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1. 发明授权

KR101176236B1 광학 활성인 시클로프로판카르복실산에스테르 화합물의제조 방법 失效
标题翻译：生产光学活性的环丙烷羧酸酯化合物的方法
公开(公告)号：KR101176236B1
公开(公告)日：2012-08-22
申请号：KR1020077002180
申请日：2005-06-30
申请人： 스미또모 가가꾸 가부시키가이샤
发明人： 이따가끼,마꼬또 , 미나미다,료
IPC分类号： C07C67/347 , C07B61/00 , C07C69/757 , C07D263/14
CPC分类号： C07B53/00 , B01J31/1815 , B01J2231/325 , B01J2531/16 , C07B2200/07 , C07C67/347 , C07C2601/02 , C07D263/14 , C07C69/757
摘要： (식중, R, R, R, R및 R은각각상기와동일한의미를나타냄)
摘要翻译：（其中R，R，R，R和R分别与上述定义相同）

2. 发明公开

KR1020120032011A 에스테르 화합물의 제조 방법 有权
标题翻译：生产酯化合物的方法
公开(公告)号：KR1020120032011A
公开(公告)日：2012-04-04
申请号：KR1020127001563
申请日：2010-05-13
申请人： 히타치가세이가부시끼가이샤 , 고쿠리츠켄큐카이하츠호진 상교기쥬츠 소고켄큐쇼
发明人： 카와카미히로유키 , 토미나가켄이치 , 사토카즈히코
IPC分类号： C07C67/347 , B01J31/20 , C07C69/24 , C07C69/75
CPC分类号： B01J31/0239 , B01J31/0237 , B01J31/0282 , B01J31/0284 , B01J31/20 , B01J37/04 , B01J2231/321 , B01J2531/821 , B01J2531/845 , C07C67/38 , C07C2601/14 , C07C2602/42 , C07C69/753 , C07C69/75 , C07C69/24
摘要： 원료로서 염가의 포름산 에스테르를 사용하고, 종래법에 따른 반응온도보다 낮은 반응온도에서, 효율 좋게 에스테르 화합물을 제조하기 위해서 유효한 방법을 제공하는 것. 루테늄 화합물과, 코발트 화합물과, 할로겐화물염을 포함하는 촉매계의 존재하에서, 분자 내에 적어도 하나의 불포화 탄소 결합을 가지는 유기 화합물과, 프롬산 에스테르를 반응시킴으로써, 에스테르 화합물을 제조한다.

3. 发明公开

KR1020050084042A 비닐 아세테이트의 카르보닐화 无效
标题翻译：醋酸乙烯酯的合成
公开(公告)号：KR1020050084042A
公开(公告)日：2005-08-26
申请号：KR1020057009720
申请日：2003-10-31
申请人： 루사이트 인터내셔널 유케이 리미티드
发明人： 이스텀그라함로날드 , 루클리지아담존 , 콜-해밀톤데이비드
IPC分类号： C07C67/36 , C07C67/347 , B01J31/24
CPC分类号： B01J31/2457 , B01J31/1616 , B01J31/165 , B01J31/1895 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J35/0013 , B01J2231/321 , B01J2531/0205 , B01J2531/0258 , B01J2531/80 , B01J2531/824 , B01J2531/842 , C07C51/09 , C07C67/03 , C07C67/30 , C07C67/31 , C07C67/38 , C07C2603/74 , C07F9/5018 , C07F9/5027 , C07F9/5045 , C07F9/52 , C07C69/675 , C07C69/67 , C07C59/08 , C07C59/01 , C07C69/68
摘要： The present invention relates to the carbonylation of an ester, specifically vinyl acetate. The process comprises the carbonylation of vinyl acetate comprising reacting vinyl acetate with carbon monoxide in the presence of a source of hydroxyl groups and of a catalyst system, the catalyst system obtainable by combining: (c) a metal of Group VIII B or a compound thereof: and (d) a bidentate phosphine of general formula (I). A process for the production of a lactate ester or acid of formula (II), comprising the steps of carbonylating vinyl acetate with carbon monoxide in the presence of a source of hydroxyl groups and of a catalyst system is also described. A process for the production of 3-hydroxy propanoate ester or acid of formula (III) comprising the steps of: carbonylating vinyl acetate with carbon monoxide in the presence of a source of hydroxyl groups and of a catalyst system also forms an aspect of the invention.
摘要翻译：本发明涉及酯，特别是乙酸乙烯酯的羰基化。该方法包括乙酸乙烯酯的羰基化，包括在羟基源和催化剂体系的存在下使乙酸乙烯酯与一氧化碳反应，所述催化剂体系可通过以下方法获得：（c）VIIIB族金属或其化合物：和（d）通式（I）的二齿膦。还描述了生产式（II）的乳酸酯或酸的方法，包括在羟基源和催化剂体系存在下使乙酸乙烯酯与一氧化碳羰基化的步骤。一种制备式（III）的3-羟基丙酸酯或酸的方法，包括以下步骤：在羟基源和催化剂体系的存在下使乙酸乙烯酯与一氧化碳羰基化也形成本发明的一个方面。

