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1. 发明授权

US09708238B2 Cycloalkane oxidation catalysts and method to produce alcohols and ketones 有权
公开(公告)号：US09708238B2
公开(公告)日：2017-07-18
申请号：US14416977
申请日：2012-07-26
申请人： Floryan Decampo , Wenjuan Zhou , Peng Wu , Kai Xue , Yueming Liu , Mingyuan He
发明人： Floryan Decampo , Wenjuan Zhou , Peng Wu , Kai Xue , Yueming Liu , Mingyuan He
IPC分类号： C07C49/385 , C07C35/02 , C07C45/28 , C07C29/48
CPC分类号： C07C49/385 , C07C29/48 , C07C35/02 , C07C45/28 , C07C2601/14 , C07C35/08 , C07C49/403
摘要： Disclosed is a method of oxidizing a cycloalkane to form a product mixture containing a corresponding alcohol and ketone, said method comprising contacting a cycloalkane with a hydroperoxide in the presence of a catalytic effective amount of a crystalline MWW-type titanosilicate catalyst. Hydroperoxides may notably be tert-butyl hydroperoxide, tert-amyl hydroperoxide, cumene hydroperoxide, ethylbenzene hydroperoxide, cyclohexyl hydroperoxide, methylcyclohexyl hydroperoxide, tetralin hydroperoxide, isobutylbenzene hydroperoxide, and ethylnaphthalene hydroperoxide.

2. 发明申请

US20150175514A1 Cycloalkane Oxidation Catalysts and Method to Produce Alcohols and Ketones 有权
标题翻译：环烷氧化催化剂和生产醇和酮的方法
公开(公告)号：US20150175514A1
公开(公告)日：2015-06-25
申请号：US14416977
申请日：2012-07-26
申请人： Floryan Decampo , Wenjuan Zhou , Peng Wu , Kai Xue , Yueming Liu , Mingyuan He
发明人： Floryan Decampo , Wenjuan Zhou , Peng Wu , Kai Xue , Yueming Liu , Mingyuan He
IPC分类号： C07C49/385 , C07C35/02
CPC分类号： C07C49/385 , C07C29/48 , C07C35/02 , C07C45/28 , C07C2601/14 , C07C35/08 , C07C49/403
摘要： Disclosed is a method of oxidizing a cycloalkane to form a product mixture containing a corresponding alcohol and ketone, said method comprising contacting a cycloalkane with a hydroperoxide in the presence of a catalytic effective amount of a crystalline MWW-type titanosilicate catalyst. Hydroperoxides may notably be tert-butyl hydroperoxide, tert-amyl hydroperoxide, cumene hydroperoxide, ethylbenzene hydroperoxide, cyclohexyl hydroperoxide, methylcyclohexyl hydroperoxide, tetralin hydroperoxide, isobutylbenzene hydroperoxide, and ethylnaphthalene hydroperoxide.
摘要翻译：公开了一种氧化环烷烃以形成含有相应的醇和酮的产物混合物的方法，所述方法包括在催化有效量的结晶MWW型钛硅酸盐催化剂的存在下使环烷烃与氢过氧化物接触。氢过氧化物可以特别是叔丁基过氧化氢，叔戊基过氧化氢，氢过氧化枯烯，氢过氧化乙苯，环己基氢过氧化物，甲基环己基氢过氧化物，四氢化萘氢过氧化物，异丁基苯氢过氧化物和乙基萘氢过氧化物。

