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1. 发明公开

KR1020030023344A 천연망간광석 촉매를 이용한 오존 제거 방법 无效
标题翻译：使用天然锰锰催化剂去除臭氧的方法
公开(公告)号：KR1020030023344A
公开(公告)日：2003-03-19
申请号：KR1020010056506
申请日：2001-09-13
申请人： 주식회사 매그린
发明人： 조성종 , 박태성 , 이진우 , 강경수 , 신창훈 , 도동섭 , 홍성창 , 김동선 , 정규철
IPC分类号： B01D53/86
CPC分类号： B01D53/8675 , B01D2255/2073 , B01D2255/20738 , B01D2257/106 , B01J23/34 , B01J23/8892 , B01J35/023
摘要： PURPOSE: A method for removing ozone using natural manganese ore catalyst having excellent catalytic activity under sever conditions is provided. CONSTITUTION: The method comprises the steps of (a) fabricating a catalyst made of natural manganese ore containing 60 to 95 wt.% of pyrolusite (β-MnO2) and 0.5 to 20 wt.% of iron oxide, wherein the catalyst contains 0.1 to 5.0 wt.% of transition metals such as Zn, Fe, Co, Ni, Cu, Au, Pt, Pd, and Rh and (b) treating air or gas containing ozone at a temperature in a range of room temperature to 200°C using the catalyst obtained in the step (a), wherein the natural manganese ore catalyst is fabricated by (a1) crushing the natural manganese ore into particles having a size of 0.1-50 micrometers, (a2) adding the transition metal to the particles, (a3) dispersing the natural manganese ore particles into water, thereby obtaining natural manganese ore slurry, and (a4) coating the natural manganese ore slurry on a structure such as pallet, saddle, cylinder and metal plate.
摘要翻译：目的：提供一种在苛刻条件下使用天然锰矿石催化剂具有优异催化活性的臭氧去除方法。构成：该方法包括以下步骤：（a）制造由含有60〜95重量％的软锰矿（β-MnO 2）和0.5〜20重量％的氧化铁的天然锰矿制成的催化剂，其中催化剂含有0.1〜 5.0重量％的过渡金属如Zn，Fe，Co，Ni，Cu，Au，Pt，Pd和Rh，和（b）在室温至200℃的温度范围内处理含臭氧的空气或气体使用在步骤（a）中获得的催化剂，其中天然锰矿石催化剂通过（a1）将天然锰矿石粉碎成尺寸为0.1-50微米的颗粒，（a2）将过渡金属加入到颗粒中，（a3）将天然锰矿石颗粒分散到水中，从而获得天然锰矿浆料，（a4）将天然锰矿浆料涂覆在托盘，鞍座，圆筒和金属板等结构上。

2. 发明公开

KR1020000031268A 연속식유동층반응기에서천연망간광석을이용한황산화물및질소산화물의제거방법 失效
标题翻译：在连续流化床反应器中使用磷灰石去除硫氧化物和氮氧化物的方法
公开(公告)号：KR1020000031268A
公开(公告)日：2000-06-05
申请号：KR1019980047217
申请日：1998-11-04
申请人： 주식회사 매그린
发明人： 박태성 , 강경수 , 홍성창 , 김동원 , 정순관
IPC分类号： B01D53/60
CPC分类号： Y02A50/2344 , Y02A50/2348 , B01D53/8637 , B01D53/04 , B01D2251/2062 , B01J20/0222 , B01J23/34
摘要： PURPOSE: A method for the removal of sulfur oxides and nitrogen oxides is provided which can remove sulfur oxides and nitrogen oxides simultaneously and effectively in a single continuous fluidized-bed reactor and treat exhaust gas on a large scale, and uses pyrolusite(beta-MnO 2 ) which is very cheap due to not requiring particular processing. CONSTITUTION: The method for the removal of sulfur oxides and nitrogen oxides simultaneously comprises adsorbing sulfur oxides in exhaust gas to pyrolusite to produce sulfide of manganese, which is expressed as the following reaction formula 1, and reducing nitrogen oxides in exhaust gas by selective catalytic reduction method using said sulfide of manganese as catalyst, while using ammonia as reducing agent, which is expressed as the following reaction formula 2 and 3: (reaction formula 1), wherein Me is metal, (reaction formula 2), (reaction formula 3).
摘要翻译：目的：提供一种去除硫氧化物和氮氧化物的方法，其可以在单个连续流化床反应器中同时有效地除去硫氧化物和氮氧化物，并大量处理废气，并使用软锰矿（β-MnO 2 ），这是因为不需要特别的处理而非常便宜。构成：同时除去硫氧化物和氮氧化物的方法包括将废气中的硫氧化物吸附到软锰矿中以产生锰的硫化物，其以下列反应式1表示，并通过选择性催化还原来还原废气中的氮氧化物使用所述硫化锰作为催化剂的方法，同时使用氨作为还原剂，其表示为以下反应式2和3：（反应式1），其中Me是金属，（反应式2），（反应式3）。

