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1. 发明专利

JP2014218659A 強度向上剤有权
标题翻译：强度增强
公开(公告)号：JP2014218659A
公开(公告)日：2014-11-20
申请号：JP2014080414
申请日：2014-04-09
申请人：大阪瓦斯株式会社 , Osaka Gas Co Ltd
发明人： YAMADA MASAHIRO , MIYAUCHI SHINSUKE , SAKAMOTO HIROKI , KAWASAKI SHINICHI , SOJO DAISAKU
IPC分类号： C08L101/00 , C07C39/17 , C07C43/23 , C08K5/00 , C08L45/00 , C08L67/03 , C08L69/00
CPC分类号： C07C39/17 , C07C43/23 , C08K5/00 , C08L45/00 , C08L67/03 , C08L69/00
摘要：【課題】樹脂の機械的強度を向上(又は上昇又は改善)できる添加剤を提供する。【解決手段】添加剤として、下記式(1)で表される9,9−ビスアリールフルオレン骨格を有する化合物を樹脂に添加し、機械的強度を向上させる。[式中、環Zは芳香族炭化水素環、R1およびR2は置換基、Xは、基−[(OR3)n−Y](式中、Yは、ヒドロキシル基、メルカプト基、グリシジルオキシ基又は(メタ)アクリロイルオキシ基、R3はアルキレン基、nは0以上の整数を示す。)又はアミノ基、kは0〜4の整数、mは0以上の整数、pは1以上の整数を示す。]【選択図】なし
摘要翻译：要解决的问题：提供能够增强（或增加或改善）树脂的机械强度的添加剂。溶解剂：作为添加剂，具有由式（1）表示的9,9-双芳基芴骨架的化合物）添加到树脂中以增强机械强度。 [式中，Z表示芳香族烃环，R R表示取代基，X表示 - [（OR）nY]（式中，Y表示羟基，巯基，缩水甘油基氧基或（甲基））丙烯酰氧基，R表示亚烷基，n表示0以上的整数）或氨基，k表示0〜4的整数，m表示0以上的整数，p表示1以上的整数，更多。]

2. 发明专利

JP2014028806A Alcohol having fluorene skeleton 审中-公开
标题翻译： ALCOHOL有FLUENENE SKELETON
公开(公告)号：JP2014028806A
公开(公告)日：2014-02-13
申请号：JP2013155889
申请日：2013-07-26
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： OSAWA SHINGO , MIYAUCHI SHINSUKE , NAGASHIMA TAICHI , KAWASAKI SHINICHI , MURASE HIROAKI
IPC分类号： C07C41/16 , C07C43/23
摘要： PROBLEM TO BE SOLVED: To provide a novel alcohol having a fluorene skeleton, which can satisfy both improvement in heat resistance and reduction in melt viscosity, reduce a flexural modulus at high temperature and maintain optical transparency even after curing, and which has excellent handleability despite the presence of a 9,9-bis(condensed polycyclic aryl)fluorene skeleton (a 9,9-bis(naphthyl)fluorene skeleton and the like).SOLUTION: The alcohol is a compound represented by the following formula. (Ring Z represents a condensed polycyclic aromatic hydrocarbon ring; Rrepresents a substituent such as an alkyl group; Rrepresents an alkylene group; Rrepresents a substituent such as a hydrocarbon group and an alkoxy group).
摘要翻译：要解决的问题：为了提供具有芴骨架的新型醇，能够同时满足耐热性的提高和熔融粘度的降低，即使在固化后也能够降低高温下的弯曲弹性模量，并且即使在固化后也具有优异的操作性 9,9-双（缩合多环芳基）芴骨架（9,9-双（萘基）芴骨架等）的存在。溶液：醇是下式表示的化合物。（环Z表示稠合多环芳烃环; R表示取代基，例如烷基; R表示亚烷基; R表示取代基，例如烃基和烷氧基）。

