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1. 发明专利

JP2005314712A Composition for forming metal particulate and metal particulate 审中-公开
标题翻译：用于形成金属颗粒和金属颗粒的组合物
公开(公告)号：JP2005314712A
公开(公告)日：2005-11-10
申请号：JP2004130750
申请日：2004-04-27
申请人： Osaka City , Osaka Gas Co Ltd , 大阪市 , 大阪瓦斯株式会社
发明人： FUJIKI TAKESHI , KAWASAKI SHINICHI , MURASE HIROAKI , SAKAMOTO HIRONORI , TANAKA MASASHI , MATSUKAWA KOYO , MATSUURA YUKITO
IPC分类号： B01J19/12 , B22F1/00 , B22F9/24 , C08K3/10 , C08L83/16 , C09D5/24 , C09D7/12 , C09D183/14 , C09D183/16
摘要： PROBLEM TO BE SOLVED: To provide a composition with which metal particulate (particularly, metal nanoparticle) can be easily and efficiently formed at high reducibility. SOLUTION: The composition is composed of: a polysilane compound; and a metal compound (e.g., a noble metal compound) capable of forming the metal particulate by reduction. The polysilane compound may be a copolymer of polysilane and a vinyl monomer comprising a unit having affinity for the metal compound and/or metal particulate. The ratio of the metal compound may be, e.g., about 1 to 40 pts.wt. to 100 pts.wt. of the polysilane compound. By allowing active energy rays to act on the composition, the polysilane compound is decomposed, thus the metal particulate (particularly, nanoparticle) can be formed. The method can be applied to various methods, and, e.g., it is also possible that the composition is applied to a substrate, so as to be exposed to form metal particulate, and further, development is performed, thus a metal particulate-containing pattern is formed. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供可以以高还原性容易且有效地形成金属颗粒（特别是金属纳米颗粒）的组合物。该组合物由聚硅烷化合物组成; 以及能够通过还原形成金属颗粒的金属化合物（例如，贵金属化合物）。聚硅烷化合物可以是聚硅烷和乙烯基单体的共聚物，其包含对金属化合物和/或金属颗粒具有亲和性的单元。金属化合物的比例可以是例如约1至40重量份。到100磅的聚硅烷化合物。通过允许活性能量射线作用于组合物，聚硅烷化合物被分解，因此可以形成金属颗粒（特别是纳米颗粒）。该方法可以应用于各种方法，例如，也可以将组合物施加到基材上，以暴露于形成金属颗粒，进一步进行显影，从而形成含金属颗粒的图案形成了。版权所有（C）2006，JPO＆NCIPI

2. 发明专利

JP2005314692A Photo-polymerizable resin composition and its cured product 有权
标题翻译：光聚合树脂组合物及其固化产品
公开(公告)号：JP2005314692A
公开(公告)日：2005-11-10
申请号：JP2005104051
申请日：2005-03-31
申请人： Osaka City , Osaka Gas Co Ltd , 大阪市 , 大阪瓦斯株式会社
发明人： MURASE HIROAKI , KAWASAKI SHINICHI , FUJIKI TAKESHI , YAMADA MITSUAKI , MATSUKAWA KOYO , MATSUURA YUKITO , MOTOKAWA TAKUYA
IPC分类号： C08G59/24
摘要： PROBLEM TO BE SOLVED: To provide a photo-polymerizable resin composition which has high adhesiveness to substrates and can produce cured products having excellent mechanical characteristics (hardness, heat resistance, and the like) and excellent optical characteristics such as high transparency and a high refractive index. SOLUTION: This photo-polymerizable resin composition comprises a fluorene skeleton-having epoxy resin [for example, a 9,9-bis(monohydroxyphenyl)fluorene diglycidyl ether, a 9,9-bis(monohydroxyphenyl)fluorene 2-4C alkylene oxide diglycidyl ether, or the like], an alkoxysilane and a photo acid generator. The alkoxysilane may be an aryltrialkoxysilane, an epoxy group-having trialkoxysilane, a tetraalkoxysilane, an alkoxysilane condensation product, or the like. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种对基材具有高粘合性并且可以生产具有优异的机械特性（硬度，耐热性等）的固化产物和优异的光学特性（如高透明度和高透光性）的光聚合性树脂组合物，高折射率。解决方案：该可光聚合树脂组合物包含具有芴骨架的环氧树脂[例如9,9-双（一羟基苯基）芴二缩水甘油醚，9,9-双（一羟基苯基）芴2-4C亚烷基氧化二缩水甘油醚等]，烷氧基硅烷和光酸发生剂。烷氧基硅烷可以是芳基三烷氧基硅烷，具有三烷氧基硅烷的环氧基，四烷氧基硅烷，烷氧基硅烷缩合产物等。版权所有（C）2006，JPO＆NCIPI

