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    • 1. 发明授权
    • 선택된 금속 조성을 갖는 백금 장식 조성물 및 그의 제조 방법
    • 具有选定金属组成的铂金装饰组合物及其制造方法
    • KR101788409B1
    • 2017-10-19
    • KR1020150157706
    • 2015-11-10
    • 헤레우스 도이칠란트 게엠베하 운트 코. 카게
    • 휴펠패트리지아말터한스-미카엘
    • C09D7/12C08K3/08B32B15/00C09D201/00
    • C09D1/00B44C1/175C03C17/10C03C2217/72C04B41/009C04B41/5116C04B41/88C04B2111/00965C09D5/38C23C18/08C04B41/4501C04B41/4554C04B41/5027C04B41/5031C04B41/5033C04B41/5035C04B41/5042C04B41/5049C04B41/505C04B41/5122C04B33/24C04B35/00
    • 본발명은, 조성물로서, i. 유기비히클, ii. 적용가능할경우, 무기첨가제, iii. 금속, 백금(Pt), 알루미늄(Al), 주석(Sn) 및비스무트(Bi)를포함하는금속-유기화합물을성분으로포함하며, Bi 대 Sn의비가 10:1 ∼ 50:1 범위이고, Al 대 Sn의비가 1:1 ∼ 15:1 범위인조성물에관한것이다. 본발명은또한층상구조로서, i. 표면을가진기판, ii. 상기표면상에, 적어도부분적으로, 중첩되어연결된금속층을포함하고, 금속층은금속, 백금(Pt), 알루미늄(Al), 주석(Sn) 및비스무트(Bi)를포함하며, 금속층 내에서 Bi 대 Sn의비가 10:1 ∼ 50:1 범위이고, Al 대 Sn의비가 1:1 ∼ 15:1 범위인층상구조에관한것이다. 본발명은또한층상구조의전구체로서, a) 표면을가진기판, b) 상기표면에적어도부분적으로중첩된조성물을포함하고, 조성물은금속, 백금(Pt), 알루미늄(Al), 주석(Sn) 및비스무트(Bi)를포함하는금속-유기화합물을포함하며, 조성물내의 Bi 대 Sn의비가 10:1 ∼ 50:1 범위이고, Al 대 Sn의비가 1:1 ∼ 15:1 범위인전구체에관한것이다. 본발명은또한층상구조를제조하는방법으로서, S1. 표면을가진기판을제공하는단계, S2. 제1 조성물을표면의적어도일부상에중첩하면서, 층상구조의전구체를얻는단계, S3. 층상구조의전구체를 500℃이상의온도에서처리하는단계를포함하는방법에관한것이다.
    • 本发明提供了一种组合物,其包含:i。 有机载体,ii。 如果适用,无机添加剂; iii。 其中Bi与Sn的比例在10:1至50:1的范围内,并且Al(Al) Sn的范围为1:1至15:1。 本发明还提供了一种分层结构,其包含:i。 具有表面的基材,ii。 其中金属层包括金属,铂(Pt),铝(Al),锡(Sn)和铋(Bi) UIBI为10:1至50:1米范围内,并且,铝锡UIBI为1:1涉及的层结构的范围:1-15。 本发明还为分层前体,a)具有表面的衬底,b)包括在该组合物到表面上,金属的组成,铂(Pt),铝(Al),锡至少部分地重叠(Sn)的 和双金属含有(Bi)的 - 包括有机化合物,铋用户需要Sn UIBI在组合物10:1至50:1范围内,并且,铝用户需要Sn UIBI为1:1至15:约1范围内的前体 会的。 本发明还提供了一种制造分层结构的方法,包括以下步骤:S1。 提供具有表面的衬底S2。 获得层状结构的前体,同时将第一组合物叠加在至少一部分表面上; S3。 在500℃或更高的温度下处理层状结构的前体。
    • 2. 发明公开
    • 선택된 금속 조성을 갖는 백금 장식 조성물 및 그의 제조 방법
    • 具有选择的金属组合物的白金装饰组合物作为其生产方法
    • KR1020160056299A