3. 发明授权

US5951963A Phosphorous containing zeolite having MFI type structure 失效
标题翻译：含有MFI型结构的含磷沸石
公开(公告)号：US5951963A
公开(公告)日：1999-09-14
申请号：US46630
申请日：1998-03-24
申请人： Mingyuan He , Xiaoming Yang , Xingtian Shu , Jinge Luo
发明人： Mingyuan He , Xiaoming Yang , Xingtian Shu , Jinge Luo
IPC分类号： B01J29/85 , C01B39/10 , C01B39/46
CPC分类号： B01J29/85 , C01B39/10 , B01J2229/16 , B01J2229/183 , B01J2229/32 , Y10S423/22 , Y10S423/30
摘要： The present invention discloses a phosphorus-containing zeolite having MFI type structure. The anhydrous composition (based on the mole ratios of oxides) of the above zeolite is0.01-0.3Na.sub.2 O.Al.sub.2 O.sub.3.0.2-1.5P.sub.2 O.sub.5.30-90SiO.sub.2Said zeolite possesses a X-ray diffraction pattern listed in Table 1. The pore volume ratio of 1.0-10 nm mesopore to 10-membered ring pore is no less than 0.5. The crystal particle size of said zeolite is in the range of 0.8-2.0 micron. Said zeolite exhibits superior hydrothermal stability in catalytic conversion of hydrocarbons. Especially, when said zeolite is applied in catalytic cracking of hydrocarbons, it will enhance the crackability of large molecules, improve gasoline octane value and stability, and reduce the sulfur content in the gasoline as well.
摘要翻译：本发明公开了具有MFI型结构的含磷沸石。上述沸石的无水组成（基于氧化物的摩尔比）为0.01-0.3Na2O.Al2O3.0.2-1.5P2O5.30-90SiO2所述沸石具有表1中列出的X射线衍射图。孔体积 1.0-10nm中孔与10元环孔的比例不小于0.5。所述沸石的晶体粒度在0.8-2.0微米的范围内。所述沸石在烃的催化转化中表现出优异的水热稳定性。特别是当所述沸石用于烃的催化裂化时，会提高大分子的裂解性，提高汽油辛烷值和稳定性，并降低汽油中的硫含量。

4. 发明授权

US07485595B2 Molecular sieve-containing catalyst for cracking hydrocarbons and a method for preparing the same 有权
标题翻译：用于裂化烃的分子筛催化剂及其制备方法
公开(公告)号：US07485595B2
公开(公告)日：2009-02-03
申请号：US10855386
申请日：2004-05-28
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： B01J29/04 , B01J29/87 , B01J29/06 , B01J21/00 , B01J29/00 , B01J29/08 , B01J21/16 , B01J23/00 , B01J23/32 , B01J23/02 , B01J23/06 , B01J23/70
CPC分类号： B01J29/088 , B01J29/061 , B01J29/146 , B01J29/166 , B01J37/0045 , B01J37/16 , B01J2229/18 , B01J2229/20 , B01J2229/42 , C10G11/05
摘要： A molecular sieve-containing catalyst for cracking hydrocarbons, comprising molecular sieve, refractory inorganic oxide, clay and a metal component, wherein the amount of said molecular sieve is from 1 to 90% by weight, the refractory inorganic oxide is from 2 to 80% by weight, the clay is from 2 to 80% by weight, and the metal component is from 0.1 to 30% by weight, calculated as the oxide of said metal having its maximum valence state, based on the total amount of the catalyst, wherein said metal component exists essentially in a reduction state and is one or more metals selected from the group consisting of metals of Group IIIA (other than aluminum), and metals of Group IVA, VA, IB, IIB, VB, VIB and VIIB, and non-noble metals of Group VIII of the periodic table. The catalyst has higher cracking activity and higher sulfur reduction activity.
摘要翻译：一种分子筛催化剂，用于裂解烃，包括分子筛，耐火无机氧化物，粘土和金属组分，其中所述分子筛的量为1至90重量％，耐火无机氧化物为2至80重量％，粘土为2〜80重量％，金属成分为0.1〜30重量％，以所述金属的最高化合价的氧化物计，基于催化剂的总量计，其中，所述金属组分基本上以还原状态存在，并且是选自IIIA族金属（铝以外）中的一种或多种金属，以及IVA，VA，IB，IIB，VB，VIB和VIIB族的金属，以及周期表第Ⅷ族的非贵金属。该催化剂具有较高的裂解活性和较高的硫还原活性。