3. 发明专利

JP2017082188A 修飾セルロース微細繊維及びその製造方法有权
公开(公告)号：JP2017082188A
公开(公告)日：2017-05-18
申请号：JP2016082445
申请日：2016-04-15
申请人：大阪瓦斯株式会社 , Osaka Gas Co Ltd
发明人： YAMADA MASAHIRO , SUGIMOTO MASAYUKI , MURASE HIROAKI , RIN RENTEI , MARUTA AYAKO
IPC分类号： C08B3/12 , D06M13/184
摘要：【課題】ナノサイズで結晶化度が高く、繊維形状の損傷が少なくてアスペクト比が大きく、且つ有機溶媒への分散性が優れた修飾セルロース微細繊維を、機械的に破砕することなく、簡便かつ効率良く生産する。【解決手段】塩基触媒又は酸触媒を含む触媒と二塩基カルボン酸無水物を含む反応性解繊液をセルロースに浸透させて、セルロースをエステル化して化学解繊し、カルボキシル基含有セルロース微細繊維を得る修飾解繊工程を経て修飾セルロース微細繊維を製造する。前記触媒はピリジン類であってもよい。前記反応性解繊液は、さらにドナー数25以上の非プロトン性溶媒を含んでいてもよい。前記二塩基カルボン酸無水物は脂肪族ジカルボン酸無水物であってもよい。前記カルボキシル基含有セルロース微細繊維は、カルボキシル基に対する反応性基及び9,9−位にアリール基を有するフルオレン化合物とさらに反応させてもよい。【選択図】なし

4. 发明专利

JP2014040615A Fluorene-based composition and molded product of the same 有权
标题翻译：基于氟的组合物及其成型产品
公开(公告)号：JP2014040615A
公开(公告)日：2014-03-06
申请号：JP2013252383
申请日：2013-12-05
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , KAWASAKI SHINICHI , MURASE HIROAKI , FUJIKI TAKESHI , SAKAMOTO HIROKI , SAKAMOTO KANA , TANAKA MASASHI , HIGASHIYAMA MASARU , YAMADA MITSUAKI , SUDA YASUHIRO
IPC分类号： C08L101/02 , C08K3/04
摘要： PROBLEM TO BE SOLVED: To provide a fluorene-based composition excellent in dispersibility of an additive and capable of making the additive exhibit the function by mixing of a small amount of the additive, and to provide a molded product of the fluorene-based composition.SOLUTION: A fluorene-based composition containing a compound represented by the formula (I) or a derivative thereof and additives is manufactured and a molded product is formed from the composition, where Xand Xare same or different, and represent a hydroxyl group, a -O(AO)H group, where A represents a Calkylene group and p represents an integer of 1 or more, an amino group or a N-mono substituted amino group, Rto Rare same or different, and represent a non-reactive group, m1 and m2 are same or different and integers of 0 or 1 to 3, m1+m2=an integer of 1 to 6, n1 to n4 are same or different and integers of 0 to 4, m1+n1 and m2+n2 are integers of 0 to 5.
摘要翻译：要解决的问题：提供一种添加剂分散性优异且能够使添加剂通过混合少量添加剂而具有功能的芴类组合物，并提供芴系组合物的成型体。解决方案：制备含有式（I）表示的化合物或其衍生物和添加剂的芴基组合物，并且由X和X相同或不同并且表示羟基的组合物形成模塑产品， O（AO）H基，其中A表示亚烷基，p表示1以上的整数，氨基或N-单取代氨基，R〜R可相同或不同，表示非反应性基团，m1 和m2相同或不同，整数为0或1〜3，m1 + m2 = 1〜6的整数，n1〜n4相同或不同，0〜4，m1 + n1，m2 + n2的整数为 0到5。