3. 发明公开

KR1020040083200A 천연 망간광석을 이용한 망간산화물 모놀리스 허니컴 및그 제조방법 无效
标题翻译：通过使用天然马来西亚和单宁蜂窝蛋白制备单宁蜂窝蛋白的方法
公开(公告)号：KR1020040083200A
公开(公告)日：2004-10-01
申请号：KR1020030017775
申请日：2003-03-21
申请人： 주식회사 매그린
发明人： 조성종 , 박태성 , 강경수 , 신창훈 , 권준희 , 이진우 , 곽민호
IPC分类号： B01J35/04
CPC分类号： B01J37/0009 , B01J23/34 , B01J35/04 , B01J37/0027 , B01J37/08
摘要： PURPOSE: A monolith honeycomb having superior durability is provided to remove noxious exhaust gas components such as nitrogen oxides, sulfur oxides, carbon monoxide and volatile organic compounds contained in exhaust gas by adsorption or catalytic reaction, and a method for preparing the same is provided. CONSTITUTION: The method comprises the steps of providing manganese dust by milling pyrolusite based natural manganese ore having a principal ingredient of MnO2 to an average particle size of 5 micrometer or less; providing a clay by kneading a mixture for preparing clay comprising 70 to 95 wt.% of the manganese dust and 5 to 30 wt.% of bentonite; aging the clay by leaving the clay alone at a temperature of 1 to 30 deg.C for 1 to 3 days; providing a monolith honeycomb by molding the aged clay in a vacuum extrusion molding machine; and cutting the monolith honeycomb to a certain size, drying the cut monolith honeycomb in a microwave dryer, and firing the dried monolith honeycomb at a temperature of 400 to 500 deg.C for 1 to 5 hours.
摘要翻译：目的：提供具有优异耐用性的整体式蜂窝体，通过吸附或催化反应除去排气中含有的氮氧化物，硫氧化物，一氧化碳，挥发性有机化合物等有害废气成分，制备其制备方法。构成方法：该方法包括以主要成分为MnO 2的研磨铁锰矿为基础的天然锰矿，平均粒径为5微米以下，提供锰粉; 通过捏合制备粘土的混合物来提供粘土，其包含70〜95重量％的锰粉和5〜30重量％的膨润土; 通过在1〜30℃的温度下单独放置粘土来老化粘土1〜3天; 通过在真空挤出成型机中成型老化的粘土提供整体式蜂窝体; 将整体蜂窝体切割成一定的尺寸，在微波干燥器中干燥切割的整料蜂窝体，并在400-500℃的温度下焙烧干燥的整料蜂窝1〜5小时。

4. 发明授权

KR100302640B1 연속식유동층반응기에서천연망간광석을이용한황산화물및질소산화물의제거방법 失效
标题翻译：在连续流化床反应器中使用天然锰矿石去除硫氧化物和氮氧化物
公开(公告)号：KR100302640B1
公开(公告)日：2001-11-30
申请号：KR1019980047217
申请日：1998-11-04
申请人： 주식회사 매그린
发明人： 박태성 , 강경수 , 홍성창 , 김동원 , 정순관
IPC分类号： B01D53/60
摘要： 본 발명은 연속식 유동층 반응기에서 천연망간광석(pyrolusite, β-MnO
2 )을 이용한 황산화물과 질소산화물의 동시 제거하는 방법에 관한 것으로, 좀 더 상세하게는 배기가스중의 황산화물은 화학흡착반응 및 질소산화물은 암모니아를 환원제로 사용하여 황산화물과 천연망간광석의 화학반응에 의해서 생성된 망간황화물에 의한 선택적 촉매 환원법에 의해 연속식 유동층 반응기에서 동시에 제거하는 방법에 관한 것이다. 상기 촉매는 온도범위 300∼500℃, 체류시간 10∼40분 범위에서 배기가스중의 황산화물과 질소산화물을 단일 반응기내에서 효과적으로 동시 제거할 수 있다.

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