4. 发明公开

KR1020000053330A 올레핀의 교차 이합체화 반응 无效
标题翻译： OLEFINS的二维化
公开(公告)号：KR1020000053330A
公开(公告)日：2000-08-25
申请号：KR1019997004341
申请日：1997-09-18
申请人： 이 아이 듀폰 디 네모아 앤드 캄파니
发明人： 브루크하트,모리스,에스. , 홉트만,엘리자베쓰,뮤리얼
IPC分类号： C07C67/347
CPC分类号： C07C67/347 , C07C69/533
摘要： PURPOSE: Provided is a process for the production of methyl 4-pentenoate (M4P) by selectively cross-dimerizing ethylene and methyl acrylate. Methyl 4-pentenoate is a nylon 6,6 intermediate. CONSTITUTION: Disclosed is a process for the preparation of methyl 4-pentenoate, which comprises contacting ethylene with methyl acrylate in the presence of a nickel II catalyst complex of the structure £QNiL1L2|+X-, wherein Q = n3 carbon-based allyl or substituted allyl, L1 = a monodentate trisubstituted phosphine ligand, L2 = a weakly coordinating ligand, X = a non-coordinating or weakly coordinating nonreactive anion; any liquid medium that may be present as solvent or diluent being non-reactive under the conditions of the process and non coordinating; and recovering the crude reaction product. Optionally, methyl 4-pentenoate can be separated from the crude reaction product by conventional methods, although the crude reaction product often can be used in further reactions without separating methyl 4-pentenoate.
摘要翻译：目的：提供通过选择性交联二聚乙烯和丙烯酸甲酯来生产4-戊烯酸甲酯（M4P）的方法。 4-戊烯酸甲酯是尼龙6,6中间体。构成：公开了一种制备4-戊烯酸甲酯的方法，该方法包括在结构为Q Q i N L 1 L 2 | + X 2的镍II催化剂络合物存在下使乙烯与丙烯酸甲酯接触，其中Q = n3碳基烯丙基或取代的烯丙基，L1 =单齿三取代膦配体，L2 =弱配位配体，X =非配位或弱配位的非反应性阴离子; 可能作为溶剂或稀释剂存在的任何液体介质在该方法和非配位条件下都是非反应性的; 并回收粗反应产物。任选地，4-戊烯酸甲酯可以通过常规方法与粗反应产物分离，尽管粗反应产物通常可以在不分离4-戊烯酸甲酯的情况下用于进一步反应。

5. 发明公开

KR880001570A 나프탈렌 유도체 失效
公开(公告)号：KR880001570A
公开(公告)日：1988-04-25
申请号：KR870006886
申请日：1987-07-01
IPC分类号： A61K31/36 , A61K31/165 , A61K31/235 , A61K31/357 , A61K31/44 , A61K31/4402 , A61K31/4406 , A61K31/4418 , A61K31/535 , A61K31/5375 , A61P3/04 , C07C67/00 , C07C67/08 , C07C67/347 , C07C69/76 , C07C69/767 , C07C69/94 , C07C213/00 , C07C219/14 , C07C231/00 , C07C235/42 , C07C313/00 , C07C323/00 , C07D213/30 , C07D213/64 , C07D213/65 , C07D295/08 , C07D295/088 , C07D317/70
摘要： 내용없음

6. 发明公开

KR860005778A 나프탈렌 유도체의 제조방법 失效
公开(公告)号：KR860005778A
公开(公告)日：1986-08-13
申请号：KR860000074
申请日：1986-01-09
IPC分类号： A61K31/085 , A61K31/235 , A61K31/265 , A61K31/34 , A61K31/343 , A61K31/357 , A61K31/36 , A61K31/365 , A61P3/06 , A61P9/10 , C07C43/315 , C07C45/00 , C07C45/71 , C07C47/57 , C07C51/38 , C07C63/34 , C07C65/24 , C07C67/00 , C07C67/08 , C07C67/347 , C07C69/94 , C07D307/87 , C07D307/88 , C07D307/92 , C07D317/68 , C07D317/70 , C07D493/04

