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1. 发明专利

JPH07150106A COATING COMPOSITION 失效
公开(公告)号：JPH07150106A
公开(公告)日：1995-06-13
申请号：JP29677293
申请日：1993-11-26
申请人： NIPPON SYNTHETIC CHEM IND , MITSUBISHI CHEM CORP
发明人： YAMAOKA HIROAKI , CHOKAI TAKASHI , OTA TAKAYUKI
IPC分类号： C09D133/14 , C09D133/04 , C09D163/00 , C09D183/04
摘要： PURPOSE:To obtain a coating composition excellent in scratch resistance, adhesion, storage stability, etc. CONSTITUTION:This composition comprises 5-85wt.%, based on the resin component, silicate oligomer represented by the formula (wherein n is an integer of 1-20; and R is 1-4 C alkyl or phenyl), 15-95 pts.wt., based on the resin component, acrylic copolymer comprising an epoxy (meth)acrylate and (meth)acrylic acid and 10-400 pts.wt., per 100 pts.wt. resin component, organic solvent.

2. 发明专利

JPH11158028A COSMETIC 失效
公开(公告)号：JPH11158028A
公开(公告)日：1999-06-15
申请号：JP32645097
申请日：1997-11-27
申请人： MITSUBISHI CHEM CORP , KOSE CORP
发明人： SANO SHIHO , YAMAOKA HIROAKI , ITO TAKESHI , KINOSHITA TAKAYO , ISHIDA KAZUHIRO , MOMOSE SHIGESADA
IPC分类号： A61K8/72 , A61K8/00 , A61K8/18 , A61K8/81 , A61K8/85 , A61Q1/00 , A61Q1/02 , A61Q1/04 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q3/02 , A61K7/00 , A61K7/02
摘要： PROBLEM TO BE SOLVED: To obtain a cosmetic with a water and oil repellency, excellent in adherence to skin, pigment dispersibility, cosmetic persistency, usability or the like, by including a copolymer having specific 2 kinds of repeating units in a specific proportion. SOLUTION: This cosmetic is obtained by including 0.01 to 90 wt.% of copolymer comprising (A) a repeating unit of formula I [R is an 1-20C alkyl or aralkyl; R is an aliphatic hydrocarbon; R is shown by formula II to IV (R is H, an 1-20C alkyl or halogen; (m) is 1 to 4; (l) is 1 to 10; -CONH- adjoins -O- of -CO-R -O- in formula I to thereby form an urethane bond) or the like; R is H or a methyl; and (n) is 3 to 200] and (B) a repeating unit of formula V (R is H or a methyl; and X is a 4-20C fluoro substituted alkyl group- containing group) in the weight ratio of (10 to 90) to (90 to 10), and, if necessary, by including an oil component such as a hydrocarbon, higher fatty acid ester, animal or plant oil, silicone oil or the like, a powder component such as an organic pigment, inorganic pigment or the like, an aqueous component, a perfume or the like.

3. 发明专利

JPH09235360A MULCHING FILM FOR AGRICULTURE 失效
公开(公告)号：JPH09235360A
公开(公告)日：1997-09-09
申请号：JP4326196
申请日：1996-02-29
申请人： MITSUBISHI CHEM MKV CO , MITSUBISHI CHEM CORP , MITSUBISHI KAGAKU FOODS KK
发明人： TASHIRO TAKESHI , YASUI MITSUO , OYAMA KANAKO , YAMAOKA HIROAKI , MIYAZAKI KEIKO , SUGIMOTO NOBUNARI
IPC分类号： A01G13/00 , C08G63/60 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To obtain the subject film having a specific film thickness, comprising a specified aliphatic copolyester, capable of being easily produced by a general plastic molding method, excellent in thermal stability, tensile strength and biodegradability, and mild for environments. SOLUTION: This mulching film has a thickness of 0.01-0.1mm and comprises an aliphatic copolyester having a number-average mol.wt. of 10000-200000 and comprising (A) 0.02-30mol.% of a unit of the formula: 0-R -CO (R is a divalent aliphatic hydrocarbon group), such as the unit of the formula [(a) is 0-10] (e.g. lactic acid unit, glycolic acid unit), (B) 35-49,99mol.% of a unit of the formula: 0-R -0 R is R such as a group of the formula: (CH2 )n [(n) is 2-10], a divalent aliphatic hydrocarbon group(e.g. the group having three to ten carbon atoms) and (C) 35-49.99mol.% of a unit of the formula: OC-R -CO R is R such as a group of the formula: (CH2 )m [(m) is 0-10], a single bond}, e.g. succinic acid units.

