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    • 2. 发明公开
    • 피롤 및 피리디논계 다공질 금속 유기 골격체
    • 基于PYRROLES和PYRIDINONES的多孔金属有机框架
    • KR1020090009265A
    • 2009-01-22
    • KR1020087028902
    • 2007-05-11
    • 바스프 에스이
    • 리히터인고슈베르트마르쿠스뮐러울리히
    • C25B3/12C07D233/54C07D235/22
    • C07D233/54B01J20/226C07D235/22C25B3/12
    • The present invention relates to a process for preparing a porous metal organic framework containing at least one organic compound coordinated to at least one metal ion, which comprises the step of oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of the at least one organic compound, where the at least one organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived at least from one of the heterocycles selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens, where the ring system is unsubstituted or has one or more substituents selected independently from the group consisting of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl, where the substituents C1-6-alkyl and phenyl are unsubstituted or have one or more substituents selected independently from the group consisting of halogen, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl.
    • 本发明涉及一种制备含有至少一种与至少一种金属离子配位的有机化合物的多孔金属有机骨架的方法,该方法包括将对应于至少一种金属离子的至少一种含阳极的金属氧化为 在所述至少一种有机化合物存在下的反应介质,其中所述至少一种有机化合物是单环,双环或多环系统,其至少衍生自选自以下的杂环之一:吡咯,α- 吡啶酮和γ-吡啶酮,并且具有至少两个环氮,其中环系是未取代的或具有一个或多个独立地选自卤素,C 1-6 - 烷基,苯基,NH 2,NH(C 1-6 - 烷基),N(C 1-6 - 烷基)2,OH,苯基和OC 1-6 - 烷基,其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自Hal 原子,NH 2,NH(C 1-6 - 烷基),N(C 1-6 - 烷基)2,OH,苯基和OC 1-6 - 烷基。