5. 发明授权

US07435332B2 Process for cracking hydrocarbon oils 有权
标题翻译：裂解烃油的工艺
公开(公告)号：US07435332B2
公开(公告)日：2008-10-14
申请号：US10949298
申请日：2004-09-27
申请人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00 , C10G9/00
CPC分类号： C10G11/05 , C10G11/04
摘要： This invention relates to a process for cracking hydrocarbon oils. The process comprises contacting a hydrocarbon oil with a catalyst that has been contacted with an atmosphere containing a reducing gas, separating cracked products and the catalyst, and regenerating the catalyst. The catalyst is a cracking catalyst containing a metal component, or a catalyst mixture of a cracking catalyst containing a metal component and a cracking catalyst free of metal component. The catalyst is contacted with the atmosphere containing a reducing gas at a temperature of 100 to 900° C. for at least 1 second, and the amount of the atmosphere containing a reducing gas is not less than 0.03 cubic meters of reducing gas per ton of the cracking catalyst containing a metal component per minute, at a pressure of 0.1-0.5 MPa in the reduction reactor. The process has enhanced capability for desulfurizing and cracking heavy oils.
摘要翻译：本发明涉及一种裂解烃油的方法。该方法包括使烃油与已经与含有还原气体的气氛接触的催化剂接触，分离裂化产物和催化剂，并再生催化剂。催化剂是含有金属组分的裂化催化剂，或含有金属组分的裂化催化剂和不含金属组分的裂化催化剂的催化剂混合物。催化剂与含有还原气体的气氛在100〜900℃的温度下接触1秒以上，含有还原气体的气氛量不低于0.03立方米/ 裂化催化剂在还原反应器中以0.1-0.5MPa的压力每分钟含有金属组分。该工艺提高脱硫和重油的能力。

6. 发明授权

US07758847B2 Molecular sieve with MFI structure containing phosphorus and metal components, preparation process and use thereof 有权
标题翻译：具有含磷和金属成分的MFI结构的分子筛，其制备方法和用途
公开(公告)号：US07758847B2
公开(公告)日：2010-07-20
申请号：US10577672
申请日：2004-10-28
申请人： Yibin Luo , Ying Ouyang , Xingtian Shu , Mingyuan He , Dianzhong Wang , Baoning Zong , Minggang Li
发明人： Yibin Luo , Ying Ouyang , Xingtian Shu , Mingyuan He , Dianzhong Wang , Baoning Zong , Minggang Li
IPC分类号： C01B39/10 , C01B39/38 , B01J29/072 , B01J29/46
CPC分类号： C01B39/026 , B01J29/084 , B01J29/405 , B01J29/46 , B01J29/48 , B01J29/80 , B01J2229/18 , B01J2229/42 , C10G11/02
摘要： A MFI-structured molecular sieve containing phosphorus and metal components has a formula expressed in anhydrous form and on the basis of oxide weight, as follows: (0˜0.3) Na2O (0.5˜5.5) Al2O3 (1.3˜10) P2O5 (0.7˜15) M1xOy (0.01˜5) M2mOn (70˜97) SiO2, wherein M1 is one of transition metals selected from the group consisting of Fe, Co and Ni, and M2 is any one of metals selected from the group consisting of Zn, Mn, Ga and Sn. Preparation processes and uses of the instant molecular sieve are also provided. The molecular sieve has an excellent performance for increasing the yield of lower olefins and increasing the aromatics content in gasoline, and can be used as a shape-selective active component for the catalytic cracking catalyst of petroleum hydrocarbons or its additives.
摘要翻译：含有磷和金属组分的MFI结构分子筛具有无水形式和氧化物重量的表达式：（0〜0.3）Na 2 O（0.5〜5.5）Al 2 O 3（1.3〜10）P 2 O 5（0.7〜 15）M1xOy（0.01〜5）M2mOn（70〜97）SiO2，其中M1是选自Fe，Co和Ni中的过渡金属之一，M2是选自Zn， Mn，Ga和Sn。还提供了即时分子筛的制备方法和用途。该分子筛具有优异的提高低级烯烃的产率和提高汽油中芳烃含量的性能，可用作石油烃或其添加剂的催化裂化催化剂的形状选择性活性成分。