5. 发明专利

JP2014028806A Alcohol having fluorene skeleton 审中-公开
标题翻译： ALCOHOL有FLUENENE SKELETON
公开(公告)号：JP2014028806A
公开(公告)日：2014-02-13
申请号：JP2013155889
申请日：2013-07-26
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： OSAWA SHINGO , MIYAUCHI SHINSUKE , NAGASHIMA TAICHI , KAWASAKI SHINICHI , MURASE HIROAKI
IPC分类号： C07C41/16 , C07C43/23
摘要： PROBLEM TO BE SOLVED: To provide a novel alcohol having a fluorene skeleton, which can satisfy both improvement in heat resistance and reduction in melt viscosity, reduce a flexural modulus at high temperature and maintain optical transparency even after curing, and which has excellent handleability despite the presence of a 9,9-bis(condensed polycyclic aryl)fluorene skeleton (a 9,9-bis(naphthyl)fluorene skeleton and the like).SOLUTION: The alcohol is a compound represented by the following formula. (Ring Z represents a condensed polycyclic aromatic hydrocarbon ring; Rrepresents a substituent such as an alkyl group; Rrepresents an alkylene group; Rrepresents a substituent such as a hydrocarbon group and an alkoxy group).
摘要翻译：要解决的问题：为了提供具有芴骨架的新型醇，能够同时满足耐热性的提高和熔融粘度的降低，即使在固化后也能够降低高温下的弯曲弹性模量，并且即使在固化后也具有优异的操作性 9,9-双（缩合多环芳基）芴骨架（9,9-双（萘基）芴骨架等）的存在。溶液：醇是下式表示的化合物。（环Z表示稠合多环芳烃环; R表示取代基，例如烷基; R表示亚烷基; R表示取代基，例如烃基和烷氧基）。

6. 发明专利

JP2013139588A Thermosetting resin composition and cured product thereof 有权
标题翻译：热固性树脂组合物及其固化产品
公开(公告)号：JP2013139588A
公开(公告)日：2013-07-18
申请号：JP2013091013
申请日：2013-04-24
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MURASE HIROAKI , MIYAUCHI SHINSUKE , YAMADA MASAHIRO
IPC分类号： C08G59/24 , C08G8/04
摘要： PROBLEM TO BE SOLVED: To obtain a thermosetting resin composition excellent in heat resistance and etching resistance.SOLUTION: There is disclosed a thermosetting resin composition composed of a phenol resin having phenol components consisting of fluorenes having a phenolic hydroxy group and phenols, and having ≥2,000 weight-average molecular weight and an epoxy compound having a fluorene backbone. The phenol resin may be a condensate obtained by condensing the methylol form of the fluorenes having the phenolic hydroxy group with the phenols in the presence of an acid catalyst. In the epoxy compound having the fluorene backbone, 9,9-bis(glycidyloxyphenyl)fluorene, 9,9-bis(mono- or di-Calkylglycidyloxyphenyl)fluorene, 9,9-bis(glycidyloxynaphthyl)fluorene, and their adducts with a Calkyleneoxide, etc., are included.
摘要翻译：要解决的问题：获得耐热性和耐蚀刻性优异的热固性树脂组合物。解决方案：公开了一种热固性树脂组合物，其由具有酚羟基的芴和苯酚的苯酚组分的酚醛树脂组成，并且具有≥ 2,000重均分子量和具有芴骨架的环氧化合物。酚醛树脂可以是在酸催化剂的存在下将具有酚羟基的芴的羟甲基形式与苯酚缩合得到的缩合物。在具有芴骨架的环氧化合物中，9,9-双（缩水甘油氧基苯基）芴，9,9-双（单 - 或二 - 烷基缩水甘油氧基苯基）芴，9,9-双（缩水甘油氧基萘基）芴及其与环氧烷烃等等。

