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    • 1. 发明专利
    • Urethane (meth)acrylate having fluorene skeleton, and its cured material
    • 具有氟橡胶的URETHANE(METH)丙烯酸酯及其固化材料
    • JP2013108091A
    • 2013-06-06
    • JP2013029659
    • 2013-02-19
    • Osaka Gas Co Ltd大阪瓦斯株式会社
    • MIYAUCHI SHINSUKEYAMADA MASAHIROMURASE HIROAKIKAWASAKI SHINICHISAMURA TETSUYAMORI RIEHANASAKA FUMIHIRO
    • C08G18/67C08F299/06
    • PROBLEM TO BE SOLVED: To provide a novel (meth)acrylate excellent in flexibility and simultaneously satisfying both properties such as high refractive index and high heat resistance, and excellent flexibility.SOLUTION: A urethane (meth)acrylate is obtained by using as reaction components: a diol having a fluorene skeleton (for example, 9,9-bis(hydroxyl(poly)Calkoxyphenyl)fluorene and 9,9-bis(mono or diCalkyl-hydroxy(poly)Calkoxyphenyl)fluorene), a specific polyisocyanate compound having a polyol skeleton and terminal isocyanate groups (for example, a urethane prepolymer made by reacting a diol compound such as an alkanediol or a polyetheric diol with a diisocyanate compound, and having isocyanate groups on both terminals), and a (meth)acrylic compound having a reactive group with the isocyanate group (for example, a hydroxyalkyl (meth)acrylate).
    • 要解决的问题:提供一种柔软性优异的新型(甲基)丙烯酸酯,同时满足高折射率,高耐热性等优异的柔软性。 解决方案:通过使用作为反应成分的聚氨酯(甲基)丙烯酸酯:具有芴骨架的二醇(例如,9,9-双(羟基(聚)C 烷氧基苯基)芴),具有多元醇骨架和末端异氰酸酯基团的特定多异氰酸酯化合物(例如,通过使二醇化合物如烷二醇或聚醚二醇与二异氰酸酯化合物反应制备的氨基甲酸酯预聚物, 两端的异氰酸酯基)和具有与异氰酸酯基具有反应性基团的(甲基)丙烯酸化合物(例如,(甲基)丙烯酸羟烷基酯)。 版权所有(C)2013,JPO&INPIT
    • 2. 发明专利
    • Urethane (meth)acrylate having fluorene skeleton and its cured product
    • 具有荧光素的URETHANE(METH)丙烯酸酯及其固化产品
    • JP2008285647A
    • 2008-11-27
    • JP2007321007
    • 2007-12-12
    • Osaka Gas Co Ltd大阪瓦斯株式会社
    • MIYAUCHI SHINSUKEYAMADA MASAHIROMURASE HIROAKIKAWASAKI SHINICHISAMURA TETSUYAMORI RIEHANASAKA FUMIHIRO
    • C08G18/67C08F299/06C08G18/32
    • PROBLEM TO BE SOLVED: To provide a new urethane (meth)acrylate which is excellent in flexibility, and can combine characteristics such as high refractive index and high heat resistance, with the excellent flexibility. SOLUTION: The present invention relates to the urethane (meth)acrylate prepared by reacting a diol having a fluorene skeleton [for example, 9,9-bis(hydroxy(poly) 2-4C alkoxyphenyl)fluorene, 9,9-bis(mono or di 1-4C alkyl-hydroxy(poly) 2-4C alkoxyphenyl)fluorene] with a specific polyisocyanate compound having a polyol skeleton and terminal isocyanate groups (for example, a urethane prepolymer having isocyanate groups at both the terminals and prepared by reacting a diol compound such as an alkane diol or a polyether-based diol with a diisocyanate compound) and a (meth)acrylic compound having reactive groups with isocyanate groups [for example, a hydroxyalkyl (meth)acrylate] as reactive components. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供柔性优异的新型氨基甲酸酯(甲基)丙烯酸酯,并且可以组合具有高折射率和高耐热性的特性,具有优异的柔韧性。 解决方案:本发明涉及通过使具有芴骨架的二醇(例如9,9-双(羟基(聚)2-4C烷氧基苯基)芴,9,9-双 (单或二1-4C烷基 - 羟基(聚)2-4C烷氧基苯基)芴]与具有多元醇骨架和末端异氰酸酯基团的特定多异氰酸酯化合物(例如,具有两端具有异氰酸酯基团的氨基甲酸酯预聚物 通过使二醇化合物如烷二醇或聚醚二醇与二异氰酸酯化合物反应)和具有异氰酸酯基的反应性基团的(甲基)丙烯酸化合物[例如,(甲基)丙烯酸羟烷基酯]作为反应性组分。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Flame retardant composition and polycarbonate resin composition
    • 阻燃组合物和聚碳酸酯树脂组合物
    • JP2013159665A
    • 2013-08-19
    • JP2012021131
    • 2012-02-02
    • Osaka Gas Co Ltd大阪瓦斯株式会社
    • SHINTAKU HIDEKITAKEMOTO TETSUYAHANASAKA FUMIHIROWAKABAYASHI KANJIMORI RIE
    • C09K21/12C08K5/5333C08L69/00
    • PROBLEM TO BE SOLVED: To provide a flame retardant excellent in flame retardancy.SOLUTION: A flame retardant composition includes an organophosphorous compound (I) having a cyclic polycarbonate structure. In compound (I), k is an integer greater than or equal to 0; m is an integer greater than or equal to 1; n1 is an integer greater than or equal to 1; n2 is an integer greater than or equal to 1; Ra represents, for example, a divalent group selected from arylene groups, or a trivalent group or groups of more valency having a substituent part further onto the divalent group, wherein the arylene group may include a hetero atom or an atomic group containing the hetero atom; and Rb represents a saturated or unsaturated alkyl group, a cycloalkyl group, an aryl group, wherein a methylene group of the alkyl group may be substituted with a hetero atom, wherein the aryl group may include a hetero atom or an atomic group containing the hetero atom, and wherein the plurality of Rbs may be the same or different from each other, when the plurality of Rbs exists.
    • 要解决的问题:提供阻燃性优异的阻燃剂。解决方案:阻燃组合物包括具有环状聚碳酸酯结构的有机亚磷化合物(I)。 在化合物(I)中,k为大于或等于0的整数; m是大于或等于1的整数; n1是大于等于1的整数; n2是大于或等于1的整数; Ra表示例如选自亚芳基的二价基团或具有取代基部分的更多价的三价基团或更多价的基团,其中亚芳基可以包括杂原子或含有杂原子的原子团 ; Rb表示饱和或不饱和的烷基,环烷基,芳基,其中烷基的亚甲基可以被杂原子取代,其中芳基可以包括杂原子或含杂原子的原子团 原子,并且其中当所述多个Rbs存在时,所述多个Rbs可以彼此相同或不同。