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    • 1. 发明专利
    • Deposition method
    • 沉积方法
    • JP2013258383A
    • 2013-12-26
    • JP2012135150
    • 2012-06-14
    • Tokyo Electron Ltd東京エレクトロン株式会社
    • IKEGAWA HIROAKIUENISHI MASAHIKOISE MASAYUKIOGAWA ATSUSHI
    • H01L21/31C23C16/455H01L21/316
    • H01L21/0262C23C16/40C23C16/402C23C16/403C23C16/405C23C16/45519C23C16/45551H01L21/68764
    • PROBLEM TO BE SOLVED: To enable a sufficient reaction between at least two reaction gases reacting with each other in a deposition method of depositing a reaction product of the two reaction gases on a substrate by alternately supplying the at least two reaction gases to the substrate.SOLUTION: A deposition method comprises: a step of supplying a first reaction gas from a first gas supply part to a first processing region and a second reaction gas which can react with the first reaction gas from a second gas supply part to a second processing region while separating the first processing region and the second processing region by supplying a separation gas from a separation gas supply part with rotating a rotary table; and a step of supplying the second reaction gas from the second gas supply part to the second processing region for a predetermined time period without supplying the reaction gas from the first gas supply part while separating the first processing region and the second processing region by supplying the separation gas from the separation gas supply part with rotating the rotary table.
    • 要解决的问题:为了使至少两个反应气体之间发生充分的反应,在沉积方法中,通过交替地将至少两种反应气体提供给基底将两种反应气体的反应产物沉积在基底上。 解决方案:沉积方法包括:将第一反应气体从第一气体供应部分供应到第一处理区域的第二反应气体和可以与第一反应气体从第二气体供应部件反应到第二处理区域的第二反应气体 同时通过从分离气体供应部分提供旋转旋转台的分离气体来分离第一处理区域和第二处理区域; 以及从第二气体供给部向第二处理区域供给第二反应气体达预定时间的步骤,而不会从第一气体供给部分供给反应气体,同时分离第一处理区域和第二处理区域, 分离气体从分离气体供应部分旋转旋转台。
    • 3. 发明专利
    • Deposition method
    • 沉积方法
    • JP2014140018A
    • 2014-07-31
    • JP2013237216
    • 2013-11-15
    • Tokyo Electron Ltd東京エレクトロン株式会社
    • IKEGAWA HIROAKIUENISHI MASAHIKOTAKAHASHI HIROSUKEOI MASATOOGAWA ATSUSHI
    • H01L21/316C23C16/34C23C16/40C23C16/455H01L21/31H01L21/318
    • H01L21/0228C23C16/45551C23C16/4584H01L21/02148H01L21/02164H01L21/02178H01L21/02189H01L21/02194H01L21/022H01L21/68764H01L21/68771
    • PROBLEM TO BE SOLVED: To provide a deposition method which can uniformly stack an oxide film or a nitride film of a laminated structure on a plurality of substrates.SOLUTION: A deposition method using a deposition apparatus including a rotary table capable of loading a plurality of substrates, a first gas supply part and a second gas supply part comprises: a first step of supplying an oxidation gas from the first and second gas supply parts to rotate the rotary table; a second step of supplying a first reaction gas containing a first element from the first gas supply part and supplying an oxidation gas from the second gas supply part to rotate the rotary table to deposit a first oxide film containing the first element on a substrate; a third step of supplying the oxidation gas from the first and second gas supply parts to rotate the rotary table; and a fourth step of supplying a second reaction gas containing a second element from the first gas supply par and supplying the oxidation gas from the second gas supply part to rotate the rotary table to deposit a second oxide film containing the second element on the substrate.