3. 发明专利

JP2013139588A Thermosetting resin composition and cured product thereof 有权
标题翻译：热固性树脂组合物及其固化产品
公开(公告)号：JP2013139588A
公开(公告)日：2013-07-18
申请号：JP2013091013
申请日：2013-04-24
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MURASE HIROAKI , MIYAUCHI SHINSUKE , YAMADA MASAHIRO
IPC分类号： C08G59/24 , C08G8/04
摘要： PROBLEM TO BE SOLVED: To obtain a thermosetting resin composition excellent in heat resistance and etching resistance.SOLUTION: There is disclosed a thermosetting resin composition composed of a phenol resin having phenol components consisting of fluorenes having a phenolic hydroxy group and phenols, and having ≥2,000 weight-average molecular weight and an epoxy compound having a fluorene backbone. The phenol resin may be a condensate obtained by condensing the methylol form of the fluorenes having the phenolic hydroxy group with the phenols in the presence of an acid catalyst. In the epoxy compound having the fluorene backbone, 9,9-bis(glycidyloxyphenyl)fluorene, 9,9-bis(mono- or di-Calkylglycidyloxyphenyl)fluorene, 9,9-bis(glycidyloxynaphthyl)fluorene, and their adducts with a Calkyleneoxide, etc., are included.
摘要翻译：要解决的问题：获得耐热性和耐蚀刻性优异的热固性树脂组合物。解决方案：公开了一种热固性树脂组合物，其由具有酚羟基的芴和苯酚的苯酚组分的酚醛树脂组成，并且具有≥ 2,000重均分子量和具有芴骨架的环氧化合物。酚醛树脂可以是在酸催化剂的存在下将具有酚羟基的芴的羟甲基形式与苯酚缩合得到的缩合物。在具有芴骨架的环氧化合物中，9,9-双（缩水甘油氧基苯基）芴，9,9-双（单 - 或二 - 烷基缩水甘油氧基苯基）芴，9,9-双（缩水甘油氧基萘基）芴及其与环氧烷烃等等。

4. 发明专利

JP2013136767A Urethane (meth)acrylate having fluorene skeleton, and cured material thereof 有权
标题翻译：具有氟橡胶的URETHANE（METH）丙烯酸酯及其固化材料
公开(公告)号：JP2013136767A
公开(公告)日：2013-07-11
申请号：JP2013029658
申请日：2013-02-19
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , YAMADA MASAHIRO , MURASE HIROAKI , KAWASAKI SHINICHI , SAMURA TETSUYA , MORI RIE , HANASAKA FUMIHIRO
IPC分类号： C08G18/67 , C08F299/06
CPC分类号： G11B7/245
摘要： PROBLEM TO BE SOLVED: To provide a novel urethane (meth)acrylate having a fluorene skeleton excellent in heat resistance and the like.SOLUTION: The urethane (meth)acrylate is obtained using as reaction components a compound having a specific fluorene skeleton [for example, 9,9-bis(mono- or di-Calkyl-hydroxy(poly)Calkoxyphenyl)fluorene, 9,9-bis(mono- or di-Caryl-hydroxy(poly)Calkoxyphenyl)fluorene, 9,9-bis(hydroxyl(poly)Calkoxynaphthyl)fluorene, and the like], a polyisocyanate compound, an a (meth)acrylic compound having a reactive group with an isocyanate group (for example, a hydroxyalkyl (meth)acrylate and the like).
摘要翻译：要解决的问题：提供具有耐热性等优异的芴骨架的新型氨基甲酸酯（甲基）丙烯酸酯。溶液：使用具有特定芴骨架的化合物作为反应成分得到氨基甲酸酯（甲基）丙烯酸酯[例如，9,9-双（单 - 或二-C烷基 - 羟基（聚）Calkoxyphenyl）芴，9,9-双（单或二 - 羧基 - 羟基（聚）Calkoxyphenyl）芴，9,9-双（聚）烷氧基萘基）芴等]，多异氰酸酯化合物，具有异氰酸酯基的反应性基团的（甲基）丙烯酸化合物（例如（甲基）丙烯酸羟烷基酯等）。