7. 发明授权

KR102019924B1 디메틸뮤코네이트의 부가 고리화 방법 有权
公开(公告)号：KR102019924B1
公开(公告)日：2019-09-09
申请号：KR1020180004978
申请日：2018-01-15
申请人： 에스케이케미칼 주식회사
发明人： 박재균 , 박정호 , 채희일
IPC分类号： C07C67/347 , C07C69/75 , C07C67/317 , C07C67/62 , C07C69/82

8. 发明授权

KR101872044B1 베타-관능화 지방족 에스테르의 제조 방법 有权
公开(公告)号：KR101872044B1
公开(公告)日：2018-06-27
申请号：KR1020137010737
申请日：2011-08-31
申请人： 코그니스 아이피 매니지먼트 게엠베하
发明人： 구쎈루카스제이 , 올만도미닉 , 디르커마르쿠스
IPC分类号： C07C69/612 , C07C229/12 , C07C229/14 , C07C67/347 , C07D295/15
CPC分类号： C07C67/347 , C07C227/06 , C07C227/08 , C07C2601/14 , C07D211/34 , C07D211/62 , C07D211/76 , C07D295/15 , C07C69/612 , C07C229/12
摘要： 본발명은올레핀산에스테르를, Rh(I)-착물을포함하는촉매계의존재하에서, 친핵성화합물인아릴보론또는디아민과함께및 산소-부재조건및 승온하에서반응시킴으로써원-팟반응으로β-관능화카르복실산에스테르를제조하는새로운경로에관한것이다.

9. 发明公开

KR1020140023943A 노르보르난 디카르복실산 에스테르의 제조 방법 无效
标题翻译：生产诺贝糖二羧酸酯的方法
公开(公告)号：KR1020140023943A
公开(公告)日：2014-02-27
申请号：KR1020137028090
申请日：2012-04-13
申请人： 히타치가세이가부시끼가이샤 , 내셔날 인스티튜트 오브 어드밴스드 인더스트리얼 사이언스 앤드 테크놀로지
发明人： 가와카미,히로유키 , 도미나가,겐이치 , 시마다,시게루 , 사토,가즈히코
IPC分类号： C07C67/347 , C07C69/753 , C07B61/00
CPC分类号： C07C67/347 , C07C67/48 , C07C2602/42 , C07C69/753
摘要： 본 발명은, 노르보르나디엔과 포름산 에스테르를 루테늄 화합물, 코발트 화합물, 할로겐화물염 및 염기성 화합물의 존재하에서 반응시키는 공정을 갖는 노르보르난 디카르복실산 에스테르의 제조 방법을 제공한다.

10. 发明授权

KR101205322B1 식물성 오일 유래의 폴리올 및 그 제조방법 有权
标题翻译：植物油基多元醇及其制备方法
公开(公告)号：KR101205322B1
公开(公告)日：2012-11-27
申请号：KR1020110094508
申请日：2011-09-20
申请人： 에이치플러스에코 주식회사
发明人： 채명수 , 이명진 , 전남석 , 조창용
IPC分类号： C07C69/732 , C07C67/31 , C07C67/313 , C07C67/347
摘要： PURPOSE: A vegetable oil-derived polyols and a manufacturing method thereof are provided to be environmentally-friendly and to enhance reactivity. CONSTITUTION: A vegetable oil-derived polyols is synthesized from vegetable oil, and is represented by chemical formula 1. A manufacturing method of vegetable oil originated polyols comprises the following steps: manufacturing a compound represented by chemical formula 4 by epoxidizing tridlyceride of chemical formula 3 as vegetable oil; performing a reaction under the presence of an acid catalyst by adding the chemical formula 4 compound after dissolving a compound represented by chemical formula 5; and removing nonreacted material and solvent.
摘要翻译：目的：提供一种植物油衍生的多元醇及其制造方法，以环境友好并提高反应性。构成：植物油衍生的多元醇由植物油合成，由化学式1表示。植物油起始多元醇的制造方法包括以下步骤：通过化学式3的三甘油二环氧化制造化学式4所示的化合物作为植物油; 通过在化学式5表示的化合物溶解后添加化学式4化合物，在酸催化剂的存在下进行反应; 并除去未反应的物质和溶剂。

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