7. 发明专利

JP2013136767A Urethane (meth)acrylate having fluorene skeleton, and cured material thereof 有权
标题翻译：具有氟橡胶的URETHANE（METH）丙烯酸酯及其固化材料
公开(公告)号：JP2013136767A
公开(公告)日：2013-07-11
申请号：JP2013029658
申请日：2013-02-19
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , YAMADA MASAHIRO , MURASE HIROAKI , KAWASAKI SHINICHI , SAMURA TETSUYA , MORI RIE , HANASAKA FUMIHIRO
IPC分类号： C08G18/67 , C08F299/06
CPC分类号： G11B7/245
摘要： PROBLEM TO BE SOLVED: To provide a novel urethane (meth)acrylate having a fluorene skeleton excellent in heat resistance and the like.SOLUTION: The urethane (meth)acrylate is obtained using as reaction components a compound having a specific fluorene skeleton [for example, 9,9-bis(mono- or di-Calkyl-hydroxy(poly)Calkoxyphenyl)fluorene, 9,9-bis(mono- or di-Caryl-hydroxy(poly)Calkoxyphenyl)fluorene, 9,9-bis(hydroxyl(poly)Calkoxynaphthyl)fluorene, and the like], a polyisocyanate compound, an a (meth)acrylic compound having a reactive group with an isocyanate group (for example, a hydroxyalkyl (meth)acrylate and the like).
摘要翻译：要解决的问题：提供具有耐热性等优异的芴骨架的新型氨基甲酸酯（甲基）丙烯酸酯。溶液：使用具有特定芴骨架的化合物作为反应成分得到氨基甲酸酯（甲基）丙烯酸酯[例如，9,9-双（单 - 或二-C烷基 - 羟基（聚）Calkoxyphenyl）芴，9,9-双（单或二 - 羧基 - 羟基（聚）Calkoxyphenyl）芴，9,9-双（聚）烷氧基萘基）芴等]，多异氰酸酯化合物，具有异氰酸酯基的反应性基团的（甲基）丙烯酸化合物（例如（甲基）丙烯酸羟烷基酯等）。

8. 发明专利

JP2012041561A Fluorene-based composition and molded product of the same 有权
标题翻译：基于氟的组合物及其成型产品
公开(公告)号：JP2012041561A
公开(公告)日：2012-03-01
申请号：JP2011262825
申请日：2011-11-30
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , KAWASAKI SHINICHI , MURASE HIROAKI , FUJIKI TAKESHI , SAKAMOTO HIRONORI , SAKAMOTO KANA , TANAKA MASASHI , HIGASHIYAMA MASARU , YAMADA MITSUAKI , SUDA YASUHIRO
IPC分类号： C08L67/00 , C08G18/32 , C08G63/197 , C08G64/04 , C08K3/04 , C08L69/00 , C08L75/04
摘要： PROBLEM TO BE SOLVED: To obtain a fluorene-based composition having excellent diepersibility of an additive and capable of making the additive exhibit its function, by mixing a small amount of a fluorene compound into the composition, and to obtain a molded product of the same.SOLUTION: The fluorene-based composition including a compound expressed by formula (I) or its derivative and the additive is prepared. The molded product is formed by using the composition. In the formula, Xand Xare the same or different and are each a hydroxy group, -O(AO)H, (wherein A denotes a 2-3C alkylene group; and p denotes an integer of at least 1), an amino group or an N-monosubstituted amino group; Rto Rare the same or different and are each a nonreactive group; m1 and m2 are the same or different and are each 0 or an integer of 1 to 3, and (m1+m2) is an integer of 1 to 6; and n1 to n4 are the same or different and are each an integer of 0 to 4, provided that (m1+n1) and (m2+n2) are each an integer of 0 to 5.
摘要翻译：要解决的问题：为了获得具有优异的添加剂双相性并且能够使添加剂显示其功能的芴基组合物，通过将少量的芴化合物混合到组合物中，并获得模塑产品一样的。解决方案：制备包含由式（I）表示的化合物或其衍生物和添加剂的基于芴的组合物。通过使用该组合物形成模塑产品。在该式中，X 1 和X 2 相同或不同，各自为羟基，-O（AO） H（其中A表示2-3C亚烷基; p表示至少为1的整数），氨基或N-单取代的氨基; R 1 到R 4 是相同或不同的，每个都是非反应组; m1和m2相同或不同，分别为0或1〜3的整数，（m1 + m2）为1〜6的整数。并且n1〜n4相同或不同，并且各自为0〜4的整数，条件是（m1 + n1）和（m2 + n2）各自为0〜5的整数。版权所有（C）2012 ，JPO＆INPIT

