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    • 1. 发明专利
    • Underground fluid observation apparatus and measurement method
    • JP5453611B2
    • 2014-03-26
    • JP2007237182
    • 2007-09-12
    • 国立大学法人九州大学
    • 秀樹 水永俊昭 田中
    • G01V9/02G01V3/08G01V3/40
    • Y02A90/344
    • PROBLEM TO BE SOLVED: To provide an underground fluid observation apparatus, capable of monitoring in real time the fluid condition of a fluid which does not require installation of a standard electrode for potential measurement and can detect a streaming current with higher accuracy. SOLUTION: The underground fluid observation apparatus includes a detection part for detecting the streaming current generated by the fluid flowing underground, which is installed at predetermined sites, in an area to be measured and an analytical part for analyzing the data of the streaming current detected by this detection part and for specifying the fluid condition of the fluid, wherein the detection part includes a first potential variation detection means for detecting the variation of the electric potential between 2 points on a first virtual line passing through the detection part; a second potential variation detection means for detecting the variation of the electric potential between 2 points on a second virtual line crossing the first virtual line and passing through the detection part; and a magnetic field variation detection means for detecting the variation in the magnetic field, at the crossing part of the first virtual line and the second virtual line. COPYRIGHT: (C)2009,JPO&INPIT
    • 4. 发明专利
    • Measuring instrument and measurement method
    • 测量仪器和测量方法
    • JP2009162587A
    • 2009-07-23
    • JP2007341107
    • 2007-12-28
    • Keio Gijuku学校法人慶應義塾
    • OGAWA KUNIYASUHAISHI TOMOYUKIITO HIDEHIRA
    • G01R33/381G01N24/08G01R33/34G01R33/3875G01R33/46
    • Y02A90/344
    • PROBLEM TO BE SOLVED: To provide techniques for stably acquiring a local echo signal arising from a protic solvent in a sample using NMR method, and further, for measuring the amount of the protic solvent with high accuracy. SOLUTION: This instrument for measuring a local echo signal, arising from the protic solvent at a specific point in the sample by using the nuclear magnetic resonance method, is equipped with a static magnetic field applying part for applying a static magnetic field to the sample, a static magnetic field intensity control part for controlling the intensity of the magnetic field applied to the sample, and an RF coil for applying a vibrating magnetic field for excitation, to a part of the sample, while acquiring an echo signal corresponding to the magnetic field for excitation. A static magnetic field intensity control means causes the applying part to thereto apply a static magnetic field of a prescribed gradient magnetic field strength variation ΔG, expressed by means of an expression: 400≥D [m]×ΔG [gauss/m]×γ [Hz/T]×10 -4 [T/gauss]×τ [sec]≥4, using the inside diameter D of the RF coil, the magnetic field strength variation ΔG, the nuclear magnetogyric ratio γ of the protic solvent, and an excitation interval τ. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供用于使用NMR方法稳定地获取样品中的质子溶剂产生的局部回波信号的技术,并且还用于以高精度测量质子溶剂的量。 解决方案:用于测量由采用核磁共振法在样品中的特定点处的质子溶剂产生的局部回波信号的仪器配备有用于施加静磁场的静磁场施加部分 样品,用于控制施加到样品的磁场的强度的静态磁场强度控制部分和用于施加振动磁场用于激发的RF线圈到样品的一部分,同时获取对应于 励磁磁场。 静态磁场强度控制装置使施加部施加规定的梯度磁场强度变化量ΔG的静磁场,其表达式为:400≥D[m]×ΔG[gauss / m]×γ [Hz / T]×10 -4 [T /高斯]×τ[sec]≥4,使用RF线圈的内径D,磁场强度变化ΔG,核磁比 质子溶剂的γ和激发间隔τ。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Surface analysis method for solid sample using cp/mas nmr
    • 使用CP / MAS NMR的固体样品的表面分析方法
    • JP2008203159A
    • 2008-09-04
    • JP2007041497
    • 2007-02-21
    • Kyoto Univ国立大学法人京都大学
    • HORII FUMITAKAKUSAKA MASAFUMIKANIE YASUMASARA HARUHIRAI RYOKO
    • G01N24/08G01N24/12
    • Y02A90/344
    • PROBLEM TO BE SOLVED: To analyze a surface of a solid sample, using a CP/MAS NMR (cross polarization/magic angle rotation nuclear magnetic resonance).