    • 要解决的问题:提供一种能够在多个基板上均匀地堆叠层叠结构的氧化物膜或氮化物膜的沉积方法。解决方案:使用包括能够加载多个基板的旋转台的沉积设备的沉积方法 基板,第一气体供应部分和第二气体供应部分包括:第一步骤,从第一和第二气体供应部分供应氧化气体以旋转旋转台; 第二步骤,从第一气体供应部分供应含有第一元素的第一反应气体,并从第二气体供应部分供应氧化气体以旋转旋转台,以将含有第一元素的第一氧化膜沉积在基底上; 第三步骤,从第一和第二气体供应部分提供氧化气体以旋转旋转台; 以及第四步骤,从第一气体供应装置供应含有第二元素的第二反应气体,并从第二气体供应部分供应氧化气体,以旋转旋转台,以将含有第二元素的第二氧化物膜沉积在基板上。
    • 4. 发明专利
    • Film deposition method
    • 膜沉积法
    • JP2014125653A
    • 2014-07-07
    • JP2012283175
    • 2012-12-26
    • Tokyo Electron Ltd東京エレクトロン株式会社
    • OSHITA KENTAROOI MASATOSASAKI HIROKOIKEGAWA HIROAKI
    • C23C16/44C23C16/34C23C16/455H01L21/28H01L21/285
    • H01L21/0228C23C16/34C23C16/4404C23C16/45551H01L21/28556H01L21/32051H01L21/68764H01L21/68771H01L21/76841
    • PROBLEM TO BE SOLVED: To provide a film deposition method which can reduce metallic contamination in a case of deposition even under a high temperature condition.SOLUTION: In a film deposition method using an ALD method, in which a substrate W is passed through a first and a second treatment regions P1, P2 to which different types of gases which react to each other are supplied by rotating a turntable 2 capable of loading the substrate W on a substrate loading part 24, the flim deposition method includes steps of: a coating step where the turntable is rotated without loading the substrate on the substrate loading part, and in a state that the substrate loading part is set to a predetermined temperature, film deposition is performed on the turntable; and a processing step where the substrate is loaded on the substrate loading part, the turntable is rotated, and in a state that the substrate loaded part or the substrate is set to the predetermined temperature or lower, film deposition is performed on the substrate.
    • 要解决的问题:提供即使在高温条件下也可以减少沉积的情况下的金属污染的成膜方法。解决方案:在使用ALD法的成膜方法中,其中基板W通过第一 以及通过使能够将基板W载置在基板载置部24上的转盘2旋转而供给彼此反应的不同种类的气体的第二处理区域P1,P2包括以下步骤:涂布步骤 其中转盘旋转而不将基板载载在基板装载部分上,并且在基板装载部分被设定在预定温度的状态下,在转台上进行薄膜沉积; 以及处理步骤,其中将基板装载在基板装载部上,转台旋转,并且在基板装载部或基板被设定在规定温度以下的状态下,在基板上进行成膜。
    • 5. 发明专利
    • Ozone production method, ozone production apparatus, method and apparatus for ozone treatment
    • 臭氧生产方法,臭氧生产装置,臭氧处理方法和装置
    • JP2005047766A
    • 2005-02-24
    • JP2003283134
    • 2003-07-30
    • Tokyo Electron Ltd東京エレクトロン株式会社
    • UMEHARA TAKAHITOHASEBE KAZUHIDEIKEGAWA HIROAKIUMEKI MAKOTOTOMITA MASAHIKO
    • C01B13/11
    • PROBLEM TO BE SOLVED: To suppress the production of metal impurities and to stably produce a large flow amount of ozone in a high concentration.