9. 发明专利

JP2011162792A Purifying method of polysilane 有权
标题翻译：多晶硅的净化方法
公开(公告)号：JP2011162792A
公开(公告)日：2011-08-25
申请号：JP2011092230
申请日：2011-04-18
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： SAKAMOTO HIRONORI , MURASE HIROAKI , FUJIKI TAKESHI
IPC分类号： C08G77/60
摘要： PROBLEM TO BE SOLVED: To provide a purifying method capable of efficiently removing metallic components preliminarily contained in a polysilane. SOLUTION: The purifying method of polysilane is carried out by bringing the polysilane containing the metallic components (1) (for example, polysilane containing ≥500 ppm metallic components (1)) into contact with a metallic component (2) constituted of a metal (b) (for example, iron, cobalt, nickel, copper or the like) having ionization tendency smaller than that of a metal (a) (for example, zinc or the like) constituting the metallic components (1). In such a method, the ratio of the metallic component (1) and the metallic component (2) expressed in terms of weight of the metal (a) and the metal (b) is ≤100 ppm per total quantity. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供能够有效地除去预先包含在聚硅烷中的金属成分的净化方法。解决方案：通过使含有金属组分（1）（例如含有≥500ppm金属组分（1）的聚硅烷）的聚硅烷与由金属组分（1）构成的金属组分（2）接触来进行聚硅烷的纯化方法，电离倾向小于构成金属成分（1）的金属（a）（例如锌等）的金属（b）（例如铁，钴，镍，铜等）。在这种方法中，以金属（a）和金属（b）的重量计，金属组分（1）和金属组分（2）的比例相对于总量为≤100ppm。版权所有（C）2011，JPO＆INPIT

10. 发明专利

JP2011042596A New heterocycle-containing compound having fluorene skeleton and method for producing the same 有权
标题翻译：具有荧光素的新的含有异氰酸酯的化合物及其生产方法
公开(公告)号：JP2011042596A
公开(公告)日：2011-03-03
申请号：JP2009190444
申请日：2009-08-19
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , MIYAUCHI SHINSUKE , NAGASHIMA TAICHI , MURASE HIROAKI , KAWASAKI SHINICHI , SHIBAHARA TETSUYA , KITAJIMA SATSUKI , HANASAKA FUMIHIRO , SATO MASAHIRO
IPC分类号： C07D213/73 , C07D213/80 , C07D307/68 , C07D333/40
摘要： PROBLEM TO BE SOLVED: To provide a new heterocycle-containing compound having a fluorene skeleton and usable as a raw material or the like for a resin excelling in heat resistance or the like. SOLUTION: The heterocycle-containing compound is represented by formula (1) (wherein, ring Ar is an aromatic hydrocarbon ring; ring Het is a heterocycle; R 1 is cyano or the like; R 2 and R 3 are each hydrocarbon or the like; A 1 is alkylene; A 2 is a direct bond or aliphatic hydrocarbon; X is a reactive group, a derivative thereof or a precursor thereof; k is an integer of 0-4; m, p and q are each an integer of ≥0; and n is an integer of ≥1). COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题：提供具有芴骨架的新的含杂环化合物，并且可用作耐热性等优异的树脂的原料等。解决方案：含杂环化合物由式（1）表示（其中环Ar为芳族烃环;环Het为杂环; R 1为氰基等; R 2 和R 3 分别为烃类等; A SP SP 1为亚烷基; A 2 为直接键或脂族烃; X为反应性基团，其衍生物或其前体; k为0-4的整数; m，p和q各自为≥0的整数; n为≥1的整数）。版权所有（C）2011，JPO＆INPIT

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