      SOLUTION: The surface of the solid sample is brought into contact with a contact liquid comprising water or an organic solvent containing
      1 H, and is rotated around an axis inclined at a magic angle in a magnetostatic field. A high-frequency pulse magnetic field having a resonance frequency of
      1 H is applied thereto, the pulse magnetic field is ended to leave
      1 H magnetization of only the contact liquid, and a resonance frequency of an objective nuclide of the sample such as
      13 C,
      29 Si,
      15 N,
      31 P and the like is measured after a prescribed diffusion time t
      d lapses. The magnetization starts to get mild in both the
      1 Hs contained in the sample and the contact liquid, from a time point when the pulse magnetic field is stopped, and a relaxation time is longer in the
      1 H of the contact liquid. A
      1 H spin of the contact liquid thereby diffuses gradually from the surface to the sample contacting therewith, after the
      1 H contained in the sample is relaxed. The magnetization transfers from the
      1 H to the nuclide such as
      13 C in the sample, in a diffusion process therein. The surface of the solid sample is structure-analyzed by measuring the diffusion process of the
      1 H spin as
      13 C NMR.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:使用CP / MAS NMR(交叉极化/魔角旋转核磁共振)分析固体样品的表面。 解决方案:将固体样品的表面与包含水或含有 1 H的有机溶剂的接触液体接触,并且以静态倾斜的魔角旋转 领域。 具有谐振频率为 1 H的高频脉冲磁场施加到其上,脉冲磁场结束,使得仅接触液体的 1 H磁化, 样品的目标核素的共振频率,例如 13,SP 30,SP 30,SP 30, 在经过规定的扩散时间t S之后测量P等。 从脉冲磁场停止的时间点起,样品和接触液体中的 1 Hs的磁化开始变得温和,在 1 H接触液体。 在样品中包含的 1 H之后,接触液体的 1 H自旋从表面逐渐扩散到与其接触的样品。 在其中的扩散过程中,磁化从样品中的 1 H转移到样品中的核素,例如 13 C。 通过测量 1 H自旋的扩散过程,固体样品的表面进行结构分析。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Ground improving method and ground improving device
    • 地面改良方法及改善地面设备
    • JP2006030145A
    • 2006-02-02
    • JP2004213711
    • 2004-07-22
    • Mikio Mizushima幹夫 水島
    • MIZUSHIMA MIKIO
    • G01V3/00
    • Y02A90/344
    • PROBLEM TO BE SOLVED: To provide a ground improving method and a ground improving device for modifying effectively the direction of an underground wave. SOLUTION: This ground improving method for measuring a magnetic field generated from the ground (step 1) and modifying the direction of the magnetic field based on a measurement result includes an earth/puncture piercing process (step S6, S14) for modifying the direction of the magnetic field by piercing an earth/puncture approximately vertically into the ground; an energy disk burying process (step S16) for burying an energy disk for modifying the direction of the magnetic field into the ground; a soil conditioner scattering process (step S7, S18) for scattering a soil conditioner (mineral element) for modifying the direction of the magnetic field on the surface of the ground; and a active water spraying process (step S10, S20) for modifying the direction of the magnetic field by scattering bamboo charcoal for modifying the direction of the magnetic field on the surface of the ground G (step S8) and by spraying active water from above the soil conditioner, and for allowing the soil conditioner to penetrate underground. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种用于有效地改变地下波的方向的地面改进方法和地面改进装置。 解决方案:用于测量从地面产生的磁场(步骤1)和基于测量结果修改磁场方向的这种地面改进方法包括用于修改的地球穿刺穿孔过程(步骤S6,S14) 通过大致垂直地穿入地面/穿刺进入地面的磁场的方向; 能量盘埋入处理(步骤S16),用于将用于修改磁场方向的能量盘埋入地下; 用于将土壤调理剂(矿物元素)散布以改变地面表面上的磁场方向的土壤调节剂散射过程(步骤S7,S18) 以及通过散射竹炭来改变地面G的表面上的磁场方向来改变磁场方向的活性喷水方法(步骤S10,S20)(步骤S8),并且通过从上方喷射活性水 土壤调理剂,并使土壤调理剂渗透到地下。 版权所有(C)2006,JPO&NCIPI