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    • 5. 发明公开
    • 염산용액을 이용한 폐무연솔더 재활용 방법
    • 使用氢氯酸回收无铅焊锡废料的方法
    • KR1020130060878A
    • 2013-06-10
    • KR1020110127170
    • 2011-11-30
    • 한국지질자원연구원
    • 유경근이재천정진기김민석김수경김병수
    • C22B3/10C22B15/00C22B11/00B09B3/00
    • Y02P10/234C22B3/10B09B3/00C22B11/00C22B15/00
    • PURPOSE: A method for recycling lead-free solder waste using hydrochloric acid is provided to efficiently and economically separate useful metal including tin metal from lead-free solder waste through a wet smelting process. CONSTITUTION: A method for recycling lead-free solder waste using hydrochloric acid is as follows. Solder waste is put into hydrochloric acid solution and an oxidant is supplied so that solid silver chloride is formed and precipitated by tin and the tin and copper are dissolved into ion to be mixed into the hydrochloric acid solution(10). The precipitated solid silver chloride obtained in the hydrochloric acid precipitation step and the hydrochloric acid solution in which the copper and tin are mixed are separated from each other(20,30). The copper is recovered by being separated from the hydrochloric acid solution after the solid-liquid separation step(40). An anode electrode and a cathode electrode are inserted into the hydrochloric acid solution and the tine is recovered from the hydrochloric acid solution through electrolytic withdrawal(50). [Reference numerals] (10) Hydrochloric acid precipitation step; (20) Solid-liquid separation step; (30) Silver recovery step; (40) Copper recovery step; (41) Substitution step; (42) Solid-liquid separation; (50) Tin recovery step
    • 目的:提供使用盐酸回收无铅焊料废物的方法,通过湿法冶炼工艺有效和经济地分离包括锡金属在内的有用金属与无铅焊料废料。 构成:使用盐酸回收无铅焊料废料的方法如下。 将废弃物放入盐酸溶液中,并供给氧化剂,使得由锡形成固体氯化银并沉淀,将锡和铜溶解成离子以混合到盐酸溶液(10)中。 在盐酸沉淀步骤中得到的沉淀固体氯化银和混合有铜和锡的盐酸溶液彼此分离(20,30)。 通过在固液分离步骤(40)之后与盐酸溶液分离来回收铜。 将阳极电极和阴极电极插入盐酸溶液中,并通过电解抽出从盐酸溶液回收齿(50)。 (附图标记)(10)盐酸沉淀步骤; (20)固液分离步骤; (30)银回收步骤; (40)铜回收步骤; (41)替代步骤; (42)固液分离; (50)锡回收步骤
    • 7. 发明公开
    • 알카리 용액을 이용한 폐금속 내 주석의 전해분리방법
    • 使用碱性溶液从使用金属中电解脱锡的方法
    • KR1020120138922A
    • 2012-12-27
    • KR1020110058354
    • 2011-06-16
    • 한국지질자원연구원
    • 김수경이재천정진기김병수
    • C25C1/14
    • C25C1/14
    • PURPOSE: A method for electrolytic parting of tin in waste metal using an alkali solution is provided to selectively leach and separate tin from waste metal by assigning tin-containing waste metal as an anode and precipitating tin leached from the anode at a cathode. CONSTITUTION: In a method for electrolytic parting of tin in waste metal using an alkali solution, a cathode and an anode are installed in an alkali solution to implement electrolytic parting, wherein tin-containing waste metal is used as the anode so that leached tin is precipitated at the cathode. The temperature of the alkali solution is maintained at 60-90°C during electrolytic parting.
    • 目的:提供一种使用碱溶液对废金属中的锡进行电解分离的方法,通过分配含锡废金属作为阳极并在阴极上从阳极析出锡来选择性地将锡与废金属浸出并分离。 构成:在使用碱溶液的废金属中电解分离锡的方法中,将阴极和阳极安装在碱溶液中以实施电解分离,其中使用含锡废金属作为阳极,使得浸出的锡为 在阴极沉淀。 在电解分离过程中碱溶液的温度保持在60-90℃。
    • 9. 发明公开
    • 초경합금 스크랩으로부터 텅스텐 및 코발트 회수방법
    • 从硬化金属中回收的钴和钴的回收方法
    • KR1020120055372A
    • 2012-05-31
    • KR1020100117087
    • 2010-11-23
    • 한국지질자원연구원
    • 이재천김지혜김병수김수경조순형
    • C22B7/00C22B34/36C22B23/00
    • Y02P10/234C22B7/00C22B23/00C22B34/36
    • PURPOSE: A method for recovering tungsten and cobalt from cemented tungsten carbide scraps is provided to effectively recover tungsten and cobalt by oxidizing cemented tungsten carbide scrap through calcination and dissolving tungsten using NaOH(Sodium Hydroxide). CONSTITUTION: A method for recovering tungsten and cobalt from cemented tungsten carbide scraps is as follows. Cemented tungsten carbide sludge is calcined and converted into oxides(S200). The oxidized cemented carbide scrap oxide is dissolved using NaOH solution in a dissolving reactor(S400). Undissolved residues are filtered from the dissolving reactor(S500). Acid is added to the dissolving reactor so that tungstic acid is precipitated and filtered through a filtering apparatus(S510). The undissolved residues are put into a leaching reactor so that cobalt is extracted with acid and alkaline solution is put into the leaching reactor again so that cobalt is recovered as hydroxide(S520).
    • 目的:提供一种从硬质合金碳化钨废料中回收钨和钴的方法,通过使用氢氧化钠(氢氧化钠)煅烧和溶解钨来氧化固结碳化钨废料,有效回收钨和钴。 构成:从固结碳化钨废料中回收钨和钴的方法如下。 水泥碳化钨污泥被煅烧并转化为氧化物(S200)。 氧化的硬质合金废氧化物在溶解反应器中用NaOH溶液溶解(S400)。 将未溶解​​的残余物从溶解反应器中过滤(S500)。 将酸加入溶解反应器中,使钨酸沉淀并通过过滤装置过滤(S510)。 将未溶解​​的残余物放入浸出反应器中,使钴用酸萃取,碱性溶液再次放入浸出反应器中,使钴作为氢氧化物回收(S520)。