7. 发明授权

US07514385B2 Rare earth y-zeolite catalyst for cracking hydrocarbons and a method for preparing same 有权
标题翻译：用于裂解烃的稀土y沸石催化剂及其制备方法
公开(公告)号：US07514385B2
公开(公告)日：2009-04-07
申请号：US10533488
申请日：2003-10-28
申请人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
发明人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
IPC分类号： B01J29/06
CPC分类号： C10G47/02 , B01J29/088 , B01J2229/16 , B01J2229/32 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C10G11/05 , C10G47/16 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2400/02 , C10L1/06
摘要： The invention discloses a rare-earth Y-zeolite-containing catalyst for cracking hydrocarbons and a method for preparing the same. The catalyst is characterized in that the rare-earth content in crystal lattice of the rare-earth Y-zeolite, calculated in RE2O3, is from 4 to 15% by weight, the original unit cell size is from 2.440 nm to 2.465 nm and the equilibrium unit cell size after 100% steam-aging treatment at 800° C. for 17 hours is larger than 2.435 nm. The catalyst is obtained in the following steps: the rare-earth Y-zeolite is dried first till its water content less than 10% by weight, then in a weight ratio of SiCl4:Y-zeolite=0.1˜0.9:1, reacts with SiCl4 gas carried by dry air, further is purged by dry air and washed by decationized water to remove the soluble by-products; the resulted rare-earth Y-zeolite is mixed with a binder and a clay, pulped and formed by spary drying. The zeolite content of the catalyst disclosed in present invention decreases 5˜25% by weight compared to the catalyst prepared in prior art for cracking heavy oil and decreasing olefin content. The catalyst is characterized with good cracking activity, high hydrothermal stability, and high conversion of heavy oil as well as excellent selectivity of gasoline, dry gas and coke; moreover, the olefin content in the produced gasoline decreases effectively.
摘要翻译：本发明公开了一种用于裂化烃的稀土Y-沸石催化剂及其制备方法。催化剂的特征在于稀土Y-沸石的晶格中的稀土含量以RE 2 O 3计算，为4〜15重量％，原始晶胞尺寸为2.440nm〜2.465nm，在800℃下进行100％蒸汽老化处理17小时后的平衡晶胞尺寸大于2.435nm。催化剂按以下步骤得到：稀土Y-沸石首先被干燥，直到其含水量低于10重量％，然后以SiCl 4 :Y-沸石= 0.1〜0.9:1的重量比与由干燥空气携带的SiCl 4气体，进一步用干燥空气清洗，并用去离子水洗涤以除去可溶性副产物; 将所得到的稀土Y沸石与粘合剂和粘土混合，通过喷雾干燥制浆并形成。与现有技术中制备的催化剂相比，本发明公开的催化剂的沸石含量降低了5〜25重量％，用于裂化重油和降低烯烃含量。催化剂的特点是具有良好的开裂活性，高水稳定性，重油转化率高，以及汽油，干气和焦炭的优异选择性; 此外，生产汽油中的烯烃含量有效降低。

8. 发明申请

US20080289997A1 PROCESS FOR CRACKING HYDROCARBON OILS 有权
标题翻译：破碎油气的方法
公开(公告)号：US20080289997A1
公开(公告)日：2008-11-27
申请号：US12027123
申请日：2008-02-06
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译：一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

9. 发明申请

US20080261802A1 Cracking Catalyst and a Preparation Process for the Same 有权
标题翻译：裂化催化剂及其制备方法
公开(公告)号：US20080261802A1
公开(公告)日：2008-10-23
申请号：US11910252
申请日：2006-03-31
申请人： Jun Du , Zheng Li , Jun Long , Mingde Xu , Zhijian Da , Huiping Tian , Mingyuan He
发明人： Jun Du , Zheng Li , Jun Long , Mingde Xu , Zhijian Da , Huiping Tian , Mingyuan He
IPC分类号： B01J29/08
CPC分类号： B01J29/088 , B01J35/002 , B01J37/0045 , B01J2229/24 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C10G11/05 , C10G2400/02
摘要： The present invention provides a cracking catalyst, containing a rare-earth Y-zeolite and a support, which is characterized in that the rare-earth content in crystal lattice of the rare-earth Y-zeolite is 4-15 wt % of RE2O3; the original unit cell size is 2.440-2.465 nm; the equilibrium unit cell size of the catalyst after 100% stream-aging at 800° C. for 17 hours is larger than 2.435 nm; the rare-earth atom content in the support is 1.0-8.0 wt % of the support. The present invention also relates to a preparation process for the same catalyst.
摘要翻译：本发明提供含有稀土Y型沸石和载体的裂化催化剂，其特征在于，稀土Y型沸石的晶格中的稀土含量为RE的4〜15重量％ SUB> 2 3

10. 发明授权

US07347930B2 Process for cracking hydrocarbon oils 有权
标题翻译：裂解烃油的工艺
公开(公告)号：US07347930B2
公开(公告)日：2008-03-25
申请号：US10964644
申请日：2004-10-15
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00 , C10G29/04
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译：一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

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