    • 2016-05-19
    • KR1020150157706
    • 2015-11-10
    • 헤레우스 도이칠란트 게엠베하 운트 코. 카게
    • 휴펠패트리지아말터한스-미카엘
    • C09D7/12C08K3/08B32B15/00C09D201/00
    • C09D1/00B44C1/175C03C17/10C03C2217/72C04B41/009C04B41/5116C04B41/88C04B2111/00965C09D5/38C23C18/08C04B41/4501C04B41/4554C04B41/5027C04B41/5031C04B41/5033C04B41/5035C04B41/5042C04B41/5049C04B41/505C04B41/5122C04B33/24C04B35/00C09D7/61B32B15/00C08K3/08C09D7/63C09D201/00
    • 본발명은, 조성물로서, i. 유기비히클, ii. 적용가능할경우, 무기첨가제, iii. 금속, 백금(Pt), 알루미늄(Al), 주석(Sn) 및비스무트(Bi)를포함하는금속-유기화합물을성분으로포함하며, Bi 대 Sn의비가 10:1 ∼ 50:1 범위이고, Al 대 Sn의비가 1:1 ∼ 15:1 범위인조성물에관한것이다. 본발명은또한층상구조로서, i. 표면을가진기판, ii. 상기표면상에, 적어도부분적으로, 중첩되어연결된금속층을포함하고, 금속층은금속, 백금(Pt), 알루미늄(Al), 주석(Sn) 및비스무트(Bi)를포함하며, 금속층 내에서 Bi 대 Sn의비가 10:1 ∼ 50:1 범위이고, Al 대 Sn의비가 1:1 ∼ 15:1 범위인층상구조에관한것이다. 본발명은또한층상구조의전구체로서, a) 표면을가진기판, b) 상기표면에적어도부분적으로중첩된조성물을포함하고, 조성물은금속, 백금(Pt), 알루미늄(Al), 주석(Sn) 및비스무트(Bi)를포함하는금속-유기화합물을포함하며, 조성물내의 Bi 대 Sn의비가 10:1 ∼ 50:1 범위이고, Al 대 Sn의비가 1:1 ∼ 15:1 범위인전구체에관한것이다. 본발명은또한층상구조를제조하는방법으로서, S1. 표면을가진기판을제공하는단계, S2. 제1 조성물을표면의적어도일부상에중첩하면서, 층상구조의전구체를얻는단계, S3. 층상구조의전구체를 500℃이상의온도에서처리하는단계를포함하는방법에관한것이다.
    • 本发明涉及一种适用于形成耐用薄膜的组合物,包括:i)有机载体; ii)无机添加剂(如果适用) 和iii)含有金属,铂(Pt),铝(Al),锡(Sn)和铋(Bi)的金属有机化合物。 这里,Bi与Sn的比例为10:1〜50:1,Al与Sn的比例为1:1〜15:1。 本发明还涉及一种分层结构,其包括:i)具有表面的基底; 以及ii)与所述表面连接以与所述表面部分重叠的金属层。 金属层包括金属,铂(Pt),铝(Al),锡(Sn)和铋(Bi)。 金属层内的Bi与Sn的比例在10:1〜50:1的范围内,Al与Sn的比例为1:1〜15:1。 本发明还涉及层状结构的前体,其包括:a)具有表面的基底; 和b)与表面部分重叠的组合物。 该组合物包括含有金属,铂(Pt),铝(Al),锡(Sn)和铋(Bi)的金属有机化合物。 组合物中Bi与Sn的比例在10:1至50:1的范围内,Al与Sn的比例在1:1至15:1的范围内。 本发明还涉及一种用于制造层状结构的方法,包括以下步骤:(S1)提供具有表面的基板; (S2)在第一组合物与所述表面的至少一部分重叠的同时获得层状结构的前体; 和(S3)在500℃以上的温度下处理层状结构体的前体。
    • 7. 发明公开
    • 실리콘 함유 기판을 위한 배리어층
    • 用于含硅基材的阻挡层
    • KR1020030051365A
    • 2003-06-25
    • KR1020020080648
    • 2002-12-17
    • 유나이티드 테크놀로지스 코포레이션
    • 홀로쟉존이.이튼해리이.
