号：US20050288528A1
公开(公告)日：2005-12-29
申请号：US11153438
申请日：2005-06-16
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani , Kazuya Oharu , Shu-zhong Wang , Taiki Hoshino , Kimiaki Kashiwagi
IPC分类号： C07C51/60 , C07C53/38 , C07C67/14 , C07C67/287 , C07C67/307
CPC分类号： C07C51/60 , C07C67/14 , C07C67/287 , C07C67/307 , C07C2603/74 , C07C55/40 , C07C53/50 , C07C69/54 , C07C69/63 , C07C69/708 , C07C69/753 , C07C69/734
摘要： The present invention provides a process A1 for producing a compound (5A), which comprises fluorinating a compound (3A-1) by liquid phase fluorination to a compound (4A-1), followed by a decomposition reaction of an ester bond; a process A2 for producing a compound (5A), which comprises fluorinating a compound (3A-2) by liquid phase fluorination to a compound (4A-2), followed by a decomposition reaction of an ester bond; and a process B for producing a compound (5B), which comprises fluorinating a compound (3B) by liquid phase fluorination to a compound (4B), followed by hydrolysis or alcoholysis. Further, the present invention provides a compound (5A) wherein n is 2 to 4, and a compound (5B) wherein n is 3 or 4. A(-CH2—OCO—R)n (3A-1) Af(-CF2—OCO—Rf)n (4A-1) A(-COOR)n (3A-2) Af(-COORf)n (4A-2) Af(-COF)n (5A) A(-OCO—R)n (3B) Af(-OCO—Rf)n (4B) Af(-OH)n (5B) provided that the carbon atom in adamantane to which —OCO—Rf is bonded, is a tertiary carbon atom, A is a n-valent group having n hydrogen atoms in adamantane converted to connecting bonds, R is a fluorinated monovalent organic group, n is an integer of from 1 to 4, Af is a group having at least one of hydrogen atoms in the group A substituted by a fluorine atom, and Rf is a fluorinated monovalent organic group.

10. 发明申请

US20050277785A1 Fluorinated adamantane derivatives 有权
标题翻译：氟化金刚烷衍生物
公开(公告)号：US20050277785A1
公开(公告)日：2005-12-15
申请号：US11143978
申请日：2005-06-03
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Eisuke Murotani
IPC分类号： C07C35/52 , C07C69/00 , C07C69/74 , C07C35/22 , C07C69/63
CPC分类号： C07C69/753 , C07C35/52 , C07C69/708 , C07C2603/74
摘要： The present invention provides novel compounds which are useful for the production of fluorinated adamantane derivatives excellent in etching resistance and useful as photolithographic material and so on. Namely, the present invention provides compounds represented by the following formulae (3) and (4): A(-G-Q-R)n (3) Af(-Gf-Q-Rf)n (4)provided that the symbols in the formula have the following meanings: A: a n-valent group having n hydrogen atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, R: a fluorinated monovalent organic group, n: an integer of from 1 to 4, G: —CH2— or a single bond, Q: —COO— or —OCO—, Af: a n-valent group (A) having n hydrogen atoms bonded to carbon atoms of adamantane converted to connecting bonds, wherein hydrogen atoms not converted to connecting bonds, may be each substituted by an alkyl group, in which at least one of hydrogen atoms forming C—H bonds is substituted by a fluorine atom, Rf: a fluorinated monovalent organic group, Gf: —CF2— or a single bond.
摘要翻译：本发明提供了可用于制备耐腐蚀性优异且用作光刻材料等的氟化金刚烷衍生物的新化合物。即，本发明提供由下式（3）和（4）表示的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> A（-GQR）（3）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead” （4）<？------------------（（（（（（（（（（-（（----------------- 公式描述=“直列公式”end =“tail”？>条件是式中的符号具有以下含义：A：具有转化为连接键的金刚烷的n个氢原子的n价基团，其中氢原子不转化成连接键，可以各自被烷基取代，R：氟化一价有机基团，n：1〜4的整数，G：-CH 2 - 或单键， Q：-COO-或-OCO-，A0：具有与键合到金刚烷的碳原子上的n个氢原子的n价基团（A）转化为连接键，其中未转化为连接键的氢原子可以各自被烷基取代，其中至少一个形成CH键的氢原子被氟原子取代：氟化一价有机基团， -CF 2 - 或单键。

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