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    • 1. 发明公开
    • 천연망간광석 촉매를 이용한 오존 제거 방법
    • 使用天然锰锰催化剂去除臭氧的方法
    • KR1020030023344A
    • 2003-03-19
    • KR1020010056506
    • 2001-09-13
    • 주식회사 매그린
    • 조성종박태성이진우강경수신창훈도동섭홍성창김동선정규철
    • B01D53/86
    • B01D53/8675B01D2255/2073B01D2255/20738B01D2257/106B01J23/34B01J23/8892B01J35/023
    • PURPOSE: A method for removing ozone using natural manganese ore catalyst having excellent catalytic activity under sever conditions is provided. CONSTITUTION: The method comprises the steps of (a) fabricating a catalyst made of natural manganese ore containing 60 to 95 wt.% of pyrolusite (β-MnO2) and 0.5 to 20 wt.% of iron oxide, wherein the catalyst contains 0.1 to 5.0 wt.% of transition metals such as Zn, Fe, Co, Ni, Cu, Au, Pt, Pd, and Rh and (b) treating air or gas containing ozone at a temperature in a range of room temperature to 200°C using the catalyst obtained in the step (a), wherein the natural manganese ore catalyst is fabricated by (a1) crushing the natural manganese ore into particles having a size of 0.1-50 micrometers, (a2) adding the transition metal to the particles, (a3) dispersing the natural manganese ore particles into water, thereby obtaining natural manganese ore slurry, and (a4) coating the natural manganese ore slurry on a structure such as pallet, saddle, cylinder and metal plate.
    • 目的:提供一种在苛刻条件下使用天然锰矿石催化剂具有优异催化活性的臭氧去除方法。 构成:该方法包括以下步骤:(a)制造由含有60〜95重量%的软锰矿(β-MnO 2)和0.5〜20重量%的氧化铁的天然锰矿制成的催化剂,其中催化剂含有0.1〜 5.0重量%的过渡金属如Zn,Fe,Co,Ni,Cu,Au,Pt,Pd和Rh,和(b)在室温至200℃的温度范围内处理含臭氧的空气或气体 使用在步骤(a)中获得的催化剂,其中天然锰矿石催化剂通过(a1)将天然锰矿石粉碎成尺寸为0.1-50微米的颗粒,(a2)将过渡金属加入到颗粒中, (a3)将天然锰矿石颗粒分散到水中,从而获得天然锰矿浆料,(a4)将天然锰矿浆料涂覆在托盘,鞍座,圆筒和金属板等结构上。
    • 2. 发明公开
    • 천연 망간광석을 이용한 망간산화물 모놀리스 허니컴 및그 제조방법
    • 通过使用天然马来西亚和单宁蜂窝蛋白制备单宁蜂窝蛋白的方法
    • KR1020040083200A
    • 2004-10-01
    • KR1020030017775
    • 2003-03-21
    • 주식회사 매그린
    • 조성종박태성강경수신창훈권준희이진우곽민호
    • B01J35/04
    • B01J37/0009B01J23/34B01J35/04B01J37/0027B01J37/08
    • PURPOSE: A monolith honeycomb having superior durability is provided to remove noxious exhaust gas components such as nitrogen oxides, sulfur oxides, carbon monoxide and volatile organic compounds contained in exhaust gas by adsorption or catalytic reaction, and a method for preparing the same is provided. CONSTITUTION: The method comprises the steps of providing manganese dust by milling pyrolusite based natural manganese ore having a principal ingredient of MnO2 to an average particle size of 5 micrometer or less; providing a clay by kneading a mixture for preparing clay comprising 70 to 95 wt.% of the manganese dust and 5 to 30 wt.% of bentonite; aging the clay by leaving the clay alone at a temperature of 1 to 30 deg.C for 1 to 3 days; providing a monolith honeycomb by molding the aged clay in a vacuum extrusion molding machine; and cutting the monolith honeycomb to a certain size, drying the cut monolith honeycomb in a microwave dryer, and firing the dried monolith honeycomb at a temperature of 400 to 500 deg.C for 1 to 5 hours.
    • 目的:提供具有优异耐用性的整体式蜂窝体,通过吸附或催化反应除去排气中含有的氮氧化物,硫氧化物,一氧化碳,挥发性有机化合物等有害废气成分,制备其制备方法。 构成方法:该方法包括以主要成分为MnO 2的研磨铁锰矿为基础的天然锰矿,平均粒径为5微米以下,提供锰粉; 通过捏合制备粘土的混合物来提供粘土,其包含70〜95重量%的锰粉和5〜30重量%的膨润土; 通过在1〜30℃的温度下单独放置粘土来老化粘土1〜3天; 通过在真空挤出成型机中成型老化的粘土提供整体式蜂窝体; 将整体蜂窝体切割成一定的尺寸,在微波干燥器中干燥切割的整料蜂窝体,并在400-500℃的温度下焙烧干燥的整料蜂窝1〜5小时。