    • C04B41/87C04B41/89C23C4/10B32B18/00
    • C04B41/009C04B41/5027C04B41/5051C04B41/52C04B41/87C04B41/89C23C4/11C23C28/042C23C28/322C23C28/3455C23C30/00F01D5/288F05D2300/222Y10T428/26Y10T428/30C04B41/4527C04B41/5037C04B41/0072C04B41/4556C04B41/5035C04B41/5024C04B41/522C04B35/565C04B35/584C04B35/806C04B35/597
    • PURPOSE: An article comprising a silicon containing substrate with a barrier layer which inhibits the formation of gaseous species of Si, particularly Si(OH)x, when the article is exposed to a high temperature, aqueous environment, such as a gas turbine engine hot section is provided. CONSTITUTION: The article comprises a substrate comprising silicon; and a barrier layer comprising an aluminosilicate selected from the group consisting of Group IIA, Group IIIB and mixtures thereof and an oxide selected from Group VB, wherein the barrier layer inhibits the formation of gaseous species of Si when the article is exposed to a high temperature, aqueous environment, wherein the substrate is selected from the group consisting of silicon containing ceramic and metal alloys containing silicon, wherein the barrier layer comprises an aluminosilicate selected from the group consisting of barium aluminosilicate, barium strontium aluminosilicate, yttrium aluminosilicate and mixtures thereof and an oxide selected from the group consisting of tantalum oxide, niobium oxide and mixtures thereof, wherein the article comprises at least 25 wt.% of the aluminosilicate and at least 25 wt.% of the oxide, wherein the barrier layer consists essentially of 25 to 75 wt.% of the oxide selected from the group consisting of Ta, Nb and mixtures thereof, wherein the barrier layer comprises essentially of 50 to 75 wt.% of the oxide selected from the group consisting of Ta, Nb and mixtures thereof, wherein the barrier layer comprises the oxide selected from the group consisting of Ta, Nb and mixtures thereof and the aluminosilicate selected from the group consisting of barium, strontium and mixtures thereof, wherein the coefficient of thermal expansion of the barrier layer is within ±3.0 ppm/deg.C the coefficient of thermal expansion of the substrate, wherein the coefficient of thermal expansion of the barrier layer is within ±0.5 ppm/deg.C the coefficient of thermal expansion of the substrate, wherein the barrier layer has a thickness of 0.1 mils or more, wherein the article includes an intermediate layer between the substrate and the barrier layer, wherein the barrier layer contains a CTE tailoring additive, and wherein the barrier layer contains an oxide of Ta.
    • 目的:一种包含具有阻挡层的含硅衬底的物品,其在制品暴露于诸如燃气轮机发动机热的高温水溶液环境中时,其阻止形成气态物质的Si,特别是Si(OH)x 提供部分。 构成:该制品包括含硅的衬底; 以及阻挡层,其包含选自IIA族,IIIB族及其混合物的铝硅酸盐和选自组VB的氧化物,其中当制品暴露于高温时,阻挡层抑制Si的气态物质的形成 水性环境,其中所述基材选自含硅陶瓷和含硅金属合金,其中所述阻挡层包含选自铝硅酸钡,硅铝酸锶钡,硅酸铝钇及其混合物的铝硅酸盐,以及 选自氧化钽,氧化铌及其混合物的氧化物,其中所述制品包含至少25重量%的硅铝酸盐和至少25重量%的氧化物,其中阻挡层基本上由25至75 选自Ta,Nb及其混合物的氧化物的重量%,其中 阻挡层基本上包含50至75重量%的选自Ta,Nb及其混合物的氧化物,其中阻挡层包含选自Ta,Nb及其混合物的氧化物,选择硅铝酸盐 由钡,锶及其混合物组成,其中阻挡层的热膨胀系数在基板的热膨胀系数在±3.0ppm /℃以内,其中阻挡层的热膨胀系数 基板的热膨胀系数在±0.5ppm /℃以内,其中阻挡层具有0.1密耳或更大的厚度,其中所述制品在所述基底和所述阻挡层之间包括中间层,其中所述阻挡层 含有CTE定制添加剂,并且其中阻挡层含有Ta的氧化物。
    • 8. 发明公开
    • 원적외선 방사 습식코팅 공정 및 시스템
    • 湿法涂层工艺和红外辐射系统
    • KR1020020072970A
    • 2002-09-19
    • KR1020010013071
    • 2001-03-14
    • 클린월드하이테크(주)
    • 장감용
    • C04B35/00C04B35/14
    • C04B35/62222A61N2005/066C04B41/4505C04B41/5027C04B41/5031C04B41/5035C04B2103/0097
    • PURPOSE: Provided is a method for coating accessories and living products with far infrared emitting materials(quartz porphyry, illite, etc.) by wet coating process. Accordingly, the resultant products emitting far infrared ray give the useful effects to our life. CONSTITUTION: The coating materials emitting far infrared ray comprise 1-5wt.% of CuO, 1-5wt.% of NiO, 1-5wt.% of biotite, 1-5wt.% of pottery stone and inorganic materials(quartz porphyry, gangue and illite) containing 30-50wt.% of SiO2, 5-25wt.% of Al2O3, 5-15wt.% of CaO, 5-15wt.% of MgO, 5-15wt.% of Fe2O3, 2.5-7.5wt.% of Na2O, 1-2wt.% of CoO3, 0.5-1.5wt.% of Ti, 0.001-0.01wt.% of Y, 0.005-0.2wt.% of La, 0.005-0.2wt.% of Ce, and 0.001-0.01wt.% of Nd. The far infrared emitting products are manufactured by coating living products(cup, glass lens), accessories and health cards with vapor generated from heating the above coating materials mixed with 20-30wt.% of water, followed by drying.