4. 发明专利

JPH08192097A HARD COAT 失效
公开(公告)号：JPH08192097A
公开(公告)日：1996-07-30
申请号：JP508595
申请日：1995-01-17
申请人： MITSUBISHI CHEM CORP
发明人： YAMAOKA HIROAKI , TAKANO SHOJI
IPC分类号： B05D1/36 , B05D7/24 , C08G77/06 , C08G77/14 , C09D5/00 , C09D133/04 , C09D133/06 , C09D133/14 , C09D183/04 , C09D183/06
摘要： PURPOSE: To obtain a hard coat excellent in scuffing and wear resistances, transparency, heat and weather resistances and adhesion. CONSTITUTION: A methacrylate compsn. having a specified compsn. is used as a primer and a hydrolyzate of a cornpsn. contg. a silicate oligomer and alkoxysilane in a weight ratio of 1:1 to 20:1 is used as an overcoat to obtain the objective hard coat excellent in scuffing and wear resistances, transparency, heat and weather resistances and adhesion.

5. 发明专利

JPH07232413A VINYL CHLORIDE RESIN LAMINATED PRODUCT 失效
公开(公告)号：JPH07232413A
公开(公告)日：1995-09-05
申请号：JP2829994
申请日：1994-02-25
申请人： MITSUBISHI CHEM MKV CO , MITSUBISHI CHEM CORP
发明人： SEKI HIROSHI , IWASAKI KENJI , YAMAOKA HIROAKI , SANO SHIHO
IPC分类号： B32B27/08 , B32B27/18 , B32B27/30
摘要： PURPOSE:To obtain excellent weatherability and antistaining properties by forming an acrylic resin layer with specific thickness compounded with a specific polymeric ultraviolet absorber consisting of specific repeating units and a fluoroplastic layer on the single surface of a vinyl chloride resin molded product. CONSTITUTION:An acrylic resin layer with a thickness of 1-10mum compounded with a polymeric ultraviolet absorber being a copolymer with intrinsic viscosity of 0.02 or more consisting of a repeating unit represented by formula I [wherein R is a 1-20C alkyl group or an aralkyl group, R is an aliphatic hydrocarbon group and R is a group represented by formula III (wherein R is a 1-20C alkyl group, a hydrogen atom or a halogen atom, m is an integer of 1-4 and p is an integer of 1-10) or -CO- and adjacent to -O- of a group represented by formula IV (wherein R is a hydrogen atom or a methyl group and n is 2-200) to form urethane)] and a repeating unit represented by formula II (wherein R is a hydrogen atom or a methyl group and X is a compd. residue having the max. peak within a wavelength range of 300-400nm) in a wt. ratio of 10:90-90:10 and a fluoroplastic layer are formed on a vinyl chloride resin molded product.

