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    • 9. 发明专利
    • PRODUCTION OF TIN FREE STEEL SHEET FOR WELDED CAN
    • JPH03180486A
    • 1991-08-06
    • JP31827089
    • 1989-12-07
    • KAWASAKI STEEL CO
    • SATO TOSHIOSATO SATORUHIMENO MAKOTOKOKADO FUMIO
    • C25D11/38C25D5/26
    • PURPOSE:To produce a tin free steel sheet excellent in weldability and corrosion resistance after coating by applying Cr plating treatment twice to the surface of a steel sheet by the use of Cr -containing plating bath while performing anodic treatment between the above Cr plating stages, carrying out initial small current treatment and then cathodic treatment, and forming a Cr oxide film. CONSTITUTION:After the surface of a cold rolled steel sheet is cleaned, this steel sheet is subjected to Cr plating in a CrO3-containing plating bath, to anodic treatment, and further to Cr plating again, by which a metallic Cr plating layer is formed by 10-150mg/m coating weight. Subsequently, the above steel sheet is subjected, if necessary, to anodic treatment again and is then subjected to initial small current treatment similarly in a plating bath consisting of a Cr - containing aqueous solution of CrO3, e.g. at 0.1-6A/dm current density and successively to cathodic treatment at ordinary current value, by which a Cr oxide film is formed by 3-30mg/m coating weight on the metallic Cr plating layer. By this method, the tin free steel sheet for welded cans excellent in corrosion resistance after coating as well as in weldability can be produced.