    • 目的:提供一种通过湿式涂布方法涂覆远红外线发射材料(石英斑岩,伊利石等)的配件和生活产品的方法。 因此,产生远红外线的产品给我们的生活带来了有用的效果。 构成:发射远红外线的涂层材料包括1-5重量%的CuO,1-5重量%的NiO,1-5重量%的黑云母,1-5重量%的陶石和无机材料(石英斑岩,ang石 和伊利石),其含有30-50重量%的SiO 2,5-25重量%的Al 2 O 3,5-15重量%的CaO,5-15重量%的MgO,5-15重量%的Fe 2 O 3,2.5-7.5重量% 的Na 2 O,1-2重量%的CoO 3,0.5-1.5重量%的Ti,0.001-0.01重量%的Y,0.005-0.2重量%的La,0.005-0.2重量%的Ce和0.001- 0.01重量%的Nd。 远红外线发射产品是通过将生产的产品(杯子,玻璃透镜),附件和保健卡片与通过加热上述与20-30重量%的水混合的涂层材料产生的蒸气来制造的,然后干燥。
    • 9. 发明公开
    • 내화벽돌및내화벽돌의탄소산화방지법
    • 用于TORPEDO LADLE CAR AND LADLE的FIREPROOF砖和防止碳氧化的方法
    • KR1020000007691A
    • 2000-02-07
    • KR1019980027144
    • 1998-07-06
    • 조선내화 주식회사
    • 범진형선우식
    • C04B35/14
    • C04B41/5035C04B41/5027C04B2235/9684F27D1/06
    • PURPOSE: A fireproof brick for torpedo ladle car and ladle and a preparation method thereof are provided, for increasing the life of the brick by preventing the oxidation of carbon in the brick. CONSTITUTION: The surface of the fireproof brick is coated with an antioxidant layer with the thickness of 0.2-1.0 mm for preventing of the oxidation of carbon. The antioxidant preferably comprises SiO2 of 30-75 weight part, Na2O and K2O of 6-20 weight part, B2O3 of 10 weight part or ZrO2 of 60 weight part, Al2O3 of 1-10 weight part, and the balance of inevitable impurities. The fireproof brick is prepared by coating the surface with the antioxidant; and preheating the brick at a temperature between 700 and 1500°C to form a glass-phase coating film by glazing.
    • 目的:提供用于鱼雷钢包车和钢包的防火砖及其制备方法,通过防止砖中碳的氧化来延长砖的使用寿命。 构成:防火砖的表面涂有厚度为0.2-1.0毫米的抗氧化层,以防止碳的氧化。 抗氧化剂优选包含30-75重量份的SiO 2,6-20重量份的Na 2 O和K 2 O,10重量份的B 2 O 3或60重量份的ZrO 2,1-10重量份的Al 2 O 3和余量的不可避免的杂质。 防火砖通过用抗氧化剂涂覆表面来制备; 并在700至1500℃的温度下预热砖以通过玻璃形成玻璃相涂层膜。
    • 10. 发明授权
    • 질화알루미늄(AIN)기판의 메탈라이징(Metallizing)방법
    • 氮化铝基体金属化方法
    • KR1019960007378B1
    • 1996-05-31
    • KR1019930008309
    • 1993-05-14
    • 코스모화학 주식회사
    • 김영태지요까와유기오호리이히데끼
    • C04B35/18
    • C04B41/5138C04B41/009C04B41/88C04B41/46C04B41/5027C04B35/581
    • The aluminum nitride substrate is metallized by (A) printing and drying a molybdenum based metallizing paste on a sintered aluminum nitride, (B) forming a metallizing layer by sintering under weak reduction atmosphere, and (C) forming a metallic plated layer on the metallized layer. The sintered aluminum nitride is made of primary aluminum nitride, less than 2wt% calcium oxide and less than 8wt% yttrium oxide. And the metallizing paste is composed of 70-97wt% molybdenum, 1-10wt% manganese compound, 1-10 wt% titanium oxide, 1-10wt% silicon oxide, and 25-50wt% the organic additive mixture such as ethyl cellulose, which contains organic binder such as n-butyl carbitol actate, organic solvent, plasticizer and dispering agent, to the total amount of the solid components.
    • 通过(A)在氮化铝烧结体上印刷和干燥钼基金属化糊料,(B)通过在弱还原气氛下烧结形成金属化层,并且(C)在金属化的 层。 烧结的氮化铝由原始氮化铝,小于2重量%的氧化钙和小于8重量%的氧化钇制成。 并且金属化糊料由70-97重量%的钼,1-10重量%的锰化合物,1-10重量%的氧化钛,1-10重量%的氧化硅和25-50重量%的有机添加剂混合物如乙基纤维素组成,其中 含有正丁基卡必醇官能团,有机溶剂,增塑剂和分散剂等有机粘合剂的固体成分总量。