6. 发明专利

JP2003206338A FILM COMPRISING ALIPHATIC POLYESTER COPOLYMER 审中-公开
公开(公告)号：JP2003206338A
公开(公告)日：2003-07-22
申请号：JP2002374758
申请日：2002-12-25
申请人： MITSUBISHI CHEM CORP
发明人： MIYAZAKI KEIKO , NOGUCHI HIROSHI , KASAI ATSUSHI , OTA TAKAYUKI , YAMAOKA HIROAKI
IPC分类号： C08J5/18 , C08G63/60 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a film comprising an aliphatic polyester which has biodegradability, and is excellent in a heat stability, tensile strengths, and the like. SOLUTION: The film comprises an aliphatic polyester copolymer comprising 0.02-30 mol% of an aliphatic oxycarboxylic acid unit represented by the formula (I): -O-R 1 -CO- (wherein R 1 is a divalent aliphatic hydrocarbon group), 35-49.99 mol% of an aliphatic or an alicyclic diol unit represented by the formula (II): -O-R 2 -O (wherein R 2 is a divalent aliphatic hydrocarbon group or a divalent alicyclic hydrocarbon group), and 35-49.99 mol% of an aliphatic dicarboxylic and unit represented by the formula (III): -OC-R 3 -CO- (wherein R 3 is a direct bond or a divalent aliphatic hydrocarbon group), the copolymer has a number- average molecular weight of 10,000-200,000. COPYRIGHT: (C)2003,JPO

7. 发明专利

JPH111420A COSMETIC 失效
公开(公告)号：JPH111420A
公开(公告)日：1999-01-06
申请号：JP16663697
申请日：1997-06-09
申请人： SHISEIDO CO LTD , MITSUBISHI CHEM CORP
发明人： UMISHIO KENICHI , FUKUI HIROSHI , ONO KAZUHISA , AOYAMA MASATO , TANAKA TOSHIYUKI , YAMAOKA HIROAKI
IPC分类号： A61K8/72 , A61K8/00 , A61K8/89 , A61Q1/00 , A61Q1/04 , A61Q1/06 , A61Q1/12 , A61Q3/02 , A61Q5/00 , A61Q17/04 , C08L83/06 , C08L83/08 , A61K7/42 , A61K7/00 , A61K7/027 , A61K7/035 , A61K7/043 , A61K7/06
摘要： PROBLEM TO BE SOLVED: To obtain a cosmetic excellent in durability of makeup, capable of continuing inhibitory effects on ultraviolet rays, having improved touch. SOLUTION: This cosmetic comprises a polysiloxane-based copolymer containing a benzophenone group or a benzotriazole group having 2,000-2,000,000 number-average molecular weight obtained by copolymerizing a polysiloxane- containing vinyl-based monomer (A) of formula I: CH2 =CR -X-(Si(R )2 O)n -Si(R )2 (in the formula, R is a hydrogen atom or a methyl group; R and R are each a 1-3C alkyl or a phenyl group and may be the same or different; (n) is an integer of 6-100; X is a phenylene group of a carbonyl oxyalkylene group of the formula COOCm H2m ((m) is an integer of 1-5), etc.) with an ultraviolet ray absorbing group-containing vinyl-based monomer (B) of formula II: CH2 CR -Y (in the formula, R is a hydrogen atom or a methyl group; Y is a benzophenone group or a benzotriazole group) in the ratio of the components A to B in the range of 10:90 to 90:10.

8. 发明专利

JPH09281746A ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER 失效
公开(公告)号：JPH09281746A
公开(公告)日：1997-10-31
申请号：JP9092796
申请日：1996-04-12
申请人： MITSUBISHI CHEM CORP
发明人： MIYAZAKI KEIKO , YANAGIHORI AKIHIKO , TAKAHASHI NORIAKI , YAMAOKA HIROAKI
IPC分类号： G03G9/08 , C08L101/16 , G03G9/087
摘要： PROBLEM TO BE SOLVED: To obtain a toner having excellent fixing property and blocking resistance by incorporating a coloring agent and a urethane polyester resin prepared by crosslinking polylactic acid with polyvalent isocyanate having specified or more functional groups. SOLUTION: This electrostatic charge image developing toner contains a coloring agent and a urethane polyester resin prepared by crosslinking polylactic acid with a polyvalent isocyanate having three or more functional groups. The toner to be used contains a urethane polyester resin obtd. by the reaction of polyvalent isocyanate having three or more functional groups with polylactic acid obtd. by dehydration condensation or open-ring reaction, preferably polylactic acid obtd. by dehydration condensation. As for lactic acid used, L- lactic acid, D-lactic acid, DL-lactic acid or a mixture of D-lactic acid and L- lactic acid can be used without no limitation. However, a polylactic acid having no melting point is preferably used because if a polylactic acid obtd. has a melting point, the fixing property of a toner decreases.