5. 发明专利

JP2013032547A Novel dibenzofluorene compound 有权
标题翻译：新型二苯并呋喃化合物
公开(公告)号：JP2013032547A
公开(公告)日：2013-02-14
申请号：JP2012245996
申请日：2012-11-08
申请人： Tokyo Institute Of Technology , 国立大学法人東京工業大学 , Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： TAKADA TOSHIKAZU , SEESUKPHRONRARAK SURASAK , MIYAUCHI SHINSUKE , YAMADA MASAHIRO , KAWASAKI SHINICHI
IPC分类号： C08G63/197 , C07C37/20 , C07C39/17 , C08G65/40
摘要： PROBLEM TO BE SOLVED: To provide a compound excellent in heat resistance and the like, and useful as a resin raw material and the like.SOLUTION: The compound is constituted of a novel dbenzofluorene compound (for example, 9,9-bis(hydroxyphenyl)-2,3:6,7-dibenzofluorene and the like ) represented by formula (1) (wherein ring Z is an aromatic hydrocarbon ring; E is oxygen or sulfur; R, Rand Rare identical or different substituents; Ris an alkylene group; k is an integer of 0 to 2; l is an integer of 0 to 3; m is an integer of ≥0; and n is an integer of ≥0).
摘要翻译：要解决的问题：提供耐热性优异的化合物，并且可用作树脂原料等。解决方案：该化合物由式（1）表示的新型d苯并芴化合物（例如9,9-双（羟基苯基）-2,3：6,7-二苯并芴等）（其中环Z 是芳香烃环; E是氧或硫; R 1 ，R 2 和R 3 是相同或不同的取代基; R“是一个亚烷基; k是0-2的整数; l是0-3的整数; m 是≥0的整数，n是≥0的整数）。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2011042596A New heterocycle-containing compound having fluorene skeleton and method for producing the same 有权
标题翻译：具有荧光素的新的含有异氰酸酯的化合物及其生产方法
公开(公告)号：JP2011042596A
公开(公告)日：2011-03-03
申请号：JP2009190444
申请日：2009-08-19
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , MIYAUCHI SHINSUKE , NAGASHIMA TAICHI , MURASE HIROAKI , KAWASAKI SHINICHI , SHIBAHARA TETSUYA , KITAJIMA SATSUKI , HANASAKA FUMIHIRO , SATO MASAHIRO
IPC分类号： C07D213/73 , C07D213/80 , C07D307/68 , C07D333/40
摘要： PROBLEM TO BE SOLVED: To provide a new heterocycle-containing compound having a fluorene skeleton and usable as a raw material or the like for a resin excelling in heat resistance or the like. SOLUTION: The heterocycle-containing compound is represented by formula (1) (wherein, ring Ar is an aromatic hydrocarbon ring; ring Het is a heterocycle; R 1 is cyano or the like; R 2 and R 3 are each hydrocarbon or the like; A 1 is alkylene; A 2 is a direct bond or aliphatic hydrocarbon; X is a reactive group, a derivative thereof or a precursor thereof; k is an integer of 0-4; m, p and q are each an integer of ≥0; and n is an integer of ≥1). COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题：提供具有芴骨架的新的含杂环化合物，并且可用作耐热性等优异的树脂的原料等。解决方案：含杂环化合物由式（1）表示（其中环Ar为芳族烃环;环Het为杂环; R 1为氰基等; R 2 和R 3 分别为烃类等; A SP SP 1为亚烷基; A 2 为直接键或脂族烃; X为反应性基团，其衍生物或其前体; k为0-4的整数; m，p和q各自为≥0的整数; n为≥1的整数）。版权所有（C）2011，JPO＆INPIT

7. 发明专利

JP2010235869A Polymer having diketopyrrolopyrrole skeleton and white light emitting material 有权
标题翻译：具有二氯硅烷基硅酮和白光发光材料的聚合物
公开(公告)号：JP2010235869A
公开(公告)日：2010-10-21
申请号：JP2009087571
申请日：2009-03-31
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , MIYAUCHI SHINSUKE , KAWASAKI SHINICHI , SHIBAYAMA KATSUHIRO , HIGUCHI SHOJI , NAKAYA TADAO , MURASE HIROAKI , YAMADA MITSUAKI
IPC分类号： C08G61/12 , C09K11/06
摘要： PROBLEM TO BE SOLVED: To provide a new polymer suitable as a light emitting material, especially as a white light emitting material, and to provide a polymer for a light emitting material. SOLUTION: The polymer includes a unit represented by the formula (1), wherein a ring Z 1 is an aromatic hydrocarbon ring or a condensed polycyclic aromatic heterocycle, and a ring Z 2 is a condensed polycyclic aromatic hydrocarbon ring. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供适合作为发光材料的新型聚合物，特别是作为白色发光材料，并提供用于发光材料的聚合物。解决方案：聚合物包括由式（1）表示的单元，其中环Z 1是芳族烃环或稠合多环芳族杂环，并且环Z 2 是稠合多环芳烃环。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2009155251A Alcohol having fluorene skeleton 审中-公开
标题翻译： ALCOHOL有FLUENENE SKELETON
公开(公告)号：JP2009155251A
公开(公告)日：2009-07-16
申请号：JP2007334280
申请日：2007-12-26
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： OSAWA SHINGO , MIYAUCHI SHINSUKE , NAGASHIMA TAICHI , KAWASAKI SHINICHI , MURASE HIROAKI
IPC分类号： C07C43/23 , C08G63/193
摘要： PROBLEM TO BE SOLVED: To provide a new fluorene skeleton-containing alcohol imparting an excellent handling property even having the fluorene skeleton. SOLUTION: This alcohol is expressed by formula (1) [wherein, R 1 is cyano, a halogen atom or an alkyl; R 2 is a branched alkylene such as a propylene group or the like; R 3 is an alkyl such as methyl (especially a 1-4C alkyl); (k) is an integer of 0 to 4; (m) is an integer of ≥1; and (n) is an integer of 2 to 4]. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供即使具有芴骨架也具有优异的处理性能的新的含芴骨架醇。解决方案：该醇由式（1）表示[其中R 1为氰基，卤素原子或烷基; R SP2是支链亚烷基，例如丙烯基等; R 3是烷基，例如甲基（特别是1-4C烷基）; （k）为0〜4的整数，（m）为≥1的整数; 和（n）为2〜4的整数]。版权所有（C）2009，JPO＆INPIT