      SOLUTION: A heat treatment apparatus 1 has an ozone production apparatus 21 and a control section 100. The ozone production apparatus 21 has an ozonator 22 for producing ozone, a raw material gas feeding source 25 connected to the ozonator 22 through a raw material gas feeding pipe 23, and an additive gas feeding source 26 connected to the ozonator 22 through an additive gas feeding pipe 24. In the raw material gas feeding pipe 23 and the additive gas feeding pipe 24, MFC 27 and 28 are provided, respectively. The control section 100 controls the MFC 27 so as to feed the raw material gas to the ozonator 22 in a rate of at least 10 L/min and controls the MFC 28 so as to feed the additive gas in such a rate that the concentration of the additive gas becomes 0.1-200 ppm in the raw material gas fed in a feeding rate of 10 L/min.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了抑制金属杂质的产生并且稳定地产生高浓度的大量臭氧流量。 解决方案:热处理装置1具有臭氧生成装置21和控制部100.臭氧生成装置21具有用于产生臭氧的臭氧发生器22,原料气体供给源25通过原料连接到臭氧发生器22 原料气体供给管23和通过添加气体供给管24与臭氧发生器22连接的添加气体供给源26.在原料气体供给管23和添加气体供给管24中,分别设有MFC27,28 。 控制部100控制MFC27,以至少10L /分钟的速度将原料气体供给至臭氧发生器22,并控制MFC28,以使加料气体的浓度为 原料气体以10升/分钟的速度供给,添加气体成为0.1〜200ppm。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • Deposition method
    • 沉积方法
    • JP2014017354A
    • 2014-01-30
    • JP2012153407
    • 2012-07-09
    • Tokyo Electron Ltd東京エレクトロン株式会社
    • IKEGAWA HIROAKIUENISHI MASAHIKOOGAWA ATSUSHI
    • H01L21/316C23C16/455H01L21/31
    • H01L21/76C23C16/40C23C16/45531H01L21/02178H01L21/02189H01L21/02194H01L21/02274H01L21/0228H01L21/67748H01L21/68764H01L21/68771
    • PROBLEM TO BE SOLVED: To improve composition controllability of a metallic compound.SOLUTION: A deposition method comprises: a first deposition step of depositing a first metal compound film by performing a cycle of exposing a substrate to a first material gas containing a first metal and exposing the substrate to a reaction gas that reacts with the first material gas one and more times; an adsorption step of adsorbing the first metal to the first metallic compound film by exposing the substrate on which the first metallic compound film is deposited, to the first material gas; and a second deposition step of depositing a second metallic compound film on the substrate by performing a cycle of exposing the substrate to which the first metal is adsorbed, to a second material gas containing a second metal and exposing the substrate to a reaction gas that reacts with the second material gas one and more times.
    • 要解决的问题:提高金属化合物的组成可控性。解决方案:沉积方法包括:第一沉积步骤,通过执行将基底暴露于含有第一金属的第一材料气体的循环来沉积第一金属化合物膜;以及 将基板暴露于与第一原料气体反应一次或多次的反应气体; 吸附步骤,通过将沉积有第一金属化合物膜的基板暴露于第一材料气体而将第一金属吸附到第一金属化合物膜上; 以及第二沉积步骤,通过执行使第一金属被吸附的基底曝光的循环,将第二金属化合物膜沉积在第二金属化合物膜上,从而将第二材料气体暴露于反应气体,反应气体 与第二材料气一次多次。
    • 9. 发明专利
    • Manufacturing method for semiconductor device, film-forming apparatus, and memory medium
    • 半导体器件的制造方法,成膜装置和存储介质
    • JP2005159316A
    • 2005-06-16
    • JP2004304638
    • 2004-10-19
    • Tokyo Electron Ltd東京エレクトロン株式会社
    • NAKAJIMA SHIGERUSAI TOKINFUJIWARA TOMONORIIKEGAWA HIROAKINAKAMURA MOTOSHI
    • H01L21/316H01L29/78
    • PROBLEM TO BE SOLVED: To provide a manufacturing method for a semiconductor device, in which, for example, a polysilicon electrode is formed on a hafnium compound film which is effective as a highly dielectric film for a gate insulating film of a MOSFET or the like, and flatband voltage shift of the semiconductor device is suppressed. SOLUTION: In a depressurized and heated atmosphere, hafnium organic compound steam is made to react on, for example, disilane gas in a reaction vessel in order to form a hafnium silicate film on a silicon film. Dichlorosilane gas and dinitrogen oxide gas are made to react on the hafnium silicate film, in order to form a silicon oxide film laminated on the hafnium silicate film as a barrier layer. A polysilicon film which becomes a gate electrode is formed on the silicon oxide film. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决的问题:提供一种半导体器件的制造方法,其中例如在铪化合物膜上形成多晶硅电极,该铪化合物膜作为用于MOSFET的栅极绝缘膜的高电介质膜是有效的 并且半导体器件的平带电压偏移被抑制。 解决方案:在减压和加热的气氛中,使铪有机化合物蒸汽在例如反应容器中的乙硅烷气体上反应,以在硅膜上形成硅酸铪膜。 使二氯硅烷气体和二氧化氮气体在硅酸铪膜上反应,以形成层叠在硅酸铪膜上作为阻挡层的氧化硅膜。 在氧化硅膜上形成成为栅电极的多晶硅膜。 版权所有(C)2005,JPO&NCIPI