9. 发明专利

JPH09233956A EXPANSION FILM FOR AGRICULTURE 失效
公开(公告)号：JPH09233956A
公开(公告)日：1997-09-09
申请号：JP4326296
申请日：1996-02-29
申请人： MITSUBISHI CHEM MKV CO , MITSUBISHI CHEM CORP
发明人： TASHIRO TAKESHI , YASUI MITSUO , OYAMA KANAKO , YAMAOKA HIROAKI , MIYAZAKI KEIKO
IPC分类号： A01G13/02 , A01G9/14 , C08G63/60 , C08J5/18 , C08L67/00 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide an expansion for agriculture, which improves weather resistance, tensile strength, biodegradability and environment maintainability and effective for house, etc., containing a specified aliphatic polyester copolymer, ultraviolet absorber and plasticizer in specified ratio and having thickness within a specified prescribed range. SOLUTION: Concerning an aliphatic polyester copolymer of 100 pts.wt., it is composed of an aliphatic hydroxycarboxylic acid such as lactic acid of 0.02-30 mole % in expression I (R is a divalent aliphatic hydrocarbon), aliphatic or alicyclic diol units such as ethylene glycol of 35-49.99 mole % in expression II (R is R or a divalent alicyclic hydrocarbon) and aliphatic dicarboxylic acid units such as oxalic acid of 35-49.99 mole % in expression III (R is a direct bond or R ), and has number-average molecular weight of 10,000 to 200,000. Concerning this film, an ultraviolet absorber such as benzophenone or benzotriasole ultraviolet absorber (B) of 0.005-5 pts.wt., and a plasticizer such as glycerin triacetate (C) of 0-50 pts.wt., are mixed with the aliphatic polyester copolymer (A) of 100 pts.wt., and its thickness is 0.05-0.3mm.

10. 发明专利

JPH09227666A POLYESTER FILM 失效
公开(公告)号：JPH09227666A
公开(公告)日：1997-09-02
申请号：JP3221296
申请日：1996-02-20
申请人： MITSUBISHI CHEM CORP
发明人： MIYAZAKI KEIKO , SAKAI AKIHIKO , KOJIMA MEGUMI , YAMAOKA HIROAKI , KASAI ATSUSHI , NAKANO TOMOMI
IPC分类号： C08J5/18 , B29C55/02 , B29K67/00 , B29L7/00 , C08G63/60
摘要： PROBLEM TO BE SOLVED: To prepare a polyester film excellent in heat stability, tensile strength, etc., by molding an aliphatic polyester copolymer comprising specified aliphatic hydroxycarboxylic acid units, specified diol units, and specified aliphatic dicarboxylic acid units. SOLUTION: This film is prepared by molding an aliphatic polyester copolymer comprising 0.02-30mol% aliphatic hydroxycarboxylic acid units represented by formula I (wherein R1 is a 1-10C aliphatic hydrocarbon group), 35-49.99mol% aliphatic diol units represented by formula II (wherein R2 is a divalent hydrocarbon group) and 35-49.99mol% aliphatic dicarboxylic acid units represented by formula III (wherein R3 is a direct bond or a divalent aliphatic hydrocarbon group) and having a number - average molecular weight of 10,000-2000,000. It has a molecular weight high enough for practical use, can be formed into desired moldings by general-purpose plastic formation processes, and has excellent properties (e.g. heat stability and tensile strength).

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