9. 发明专利

JP2009079013A Monofunctional fluorene skeleton-containing (meth)acrylate and method for producing the same 有权
标题翻译：含有（甲基）丙烯酸酯的单功能荧光酮及其制造方法
公开(公告)号：JP2009079013A
公开(公告)日：2009-04-16
申请号：JP2007250542
申请日：2007-09-27
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , MIYAUCHI SHINSUKE , MURASE HIROAKI , NAGASHIMA TAICHI , KAWASAKI SHINICHI
IPC分类号： C07C69/54 , C07C67/02 , C08F20/10
摘要： PROBLEM TO BE SOLVED: To provide a monofunctional (meth)acrylate useful as a diluent or the like of a thermally curable or photo-curable (meth)acrylate-based resin. SOLUTION: The monofunctional (meth)acrylate is obtained by reacting a compound represented by the formula (wherein R 1 is a cyano group, a halogen atom or an alkyl group, R 3 is an alkylene group, R 4 is a direct bond, an alkylidene group or an alkylene group, R 5 is a substituent, k is an integer of 0-4, m is an integer not less than 0 and n is 0 or 1) with (meth)acrylic acid or a derivative thereof (such as a (meth)acrylic acid halide and (meth)acrylic acid anhydride). COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供可用作可热固化或光固化（甲基）丙烯酸酯类树脂的稀释剂等的单官能（甲基）丙烯酸酯。解决方案：单官能（甲基）丙烯酸酯通过使下式表示的化合物（其中R 1 为氰基，卤素原子或烷基，R 3 是亚烷基，R 4是直接键，亚烷基或亚烷基，R SP 5是取代基，k是0的整数 -4，m为不小于0且n为0或1的整数）与（甲基）丙烯酸或其衍生物（例如（甲基）丙烯酰卤和（甲基）丙烯酸酐）。版权所有（C）2009，JPO＆INPIT

10. 发明专利

JP2008255308A Phenoxy resin having fluorene backbone and method for producing the same 有权
标题翻译：具有荧光底板的苯酚树脂及其制造方法
公开(公告)号：JP2008255308A
公开(公告)日：2008-10-23
申请号：JP2007109766
申请日：2007-04-18
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , MURASE HIROAKI , YAMADA MASAHIRO , MOTOKAWA TAKUYA
IPC分类号： C08G65/40
摘要： PROBLEM TO BE SOLVED: To obtain a phenoxy resin having excellent heat resistance, electrical insulating properties and transparency.
SOLUTION: The method for producing a phenoxy resin comprises reacting a phenol (A) at least composed of a specific fluorene (A1) containing a phenolic hydroxy group such as a 9,9-bis(alkyl-hydroxyphenyl)fluorene (e.g. 9,9-bis(4-hydroxy-3-methylphenyl)fluorene, 9,9-bis(4-hydroxy-3,5-dimethylphenyl)fluorene etc.) with a difunctional epoxy compound (e.g. bisphenol type epoxy resin etc.). In the phenol (A), the ratio of the fluorene (A1) may be ≥80 mol% based on the total of the phenol (A).
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：获得耐热性，电绝缘性和透明性优异的苯氧基树脂。解决方案：苯氧基树脂的制备方法包括使至少由含有酚羟基的特定芴（A1）组成的酚（A）如9,9-双（烷基 - 羟基苯基）芴（例如 9,4-双（4-羟基-3-甲基苯基）芴，9,9-双（4-羟基-3,5-二甲基苯基）芴等）与双官能环氧化合物（如双酚型环氧树脂等）。在苯酚（A）中，芴（A1）的比例可以相对于苯酚（A）的总量为≥80摩尔％。版权所有（C）2009，JPO＆INPIT

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