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    • 2. 发明公开
    • 피롤 및 피리디논계 다공질 금속 유기 골격체
    • 基于PYRROLES和PYRIDINONES的多孔金属有机框架
    • KR1020090009265A
    • 2009-01-22
    • KR1020087028902
    • 2007-05-11
    • 바스프 에스이
    • 리히터인고슈베르트마르쿠스뮐러울리히
    • C25B3/12C07D233/54C07D235/22
    • C07D233/54B01J20/226C07D235/22C25B3/12
    • The present invention relates to a process for preparing a porous metal organic framework containing at least one organic compound coordinated to at least one metal ion, which comprises the step of oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of the at least one organic compound, where the at least one organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived at least from one of the heterocycles selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens, where the ring system is unsubstituted or has one or more substituents selected independently from the group consisting of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl, where the substituents C1-6-alkyl and phenyl are unsubstituted or have one or more substituents selected independently from the group consisting of halogen, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl.
    • 本发明涉及一种制备含有至少一种与至少一种金属离子配位的有机化合物的多孔金属有机骨架的方法,该方法包括将对应于至少一种金属离子的至少一种含阳极的金属氧化为 在所述至少一种有机化合物存在下的反应介质,其中所述至少一种有机化合物是单环,双环或多环系统,其至少衍生自选自以下的杂环之一:吡咯,α- 吡啶酮和γ-吡啶酮,并且具有至少两个环氮,其中环系是未取代的或具有一个或多个独立地选自卤素,C 1-6 - 烷基,苯基,NH 2,NH(C 1-6 - 烷基),N(C 1-6 - 烷基)2,OH,苯基和OC 1-6 - 烷基,其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自Hal 原子,NH 2,NH(C 1-6 - 烷基),N(C 1-6 - 烷基)2,OH,苯基和OC 1-6 - 烷基。
    • 8. 发明公开
    • 저알파선 방출 메탄설폰산 주석용액의 제조방법 및 메탄설폰산 주석용액
    • 低硫酸钠甲磺酸盐和低硫酸钠甲磺酸盐的制备方法
    • KR1020130059914A
    • 2013-06-07
    • KR1020110126150
    • 2011-11-29
    • 김동현김동훈주식회사 엠에스씨
    • 김동현김동훈
    • C25B3/12C07F7/22
    • C25B3/12C07F7/22C25B9/166C25B15/08
    • PURPOSE: A manufacturing method of base alpha ray emitting methanesulphonic acid tin solution and the methanesulphonic acid tin solution are provided to obtain a coating thin film with little particles emitting alpha rays and to preserve the solution for a long time as a change with the passage of time is slow. CONSTITUTION: A manufacturing method of base alpha ray emitting methanesulphonic acid tin solution comprises the following steps: a step(S10) of preparing an electrolytic cell in which a pair of product chambers in both sides of an anode and a cathode chamber are connected; a step(S20) of respectively preparing anode electrolyte and a cathode electrolyte respectively inserted into the prepared electrolytic cell; a step(S30) of inserting the prepared electrolytes respectively into the electrolytic cell and installing an anode formed of tin in an anode chamber and an cathode formed of titanium in which platinum is coated in the cathode chamber; and a step(S40) of electrolyzing the installed cathode and anode by applying power. [Reference numerals] (S10) First step for preparing an electrolytic cell; (S20) Second step for preparing an anode electrolyte and a cathode electrolyte; (S30) Third step for installing an anode and a cathode; (S40) Fourth step for electrolyzing the installed cathode and anode by applying power
    • 目的:提供碱性α射线甲基磺酸锡溶液和甲磺酸锡溶液的制备方法,以获得具有少量发射α-射线的颗粒的涂层薄膜,并且长时间保持溶液随着通过而变化 时间很慢 制备方法:制备碱α射线甲烷磺酸锡溶液的方法包括以下步骤:制备其中连接阳极和阴极室两侧的一对产物室的电解池的步骤(S10); 分别制备分别插入制备的电解槽中的阳极电解质和阴极电解质的步骤(S20) 将制备的电解质分别插入电解槽中并将由锡构成的阳极安装在阳极室中的步骤(S30)和由阴极形成的铂形成的阴极; 以及通过施加电力来电解所安装的阴极和阳极的步骤(S40)。 (附图标记)(S10)制备电解槽的第一步骤; (S20)制备阳极电解质和阴极电解质的第二步骤; (S30)安装阳极和阴极的第三步骤; (S40)通过施加电力来电解所安装的阴极和阳极的第四步骤
    • 9. 发明公开
    • 다공질 금속 유기 골격체의 제조 방법
    • 制备多孔金属有机框架的方法
    • KR1020090031358A
    • 2009-03-25
    • KR1020087030506
    • 2007-05-11
    • 바스프 에스이
    • 퓌터헤르만슈베르트마르쿠스리히터인고뮐러울리히트루칸나탈리아
    • C25B3/12
    • C25B3/12
    • The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
    • 本发明涉及一种制备多孔金属有机骨架的方法,所述多孔金属有机骨架包括与至少一种金属离子配位的至少两种有机化合物,其包括以下步骤:(a)至少一种含有金属的阳极氧化对应于至少一种金属 在第一有机化合物是任选取代的单环,双环或多环饱和或不饱和烃的情况下,在反应介质中存在至少第一有机化合物,其中至少两个环碳被选自以下的杂原子代替: 的N,O和S,以形成含有至少一种金属离子和第一有机化合物的反应中间体; 和(b)反应中间体在规定温度下与至少第二有机化合物的反应,所述至少第二有机化合物与至少一种金属离子配位,其中第二有机化合物衍生自二羧酸,三羧酸或四羧酸。